Objective To investigate reductive dechlorination of 4-chlorophenol （4-CP） by nanoscale Fe^0 under different conditions. Methods Nanoscale Fe^0 was synthesized by using reductive method. 4-CP and its intermediate pr...Objective To investigate reductive dechlorination of 4-chlorophenol （4-CP） by nanoscale Fe^0 under different conditions. Methods Nanoscale Fe^0 was synthesized by using reductive method. 4-CP and its intermediate products were analyzed by HPLC. Chlorine ion was quantified with DX-100 ion chromatograph. Nano-iron particles were observed under a FEI Quanta 200 FEG environmental scanning electron microscope （ESEM）. Results The size of the particles was in the range of 10-100 nm. The nano-iron particles could reduce 4-CP effectively. The initial concentration of 4-CP increased with the decrease of the relative degradation rate, whereas the reduced amount of 4-CP increased. Temperature could influence both the dechlorination rate and the reaction pathway. Moreover, the stability and durability of nanoscale Fe^0 was evaluated through batch studies over extended periods of time. Conclusion The nanoscale Fe^0 can be used for sustainable treatment of contaminants in groundwater.展开更多
This paper reported the degradation of 4-CP wastewater by a novel photocatalysis oxidation system--UV/Fe2+/air system, in which air was used as a cheap oxidant that reacted with the excitation state of organics to for...This paper reported the degradation of 4-CP wastewater by a novel photocatalysis oxidation system--UV/Fe2+/air system, in which air was used as a cheap oxidant that reacted with the excitation state of organics to form H2O2 under the UV light. The formed H2O2 reacted with the added ferrous ion to form Fenton reaction and led to the quick degradation of organic pollutants. It was found that 4-CP could be completely removed within 40 min. The deg-radation of 4-CP in the UV/Fe2+/air system was superior to the conventional UV/Fenton system (the initial concentration of H2O2 was 22 mg?L<sup>-1). UV/Fe2+/air is an effective and cheap method for treatment of the organics that can be excited by UV light.展开更多
基金The work was supported by the National Natural Science Foundation of China (Grant No. 50325824 50678089).
文摘Objective To investigate reductive dechlorination of 4-chlorophenol （4-CP） by nanoscale Fe^0 under different conditions. Methods Nanoscale Fe^0 was synthesized by using reductive method. 4-CP and its intermediate products were analyzed by HPLC. Chlorine ion was quantified with DX-100 ion chromatograph. Nano-iron particles were observed under a FEI Quanta 200 FEG environmental scanning electron microscope （ESEM）. Results The size of the particles was in the range of 10-100 nm. The nano-iron particles could reduce 4-CP effectively. The initial concentration of 4-CP increased with the decrease of the relative degradation rate, whereas the reduced amount of 4-CP increased. Temperature could influence both the dechlorination rate and the reaction pathway. Moreover, the stability and durability of nanoscale Fe^0 was evaluated through batch studies over extended periods of time. Conclusion The nanoscale Fe^0 can be used for sustainable treatment of contaminants in groundwater.
基金supported by the National Natural Science Foundation of China(Grant No.20176053).
文摘This paper reported the degradation of 4-CP wastewater by a novel photocatalysis oxidation system--UV/Fe2+/air system, in which air was used as a cheap oxidant that reacted with the excitation state of organics to form H2O2 under the UV light. The formed H2O2 reacted with the added ferrous ion to form Fenton reaction and led to the quick degradation of organic pollutants. It was found that 4-CP could be completely removed within 40 min. The deg-radation of 4-CP in the UV/Fe2+/air system was superior to the conventional UV/Fenton system (the initial concentration of H2O2 was 22 mg?L<sup>-1). UV/Fe2+/air is an effective and cheap method for treatment of the organics that can be excited by UV light.
