Hybrid model for BOF oxygen blowing time prediction based on oxygen balance mechanism and deep neural network

The amount of oxygen blown into the converter is one of the key parameters for the control of the converter blowing process,which directly affects the tap-to-tap time of converter. In this study, a hybrid model based on oxygen balance mechanism (OBM) and deep neural network (DNN) was established for predicting oxygen blowing time in converter. A three-step method was utilized in the hybrid model. First, the oxygen consumption volume was predicted by the OBM model and DNN model, respectively. Second, a more accurate oxygen consumption volume was obtained by integrating the OBM model and DNN model. Finally, the converter oxygen blowing time was calculated according to the oxygen consumption volume and the oxygen supply intensity of each heat. The proposed hybrid model was verified using the actual data collected from an integrated steel plant in China, and compared with multiple linear regression model, OBM model, and neural network model including extreme learning machine, back propagation neural network, and DNN. The test results indicate that the hybrid model with a network structure of 3 hidden layer layers, 32-16-8 neurons per hidden layer, and 0.1 learning rate has the best prediction accuracy and stronger generalization ability compared with other models. The predicted hit ratio of oxygen consumption volume within the error±300 m^(3)is 96.67%;determination coefficient (R^(2)) and root mean square error (RMSE) are0.6984 and 150.03 m^(3), respectively. The oxygen blow time prediction hit ratio within the error±0.6 min is 89.50%;R2and RMSE are0.9486 and 0.3592 min, respectively. As a result, the proposed model can effectively predict the oxygen consumption volume and oxygen blowing time in the converter.

Measurement of solidprecipitation and blowing snow: current status and challenges

In this article,the relevant instruments and techniques for measuring solid precipitation and blowing snow are reviewed,with a focus on the in situ instrument measurements.Moreover,a literature review and specific observation activities for solid precipitation are provided,the working principles of several instruments are introduced,and the advantages and disadvantages,measurement performance,and specific application scenarios of the instruments are evaluated.Currently,there are numerous solid precipitation measurement instruments available,and the standardization and sustainability of these measurements also need to be considered.The purpose of the review is not to be exhaustive but to provide readers with information on the current status of the development of relevant technologies and the prospects for their application in the polar regions.

Exploration and Practice of Nitrogen Addition Process for LF Refining Ladle Bottom Blowing Nitrogen Steel Liquid

This article discusses and analyzes the law of nitrogen increase in liquid steel and the main factors affect-ing the nitrogen increasing of molten steel,through the way of adding nitrogen to molten steel by bottom blowing nitrogen gas in LF refining process.It is considered that the main factors affecting the nitrogen increasing instability of molten steel are the initial temperature of LF refining,nitrogen relative element,surface active elements[O]and[S]of steel liquid,and bottom blowing rate of ladle.The large-scale production practice shows that T[O]not more than 50×10-6 and[S]is not more than 0.020 in LF refining at the initial temperature of not less than 1570.The liquid steel nitrogen enrichment test is carried out by ladle bottom blowing nitrogen gas after 20 min of refining,the flow rate is set as(6.0~7.0)NL/min per ton,and it is turned to 2 NL/min at 6 min before the end of refining,the nitrogen increasing rate of liquid steel is basically stable at(5~6)×10-6 per minute.

Effect of gas blowing nozzle angle on multiphase flow and mass transfer during RH refining process

A three-dimensional mathematical model was developed to investigate the effect of gas blowing nozzle angles on multiphase flow,circulation flow rate,and mixing time during Ruhrstahl-Heraeus(RH) refining process.Also,a water model with a geometric scale of 1:4 from an industrial RH furnace of 260 t was built up,and measurements were carried out to validate the mathematical model.The results show that,with a conventional gas blowing nozzle and the total gas flow rate of 40 L·min^(-1),the mixing time predicted by the mathematical model agrees well with the measured values.The deviations between the model predictions and the measured values are in the range of about 1.3%–7.3% at the selected three monitoring locations,where the mixing time was defined as the required time when the dimensionless concentration is within 3% deviation from the bath averaged value.In addition,the circulation flow rate was 9 kg·s^(-1).When the gas blowing nozzle was horizontally rotated by either 30° or 45°,the circulation flow rate was found to be increased by about 15% compared to a conventional nozzle,due to the rotational flow formed in the up-snorkel.Furthermore,the mixing time at the monitoring point 1,2,and 3 was shortened by around 21.3%,28.2%,and 12.3%,respectively.With the nozzle angle of 30° and 45°,the averaged residence time of 128 bubbles in liquid was increased by around 33.3%.

Eco-friendly physical blowing agent mass loss of bio-based polyurethane rigid foam materials

Through systematical experiment design, the physical blowing agent(PBA) mass loss of bio-based polyurethane rigid foam(PURF)in the foaming process was measured and calculated in this study, and different eco-friendly PBA mass losses were measured quantitatively for the first time. The core of the proposed method is to add water to replace the difference, and this method has a high fault tolerance rate for different foaming forms of foams. The method was proved to be stable and reliable through the standard deviations σ1and σ2for R1(ratio of the PBA mass loss to the material total mass except the PBA) and R2(ratio of the PBA mass loss to the PBA mass in the material total mass) in parallel experiments. It can be used to measure and calculate the actual PBA mass loss in the foaming process of both bio-based and petroleumbased PURF. The results show that the PBA mass loss in PURF with different PBA systems is controlled by its initial mass content of PBA in PU materials ω. The main way for PBA to dissipate into the air is evaporation/escape along the upper surface of foam. This study further reveals the mechanism of PBA mass loss: the evaporation/escape of PBA along the upper surface of foam is a typical diffusion behavior. Its spread power comes from the difference between the chemical potential of PBA in the interface layer and that in the outside air. For a certain PURF system, R1has approximately linear relationship with the initial mass content of PBA in PU materials ω, which can be expressed by the functional relationship R1= kω, where k is a variable related to PBA’s own attributes.

Blown Film Extrusion Process for Polybags: Technical Overview and Applications

The choice of extrusion process is a decisive factor that affects the finished product quality for polybag manufacturing. One important component influencing the quality of the finished product is the selection of the extrusion technique. Two popular procedures that vary in the kind of dye used and the final product’s texture are cast film and blown film. In the horizontal extrusion moulding method known as “cast film”, heated resin is injected into a flat dye and allowed to cool on chill rolls. The film produced is clear, lightweight, and appropriate for lamination;its thickness varies based on the winding speed and the film is slower to crystallize and has less clarity but more durability because the resin molecules have reoriented, facing limitation of high wastage generation. This study primarily focused on the preparation of polybag film using the blown film extrusion process, utilizing high-quality polymer resins such as polyester polyethylene (PP) and linear low-density polyethylene (LLDPE) to minimize waste generation. The novelty of the process was reflected in minimising the waste generation. The control parameters considered in this study are temperature, pressure, and air intake volume. We investigated the influence of these critical process control parameters on the gauge thickness, optical properties, and mechanical strength of the polybag film produced through blown film extrusion. Additionally, we replicated the blown film process using simulation software developed at Pennsylvania College of Technology. The simulation results confirmed the overall stability of the polybag film produced through the blown film extrusion process.

Thermodynamic behavior and morphology of impurities in metallurgical grade silicon in process of O_2 blowing

Gas blowing is a valid method to remove the impurities from metallurgical grade silicon（MG-Si） melt.The thermodynamic behavior of impurities Fe,Al,Ca,Ti,Cu,C,B and P in MG-Si was studied in the process of O2 blowing.The removal efficiencies of impurities in MG-Si were investigated using O2 blowing in ladle.It is found that the removal efficiencies are higher than 90% for Ca and Al and nearly 50% for B and Ti.The morphology of inclusions was analyzed and the phases Al3Ni,NiSi2 and Al3Ni were confirmed in MG-Si by X-ray diffraction.It was found that SiB4 exists in Si？B binary system.The chemical composition of inclusions in MG-Si before and after refining was analyzed by SEM-EDS.It is found that the amount of white inclusion reduces for the removal of most Al and Ca in the forms of molten slag inclusion and the contents of Fe,Ni and Mn in inclusion increase for their inertia in silicon melt with O2 blowing.

Water modeling of molten steel flow in a multi-strand tundish with gas blowing

Fluid flow characteristics in a four-strand tundish with gas blowing were studied by water modeling experiments.It is found that gas blowing can greatly improve the flow characteristics in the tundish with a turbulence inhibitor.It dramatically increases the peak concentration time,and greatly decreases the dead volume,and reduces the minimum residence time.The gas blowing location,gas flow rate,and porous plug area greatly influence the flow characteristics in the tundish; the gas blowing location near the baffle,smaller gas flow rate,and smaller porous plug area are better for improving the fluid flow characteristics.Using gas blowing can reduce the difference of flows at the middle outlets and side outlets for the multi-strand tundish.Bubbles produced by gas blowing can absorb small inclusions and provide the condition for inclusion collision and aggregation.Therefore,introducing gas blowing into a tundish and combining the turbulence inhibitor can improve inclusion floating and removal,and the cleanness of molten steel can be advanced.

VOLUMETRIC MASS TRANSFER COEFFICIENT BETWEEN SLAG AND METAL IN COMBINED BLOWING CONVERTER

The effects of operation parameters of combined blowing converter on the volumetric mass transfer coefficient between slag and steel are studied with a cold model with water simulating steel, oil simulating slag and benzoic acid as the transferred substance between water and oil. The results show that, with lance level of 2.1m and the top blowing rate of 25000Nm3/h, the volumetric mass transfer coefficient changes most significantly when the bottom blowing rate ranges from 384 to 540Nm3/h. The volumetric mass transfer coefficient reaches its maximum when the lance level is 2.1m, the top blowing rates is 30000Nm3/h, and the bottom blowing rate is 384Nm3/h with tuyeres located symmetrically at 0.66D of the converter bottom.

Self-sustained Oscillation Pulsed Air Blowing System for Energy Saving

Currently, many studies have been made for years on dimensions of pneumatic nozzle, which influence the flow characteristic of blowing system. For the purpose of outputting the same blowing force, the supply pressure could be reduced by decreasing the ratio of length to diameter of nozzle. The friction between high speed air and pipe wall would be reduced if the nozzle is designed to be converging shape comparing with straight shape. But the volume flow and pressure, discussed in these studies, do not describe energy loss of the blowing system directly. Pneumatic power is an innovative principle to estimate pneumatic system’s energy consumption directly. Based on the above principle, a pulse blowing method is put forward for saving energy. A flow experiment is carried out, in which the high speed air flows from the pulse blowing system and continuous blowing system respectively to a plate with grease on top. Supply pressure and the volume of air used for removing the grease are measured to calculate energy consumption. From the experiment result, the pulse blowing system performs to conserve energy comparing with the continuous blowing system. The frequency and duty ratio of pulse flow influence the blowing characteristic. The pulse blowing system performs to be the most efficient at the specified frequency and duty ratio. Then a pneumatic self-oscillated method based on air operated valve is put forward to generate pulse flow. A simulation is made about dynamic modeling the air operated valve and calculating the motion of the valve core and output pressure. The simulation result verifies the system to be able to generate pulse flow, and predicts the key parameters of the frequency and duty ratio measured by experiment well. Finally, on the basis of simplifying and solution of the pulse blowing system’s mathematic model, the relationship between system’s frequency duty ratio and the dimensions of components is simply described with four algebraic equations. The system could be designed with specified frequency and duty ratio according to the four equations. This study provides theoretical basis for designing energy-saving air blowing system.

Role of blowing snow in snow processes in Qilian Mountainous region

Blowing snow is an important part of snow hydrologic processes in mountainous region, however the related researches were rare for the Qilian mountainous region where blowing snow is frequent. Using the observation dataset in 2008 snow season in Binggou wa- tershed in Qilian mountainous region, we systematically studied the energy and mass processes of blowing snow by field observation and model simulation. The results include the analysis of snow observation, the occurrence probability of blowing snow, blowing snow transport and blowing snow sublimation. It was found that blowing snow was obvious in high altitude region （4,146 m）, the snow redislribution phenomena was remarkable. In Yakou station in the study region, blowing snow was easily occurred in midwinter and early spring when no snowmelt, the blowing snow transport was dominated in this period; when snowmelt beginning, the occur- rence probability of blowing snow decreased heavily because of the increasing air temperature, melt, and refrozen phenomena. The blowing snow sublimation accounted for 41.5% of total snow sublimation at Yakou station in 2008 snow season.

Cold model on bubble growth and detachment in bottom blowing process

The bubble growth and detachment behavior in the bottom blowing process were investigated. Four multi-hole nozzle configurations with different opening ratios were assessed experimentally using high-speed photography and digital image processing. For these configurations, the experiments reveal that the bubble growth consists of a petal-like stage, an expansion stage and a detachment stage. The petal-like shape is qualitatively described through the captured images, while the non-spherical bubbles are analyzed by the aspect ratio. The bubble size at the detachment is quantified by the maximum caliper distance and the bubble equivalent diameter. Considering the dependence on the opening ratio, different prediction models for the ratio of maximum caliper distance to hydraulic diameter of the nozzle outlet and the dimensionless bubble diameter are established. The comparative analysis results show that the proposed prediction model can accurately predict the bubble detachment size under the condition of multi-hole nozzles.

Numerical Simulation of the Air Jet Flow Field in the Melt Blowing Process

The theoretical model of the flow field of the dual slot die in melt blowing process is founded. The model is solved numerically with finite difference method. The distributions of the air velocity component in x direction along x-axis and y-axis and the air temperature distributions along x-axis and y-axis are obtained via numerical computation. The computation results coincide with the experimental data given by Harphain and Shambaugh. The distributions of the air velocity and air temperature are introduced into the air drag model of melt blowing. The model prediction of the fiber diameter agrees with the experimental data well.

Effect of Fe/SiO2 and CaO/SiO2 mass ratios on metal recovery rate and metal content in slag in oxygen-enriched direct smelting of jamesonite concentrate

The oxygen-enriched direct smelting of jamesonite concentrate was carried out at 1250℃by changing the slag composition.The effects of Fe/SiO2 and Ca O/SiO2 mass ratios on the metal recovery rate as well as metal content in slag were investigated.Experimental results indicated that the metal(Pb+Sb)recovery rate was up to 88.30%,and metal(Pb+Sb)content in slag was below 1 wt.%under the condition of slag composition of 21-22 wt.%Fe,19-20 wt.%SiO2 and 17-18 wt.%Ca O with Fe/SiO2 mass ratio of 1.1:1 and Ca O/SiO2 mass ratio of 0.9:1.The microanalysis of the alloy and slag demonstrated that the main phases in the alloy contained metallic Pb,metallic Sb and a small amount of Cu2 Sb and Fe Sb2 intermetallic compounds.The slag was mainly composed of kirschsteinite and fayalite.Zinc in the raw material was mainly oxidized into the slag phase in the form of zinc oxide.

Preparation of Microcapsules Containing Water Droplets Stabilized with Solid Powder and Application to Blowing Agent

We have tried to prepare the microcapsules containing water droplets stabilized with solid powder by utilizing the (W/O)/W emulsion. The water droplets as core material were stabilized in the monomer droplets with titanium dioxide (TiO2) as a particulate surfactant. Before adding the TiO2 powder into the monomer phase, the powder was modified with triethoxyvinylsilane to adjust the degree of hydrophobicity and to promote adhesion on the interface between the inner water phase and the monomer phase in the (W/O) emulsion. It was investigated how the degree of hydrophobicity of the TiO2 powder affected the stability of water droplets in the (W/O) emulsion and the (W/O) droplets in the (W/O)/W emulsion. Moreover, the microcapsule diameters were measured before and after the expansion operation where the water droplets microencapsulated were applied as a blowing agent. The expansion ratio was increased with increase in the stability of the water droplets and the amount of water microencapsulated.

NUMERICAL STUDY ON THE FLOW AROUND A CIRCULAR CYLINDER WITH SURFACE SUCTION OR BLOWING USING VORTICITY-VELOCITY METHOD

A vorticity-velocity method was used to study the incompressible viscous fluid flow around a circular cylinder with surface suction or blowing. The resulted high order implicit difference equations were effeciently solved by the modified incomplete LU decomposition conjugate gradient scheme ( MILU-CG). The effects of surface suction or blowing' s position and strength on the vortex structures in the cylinder wake, as well as on the drag and lift forces at Reynoldes number Re = 100 were investigated numerically. The results show that the suction on the shoulder of the cylinder or the blowing on the rear of the cylinder can effeciently suppress the asymmetry of the vortex wake in the transverse direction and greatly reduce the lift force; the suction on the shoulder of the cylinder, when its strength is properly chosen, can reduce the drag force significantly, too.

Simulation and Experiment for Oxygen-enriched Combustion Engine Using Liquid Oxygen to Solidify CO2

For capturing and recycling of CO2 in the internal combustion engine, Rankle cycle engine can reduce the exhaust pollutants effectively under the condition of ensuring the engine thermal efficiency by using the techniques of spraying water in the cylinder and optimizing the ignition advance angle. However, due to the water spray nozzle need to be installed on the cylinder, which increases the cylinder head design difficulty and makes the combustion conditions become more complicated. In this paper, a new method is presented to carry out the closing inlet and exhaust system for internal combustion engines. The proposed new method uses liquid oxygen to solidify part of cooled CO2 from exhaust system into dry ice and the liquid oxygen turns into gas oxygen which is sent to inlet system. The other part of CO2 is sent to inlet system and mixed with oxygen, which can reduce the oxygen-enriched combustion detonation tendency and make combustion stable. Computing grid of the IP52FMI single-cylinder four-stroke gasoline-engine is established according to the actual shape of the combustion chamber using KIVA-3V program. The effects of exhaust gas recirculation （EGR） rate are analyzed on the temperatures, the pressures and the instantaneous heat release rates when the EGR rate is more than 8%. The possibility of enclosing intake and exhaust system for engine is verified. The carbon dioxide trapping device is designed and the IP52FMI engine is transformed and the CO2 capture experiment is carried out. The experimental results show that when the EGR rate is 36% for the optimum EGR rate. When the liquid oxygen of 35.80-437.40 g is imported into the device and last 1-20 min, respectively, 21.50-701.30 g dry ice is obtained. This research proposes a new design method which can capture CO2 for vehicular internal combustion engine.

Slag Splashing in a Basic Oxygen Furnace under Different Blowing Conditions

The influence of three different blowing conditions on the slag splashing process in a basic oxygen furnace for steelmaking is analyzed here using two-dimensional transient Computational Fluid Dynamics simulations. Four blowing conditions are considered in the computer runs: top blowing, combined blowing using just a bottom centered nozzle, combined blowing using two bottom lateral nozzles, and full combined blowing using the three top and the three bottom nozzles. Computer simulations show that full combined blowing provides greater slag splashing than conventional top blowing.

The Effect of the Process on Mechanical Properties of Polylactic Acid-Date Palm Leaf Fibers Composite Films Produced By Extrusion Blowing

Biocomposite films prepared with melt compounding and film blowing have become a new trend in plastic research to deliver more eco-friendly packages.Polylactic acid(PLA)was melt compounded with minimally processed date palm leaf fiber(DPLF)and converted into films by blown film extrusion.The compounding was done in order to enhance the film mechanical properties in one hand,and to decrease the film production cost in the other hand.In this present study,a reference PLA film and films with 1%,2%,and 5%of DPLF(weight%)were produced with different process parameters.The spatial variations in films thickness and lay flat width indicate that the addition of DPLF up to 2%enhances the bubble stability for the tested process parameters.However,the composite with 5%DPLF shows nearly the same processability window as the neat PLA.The structural and mechanical characterizations of films suggest a reinforcing effect of the PLA matrix up to 2%of fiber(with an optimum at 1%).Larger DPLF loading leads to depressed and more anisotropic mechanical properties,related to an increased density of defects at the fiber-PLA fragile interface and to a DPLF-induced enhanced PLA thermal degradation and amorphous phase orientation.

Streamlines in the Two-Dimensional Spreading of a Thin Fluid Film: Blowing and Suction Velocity Proportional to the Height

The two-dimensional spreading under gravity of a thin fluid film with suction (fluid leak-off) or blowing (fluid injection) at the base is considered. The thin fluid film approximation is imposed. The height of the thin film satisfies a nonlinear diffusion equation with a source/sink term. The Lie point symmetries of the nonlinear diffusion equation are derived and exist, which provided the fluid velocity at the base, vn satisfies a first order linear partial differential equation. The general form has algebraic time dependence while a special case has exponential time dependence. The solution in which vn is proportional to the height of the thin film is studied. The width of the base always increases with time even for suction while the height decreases with time for sufficiently weak blowing. The streamlines of the fluid flow inside the thin film are plotted by first solving a cubic equation. For sufficiently weak blowing there is a dividing streamline, emanating from the stagnation point on the centre line which separates the fluid flow into two regions, a lower region consisting of rising fluid and dominated by fluid injection at the base and an upper region consisting of descending fluid and dominated by spreading due to gravity. For sufficiently strong blowing the lower region expands to completely fill the whole thin film.