Predicting the best shutdown time of a steam ethylene cracking furnace in industrial practice remains a challenge due to the complex coking process. As well known, the shutdown time of a furnace is mainly determined b...Predicting the best shutdown time of a steam ethylene cracking furnace in industrial practice remains a challenge due to the complex coking process. As well known, the shutdown time of a furnace is mainly determined by coking condition of the transfer line exchangers (TLE) when naphtha or other heavy hydrocarbon feedstocks are cracked. In practice, it is difficult to measure the coke thickness in TLE through experimental method in the complex industrial situation. However, the outlet temperature of TLE (TLEOT) can indirectly characterize the coking situation in TLE since the coke accumulation in TLE has great influence on TLEOT. Thus, the TLEOT could be a critical factor in deciding when to shut down the furnace to decoke. To predict the TLEOT, a paramewic model was proposed in this work, based on theoretical analysis, mathematic reduction, and parameters estimation. The feasibility of the proposed model was further checked through industrial data and good agreements between model prediction and industrial data with maximum deviation 2% were observed.展开更多
Experimental analysis was conducted to study the impact of fuel-air mixing and dilution jet on the temperature distribution in a small gas turbine combustor using various optical diagnostic techniques.The strength and...Experimental analysis was conducted to study the impact of fuel-air mixing and dilution jet on the temperature distribution in a small gas turbine combustor using various optical diagnostic techniques.The strength and velocity of the swirler at the venturi exit were adjusted to modify the fuel-air mixture,which is presumed to dominate the heat release of the main combustion zone.Additionally,the dilution hole configuration,including the number and size of the holes,was varied to investigate the dilution effect on outlet temperature distribution.Various optical diagnostic techniques,such as particle image velocimetry,planar Mie scattering,and OH~*chemiluminescence,were used to measure the flow field,fuel spray distribution,and flame structure,respectively.A reduction in swirling strength led to a decrease in the average flow rate in the throat,which improved the structure and symmetry of the axial vortex system in the sleeve,enhanced the mixing of fuel and gas in the dome swirling air,and ultimately,improved the temperature uniformity of the heat release zone.Compared to larger and sparse dilution jets,smaller and dense dilution jets tended to generate hot spots shifted towards the radial middle area.展开更多
Co-cracking is a process where the mixtures of different hydrocarbon feedstocks are cracked in a steam pyrolysis furnace, and widely adopted in chemical industries. In this work, the simulations of the co-cracking of ...Co-cracking is a process where the mixtures of different hydrocarbon feedstocks are cracked in a steam pyrolysis furnace, and widely adopted in chemical industries. In this work, the simulations of the co-cracking of ethane and propane, and LPG and naphtha mixtures have been conducted, and the software packages of COILSIM1 D and Sim CO are used to account for the cracking process in a tube reactor. The effects of the mixing ratio, coil outlet temperature, and pressure on cracking performance have been discussed in detail. The co-cracking of ethane and propane mixture leads to a lower profitability than the cracking of single ethane or single propane. For naphtha, cracking with LPG leads to a higher profitability than single cracking of naphtha, and more LPG can produce a higher profitability.展开更多
Borehole thermal energy storage(BTES)systems have garnered significant attention owing to their efficacy in storing thermal energy for heating and cooling applications.Accurate modeling is paramount for ensuring the p...Borehole thermal energy storage(BTES)systems have garnered significant attention owing to their efficacy in storing thermal energy for heating and cooling applications.Accurate modeling is paramount for ensuring the precise design and operation of BTES systems.This study conducts a sensitivity analysis of BTES modeling by employing a comparative investigation of five distinct parameters on a wedge-shaped model,with implications extendable to a cylindrical configuration.The parameters examined included two design factors(well spacing and grout thermal conductivity),two operational variables(charging and discharging rates),and one geological attribute(soil thermal conductivity).Finite element simulations were carried out for the sensitivity analysis to evaluate the round-trip efficiency,both on a per-cycle basis and cumulatively over three years of operation,serving as performance metrics.The results showed varying degrees of sensitivity across different models to changes in these parameters.In particular,the round-trip efficiency exhibited a greater sensitivity to changes in spacing and volumetric flow rate.Furthermore,this study underscores the importance of considering the impact of the soil and grout-material thermal conductivities on the BTES-system performance over time.An optimized scenario is modelled and compared with the base case,over a comparative assessment based on a 10-year simulation.The analysis revealed that,at the end of the 10-year period,the optimized BTES model achieved a cycle efficiency of 83.4%.This sensitivity analysis provides valuable insights into the merits and constraints of diverse BTES modeling methodologies,aiding in the selection of appropriate modeling tools for BTES system design and operation.展开更多
基金Supported by the Major State Basic Research Development Program of China (2012CB720500)the National Natural Science Foundation of China (U1162202, 21276078)+2 种基金the National Science Fund for Outstanding Young Scholars (61222303)the Shanghai Key Technologies R&D Program (12dz1125100)the Shanghai Leading Academic Discipline Project (B504)
文摘Predicting the best shutdown time of a steam ethylene cracking furnace in industrial practice remains a challenge due to the complex coking process. As well known, the shutdown time of a furnace is mainly determined by coking condition of the transfer line exchangers (TLE) when naphtha or other heavy hydrocarbon feedstocks are cracked. In practice, it is difficult to measure the coke thickness in TLE through experimental method in the complex industrial situation. However, the outlet temperature of TLE (TLEOT) can indirectly characterize the coking situation in TLE since the coke accumulation in TLE has great influence on TLEOT. Thus, the TLEOT could be a critical factor in deciding when to shut down the furnace to decoke. To predict the TLEOT, a paramewic model was proposed in this work, based on theoretical analysis, mathematic reduction, and parameters estimation. The feasibility of the proposed model was further checked through industrial data and good agreements between model prediction and industrial data with maximum deviation 2% were observed.
基金financially supported by the National Science and Technology Major Project(J2019-Ⅲ-0014-0057)the National Natural Science Foundation of China(92041001)。
文摘Experimental analysis was conducted to study the impact of fuel-air mixing and dilution jet on the temperature distribution in a small gas turbine combustor using various optical diagnostic techniques.The strength and velocity of the swirler at the venturi exit were adjusted to modify the fuel-air mixture,which is presumed to dominate the heat release of the main combustion zone.Additionally,the dilution hole configuration,including the number and size of the holes,was varied to investigate the dilution effect on outlet temperature distribution.Various optical diagnostic techniques,such as particle image velocimetry,planar Mie scattering,and OH~*chemiluminescence,were used to measure the flow field,fuel spray distribution,and flame structure,respectively.A reduction in swirling strength led to a decrease in the average flow rate in the throat,which improved the structure and symmetry of the axial vortex system in the sleeve,enhanced the mixing of fuel and gas in the dome swirling air,and ultimately,improved the temperature uniformity of the heat release zone.Compared to larger and sparse dilution jets,smaller and dense dilution jets tended to generate hot spots shifted towards the radial middle area.
基金Supported by the National Natural Science Foundation of China(21276078)Shanghai Key Technologies R&D Programe(12dz1125100)+1 种基金Natural Science Foundation of Shanghai(13ZR1411300)Shanghai Leading Academic Discipline Project(B504)
文摘Co-cracking is a process where the mixtures of different hydrocarbon feedstocks are cracked in a steam pyrolysis furnace, and widely adopted in chemical industries. In this work, the simulations of the co-cracking of ethane and propane, and LPG and naphtha mixtures have been conducted, and the software packages of COILSIM1 D and Sim CO are used to account for the cracking process in a tube reactor. The effects of the mixing ratio, coil outlet temperature, and pressure on cracking performance have been discussed in detail. The co-cracking of ethane and propane mixture leads to a lower profitability than the cracking of single ethane or single propane. For naphtha, cracking with LPG leads to a higher profitability than single cracking of naphtha, and more LPG can produce a higher profitability.
文摘Borehole thermal energy storage(BTES)systems have garnered significant attention owing to their efficacy in storing thermal energy for heating and cooling applications.Accurate modeling is paramount for ensuring the precise design and operation of BTES systems.This study conducts a sensitivity analysis of BTES modeling by employing a comparative investigation of five distinct parameters on a wedge-shaped model,with implications extendable to a cylindrical configuration.The parameters examined included two design factors(well spacing and grout thermal conductivity),two operational variables(charging and discharging rates),and one geological attribute(soil thermal conductivity).Finite element simulations were carried out for the sensitivity analysis to evaluate the round-trip efficiency,both on a per-cycle basis and cumulatively over three years of operation,serving as performance metrics.The results showed varying degrees of sensitivity across different models to changes in these parameters.In particular,the round-trip efficiency exhibited a greater sensitivity to changes in spacing and volumetric flow rate.Furthermore,this study underscores the importance of considering the impact of the soil and grout-material thermal conductivities on the BTES-system performance over time.An optimized scenario is modelled and compared with the base case,over a comparative assessment based on a 10-year simulation.The analysis revealed that,at the end of the 10-year period,the optimized BTES model achieved a cycle efficiency of 83.4%.This sensitivity analysis provides valuable insights into the merits and constraints of diverse BTES modeling methodologies,aiding in the selection of appropriate modeling tools for BTES system design and operation.