In the present work, the exchangeable acidity of a red soilcolloid and a latosol colloid at different pH during reacting withfour neutral salts was measured. The results show that theexchangeable acidity increased wit...In the present work, the exchangeable acidity of a red soilcolloid and a latosol colloid at different pH during reacting withfour neutral salts was measured. The results show that theexchangeable acidity increased with increasing amounts of the neutralsalts added, and the relation between them was almost linear. Whenthe amount of the neutral salt added was lower than a certain value,the slop of the line was high, and the slop turned low when theamount exceeded that value, so there was a turning point in eachline. The addition amounts of the neutral salts for the turningpoints were affected by the cation species of the neutral salts, butpH had less effect on them. After the turning points occurred, theexchangeable acidity of the red soil colloid still graduallyincreased with the addition amounts of the neutral salts, but that ofthe latosol colloid did not increase any more.展开更多
New liquid-liquid equilibrium data for polyethylene glycol （PEG） 3000 ＋ CHO2K ＋ H20 systems were measured at 298.15 K and pH values of 7.95, 8.40 and 9.98. It was found that an increase in pH caused the binodal cu...New liquid-liquid equilibrium data for polyethylene glycol （PEG） 3000 ＋ CHO2K ＋ H20 systems were measured at 298.15 K and pH values of 7.95, 8.40 and 9.98. It was found that an increase in pH caused the binodal curve to be displaced downward and the two-phase region to expand. Accordingly, the binodal curve was adjusted to the Pirdashti equation and the tie-line compositions were correlated using the Othmer-Tobias, Bancroft and Hand equations. The study measured the refractive index and densities of several homogeneous binary and ternary solutions. The solutions were used for calibration within a range of 0% to 30% of the mass of the PEG and potassium formate. The density and refractive index data show a linear variation with the mass fraction of the polymer and the salt. The effect of pH on the binodal, tie-line lengths （TLL） and slope of the tie-line （STL） in the systems was exam- ined. It was found that an increase in pH increased the TLL and decreased the STL It was observed that the density of the aqueous two-phase system was influenced by the TLL The difference in density between phases （△p） increased as the TLL and pH increased. It was found that the TLL and Ap showed a linear relationship. The effective excluded volume （EEV） of the PEG was obtained and it was found that EEV also increased as the pH increased.展开更多
基金Project (Nos. 49971046 and 49831005) supported by the National Natural Science Foundation of China.
文摘In the present work, the exchangeable acidity of a red soilcolloid and a latosol colloid at different pH during reacting withfour neutral salts was measured. The results show that theexchangeable acidity increased with increasing amounts of the neutralsalts added, and the relation between them was almost linear. Whenthe amount of the neutral salt added was lower than a certain value,the slop of the line was high, and the slop turned low when theamount exceeded that value, so there was a turning point in eachline. The addition amounts of the neutral salts for the turningpoints were affected by the cation species of the neutral salts, butpH had less effect on them. After the turning points occurred, theexchangeable acidity of the red soil colloid still graduallyincreased with the addition amounts of the neutral salts, but that ofthe latosol colloid did not increase any more.
文摘New liquid-liquid equilibrium data for polyethylene glycol （PEG） 3000 ＋ CHO2K ＋ H20 systems were measured at 298.15 K and pH values of 7.95, 8.40 and 9.98. It was found that an increase in pH caused the binodal curve to be displaced downward and the two-phase region to expand. Accordingly, the binodal curve was adjusted to the Pirdashti equation and the tie-line compositions were correlated using the Othmer-Tobias, Bancroft and Hand equations. The study measured the refractive index and densities of several homogeneous binary and ternary solutions. The solutions were used for calibration within a range of 0% to 30% of the mass of the PEG and potassium formate. The density and refractive index data show a linear variation with the mass fraction of the polymer and the salt. The effect of pH on the binodal, tie-line lengths （TLL） and slope of the tie-line （STL） in the systems was exam- ined. It was found that an increase in pH increased the TLL and decreased the STL It was observed that the density of the aqueous two-phase system was influenced by the TLL The difference in density between phases （△p） increased as the TLL and pH increased. It was found that the TLL and Ap showed a linear relationship. The effective excluded volume （EEV） of the PEG was obtained and it was found that EEV also increased as the pH increased.
