Insights into the Origins of Solar-Assisted Electrochemical Water Oxidation in Allotropic Co_(5.47)N/CON Heterojunctions

Solar irradiation can efficiently promote the kinetics of the oxygen evolution reaction(OER)during water splitting,where heterojunction catalysts exhibit excellent photoresponsive properties.However,insights into the origins of photoassisted OER catalysis remain unclear,especially the interfaced promotion under convergent solar irradiation(CSI).Herein,novel allotropic Co_(5.47)N/CoN heterojunctions were synthesized,and corresponding OER mechanisms under CSI were comprehensively uncovered from physical and chemical aspects using the in situ Raman technique and electrochemical cyclic voltammetry method.Our results provide a unique mechanism where high-energy UV light promotes the Co^(3+/4+)conversion process in addition to the ordinary photoelectric effect excitation of the Co^(2+)material.Importantly,visible light under CSI can produce a photothermal effect for Co^(2+)excitation and Co^(3+/4+)conversion,which promotes the OER significantly more than the usual photoelectric effect.As a result,Co_(5.47)N/CoN(containing 28%CoN)obtained 317.9%OER enhancement,which provides a pathway for constructing excellent OER catalysts.

Origin of Overpressure and its Effect on Hydrocarbon Enrichment in the Hinterland of Junggar Basin,NW China

Overpressure is widely developed in deep petroliferous strata in the hinterland of the Junggar Basin.However,a comprehensive understanding of its origin and effect on hydrocarbon distribution and enrichment remains lacking.In this study,we employ five empirical methods and comprehensive geological analysis to identify the origin of overpressure,and uncover the effect of overpressure on hydrocarbon enrichment.The results indicate that disequilibrium compaction is not a significant factor in overpressure generation.Instead,hydrocarbon generation,pressure transfer and diagenesis are the primary causes.The empirical methods support this conclusion.There is a positive correlation between overpressure intensity and source rock thickness and maturity.Notably,widespread cross-formational migration of hydrocarbon bearing fluid occurred,with sandstone overpressure exceeding that of adjacent shale in non-source strata.Furthermore,there is a distinct transformation from smectite to illite near the top of overpressure.Hydrocarbon generation pressurization and pressure transfer significantly effect hydrocarbon enrichment.The overpressure caused by hydrocarbon generation drives hydrocarbon migration and accumulation,establishing an optimal energy configuration between reservoir and cap rock.Faults play a crucial role in hydrocarbon vertical migration and pressure relief.The overpressure in reservoirs can reduce the porosity and permeability thresholds and enhance the charging capacity of oil and gas.

Origin of the Dashuigou independent tellurium deposit at Qinghai–Xizang Plateau: constraints from the light stable isotopes C, O, and H

By studying the light isotopic compositions of carbon,oxygen,and hydrogen,combined with previous research results on the ore-forming source of the deposit,the authors try to uncover its metallogenic origin.The δ^(18)O and δ^(13)C isotope signatures of dolomite samples vary between 10.2 and 13.0‰,and between−7.2 and−5.2‰,respectively,implying that the carbon derives from the upper mantle.δD and δ^(18) O of quartz,biotite,and muscovite from diff erent ore veins of the deposit vary between−82 and−59‰,and between 11.6 and 12.4‰,respectively,implying that the metallogenic solutions are mainly magmatic.According to the relevant research results of many isotope geologists,the fractionation degree of hydrogen isotopes increases as the depth to the Earth’s core increases,and the more diff erentiated the hydrogen isotopes are,the lower their values will be.In other words,mantle-derived solutions can have extremely low hydrogen isotope values.This means that the δD‰ value−134 of the pyrrhotite sample numbered SD-34 in this article may indicate mantle-derived oreforming fl uid of the deposit.The formation of the Dashuigou tellurium deposit occurred between 91.71 and 80.19 Ma.

Research on the origin and evolution of technical management regulations for railway

Purpose–To facilitate technical managers and field workers to master and understand the provisions of Technical Management Regulations for Railway more accurately,so as to better serve the comprehensive revision of the Regulations,this paper carries out the research on the traceability and evolution of the provisions of the Regulations.Design/methodology/approach–This paper studies and analyzes the evolution of the 11th edition of the Regulations by analyzing the relevance of clauses and summarizes the historical background of the development of calendar editions of the Regulations.The basic research on the traceability and evolution of the Regulations is carried out from four aspects:the continuity of the development of the Regulations,the authority of contents,the relevance of clauses and the richness of historical materials.Findings–From the first edition of the Regulations issued by the former Ministry of Railways in 1950 to the 11th edition,there have been ten comprehensive revisions.There is a strong correlation and continuity between the calendar editions of the Regulations in terms of chapter structure and clauses.Studying the context of the terms of the Regulations is an important way to understand and master the current clauses of the Regulations.Originality/value–Through the research on the traceability and evolution of the clauses of the Regulations,one is to explore the context of the development of railway technical equipment in China,the other is to clarify the historical background when the provisions were formulated and the third is to trace the development and evolution of the provisions.The revision of the Regulations is based on an accurate grasp of the context of the provisions,which can effectively judge the possible security risks caused by the revision of the provisions and avoid the possible risks in field implementation from the source.

Gibbon vocal communication provides insights into the origin and evolution of human music and language

Humans across cultures convey feelings and thoughts through music.Despite its ubiquity,the origins and evolution of music remain enigmatic.Archaeological evidence has traced the history of music back at least 40000 years ago based on prehistoric bone flutes(Fitch,2006).Comparative studies have also explored earlier histories by identifying common musical features between animals and humans(Fitch,2006).For example,songbirds exhibit categorical rhythms similar to human music(Roeske et al.,2020),and humans can recognize emotional arousal in signals across all classes of terrestrial vertebrates(Filippi et al.,2017).These findings,while surprising,align with the longstanding human perception of animal signals as music(Gray et al.,2001).The universality of music and its features intensifies the fundamental question posed by Darwin(1871):how has a behavior that is energetically costly and seemingly non-adaptive evolved to become so widespread?This question can be further divided into two sub-questions(Savage et al.,2021):(1)how do musical features contribute to the production or expressive power of music(i.e.,mechanisms),and(2)how does music benefit performers in terms of survival,reproductions,or other aspects(i.e.,functions).

Unroofing Technique for Anomalous Origin of the Left Coronary Artery from the Right Sinus of Valsalva: Report of a Case

Anomalous origin of the left coronary artery (AOLCA) from the right sinus of Valsalva constitutes a rare congenital coronary artery anomaly. Patients with an anomalous left main coronary artery face a significantly higher risk of sudden cardiac death compared to those with an anomalous right coronary artery. The anomalous coronary artery traversing between the ascending aorta and the pulmonary artery markedly heightens the risk of myocardial ischemia, arrhythmia, and sudden death. Symptomatic patients often exhibit a longer intramural course of the coronary artery, which may necessitate earlier intervention or influence the choice of surgical repair method. Surgical intervention is advocated for patients with this anomaly, even in the absence of symptoms. For anomalous aortic origin of a coronary artery from the opposite sinus of Valsalva with an intramural course, coronary unroofing is the preferred revascularization procedure. This report presents a case of AOLCA originating from the right sinus of Valsalva, treated surgically using the unroofing technique for the aortic intramural segment of the anomalous coronary artery traversing between the great vessels. The unroofing technique is recommended for treating AOLCA with an extensive intramural course that does not involve the commissure.

Scientists Clarify the Origins of Lunar Metallic Iron

Metallic iron nanoparticles(npFe0)are widespread on the Moon,and their accumulation changes the optical spectra of the lunar surface over time.How the surface color changes largely depends on the size of npFe0:smaller npFe0 reddens the reflectance spectra,while larger npFe0 causes darkening.The resultant color variations greatly complicate remote sensing studies,posing long-term puzzles to astronomers.

Tracing the Origin and Migration of Humans-Significant Progress in Paleoanthropological and Paleolithic Fields Made by IVPP

Over the past 15 years,the Paleoanthropological and Paleolithic team from the Institute of Vertebrate Paleontology and Paleoanthropology(IVPP),Chinese Academy of Sciences,has made significant progress in understanding modern human origins and evolution through extensive fieldwork,fossil and artifact discoveries,and cutting-edge ancient molecular analysis.The new fossil findings from Hualongdong,Xuchang,the first report on Harbin,and the reevaluations of previously found fossils like Xujiayao revealed high population diversity in East Asia during the late Middle Pleistocene,implying multiple evolutionary lineages linked to modern humans,Neanderthals,or Denisovans.Different species names were proposed for these unique fossils.Discoveries from Zhiren Cave and Fuyan Cave refreshed our knowledge of modern human emergence in China,sparking debates between the“Recent African Origin”and“Multiregional Evolution”hypothesis.Additionally,new archaeological evidence from Nwya Devu and Xiamabei highlighted human adaptations to extreme climates and technological innovations.Genomic studies further revealed complex patterns of modern human dispersal,admixture,and adaptation in China,especially in the past 40,000 years.The first mitochondrial DNA of Denisovan outside Denisova Cave was successfully extracted from the sediments on the Plateau,suggesting the long-term occupation of this population in this area.

Textual Research on Name, Variety and Property of the Multi-origin Tibetan Herb "Azhong"

By consulting ancient Tibetan medical literature such as books of materia medica,medical works,and prescription books,as well as modern and contemporary literature and materials,and in combination with the interview and investigation of clinical use and expert consultation,we collated and verified the name,variety classification,plant origin,application and other recorded information of Tibetan herb"Azhong",and summarized and analyzed the phenomenon of mixed use or substitution of medicinal plants.According to textual research,it first appeared in the Four Medical Tantras.The Tibetan herb"Azhong"is simply recorded in the ancient books and Materia Medica,which are collectively called"Azhong".Since the 15 th century,there have been varieties such as Za Azhong,Kan Azhong,Xing Azhong,Pumou Azhong,Zha Azhong,Bang Azhong,and the top grade is called Azhong Nabu and Nacang Azhong,and the bottom grade is Azhong Gabu.According to modern literature,the origin of"Azhong"involves 12 species of plants belonging to 8 genera,5 families.At present,Arenaria kansuensis Maxim,Ajania purpurea Shih.and Thalictrum squamiferum Lecoy are the mainstream medicinal materials of"Azhong".There is a certain basis for clinical application and theoretical records in the literature in terms of the mutual alternative use of Tibetan medicinal materials such as"Azhong"and traditional medicinal materials in different regions.Therefore,it is necessary to use modern chemical technology and pharmacological experiments to conduct a comparative study on the material basis and biological activity of different varieties of medicinal materials,and carry out a survey on resources and use status,so as to standardize the use of their varieties and origins and improve the safety of clinical medication.

Analysis on the Origin and Phylogenetic Status of Tong Sheep Using 12 Blood Protein and Nonprotein Markers

This study is based on the Tong sheep obtained by the random sampling method of typical colonies in the central area of Baishui County in Shaanxi Province, China. An investigation was undertaken to clarify the gene constitution of blood protein and nonprotein types of Tong sheep. Twelve genetic markers were examined by starch-gel electrophoresis and cellulose acetate electrophoresis. Polymorphism in Tong sheep was found at the following 10 loci, transferrin （Tf）, alkaline phosphatase （Alp）, leucine aminopeptidase （Lap）, arylesterase （Ary-Es）, hemoglobin-β （Hb-β）, X-protein （X-p）, carbonic anhydrase （CA）, catalase （Cat）, malate dehydrogenase （MDH）, and lysine （Ly）, whereas, albumin （A1） and postalbumin （Po） loci were monomorphic. Genetic approach degree method and phylogenetic relationship clustering method were used to judge the origin and phylogenetic status of Tong sheep. Results from both methods maintained that Tong sheep belonged to the ＂Mongolia group＂, and Mongolia sheep was the origin of Tong sheep. This was also supported by the history of Tong sheep breeding. Compared to the phylogenetic relationship clustering method, the genetic approach degree method was more reliable for the extraction from East and South of Central Asia, and was more effective in reflecting the breeding course of Tong sheep.

Geochemistry and origins of hydrogen-containing natural gases in deep Songliao Basin,China:Insights from continental scientific drilling

The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen gas.The gas composition and stable isotope characteristics vary significantly,but the origin analysis of different gas types has previously been weak.Based on the geochemical parameters of gas samples from different depths and the analysis of geological settings,this research covers the diverse origins of natural gas in different strata.The gas components are mainly methane with a small amount of C_(2+),and non-hydrocarbon gases,including nitrogen(N_(2)),hydrogen(H_(2)),carbon dioxide(CO_(2)),and helium(He).At greater depth,the carbon isotope of methane becomes heavier,and the hydrogen isotope points to a lacustrine sedimentary environment.With increasing depth,the origins of N_(2)and CO_(2)change gradually from a mixture of organic and inorganic to inorganic.The origins of hydrogen gas are complex and include organic sources,water radiolysis,water-rock(Fe^(2+)-containing minerals)reactions,and mantle-derived.The shales of Denglouku and Shahezi Formations,as source rocks,provide the premise for generation and occurrence of organic gas.Furthermore,the deep faults and fluid activities in Basement Formation control the generation and migration of mantle-derived gas.The discovery of a high content of H_(2)in study area not only reveals the organic and inorganic association of natural-gas generation,but also provides a scientific basis for the exploration of deep hydrogen-rich gas.

Study on Origin and Cultural Connotation of Names in English-speaking Countries

The names in English-speaking countries are full of historical origin and cultural connotation. For the significance of family name and given name, this paper focus on the origin and culture connotation of family name and given name, and also the hidden influences of name played on human beings. Moreover, the relationship between development of society and English name will also be concerned because we can not ignore that the development of society has made great effects to English name.According to the whole essay, we can easily realize the origin and connotation of English name through all my researches and analyses.

On the Relationship between the Original and the Translated Version——The Interpretation of Benjamin's Three Metaphors

This paper explores the relationship between the original and its translation by interpreting Benjamin's three metaphors from his The Translator's Task. The exploration starts with the metaphor of"the tangent of a circle",where it is interpreted that although the translated version should be faithful to its original in terms of meaning,yet it is a deviation due to different internal and external factors. Then,in the metaphor of"afterlife",the discussion demonstrates that the translated version proceeds from the original,but the original depends on it for its survival and afterlife in different eras. Later,based on the metaphor of"fragments of a vessel",the author states that the original and its translation are equal and complementary,just like the fragments of a vessel,responsible for the development and renewal of each other through translation. Finally,it is concluded that a better understanding of their relationship can offer us a new perspective in translation studies and practice.

Genetic dissection and origin of pleiotropic loci underlying multilevel fiber quality traits in upland cotton(Gossypium hirsutum L.)

Cotton fiber quality is a persistent concern that determines planting benefits and the quality of finished textile products.However,the limitations of measurement instruments have hindered the accurate evaluation of some important fiber characteristics such as fiber maturity,fineness,and neps,which in turn has impeded the genetic improvement and industrial utilization of cotton fiber.Here,12 single fiber quality traits were measured using Advanced Fiber Information System(AFIS)equipment among 383 accessions of upland cotton(Gossypium hirsutum L.).In addition,eight conventional fiber quality traits were assessed by the High Volume Instrument(HVI)System.Genome-wide association study(GWAS),linkage disequilibrium(LD)block genotyping and functional identification were conducted sequentially to uncover the associated elite loci and candidate genes of fiber quality traits.As a result,the previously reported pleiotropic locus FL_D11 regulating fiber length-related traits was identified in this study.More importantly,three novel pleiotropic loci(FM_A03,FF_A05,and FN_A07)regulating fiber maturity,fineness and neps,respectively,were detected based on AFIS traits.Numerous highly promising candidate genes were screened out by integrating RNA-seq and qRT-PCR analyses,including the reported GhKRP6 for fiber length,the newly identified GhMAP8 for maturity and GhDFR for fineness.The origin and evolutionary analysis of pleiotropic loci indicated that the selection pressure on FL_D11,FM_A03 and FF_A05 increased as the breeding period approached the present and the origins of FM_A03 and FF_A05 were traced back to cotton landraces.These findings reveal the genetic basis underlying fiber quality and provide insight into the genetic improvement and textile utilization of fiber in G.hirsutum.

Xingxueanthus: An Enigmatic Jurassic Seed Plant and Its Implications for the Origin of Angiospermy

The origin of angiosperms has been tantalizing botanists for centuries. Despite the efforts of palaeobotanists, most of the pre-Cretaceous angiosperms are regarded either non-convincing or misdated. The applications of SEM and LM （light microscope） enable us to recognize a coalified fossil plant, Xingxueanthus sinensis gen. et sp. nov., from the Haifanggou Formation （Middle Jurassic, 〉160 Ma） in western Liaoning, China. Xingxueanthus is an ＂inflorescence＂ with more than 20 female units spirally arranged. Each female unit is situated in the axii of a bract. The female unit is composed of an ovule-container and a style-like projection at the top. There is a vertical column bearing several ovules in the ovule-container. The general morphology and the internal structure of Xingxueanthus distinguish itself from any known fossil and extant gymnosperms, and its structures are more comparable to those of angiosperms. Xingxueanthus, if taken as a gymnosperm, would represent a new class, demonstrate an evolutionarily advanced status of ovule-protection in gymnosperms never seen before, and provide new insights into the origin of angiospermy. Alternatively, if taken as an angiosperm, together with Schmeissneria, it would increase the diversity of Jurassic angiosperms, which has been underestimated for a long time, and suggest a much earlier origin of angiospermy than currently accepted.

Origin and phylogenetic analysis of Tibetan Mastiff based on the mitochondrial DNA sequence

At present, the Tibetan Mastiff is the oldest and most ferocious dog in the world. However, the origin of the Tibetan Mastiff and its phylogenetic relationship with other large breed dogs such as Saint Bernard are unclear. In this study, the primers were designed accord- ing to the mitochondrial genome sequence of the domestic dog, and the 2,525 bp mitochondrial sequence, containing the whole sequence of Cytochrome b, tRNA-Thr, tRNA-Pro, and control region of the Tibetan Mastiff, was obtained. Using grey wolves and coyotes as out- groups, the Tibetan Mastiff and 12 breeds of domestic dogs were analyzed in phylogenesis. Tibetan Mastiff, domestic dog breeds, and grey wolves were clustered into a group and coyotes were clustered in a group separately. This indicated that the Tibetan Mastiff and the other domestic dogs originated from the grey wolf, and the Tibetan Mastiff belonged to Carnivora, Canidae, Canis, Canis lupus, Canis lupus familiaris on the animal taxonomy. In domestic dogs, the middle and small breed dogs were clustered at first; German Sheepdog, Swedish Elkhound, and Black Russian Terrier were clustered into one group, and the Tibetan Mastiff, Old English Sheepdog, Leonberger, and Saint Bernard were clustered in another group. This confirmed the viewpoint that many of the famous large breed dogs worldwide such as Saint Bernard possibly had the blood lineage of the Tibetan Mastiff, based on the molecular data. According to the substitution rate, we concluded that the approximate divergence time between Tibetan Mastiff and grey wolf was 58,000 years before the present （YBP）, and the approximate divergence time between other domestic dogs and grey wolf was 42,000 YBP, demonstrating that the time of origin of the Tibetan Mastiff was earlier than that of the other domestic dogs.

Brain stem cells as the cell of origin in glioma

Glioma incidence rates in the United States are near 20000 new cases per year, with a median survival time of 14.6 mo for high-grade gliomas due to limited therapeutic options. The origins of these tumors and their many subtypes remain a matter of investigation. Evidence from mouse models of glioma and human clinical data have provided clues about the cell types and initiating oncogenic mutations that drive gliomagenesis, a topic we review here. There has been mixed evidence as to whether or not the cells of origin are neural stem cells, progenitor cells or differentiated progeny. Many of the existing murine models target cell populations defined by lineage-specific promoters or employ lineagetracing methods to track the potential cells of origin. Our ability to target specific cell populations will likely increase concurrently with the knowledge gleaned from an understanding of neurogenesis in the adult brain. The cell of origin is one variable in tumorigenesis, as oncogenes or tumor suppressor genes may differentially transform the neuroglial cell types. Knowledge of key driver mutations and susceptible cell types will allow us to understand cancer biology from a developmental standpoint and enable early interventional strategies and biomarker discovery.

Origins and evolution of plant diversity in the Hengduan Mountains, China

1.Introduction The Hengduan Mountains region(HDM)in southwest China,one of the earth's 34 biodiversity hotspots,is characterized by its unique geology,dramatic topography,a climate where snow and below freezing temperatures can occur on any day of the year,by its location at elevations averaging between(1400e)2000 and4500(e5300)meters above sea level(m a.s.l.),and by one of

The possibility analysis of habitats,origin and reappearance of bloom green alga(Enteromorpha prolifera) on inshore of western Yellow Sea

Combining some information from field investigation of algae along the coastal areas in China and a few pictures materialized from the western Yellow Sea in 2008,authors analyze the necessary conditions and possible water area in China producing a large biomass,some reasons for firestorm,and the possibility of the reappearance of marine bloom green alga Enteromorpha prolifera.The change of habitats and the increase of nutritional levels related to the water area could be considered as direct reasons.It was transferred northward by the combination of the flow of rainwater,wind and alongshore marine current.The original region of large biomass produced is possibly located in the southwestern Yellow sea.It will possibly be appearing again in the coming years or in the future.A summary is also given referring to its reproduction,development and distribution worldwide.

The telomere-to-telomere genome of Fragaria vesca reveals the genomic evolution of Fragaria and the origin of cultivated octoploid strawberry

Fragaria vesca,commonly known as wild or woodland strawberry,is the most widely distributed diploid Fragaria species and is native to Europe and Asia.Because of its small plant size,low heterozygosity,and relative ease of genetic transformation,F.vesca has been a model plant for fruit research since the publication of its Illumina-based genome in 2011.However,its genomic contribution to octoploid cultivated strawberry remains a long-standing question.Here,we de novo assembled and annotated a telomere-to-telomere,gap-free genome of F.vesca‘Hawaii 4’,with all seven chromosomes assembled into single contigs,providing the highest completeness and assembly quality to date.The gap-free genome is 220785082 bp in length and encodes 36173 protein-coding gene models,including 1153 newly annotated genes.All 14 telomeres and seven centromeres were annotated within the seven chromosomes.Among the three previously recognized wild diploid strawberry ancestors,F.vesca,F.iinumae,and F.viridis,phylogenomic analysis showed that F.vesca and F.viridis are the ancestors of the cultivated octoploid strawberry F.×ananassa,and F.vesca is its closest relative.Three subgenomes of F.×ananassa belong to the F.vesca group,and one is sister to F.viridis.We anticipate that this high-quality,telomere-to-telomere,gap-free F.vesca genome,combined with our phylogenomic inference of the origin of cultivated strawberry,will provide insight into the genomic evolution of Fragaria and facilitate strawberry genetics and molecular breeding.