The transfer kinetics of phenol between aqueous phase and N,N di(methyl heptyl) acetaminde (N503) in kerosene has been studied using Lewis cell technique. The effects of the factors including the concentrations of p...The transfer kinetics of phenol between aqueous phase and N,N di(methyl heptyl) acetaminde (N503) in kerosene has been studied using Lewis cell technique. The effects of the factors including the concentrations of phenol in aqueous phase and organic phase, the concentration of N503 in organic phase, the acidity of aqueous phase, the stirring speed and the temperature on the rates of forward and backward extraction of phenol have been examined. The regularity of extraction rate has been obtained. According to experimental results, the rates of both forward and backward extraction of phenol might be controlled by diffusion process. The diffusion step of phenol from aqueous phase to interface for forward extraction and from interface to aqueous phase for backward extraction might be the rate controlling steps.展开更多
A novel lanthanum（III） complex, [LaL2（NO3）3].H2O （1） based on L （L = N-（na- phthalene-l-yl）-2-（quinolin-8-yloxy）acetamide）, was synthesized and characterized by X-ray diffraction. The crystal of I belongs ...A novel lanthanum（III） complex, [LaL2（NO3）3].H2O （1） based on L （L = N-（na- phthalene-l-yl）-2-（quinolin-8-yloxy）acetamide）, was synthesized and characterized by X-ray diffraction. The crystal of I belongs to the monoclinic system, space group C2c with Mr= 1017.69, a = 25.1438（17）, b = 13.5950（9）, c = 18.2349（12） A, β= 132.4980（10）° V= 4595.8（5） A3, Z= 4, Dc = 1.471 Mg/m3, F（000） = 2056,μ= 1.004 mm-1, R = 0,0588 and wR = 0.1402. The central La（lI1） ion is coordinated to four oxygen atoms, two nitrogen atoms from two independent acetarnide ligands and six oxygen atoms from three nitrate anions, possessing a distorted icosahedron coordination geometry. In the crystal of 1, intermolecular N-H……O hydrogen bonds linked the molecules into chains along the c axis. In solid state and CH3CN solution, complex 1 exhibits stronger fluorescent emission than the ligand L.展开更多
The kinetics of La-Co alloy film in acetamide-urea-NaBr molten salt electrolyte at 353K was investigated. It is shown that the reduction of Co(Ⅱ) to Co is irreversible reaction with the transfer coefficient of 0.28...The kinetics of La-Co alloy film in acetamide-urea-NaBr molten salt electrolyte at 353K was investigated. It is shown that the reduction of Co(Ⅱ) to Co is irreversible reaction with the transfer coefficient of 0.28 and the diffusion coefficient of 7.46×10 -5 cm 2/s. While La(Ⅲ) cannot be reduced to La directly; but can be codeposited with cobalt. The content of La in the uncrystallized La-Co alloy film increases with increasing cathodic overpotential, molar ratio of La 3+ to Co 2+ and electrolysis time as well, and reaches the maximum of 66.32%.展开更多
The reduction of Ni(Ⅱ) is an irreversible reaction and La(Ⅲ) cannot be reduced to La directly but be co-deposited inductively in the present of Ni(Ⅱ) in the Acetamide-Urea-NaBr molten salt electrolyte at 353 K. The...The reduction of Ni(Ⅱ) is an irreversible reaction and La(Ⅲ) cannot be reduced to La directly but be co-deposited inductively in the present of Ni(Ⅱ) in the Acetamide-Urea-NaBr molten salt electrolyte at 353 K. The uncrystallized alloy film of La-Ni is obtained by potentiostatic electrolysis, and the amount of La grows with increasing cathodic overpotential, molar ratios of La(Ⅲ) to Ni(Ⅱ) and the electrolysis time. The maximum amount of La in alloy film reaches to 78.81% (mass fraction) in present study.展开更多
New 3 -oxo-benzoisothiazoline-2-acetamide 1, 1-dioxides (IIa-b) ware synthesizedand whose reaction with alkoxides was studied. The reaction results indicated that differentproducts were obtained owing to the different...New 3 -oxo-benzoisothiazoline-2-acetamide 1, 1-dioxides (IIa-b) ware synthesizedand whose reaction with alkoxides was studied. The reaction results indicated that differentproducts were obtained owing to the different time of reaction with alkoxides展开更多
The polymerization of acrylamide (AAM)in H_2O/DMF or in H_2O/CH_3CN mixed solvent initiated with ceric ion (Ce^(4+) )/N-(substituted phenyl)-acetamide systems have been studied. The redox polymerization was revealed b...The polymerization of acrylamide (AAM)in H_2O/DMF or in H_2O/CH_3CN mixed solvent initiated with ceric ion (Ce^(4+) )/N-(substituted phenyl)-acetamide systems have been studied. The redox polymerization was revealed by the low value of overall activation energy (E_α) of AAM polymerization using ceric ion/N-(substituted phenyl) acetamide system as an initiator. The end group of polymer formed was detected by IR spectrum analysis method, it revealed the presence of N-(m-acetoxy-methylphenyl) acetamide (m-AAe) moiety end group in the polymer obtained with ceric ion/m-AAe initiation system.展开更多
Acetylation and benzoylation reactions of certain aromatic aldehydes, ketones with Vilsmeier-Haack Re- agents using Acetamide and Oxychloride (SOCl2 or POCl3) under conventional (thermal) and non conven- tional [micro...Acetylation and benzoylation reactions of certain aromatic aldehydes, ketones with Vilsmeier-Haack Re- agents using Acetamide and Oxychloride (SOCl2 or POCl3) under conventional (thermal) and non conven- tional [microwave irradiated (MIR), ultrasonic assisted and solvent free mortar pestle (grinding)] conditions. Reactions afforded good to excellent yields of products with both the VH reagents, reaction times were fairly less in the case of [amide/POCl3] than those of [amide/SOCl2] reagent. Reactions are dramatically acceler- ated in under sonicated and microwave irradiations with a trend: MIR (few seconds) >> Sonication (minutes) > Grinding (min) >> thermal (several hrs).展开更多
2-hydroxy N methyl N phenyl acetamide was synthesized by using N methylaniline, chloracetyl chloride, anhydrous sodium acetate and methanol through the acetylation, esterfication and ester interchange steps. The acety...2-hydroxy N methyl N phenyl acetamide was synthesized by using N methylaniline, chloracetyl chloride, anhydrous sodium acetate and methanol through the acetylation, esterfication and ester interchange steps. The acetylation of N methylaniline with chloracetyl chloride, catalyzed by triethylamide with mole ratio n (C 6H 5NHCH 3)∶ n (ClCH 2C(O)Cl)∶ n (N(C 2H 5) 3)=1∶1.05∶1, the yield of 2 chloro N methyl N phenyl acetamide(Ⅰ) was 93.8%; Then the esterification of Ⅰ with anhydrous sodium acetate in the presence of phase transfer catalyst tetrabutyl ammonia bromide gave 97.3% yield of 2 acetoxyl N methyl N phenyl acetamide (Ⅱ); The ester interchange of with methanol catalyzed by potassium hydroxide gave 2 hydroxy N methyl N phenyl acetamide (Ⅲ) in 96.4% yield. And the total yield was 88.0%. IR and MS spectroscopy of products were analyzed and their characteristic peaks were assigned. Combining the results of elemental analysis, the molecular structure of Ⅰ, Ⅱ and Ⅲ was identified.展开更多
Electroreduction of Co(Ⅱ) to metallic Co in acetamide-urea-NaBr melt at 353 K is irreversible in one step. Gd(Ⅲ) is not reduced to Gd alone, but can be inductively codeposited with Co(Ⅱ). The amorphous Gd-Co alloy ...Electroreduction of Co(Ⅱ) to metallic Co in acetamide-urea-NaBr melt at 353 K is irreversible in one step. Gd(Ⅲ) is not reduced to Gd alone, but can be inductively codeposited with Co(Ⅱ). The amorphous Gd-Co alloy films were obtained by potentiostatic electrolysis. With the cathode potential shifting to negative direction, the content of gadolinium in the alloy increases and can get to 65.89% (mass fraction). The additive of Na 2EDTA can make the diameter of the particles of crystalline alloy smaller and change the shape of particles.展开更多
Indole-3-acetic acid (IAA) a phytohormon of auxin type is synthesized by different ways in plants and some bacteria (Agrobacteria, Pseudomonas and some others). The enzyme indolylacetamide hydrolase transforms indolyl...Indole-3-acetic acid (IAA) a phytohormon of auxin type is synthesized by different ways in plants and some bacteria (Agrobacteria, Pseudomonas and some others). The enzyme indolylacetamide hydrolase transforms indolylacetamide to IAA mainly in bacteria. However, recently published data showed that some plants can also hydrolyze indolylacetamide into IAA. In order to elucidate the role of indolylacetamide as an auxin precursor in plants and bacteria, productive method of determination of the activity of indoleacetamide hydrolase is necessary. The simple, inexpensive and productive method for the measurement of indoleacetamide hydrolase activity was elaborated based on significant difference between IAAM and IAA in color developed with Salkovski’ reagent. The light absorbance increased during conversion of IAAM to IAA by protein extracts from some plant cells and this increase may be used for quantitative estimation of indoleacetamide hydrolase activity. The method is suitable for fast discovery of indoleacetamide hydrolase activity before planning more complicated analyses and for the analysis of many probes at a short time in physiological and biochemical experiments. A detailed protocol for determination of indoleacetamide hydrolase activity by the elaborated method is described.展开更多
文摘The transfer kinetics of phenol between aqueous phase and N,N di(methyl heptyl) acetaminde (N503) in kerosene has been studied using Lewis cell technique. The effects of the factors including the concentrations of phenol in aqueous phase and organic phase, the concentration of N503 in organic phase, the acidity of aqueous phase, the stirring speed and the temperature on the rates of forward and backward extraction of phenol have been examined. The regularity of extraction rate has been obtained. According to experimental results, the rates of both forward and backward extraction of phenol might be controlled by diffusion process. The diffusion step of phenol from aqueous phase to interface for forward extraction and from interface to aqueous phase for backward extraction might be the rate controlling steps.
基金supported by the National Natural Science Foundation of China(21001040)Education Department of Henan Province(No.12B150011 and 14B150029)
文摘A novel lanthanum（III） complex, [LaL2（NO3）3].H2O （1） based on L （L = N-（na- phthalene-l-yl）-2-（quinolin-8-yloxy）acetamide）, was synthesized and characterized by X-ray diffraction. The crystal of I belongs to the monoclinic system, space group C2c with Mr= 1017.69, a = 25.1438（17）, b = 13.5950（9）, c = 18.2349（12） A, β= 132.4980（10）° V= 4595.8（5） A3, Z= 4, Dc = 1.471 Mg/m3, F（000） = 2056,μ= 1.004 mm-1, R = 0,0588 and wR = 0.1402. The central La（lI1） ion is coordinated to four oxygen atoms, two nitrogen atoms from two independent acetarnide ligands and six oxygen atoms from three nitrate anions, possessing a distorted icosahedron coordination geometry. In the crystal of 1, intermolecular N-H……O hydrogen bonds linked the molecules into chains along the c axis. In solid state and CH3CN solution, complex 1 exhibits stronger fluorescent emission than the ligand L.
文摘The kinetics of La-Co alloy film in acetamide-urea-NaBr molten salt electrolyte at 353K was investigated. It is shown that the reduction of Co(Ⅱ) to Co is irreversible reaction with the transfer coefficient of 0.28 and the diffusion coefficient of 7.46×10 -5 cm 2/s. While La(Ⅲ) cannot be reduced to La directly; but can be codeposited with cobalt. The content of La in the uncrystallized La-Co alloy film increases with increasing cathodic overpotential, molar ratio of La 3+ to Co 2+ and electrolysis time as well, and reaches the maximum of 66.32%.
文摘The reduction of Ni(Ⅱ) is an irreversible reaction and La(Ⅲ) cannot be reduced to La directly but be co-deposited inductively in the present of Ni(Ⅱ) in the Acetamide-Urea-NaBr molten salt electrolyte at 353 K. The uncrystallized alloy film of La-Ni is obtained by potentiostatic electrolysis, and the amount of La grows with increasing cathodic overpotential, molar ratios of La(Ⅲ) to Ni(Ⅱ) and the electrolysis time. The maximum amount of La in alloy film reaches to 78.81% (mass fraction) in present study.
文摘New 3 -oxo-benzoisothiazoline-2-acetamide 1, 1-dioxides (IIa-b) ware synthesizedand whose reaction with alkoxides was studied. The reaction results indicated that differentproducts were obtained owing to the different time of reaction with alkoxides
基金The project supported by the National Natural Science Foundation of China
文摘The polymerization of acrylamide (AAM)in H_2O/DMF or in H_2O/CH_3CN mixed solvent initiated with ceric ion (Ce^(4+) )/N-(substituted phenyl)-acetamide systems have been studied. The redox polymerization was revealed by the low value of overall activation energy (E_α) of AAM polymerization using ceric ion/N-(substituted phenyl) acetamide system as an initiator. The end group of polymer formed was detected by IR spectrum analysis method, it revealed the presence of N-(m-acetoxy-methylphenyl) acetamide (m-AAe) moiety end group in the polymer obtained with ceric ion/m-AAe initiation system.
文摘Acetylation and benzoylation reactions of certain aromatic aldehydes, ketones with Vilsmeier-Haack Re- agents using Acetamide and Oxychloride (SOCl2 or POCl3) under conventional (thermal) and non conven- tional [microwave irradiated (MIR), ultrasonic assisted and solvent free mortar pestle (grinding)] conditions. Reactions afforded good to excellent yields of products with both the VH reagents, reaction times were fairly less in the case of [amide/POCl3] than those of [amide/SOCl2] reagent. Reactions are dramatically acceler- ated in under sonicated and microwave irradiations with a trend: MIR (few seconds) >> Sonication (minutes) > Grinding (min) >> thermal (several hrs).
文摘2-hydroxy N methyl N phenyl acetamide was synthesized by using N methylaniline, chloracetyl chloride, anhydrous sodium acetate and methanol through the acetylation, esterfication and ester interchange steps. The acetylation of N methylaniline with chloracetyl chloride, catalyzed by triethylamide with mole ratio n (C 6H 5NHCH 3)∶ n (ClCH 2C(O)Cl)∶ n (N(C 2H 5) 3)=1∶1.05∶1, the yield of 2 chloro N methyl N phenyl acetamide(Ⅰ) was 93.8%; Then the esterification of Ⅰ with anhydrous sodium acetate in the presence of phase transfer catalyst tetrabutyl ammonia bromide gave 97.3% yield of 2 acetoxyl N methyl N phenyl acetamide (Ⅱ); The ester interchange of with methanol catalyzed by potassium hydroxide gave 2 hydroxy N methyl N phenyl acetamide (Ⅲ) in 96.4% yield. And the total yield was 88.0%. IR and MS spectroscopy of products were analyzed and their characteristic peaks were assigned. Combining the results of elemental analysis, the molecular structure of Ⅰ, Ⅱ and Ⅲ was identified.
文摘Electroreduction of Co(Ⅱ) to metallic Co in acetamide-urea-NaBr melt at 353 K is irreversible in one step. Gd(Ⅲ) is not reduced to Gd alone, but can be inductively codeposited with Co(Ⅱ). The amorphous Gd-Co alloy films were obtained by potentiostatic electrolysis. With the cathode potential shifting to negative direction, the content of gadolinium in the alloy increases and can get to 65.89% (mass fraction). The additive of Na 2EDTA can make the diameter of the particles of crystalline alloy smaller and change the shape of particles.
文摘Indole-3-acetic acid (IAA) a phytohormon of auxin type is synthesized by different ways in plants and some bacteria (Agrobacteria, Pseudomonas and some others). The enzyme indolylacetamide hydrolase transforms indolylacetamide to IAA mainly in bacteria. However, recently published data showed that some plants can also hydrolyze indolylacetamide into IAA. In order to elucidate the role of indolylacetamide as an auxin precursor in plants and bacteria, productive method of determination of the activity of indoleacetamide hydrolase is necessary. The simple, inexpensive and productive method for the measurement of indoleacetamide hydrolase activity was elaborated based on significant difference between IAAM and IAA in color developed with Salkovski’ reagent. The light absorbance increased during conversion of IAAM to IAA by protein extracts from some plant cells and this increase may be used for quantitative estimation of indoleacetamide hydrolase activity. The method is suitable for fast discovery of indoleacetamide hydrolase activity before planning more complicated analyses and for the analysis of many probes at a short time in physiological and biochemical experiments. A detailed protocol for determination of indoleacetamide hydrolase activity by the elaborated method is described.
