The effects of gravity,capillary force,and viscous force on the migration characteristics of oil and gas interface in oxygen-reduced air-assisted gravity drainage(OAGD)were studied through a two-dimensional visualizat...The effects of gravity,capillary force,and viscous force on the migration characteristics of oil and gas interface in oxygen-reduced air-assisted gravity drainage(OAGD)were studied through a two-dimensional visualization model.The effects of bond number,capillary number and low-temperature oxidation on OAGD recovery were studied by long core displacement experiments.On this basis,the low-temperature oxidation number was introduced and its relationship with the OAGD recovery was established.The results show that the shape and changing law of oil and gas front are mainly influenced by gravity,capillary force and viscous force.When the bond number is constant(4.52×10-4),the shape of oil-gas front is controlled by capillary number.When the capillary number is less than 1.68×10-3,the oil and gas interface is stable.When the capillary number is greater than 2.69×10-2,the oil and gas interface shows viscous fingering.When the capillary number is between 1.68×10-3 and 2.69×10-2,the oil and gas interface becomes capillary fingering.The core flooding experiments results show that for OAGD stable flooding,before the gas breakthrough,higher recovery is obtained in higher gravity number and lower capillary number.In this stage,gravity is predominant in controlling OAGD recovery and the oil recovery could be improved by reducing injection velocity.After gas breakthrough,higher recovery was obtained in lower gravity and higher capillary numbers,which means that the viscous force had a significant influence on the recovery.Increasing gas injection velocity in this stage is an effective measure to improve oil recovery.The low-temperature oxidation number has a good correlation with the recovery and can be used to predict the OAGD recovery.展开更多
Oxygen-reducing air flooding is a low-permeability reservoir recovery technology with safety and low-cost advantages.However,in the process of air injection and drive,carbon in the air is oxidized through the crude oi...Oxygen-reducing air flooding is a low-permeability reservoir recovery technology with safety and low-cost advantages.However,in the process of air injection and drive,carbon in the air is oxidized through the crude oil reservoir to generate CO_(2),and this can cause serious corrosion in the recovery well.In this study,experiments on the corrosion of J55 tubular steel in a fluid environment with coexisting O_(2)and CO_(2)in an autoclave are presented.In particular,a weight loss method and a 3D morphometer were used to determine the average and the local corrosion rate.The corrosion surface morphology and composition were also measured by means of scanning electron microscopy(SEM)and an X-ray diffractometer(XRD).The corrosion pattern and morphological characteristics of J55 steel were analyzed in the O2/CO_(2)environment for different degrees of oxygen-reduction.As made evident by the experimental results,the corrosion products were mainly ferrous carbonate and iron oxide.In general,air injection increases the degree of oxygen reduction,from oxygen corrosion characteristics to CO_(2)corrosion-based characteristics.As a result,the corrosion product film becomes denser,and the corrosion rate is lower.展开更多
It is necessary to understand the features of air pressure in a drainage stack of a high-rise building for properly designing and operating a drainage system. This paper presents a mathematical model for predicting th...It is necessary to understand the features of air pressure in a drainage stack of a high-rise building for properly designing and operating a drainage system. This paper presents a mathematical model for predicting the stack performance. A step function is used to describe the effect of the air entrainment caused by the water discharged from branch pipes. An additional source term is introduced to reflect the gas-liquid interphase interaction (GLII) and stack base effect. The drainage stack is divided into upper and base parts. The air pressure in the upper part is predicted by a total variation diminishing (TVD) scheme, while in the base part, it is predicted by a characteristic line method (CLM). The predicted results are compared with the data measured in a real-scale high- rise test building. It is found that the additional source term in the present model is effective. It intensively influences the air pressure distribution in the stack. The air pressure is also sensitive to the velocity-adjusting parameter (VAP), the branch pipe air entrainment, and the conditions on the stack bottom.展开更多
Light crude oil from the lower member of the Paleogene Xiaganchaigou Formation of Gaskule in Qinghai Oilfield was selected to carry out thermal kinetic analysis experiments and calculate the activation energy during t...Light crude oil from the lower member of the Paleogene Xiaganchaigou Formation of Gaskule in Qinghai Oilfield was selected to carry out thermal kinetic analysis experiments and calculate the activation energy during the oil oxidation process.The oxidation process of crude oi l in porous medium was modeled by crude oil static oxidation experiment,and the component changes of crude oil before and after low-temperature oxidation were compared through Fourier transform ion cy-clotron resonance mass spectrometry and gas chromatography;the dynamic displacement experiment of oxygen-reduced air was combined with NMR technology to analyze the oil recovery degree of oxygen-reduced air flooding.The whole process of crude oil oxidation can be divided into four stages:light hydrocarbon volatilization,low-temperature oxidation,fuel deposition,and high temperature oxidation;the high temperature oxidation stage needs the highest activation energy,followed by the fuel deposition stage,and the low-temperature oxidation stage needs the lowest activation energy;the concentration of oxygen in the reaction is negatively correlated with the activation energy required for the reaction;the higher the oxygen concentration,the lower the average activation energy required for oxidation reaction is;the low-temperature oxidation reaction between crude oil and air generates a large amount of heat and CO,CO_(2) and CH4,forming flue gas drive in the reservoir,which has certain effects of mixing phases,reducing viscosity,lowering interfacial tension and promoting expansion of crude oil,and thus helps enhance the oil recovery rate.Under suitable reservoir temperature condition,the degree of recovery of oxygen-reduced air flooding is higher than that of nitrogen flooding for all scales of pore throat,and the air/oxygen-reduced air flooding de-velopment should be preferred.展开更多
The mechanisms of oxygen-reduced air flooding(ORAF)and the explosion limit and the corrosion control approaches were studied based on the pilots of oxygen-reduced air flooding(ORAF)in the Dagang,Changqing and Daqing o...The mechanisms of oxygen-reduced air flooding(ORAF)and the explosion limit and the corrosion control approaches were studied based on the pilots of oxygen-reduced air flooding(ORAF)in the Dagang,Changqing and Daqing oil fields in China.On the foundation of indoor investigations and pilots,the explosion limits,oxygen reduction limits and corrosion control approaches were clarified.When the temperature of reservoir is equal to and higher than 120℃,there is a violent reaction between oxygen and crude oil,that means the effect of low temperature oxidation would be fully taken use of to enhance oil recovery by air flooding directly;nitrogen dominated immiscible flooding with oxygen-reduced air should be applied in cases where reservoir temperature is below 120℃ with little oxygen consumption and little heat generated.The oxygen-reduced air flooding is suitable for 3 types of reservoirs:low permeability reservoir,water flooding development reservoir of high water-cut and high temperature and high salinity reservoir.In the process of development,in order to ensure safety,the oxygen reduction limits should be controlled fewer than 10%,while oxygen-reduced air can obviously reduce the corrosion rate of pipes;The surface pipelines and injection wells don’t need to consider about oxygen corrosion with no water,special materials and structure of pipe or corrosion inhibitor can be applied to the surface pipelines and injection wellbores with water.Air/oxygen-reduced air is a low-cost displacement medium and it could be applied in many special conditions of low permeability reservoir for energy supplement,huff and puff and displacement,that means oxygen-reduced air flooding has become the most potential strategic technology in 20 years.展开更多
The adjustment of the gas drainage rate has an immediate impact on air leakage in gob,thus resulting in the change of self-heating of coal.While regulating the gas drainage parameters,the risk of spontaneous combustio...The adjustment of the gas drainage rate has an immediate impact on air leakage in gob,thus resulting in the change of self-heating of coal.While regulating the gas drainage parameters,the risk of spontaneous combustion of coal should be considered.The risk assessment of gas control and spontaneous combustion of coal under gas drainage in a tunnel was investigated at different gas drainage rates.The distributions of the air volume along the working face,the gas management effects and the width of the oxidation zone were subjected to risk analysis.As the simulation results showed,with increasing gas drainage rate,although the safety of gas dilution by ventilation was assured,the intensifying air leakage caused the oxidation zone to move into the deeper gob and led to an increase in the width of the oxidation zone.A risk assessment method was proposed to determine a suitable gas drainage rate for the upper tunnel.The correctness of the risk assessment and the validity of the numerical modelling were confirmed by the field measurements.展开更多
基金Supported by the National Science and Technology Major Project(ZX20170054)
文摘The effects of gravity,capillary force,and viscous force on the migration characteristics of oil and gas interface in oxygen-reduced air-assisted gravity drainage(OAGD)were studied through a two-dimensional visualization model.The effects of bond number,capillary number and low-temperature oxidation on OAGD recovery were studied by long core displacement experiments.On this basis,the low-temperature oxidation number was introduced and its relationship with the OAGD recovery was established.The results show that the shape and changing law of oil and gas front are mainly influenced by gravity,capillary force and viscous force.When the bond number is constant(4.52×10-4),the shape of oil-gas front is controlled by capillary number.When the capillary number is less than 1.68×10-3,the oil and gas interface is stable.When the capillary number is greater than 2.69×10-2,the oil and gas interface shows viscous fingering.When the capillary number is between 1.68×10-3 and 2.69×10-2,the oil and gas interface becomes capillary fingering.The core flooding experiments results show that for OAGD stable flooding,before the gas breakthrough,higher recovery is obtained in higher gravity number and lower capillary number.In this stage,gravity is predominant in controlling OAGD recovery and the oil recovery could be improved by reducing injection velocity.After gas breakthrough,higher recovery was obtained in lower gravity and higher capillary numbers,which means that the viscous force had a significant influence on the recovery.Increasing gas injection velocity in this stage is an effective measure to improve oil recovery.The low-temperature oxidation number has a good correlation with the recovery and can be used to predict the OAGD recovery.
基金Major national science and technology projects“Key Techniques for the Development of Low Abundance Tight Low Permeability Reservoirs”(2016ZX05048).
文摘Oxygen-reducing air flooding is a low-permeability reservoir recovery technology with safety and low-cost advantages.However,in the process of air injection and drive,carbon in the air is oxidized through the crude oil reservoir to generate CO_(2),and this can cause serious corrosion in the recovery well.In this study,experiments on the corrosion of J55 tubular steel in a fluid environment with coexisting O_(2)and CO_(2)in an autoclave are presented.In particular,a weight loss method and a 3D morphometer were used to determine the average and the local corrosion rate.The corrosion surface morphology and composition were also measured by means of scanning electron microscopy(SEM)and an X-ray diffractometer(XRD).The corrosion pattern and morphological characteristics of J55 steel were analyzed in the O2/CO_(2)environment for different degrees of oxygen-reduction.As made evident by the experimental results,the corrosion products were mainly ferrous carbonate and iron oxide.In general,air injection increases the degree of oxygen reduction,from oxygen corrosion characteristics to CO_(2)corrosion-based characteristics.As a result,the corrosion product film becomes denser,and the corrosion rate is lower.
基金Project supported by the National Natural Science Foundation of China (No. 10972212)
文摘It is necessary to understand the features of air pressure in a drainage stack of a high-rise building for properly designing and operating a drainage system. This paper presents a mathematical model for predicting the stack performance. A step function is used to describe the effect of the air entrainment caused by the water discharged from branch pipes. An additional source term is introduced to reflect the gas-liquid interphase interaction (GLII) and stack base effect. The drainage stack is divided into upper and base parts. The air pressure in the upper part is predicted by a total variation diminishing (TVD) scheme, while in the base part, it is predicted by a characteristic line method (CLM). The predicted results are compared with the data measured in a real-scale high- rise test building. It is found that the additional source term in the present model is effective. It intensively influences the air pressure distribution in the stack. The air pressure is also sensitive to the velocity-adjusting parameter (VAP), the branch pipe air entrainment, and the conditions on the stack bottom.
文摘Light crude oil from the lower member of the Paleogene Xiaganchaigou Formation of Gaskule in Qinghai Oilfield was selected to carry out thermal kinetic analysis experiments and calculate the activation energy during the oil oxidation process.The oxidation process of crude oi l in porous medium was modeled by crude oil static oxidation experiment,and the component changes of crude oil before and after low-temperature oxidation were compared through Fourier transform ion cy-clotron resonance mass spectrometry and gas chromatography;the dynamic displacement experiment of oxygen-reduced air was combined with NMR technology to analyze the oil recovery degree of oxygen-reduced air flooding.The whole process of crude oil oxidation can be divided into four stages:light hydrocarbon volatilization,low-temperature oxidation,fuel deposition,and high temperature oxidation;the high temperature oxidation stage needs the highest activation energy,followed by the fuel deposition stage,and the low-temperature oxidation stage needs the lowest activation energy;the concentration of oxygen in the reaction is negatively correlated with the activation energy required for the reaction;the higher the oxygen concentration,the lower the average activation energy required for oxidation reaction is;the low-temperature oxidation reaction between crude oil and air generates a large amount of heat and CO,CO_(2) and CH4,forming flue gas drive in the reservoir,which has certain effects of mixing phases,reducing viscosity,lowering interfacial tension and promoting expansion of crude oil,and thus helps enhance the oil recovery rate.Under suitable reservoir temperature condition,the degree of recovery of oxygen-reduced air flooding is higher than that of nitrogen flooding for all scales of pore throat,and the air/oxygen-reduced air flooding de-velopment should be preferred.
文摘The mechanisms of oxygen-reduced air flooding(ORAF)and the explosion limit and the corrosion control approaches were studied based on the pilots of oxygen-reduced air flooding(ORAF)in the Dagang,Changqing and Daqing oil fields in China.On the foundation of indoor investigations and pilots,the explosion limits,oxygen reduction limits and corrosion control approaches were clarified.When the temperature of reservoir is equal to and higher than 120℃,there is a violent reaction between oxygen and crude oil,that means the effect of low temperature oxidation would be fully taken use of to enhance oil recovery by air flooding directly;nitrogen dominated immiscible flooding with oxygen-reduced air should be applied in cases where reservoir temperature is below 120℃ with little oxygen consumption and little heat generated.The oxygen-reduced air flooding is suitable for 3 types of reservoirs:low permeability reservoir,water flooding development reservoir of high water-cut and high temperature and high salinity reservoir.In the process of development,in order to ensure safety,the oxygen reduction limits should be controlled fewer than 10%,while oxygen-reduced air can obviously reduce the corrosion rate of pipes;The surface pipelines and injection wells don’t need to consider about oxygen corrosion with no water,special materials and structure of pipe or corrosion inhibitor can be applied to the surface pipelines and injection wellbores with water.Air/oxygen-reduced air is a low-cost displacement medium and it could be applied in many special conditions of low permeability reservoir for energy supplement,huff and puff and displacement,that means oxygen-reduced air flooding has become the most potential strategic technology in 20 years.
基金financially sponsored by the National Natural Science Foundation of China (Nos. 51774114 and 51404090)
文摘The adjustment of the gas drainage rate has an immediate impact on air leakage in gob,thus resulting in the change of self-heating of coal.While regulating the gas drainage parameters,the risk of spontaneous combustion of coal should be considered.The risk assessment of gas control and spontaneous combustion of coal under gas drainage in a tunnel was investigated at different gas drainage rates.The distributions of the air volume along the working face,the gas management effects and the width of the oxidation zone were subjected to risk analysis.As the simulation results showed,with increasing gas drainage rate,although the safety of gas dilution by ventilation was assured,the intensifying air leakage caused the oxidation zone to move into the deeper gob and led to an increase in the width of the oxidation zone.A risk assessment method was proposed to determine a suitable gas drainage rate for the upper tunnel.The correctness of the risk assessment and the validity of the numerical modelling were confirmed by the field measurements.