The novel reactive transfer printing of silk was carried out through a hot-press adhesion and steaming. The special transfer paper was prepared by coating the paste mainly containing hot-melt adhesive hlgh-substituted...The novel reactive transfer printing of silk was carried out through a hot-press adhesion and steaming. The special transfer paper was prepared by coating the paste mainly containing hot-melt adhesive hlgh-substituted hydroxypropyl cellulose （H-HPC） and printing thickener earboxymethyl cellulose （CMC）. The effects of each ingredient in the paste on color yield of the prints and dye penetration were investigated. The major results indicate that, color yield is chiefly governed by the adhesion extent imparted by H-HPC, the type of fixing alkaline agent, and the content of urea. Trichloroacetic acid （TCAA） as the fixing alkaline agent and adding 5% urea can enhance the color depth obviously. Dye penetration depends on the coating quantity on the transfer paper, the contents of urea and dicyandiamide. The printed silk possesses a higher color yield, color fastness of grade 3 or above, clear sharpness, and good handle when the paste contains 3 % H-HPC, 0. 7 % CMC, 3 % TCAA, 5 % urea, 3 % dicyandiamide, and 0. 5 % physical sorbent nano-silica.展开更多
Desktop 3D printers have revolutionized how designers and makers prototype and manufacture certain products.Highly popular fuse deposition modeling(FDM)desktop printers have enabled a shift to low-cost consumer goods ...Desktop 3D printers have revolutionized how designers and makers prototype and manufacture certain products.Highly popular fuse deposition modeling(FDM)desktop printers have enabled a shift to low-cost consumer goods markets,through reduced capital equipment investment and consumable material costs.However,with this drive to reduce costs,the computer numerical control(CNC)systems implemented in FDM printers are often compromised by poor accuracy and contouring errors.This condition is most critical as users begin to use 3D-printed components in load-bearing applications or to perform mechanical functions.Improved methods of low-cost 3D printer calibration are needed before their open-design potential can be realized in applications,including 3D-printed orthotics and prosthetics.This paper applies methodologies associated with high-precision CNC machining systems,namely,kinematic error modeling and compensation coupled with standardized test methods from ISO230-4,such as the ballbar for kinematic and dynamic error measurements,to examine the influence and feasibility for use on low-cost CNC/3D printing platforms.Recently,the U.S.Food and Drug Administration's"Technical considerations for additive manufactured medical devices"highlighted the need to develop standards specific to additive manufacturing in regulated manufacturing environments.This paper shows the benefits of the methods described within ISO230-4 for error assessment,alongside applying kinematic error modeling and compensation to the popular kinematic configuration of an Ultimaker 3D printer.A Renishaw ballbar QC10 is used to quantify the Ultimaker's errors and thereby populate the error model.This method quantifies machine errors and populates these in a mathematical model of the CNC system.Then,a post-processor can be used to compensate the printing code.Subsequently,the ballbar is used to demonstrate the dramatic impact of the error compensation model on the accuracy and contouring of the Ultimaker printer with 58%reduction in overall circularity error and 90%reduction in squareness error.展开更多
A mesoscopic model has been established to investigate the thermodynamic mechanisms and densification behavior of nickel-based superalloy during additive manufacturing/three-dimensional （3D） printing （AM/3DP） by n...A mesoscopic model has been established to investigate the thermodynamic mechanisms and densification behavior of nickel-based superalloy during additive manufacturing/three-dimensional （3D） printing （AM/3DP） by numerical simulation, using a finite volume method （FVM）. The influence of the applied linear energy density （LED） on dimensions of the molten pool, thermodynamic mechanisms within the pool, bubbles migration and resultant densification behavior of AM/3DP-processed superalloy has been discussed. It reveals that the center of the molten pool slightly shifts with a lagging of 4 ktm towards the center of the moving laser beam. The Mar- angoni convection, which has various flow patterns, plays a crucial role in intensifying the convective heat and mass transfer, which is responsible for the bubbles migration and densification behavior of AM/3DP-processed parts. At an optimized LED of 221.5 J/m, the outward convection favors the numerous bubbles to escape from the molten pool easily and the resultant considerably high relative density of 98.9 % is achieved. However, as the applied LED further increases over 249.5 J/m, the convection pattern is apparently intensified with the formation of vortexes and the bubbles tend to be entrapped by the rotating flow within the molten pool, resulting in a large amount of residual porosity and a sharp reduction in densification of the superalloy. The change rules of the relative density and the corresponding distribution of porosity obtained by experiments are in accordance with the simulation results.展开更多
Proton-conducting oxides offer a promising electrolyte solution for intermediate temperature solid oxide fuel cells（SOFCs） due to their high conductivity and low activation energy. However, the lower operation tempe...Proton-conducting oxides offer a promising electrolyte solution for intermediate temperature solid oxide fuel cells（SOFCs） due to their high conductivity and low activation energy. However, the lower operation temperature leads to a reduced cathode activity and thus a poorer fuel cell performance. La_（0.8）Sr_（0.2）MnO_（3-δ）（LSM） is the classical cathode material for high-temperature SOFCs, which lack features as a proper SOFC cathode material at intermediate temperatures.Despite this, we here successfully couple nanostructured LSM cathode with proton-conducting electrolytes to operate below600℃ with desirable SOFC performance. Inkjet printing allows depositing nanostructured particles of LSM on Y-doped Ba ZrO_3（BZY） backbones as cathodes for proton-conducting SOFCs, which provides one of the highest power output for the BZY-based fuel cells below 600 ℃. This somehow changes the common knowledge that LSM can be applied as a SOFC cathode materials only at high temperatures（above 700 ℃）.展开更多
基金Jiangsu Province Project of Postgraduate Innovation Engineering,China(No.CXZZ12_0821)Industry-academic Joint Technological Innovations Fund Project of Jiangsu Province,China(No.BY2012120)Suzhou Project of Scientific and Technical Supporting,China(No.ZXS2012001)
文摘The novel reactive transfer printing of silk was carried out through a hot-press adhesion and steaming. The special transfer paper was prepared by coating the paste mainly containing hot-melt adhesive hlgh-substituted hydroxypropyl cellulose （H-HPC） and printing thickener earboxymethyl cellulose （CMC）. The effects of each ingredient in the paste on color yield of the prints and dye penetration were investigated. The major results indicate that, color yield is chiefly governed by the adhesion extent imparted by H-HPC, the type of fixing alkaline agent, and the content of urea. Trichloroacetic acid （TCAA） as the fixing alkaline agent and adding 5% urea can enhance the color depth obviously. Dye penetration depends on the coating quantity on the transfer paper, the contents of urea and dicyandiamide. The printed silk possesses a higher color yield, color fastness of grade 3 or above, clear sharpness, and good handle when the paste contains 3 % H-HPC, 0. 7 % CMC, 3 % TCAA, 5 % urea, 3 % dicyandiamide, and 0. 5 % physical sorbent nano-silica.
基金supported by Science Foundation Ireland through the I-Form Advanced Manufacturing Research Centre 16/RC/3872
文摘Desktop 3D printers have revolutionized how designers and makers prototype and manufacture certain products.Highly popular fuse deposition modeling(FDM)desktop printers have enabled a shift to low-cost consumer goods markets,through reduced capital equipment investment and consumable material costs.However,with this drive to reduce costs,the computer numerical control(CNC)systems implemented in FDM printers are often compromised by poor accuracy and contouring errors.This condition is most critical as users begin to use 3D-printed components in load-bearing applications or to perform mechanical functions.Improved methods of low-cost 3D printer calibration are needed before their open-design potential can be realized in applications,including 3D-printed orthotics and prosthetics.This paper applies methodologies associated with high-precision CNC machining systems,namely,kinematic error modeling and compensation coupled with standardized test methods from ISO230-4,such as the ballbar for kinematic and dynamic error measurements,to examine the influence and feasibility for use on low-cost CNC/3D printing platforms.Recently,the U.S.Food and Drug Administration's"Technical considerations for additive manufactured medical devices"highlighted the need to develop standards specific to additive manufacturing in regulated manufacturing environments.This paper shows the benefits of the methods described within ISO230-4 for error assessment,alongside applying kinematic error modeling and compensation to the popular kinematic configuration of an Ultimaker 3D printer.A Renishaw ballbar QC10 is used to quantify the Ultimaker's errors and thereby populate the error model.This method quantifies machine errors and populates these in a mathematical model of the CNC system.Then,a post-processor can be used to compensate the printing code.Subsequently,the ballbar is used to demonstrate the dramatic impact of the error compensation model on the accuracy and contouring of the Ultimaker printer with 58%reduction in overall circularity error and 90%reduction in squareness error.
基金supported by the National Natural Science Foundation of China (51575267, 51322509)the Top-Notch Young Talents Program of China+9 种基金the Outstanding Youth Foundation of Jiangsu Province of China (BK20130035)the Program for New Century Excellent Talents in University (NCET-13-0854)the Science and Technology Support Program (the Industrial Part)Jiangsu Provincial Department of Science and Technology of China (BE2014009-2)the 333 high-level talents training project (BRA2015368)the Science and Technology Foundation for Selected Overseas Chinese Scholar, Ministry of Human Resources and Social Security of Chinathe Aeronautical Science Foundation of China (2015ZE52051)the Shanghai Aerospace Science and Technology Innovation Fund (SAST2015053)the Fundamental Research Funds for the Central Universities (NE2013103, NP2015206 and NZ2016108)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘A mesoscopic model has been established to investigate the thermodynamic mechanisms and densification behavior of nickel-based superalloy during additive manufacturing/three-dimensional （3D） printing （AM/3DP） by numerical simulation, using a finite volume method （FVM）. The influence of the applied linear energy density （LED） on dimensions of the molten pool, thermodynamic mechanisms within the pool, bubbles migration and resultant densification behavior of AM/3DP-processed superalloy has been discussed. It reveals that the center of the molten pool slightly shifts with a lagging of 4 ktm towards the center of the moving laser beam. The Mar- angoni convection, which has various flow patterns, plays a crucial role in intensifying the convective heat and mass transfer, which is responsible for the bubbles migration and densification behavior of AM/3DP-processed parts. At an optimized LED of 221.5 J/m, the outward convection favors the numerous bubbles to escape from the molten pool easily and the resultant considerably high relative density of 98.9 % is achieved. However, as the applied LED further increases over 249.5 J/m, the convection pattern is apparently intensified with the formation of vortexes and the bubbles tend to be entrapped by the rotating flow within the molten pool, resulting in a large amount of residual porosity and a sharp reduction in densification of the superalloy. The change rules of the relative density and the corresponding distribution of porosity obtained by experiments are in accordance with the simulation results.
基金supported by the National Natural Science Foundation of China (51602238)the Thousand Talents Plan
文摘Proton-conducting oxides offer a promising electrolyte solution for intermediate temperature solid oxide fuel cells（SOFCs） due to their high conductivity and low activation energy. However, the lower operation temperature leads to a reduced cathode activity and thus a poorer fuel cell performance. La_（0.8）Sr_（0.2）MnO_（3-δ）（LSM） is the classical cathode material for high-temperature SOFCs, which lack features as a proper SOFC cathode material at intermediate temperatures.Despite this, we here successfully couple nanostructured LSM cathode with proton-conducting electrolytes to operate below600℃ with desirable SOFC performance. Inkjet printing allows depositing nanostructured particles of LSM on Y-doped Ba ZrO_3（BZY） backbones as cathodes for proton-conducting SOFCs, which provides one of the highest power output for the BZY-based fuel cells below 600 ℃. This somehow changes the common knowledge that LSM can be applied as a SOFC cathode materials only at high temperatures（above 700 ℃）.
