A new solvent polymeric membrane (SPM)pH2sensor based on 4,4'-bis (N, N-didecylamino)methyl)azobenzene as neutral carricr has been reported. It has excellent pH response characteristics with the linear response ra...A new solvent polymeric membrane (SPM)pH2sensor based on 4,4'-bis (N, N-didecylamino)methyl)azobenzene as neutral carricr has been reported. It has excellent pH response characteristics with the linear response range (1.7—13.2)much wider than that of similar SPM pH sensors reported so far. The sensor has a theoretical Nernstian response of 57.4+0.2V/pH(at 20℃)without super—Nernstian response phenomenon.展开更多
A membrane with high stability and ion conductivity in wide pH range is essential for energy storage devices.Here,we report a novel membrane with hierarchical core-shell structure,which demonstrates high stability and...A membrane with high stability and ion conductivity in wide pH range is essential for energy storage devices.Here,we report a novel membrane with hierarchical core-shell structure,which demonstrates high stability and ion conductivity,simultaneously under a wide pH range applications.Spectral characterizations and theoretical calculation indicate that the non-solvent induces the chain segment configuration and eventually leads to polymer-polymer phase separation,thus forming hierarchical porous core-shell structure.Benefiting from this structure,an acidic vanadium flow battery(VFB)with such a membrane shows excellent performance over 400 cycles with an energy efficiency(EE)of above 81%at current density of 120 mA cm^(-2) and an alkaline zinc-iron flow battery(AZIFB)delivers a cycling stability for more than 200 cycles at 160 mA cm^(-2),along with an EE of above 82%.This paper provides a cost-effective and simple way to fabricate membranes with high performance for variety of energyrelated devices.展开更多
Photocatalytic Fenton reactions combined the advantages from both photocatalysis and Fenton reaction in mineralizing organic pollutants. The key problems are the efficiency and recycling stability. Herein, we reported...Photocatalytic Fenton reactions combined the advantages from both photocatalysis and Fenton reaction in mineralizing organic pollutants. The key problems are the efficiency and recycling stability. Herein, we reported a novel Fe_(2)O_(3)/TiO_(2)/reduced graphene oxide(FTG) nanocomposite synthesized by a facile solvothermal method. The TiO_(2)in FTG degraded organic pollutants and mineralized intermediates via photocatalysis under visible light irradiation, which could also promote Fenton reaction by accelerating Fe^(3+)-Fe^(2+)recycle. Meanwhile, the Fe_(2)O_(3)rapidly degraded organic pollutants via Fenton reactions, which also promoted photocatalysis by enhancing visible light absorbance and diminishing photoelectronhole recombination. The high distribution of TiO_(2)and Fe_(2)O_(3)on rGO, together with their strong interaction resulted in enhanced synergetic cooperation between photocatalysis and Fenton reactions, leading to the high mineralization efficiency of organic pollutants. More importantly, it could also inhibit the leaching of Fe species, leading to the long lifetime of FTG during photocatalytic Fenton reactions in a wide pH range from 3.4 to 9.2.展开更多
The aim of this project is to find out the changes that occur in physical properties of denim when it is subjected to enzyme stone and acid wash or to find out the impact of enzyme stone and acid wash. 97% cotton 3% e...The aim of this project is to find out the changes that occur in physical properties of denim when it is subjected to enzyme stone and acid wash or to find out the impact of enzyme stone and acid wash. 97% cotton 3% elastomer twill, weave 3/1, construction 72 × 40/9 × 7 indigo dyed denim fabric leg panels as per lab standard recipe are used here to examine. Firstly, desizing was done as pre-treatments and after treatment was silicon softener. After washing process, different samples from both washing are going to express different behavior on physical properties. This experiment is done to find out the discrimination in tearing strength, shrinkage %, color fastness to wash, color fastness to rubbing, pH rate between stone enzyme wash and acid wash of denim garments.展开更多
It is of vital importance to design efficient and low-cost bifunctional catalysts for the electrochemical water splitting under alkaline and neutral pH conditions.In this work,we report an efficient and stable NiCo_(2...It is of vital importance to design efficient and low-cost bifunctional catalysts for the electrochemical water splitting under alkaline and neutral pH conditions.In this work,we report an efficient and stable NiCo_(2)S_(4)/N,S co-doped reduced graphene oxide(NCS/NS-rGO)electrocatalyst for water splitting,in which NCS microspheres are composed of one-dimentional(1D)nanorods grown homogeneously on the surface of NS-rGOs).The synergetic effect,abundant active sites,and hybridization of NCS/NS-rGO endow their outstanding electrocatalytic performance for hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)in both alkaline and neutral conditions.Furthermore,NCS/NS-rGO employed as both anode and cathode in a two-electrode alkaline and neutral system electrolyzers deliver 10 mA/cm^(2) with the low cell voltage of 1.58 V in alkaline and 1.91 V in neutral condition.These results illustrate the rational design of carbon-supported nickel-cobalt based bifunctional materials for practical water splitting over a wide pH range.展开更多
It is important to develop economical and durable electrocatalysts for sustainable energy conversion technology.However,the current catalysts still suffer from insufficient hydrogen adsorption energy.Herein,we report ...It is important to develop economical and durable electrocatalysts for sustainable energy conversion technology.However,the current catalysts still suffer from insufficient hydrogen adsorption energy.Herein,we report a kind of novel bi-phosphide catalyst through constructing heterogeneous structures and cation doping.The obtained sample delivers an outstanding hydrogen evolution reaction(HER)performance at all pH range.As oxygen evolution reaction(OER)electrocatalyst,Fe-CoP@Ni_(2)P samples show an overpotential of 237 mV at 50 mA·cm^(−2) in alkaline solution.For electrolysis of water,Fe-CoP@Ni_(2)P catalysts deliver a cell voltage of 1.59 V at 50 mA·cm^(−2) and long durability.Furthermore,density functional theory(DFT)calculation further confirms that the doped heterostructure promotes Gibbs free energy for hydrogen adsorption.And the significant increase in the density of total states(DOS)also enhances the catalytic activity of HER.展开更多
基金Project supported by the National Natural Science Foundation of China partially by Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Academia Sinica.
文摘A new solvent polymeric membrane (SPM)pH2sensor based on 4,4'-bis (N, N-didecylamino)methyl)azobenzene as neutral carricr has been reported. It has excellent pH response characteristics with the linear response range (1.7—13.2)much wider than that of similar SPM pH sensors reported so far. The sensor has a theoretical Nernstian response of 57.4+0.2V/pH(at 20℃)without super—Nernstian response phenomenon.
基金the financial support from NSFC(21925804,U1808209 and 21908214)CAS Engineering Laboratory for Electrochemical Energy Storage,CAS,STS program.Major scientific and technological innovation project of Shandong(2018YFJH0106)+1 种基金the CAS(DNL201910)Youth Innovation Promotion Association CAS。
文摘A membrane with high stability and ion conductivity in wide pH range is essential for energy storage devices.Here,we report a novel membrane with hierarchical core-shell structure,which demonstrates high stability and ion conductivity,simultaneously under a wide pH range applications.Spectral characterizations and theoretical calculation indicate that the non-solvent induces the chain segment configuration and eventually leads to polymer-polymer phase separation,thus forming hierarchical porous core-shell structure.Benefiting from this structure,an acidic vanadium flow battery(VFB)with such a membrane shows excellent performance over 400 cycles with an energy efficiency(EE)of above 81%at current density of 120 mA cm^(-2) and an alkaline zinc-iron flow battery(AZIFB)delivers a cycling stability for more than 200 cycles at 160 mA cm^(-2),along with an EE of above 82%.This paper provides a cost-effective and simple way to fabricate membranes with high performance for variety of energyrelated devices.
基金supported by the National Key Research and Development Program of China (No.2020YFA0211004)the National Natural Science Foundation of China (Nos.22176128 and 21876114)+4 种基金the Program of Shanghai Academic Research Leader (No. 21XD1422800)Shanghai Government (Nos. 19DZ1205102 and 19160712900)Chinese Education Ministry Key Laboratory and International Joint Laboratory on Resource Chemistry, and Shanghai Eastern Scholar Program, “111 Innovation and Talent Recruitment Base on Photochemical and Energy Materials” (No. D18020)Shanghai Engineering Research Center of Green Energy Chemical Engineering (No. 18DZ2254200)Shanghai Frontiers Science Center of Biomimetic Catalysis。
文摘Photocatalytic Fenton reactions combined the advantages from both photocatalysis and Fenton reaction in mineralizing organic pollutants. The key problems are the efficiency and recycling stability. Herein, we reported a novel Fe_(2)O_(3)/TiO_(2)/reduced graphene oxide(FTG) nanocomposite synthesized by a facile solvothermal method. The TiO_(2)in FTG degraded organic pollutants and mineralized intermediates via photocatalysis under visible light irradiation, which could also promote Fenton reaction by accelerating Fe^(3+)-Fe^(2+)recycle. Meanwhile, the Fe_(2)O_(3)rapidly degraded organic pollutants via Fenton reactions, which also promoted photocatalysis by enhancing visible light absorbance and diminishing photoelectronhole recombination. The high distribution of TiO_(2)and Fe_(2)O_(3)on rGO, together with their strong interaction resulted in enhanced synergetic cooperation between photocatalysis and Fenton reactions, leading to the high mineralization efficiency of organic pollutants. More importantly, it could also inhibit the leaching of Fe species, leading to the long lifetime of FTG during photocatalytic Fenton reactions in a wide pH range from 3.4 to 9.2.
文摘The aim of this project is to find out the changes that occur in physical properties of denim when it is subjected to enzyme stone and acid wash or to find out the impact of enzyme stone and acid wash. 97% cotton 3% elastomer twill, weave 3/1, construction 72 × 40/9 × 7 indigo dyed denim fabric leg panels as per lab standard recipe are used here to examine. Firstly, desizing was done as pre-treatments and after treatment was silicon softener. After washing process, different samples from both washing are going to express different behavior on physical properties. This experiment is done to find out the discrimination in tearing strength, shrinkage %, color fastness to wash, color fastness to rubbing, pH rate between stone enzyme wash and acid wash of denim garments.
基金supported by the National Natural Science Foundation of China(Nos.51962032,61704114,and 51764049)the Youth Innovative Talents Cultivation Fund,Shihezi University(No.KX01480109)the Opening Project of The Research Center for Material Chemical Engineering Technology of Xinjiang Bingtuan(No.2017BTRC007).
文摘It is of vital importance to design efficient and low-cost bifunctional catalysts for the electrochemical water splitting under alkaline and neutral pH conditions.In this work,we report an efficient and stable NiCo_(2)S_(4)/N,S co-doped reduced graphene oxide(NCS/NS-rGO)electrocatalyst for water splitting,in which NCS microspheres are composed of one-dimentional(1D)nanorods grown homogeneously on the surface of NS-rGOs).The synergetic effect,abundant active sites,and hybridization of NCS/NS-rGO endow their outstanding electrocatalytic performance for hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)in both alkaline and neutral conditions.Furthermore,NCS/NS-rGO employed as both anode and cathode in a two-electrode alkaline and neutral system electrolyzers deliver 10 mA/cm^(2) with the low cell voltage of 1.58 V in alkaline and 1.91 V in neutral condition.These results illustrate the rational design of carbon-supported nickel-cobalt based bifunctional materials for practical water splitting over a wide pH range.
基金supported by the National Natural Science Foundation of China(No.52172218).
文摘It is important to develop economical and durable electrocatalysts for sustainable energy conversion technology.However,the current catalysts still suffer from insufficient hydrogen adsorption energy.Herein,we report a kind of novel bi-phosphide catalyst through constructing heterogeneous structures and cation doping.The obtained sample delivers an outstanding hydrogen evolution reaction(HER)performance at all pH range.As oxygen evolution reaction(OER)electrocatalyst,Fe-CoP@Ni_(2)P samples show an overpotential of 237 mV at 50 mA·cm^(−2) in alkaline solution.For electrolysis of water,Fe-CoP@Ni_(2)P catalysts deliver a cell voltage of 1.59 V at 50 mA·cm^(−2) and long durability.Furthermore,density functional theory(DFT)calculation further confirms that the doped heterostructure promotes Gibbs free energy for hydrogen adsorption.And the significant increase in the density of total states(DOS)also enhances the catalytic activity of HER.