A comprehensive kinetic model of NO formation during coke combustion in packed-bed in presence of noncombustible particles was developed. The detailed homogeneous gas-phase chemistry (including 102 chemical reactions...A comprehensive kinetic model of NO formation during coke combustion in packed-bed in presence of noncombustible particles was developed. The detailed homogeneous gas-phase chemistry (including 102 chemical reactions), heterogeneous gas-solid chemistry (including 11 reactions) of coke combustion and NO formation, and the heat and mass transfer were taken into account in the present model. The governing equations which are strongly coupled, non-linear and unsteady with 26 unknowns in total, were dispersed into differential equations with the finite differential method. Meanwhile, all the differential equations were numerically solved to give the time-histories and space-distributions oftemperatures of the bed and gas phase as well as the concentrations of all the gaseous species. By comparison, the experimental data were explained well by the calculated results. Based on the kinetic and mathematical model, the effects of O2 content of inlet gas, the initial chemical analysis of coke, bed-temperature and local reductive atmosphere (CO/O2) on NO formation during packed-bed coke combustion were numerically discussed. It was found that coke samples with a higher initial content of [N] and volatile matters, combusted under a suitable O2-containing atmosphere produced less NO emission. The reactions between CO and NO, catalyzed by high temperature surface of coke particles may be responsible for efficient reduction of NO.展开更多
Fractured, very permeable rock hosting repositories for radioactive waste will require grouting. New grout types of possible use where long-term performance is needed should have a small amount of cement for minimizin...Fractured, very permeable rock hosting repositories for radioactive waste will require grouting. New grout types of possible use where long-term performance is needed should have a small amount of cement for minimizing the increase in porosity that will follow from the ultimate dissolution and erosion of this component. They have to be low-viscous and gain strength early after injection and packing theory can assist designers in selecting suitable proportions of various grout components. Optimum particle packing means that the porosity is at minimum and that the amount of cement paste needed to fill the voids between aggregate particles is very small. Low porosity and microstructural stability must be guaranteed for long periods of time. Organic additives for reaching high fluidity cannot be used since they can give off colloids that carry released radionuclides and talc can be an alternative superplasticizer. Low-pH cement reacts with talc to give high strength with time while Portland cement gives early but limited strengthening. The clay mineral palygorskite can be used for early gelation because of its thixotropic properties. Once forced into the rock fractures or channels in soil it stiffens and serves as a filter that prevents fine particles to migrate through it be lost. However, its hydrophilic potential is too high to give the grout a high density and high strength. According to the experiments carried out, most of the investigated grouts are injectable in fractures with apertures down to 100 μm.展开更多
The traditional fixed-bed reactor design is usually not suitable for the low tube-to-particle diameter ratios(N = D/d b 8) where the local phenomena of channeling near the wall and backflow in the bed are dominant. Th...The traditional fixed-bed reactor design is usually not suitable for the low tube-to-particle diameter ratios(N = D/d b 8) where the local phenomena of channeling near the wall and backflow in the bed are dominant. The recent"solid particle" meshing method is too complicated for mesh generation, especially for non-spherical particles in large random packed beds, which seriously hinders its development. In this work, a novel high-fidelity mesh model is proposed for simulation of fixed bed reactors by combining the immersed boundary and adaptive meshing methods. This method is suitable for different shapes of particles, which ingeniously avoids handling the complex "contact point" problem. Several packed beds with two different shapes of particles are investigated with this model, and the local flow in the bed is simulated without geometrical simplification. The predicted pressure drop across the fixed bed and heat transfer of the single particle are in good agreement with the corresponding empirical relations. Compared with spherical particles, the packed bed packing with pentaphyllous particles has lower pressure drop and better heat/mass transfer performance, and it shows that this method can be used for the screening of particle shapes in a fixed bed.展开更多
A phenomenological anisotropic model has been presented for the surface roughness modeling of pack rolling. The model is an assembly of grains in different orientations and sizes. The grain size is assumed to be in lo...A phenomenological anisotropic model has been presented for the surface roughness modeling of pack rolling. The model is an assembly of grains in different orientations and sizes. The grain size is assumed to be in log-normal distribution. To model the macro anisotropic mechanical behavior of the grains induced by the slip deformation, the grains are assumed as isolated anisotropic units. The units have different mechanic behavior, and depend on the crystallographic orientations and the external loading as well as the interaction of the adjunctive grains. In the paper, the material properties of the grains are assumed as uniform distributions. The roughness of the contact surfaces depends on the distribution types and the scatters of the distributions. It is found that the initial roughness of the contact surfaces has a little influence on the surface roughness when the rolling deformation is large. The comparison between the phenomenological model and crystallographic model shows that the phenomenological model can also give out a reasonable result, while it only takes much less CPU time. The agreement between the single sheet model and the pack rolling model shows that in a certain degree the pack rolling model can be replaced by the single sheet model to decrease the CPU time.展开更多
Determination of the critical state line(CSL)is important to characterize engineering properties of granular soils.Grain size distribution(GSD)has a significant influence on the location of CSL.The influence of partic...Determination of the critical state line(CSL)is important to characterize engineering properties of granular soils.Grain size distribution(GSD)has a significant influence on the location of CSL.The influence of particle breakage on the CSL is mainly attributed to the change in GSD due to particle breakage.However,GSD has not been properly considered in modeling the CSL with influence of particle breakage.This study aims to propose a quantitative model to determine the CSL considering the effect of GSD.We hypothesize that the change of critical state void ratio with respect to GSD is caused by the same mechanism that influences of the change of minimum void ratio with respect to GSD.Consequently,the particle packing model for minimum void ratio proposed by Chang et al.(2017)is extended to predict critical state void ratio.The developed model is validated by experimental results of CSLs for several types of granular materials.Then the evolution of GSD due to particle breakage is incorporated into the model.The model is further evaluated using the experimental results on rockfill material,which illustrates the applicability of the model in predicting CSL for granular material with particle breakage.展开更多
The molten liquid flow inside a packed bed is a familiar momentum transportation phenomenon in a blast furnace. With regard to the reported mathematical models describing the liquid flow within a packed bed, there are...The molten liquid flow inside a packed bed is a familiar momentum transportation phenomenon in a blast furnace. With regard to the reported mathematical models describing the liquid flow within a packed bed, there are some obstacles for their application in engineering design, or some limitations in the model itself. To overcome these problems, the forces from the packed bed to the liquid flow were divided into appropriate body and surface forces on the basis of three assumptions. Consequently, a new mathematical model was built to present the liquid flow inside the coke bed in a blast furnace. The mathematical model can predict the distribution of liquid flowrate and the liquid flowing range inside the packed bed at any time. The predicted results of this model accord well with the experimental data. The model will be applied considerably better in the simulation on the ironmaking process compared with the existent models.展开更多
In this study, we carried out model tests to investigate the ice failure process and the resistance experienced by a transport vessel navigating in the Arctic region in pack ice conditions. We tested different navigat...In this study, we carried out model tests to investigate the ice failure process and the resistance experienced by a transport vessel navigating in the Arctic region in pack ice conditions. We tested different navigation velocities, ice plate sizes, and ice concentrations. During the tests, we closely observed several phenomena, including the modes of interaction of the ice ship and the moving and failure modes of ice. We also measured the vessel resistances under different conditions. The test results indicate that the navigation velocity is a significant determinant of the moving and failure modes of ice. Moreover, vessel resistance is remarkably dependent on the ice concentration and navigation velocity. The variances of the mean and maximum resistance are also compared and discussed in detail.展开更多
A mathematical model for the process of removal of aerosols from gases in channels filled with packing is considered. Equations for transport of aerosol particles and results of their numerical solution are given. Inf...A mathematical model for the process of removal of aerosols from gases in channels filled with packing is considered. Equations for transport of aerosol particles and results of their numerical solution are given. Influence of operating conditions and of design characteristics of the packed apparatus on gas purification efficiency is analyzed.展开更多
Thermal Energy Storage is becoming a necessary component of sustainable energy production systems as it helps alleviate intrinsic limitations of Renewable Energy Sources, such as intermittent use and mismatch between ...Thermal Energy Storage is becoming a necessary component of sustainable energy production systems as it helps alleviate intrinsic limitations of Renewable Energy Sources, such as intermittent use and mismatch between power demand and supply. This paper discusses a packed bed thermocline tank as a thermal energy storage solution. Firstly, this paper presents the development of a numerical model calculating heat transfers within the tank, based on a discretization over several nodes and the nodal formulation of the heat balance equation. The model considers a filler material and a heat transferring fluid and uses the finite difference method to calculate the temperature evolution of the two media across the tank. The model was validated with two different packed bed systems from the literature during a discharging process, presenting a good fit with the experimental results. Secondly, the experimental packed bed is presented and characterized for a charging cycle from ambient temperature to approximately 180?C. The charging experiment was accurately reproduced with the numerical model requiring minimal computational time. Two additional charging modes were simulated with different inlet HTF conditions: constant temperature and varying temperature following the profile produced by a thermal solar collector field. The temperature profiles obtained from the three charging modes were analysed and compared to each other. The proposed numerical and experimental tools will be used in future studies for a better understanding of the design and operating conditions of packed bed thermal energy storage systems.展开更多
A laboratory scale aerobic fixed film bioreactor packed with glass beads for biofilm growth was used to evaluate the removal efficiencies of COD and phenol for a carbohydrate—phenol mixture in wastewater. It was done...A laboratory scale aerobic fixed film bioreactor packed with glass beads for biofilm growth was used to evaluate the removal efficiencies of COD and phenol for a carbohydrate—phenol mixture in wastewater. It was done by an indigenous mixed culture inoculums developed after collecting sludge from a return line of an activated sludge plant. The test result on continuous flow in the above biofilm reactor indicated an optimum hydraulic loading range of 4-6.4 m3day-1m-2 for attainment of reasonable amount of COD removal in case of carbohydrate substrate only. The COD removal efficiency, however, gradually depleted from 100% to 54% by gradual increase in organic loading (OLR) from 0.72-4.32 kgday-1m-3, beyond which removal was not significant. For the identical loading conditions, in presence of phenol in the substrate along with carbohydrate, the COD removal was observed varying from 100-40% in the above organic loading range. The COD removal kinetics in presence of phenol also shows a decreasing trend compared to data obtained without the presence of phenol in wastewater that reveals biological inhibition. The experimental data were fitted in a simple plug flow model for evaluating the zero order, first order and Monod form of rate equations to evaluate the kinetics. It was found that Monod type rate equations combining a zero and first order rate expression is the best fit for the above hydraulic and organic loading that gives a best fit half velocity constant value of 35 mgL-1 (R2 = 0.9612).展开更多
为降低连续刚构桥跨中下挠幅度,针对弹性模量与徐变2种影响因素,提出一种基于骨料紧密堆积理论的配合比优化控制方法,并对比原配合比研究了优化控制方法对不同龄期与环境下的弹性模量与徐变的影响;结合SEM(scanning electron microscope...为降低连续刚构桥跨中下挠幅度,针对弹性模量与徐变2种影响因素,提出一种基于骨料紧密堆积理论的配合比优化控制方法,并对比原配合比研究了优化控制方法对不同龄期与环境下的弹性模量与徐变的影响;结合SEM(scanning electron microscope)与MIP(mercury intrusion porosimetry)试验,从混凝土微观层面分析优化机理,以CEB-FIP(1990)模型为基础,提出考虑弹性模量成熟度的修正模型.结果表明:优化控制方法对早龄期混凝土弹性模量具有明显的控制效果,但界面过渡区面积的增加限制了后期弹性模量的发展;相同条件下,优化后混凝土徐变系数较原配合比降低了12%~23%;环境对混凝土徐变影响与优化控制方法相比占主导作用,不同环境下混凝土徐变变化幅度在45%~60%;混凝土徐变随加载龄期延长而减小,且优化后混凝土在较小加载龄期时,徐变仍比较大加载龄期的原配合比混凝土徐变降低3%~13%;优化后混凝土早龄期内部孔隙与微裂缝数量减少,改善了混凝土内部结构;修正后的CEB-FIP(1990)模型对徐变预测精度更高.展开更多
文摘A comprehensive kinetic model of NO formation during coke combustion in packed-bed in presence of noncombustible particles was developed. The detailed homogeneous gas-phase chemistry (including 102 chemical reactions), heterogeneous gas-solid chemistry (including 11 reactions) of coke combustion and NO formation, and the heat and mass transfer were taken into account in the present model. The governing equations which are strongly coupled, non-linear and unsteady with 26 unknowns in total, were dispersed into differential equations with the finite differential method. Meanwhile, all the differential equations were numerically solved to give the time-histories and space-distributions oftemperatures of the bed and gas phase as well as the concentrations of all the gaseous species. By comparison, the experimental data were explained well by the calculated results. Based on the kinetic and mathematical model, the effects of O2 content of inlet gas, the initial chemical analysis of coke, bed-temperature and local reductive atmosphere (CO/O2) on NO formation during packed-bed coke combustion were numerically discussed. It was found that coke samples with a higher initial content of [N] and volatile matters, combusted under a suitable O2-containing atmosphere produced less NO emission. The reactions between CO and NO, catalyzed by high temperature surface of coke particles may be responsible for efficient reduction of NO.
文摘Fractured, very permeable rock hosting repositories for radioactive waste will require grouting. New grout types of possible use where long-term performance is needed should have a small amount of cement for minimizing the increase in porosity that will follow from the ultimate dissolution and erosion of this component. They have to be low-viscous and gain strength early after injection and packing theory can assist designers in selecting suitable proportions of various grout components. Optimum particle packing means that the porosity is at minimum and that the amount of cement paste needed to fill the voids between aggregate particles is very small. Low porosity and microstructural stability must be guaranteed for long periods of time. Organic additives for reaching high fluidity cannot be used since they can give off colloids that carry released radionuclides and talc can be an alternative superplasticizer. Low-pH cement reacts with talc to give high strength with time while Portland cement gives early but limited strengthening. The clay mineral palygorskite can be used for early gelation because of its thixotropic properties. Once forced into the rock fractures or channels in soil it stiffens and serves as a filter that prevents fine particles to migrate through it be lost. However, its hydrophilic potential is too high to give the grout a high density and high strength. According to the experiments carried out, most of the investigated grouts are injectable in fractures with apertures down to 100 μm.
基金Supported by the National Key Research and Development Program(2016YFB0301702)National Natural Science Foundation of China(21490584,21878298,91534105)+2 种基金Major National Scientific Instrument and Equipment Development Project(21427814)Key Research Program of Frontier Sciences of CAS(QYZDJ-SSW-JSC030)Jiangsu National Synergetic Innovation Center for Advanced Materials.
文摘The traditional fixed-bed reactor design is usually not suitable for the low tube-to-particle diameter ratios(N = D/d b 8) where the local phenomena of channeling near the wall and backflow in the bed are dominant. The recent"solid particle" meshing method is too complicated for mesh generation, especially for non-spherical particles in large random packed beds, which seriously hinders its development. In this work, a novel high-fidelity mesh model is proposed for simulation of fixed bed reactors by combining the immersed boundary and adaptive meshing methods. This method is suitable for different shapes of particles, which ingeniously avoids handling the complex "contact point" problem. Several packed beds with two different shapes of particles are investigated with this model, and the local flow in the bed is simulated without geometrical simplification. The predicted pressure drop across the fixed bed and heat transfer of the single particle are in good agreement with the corresponding empirical relations. Compared with spherical particles, the packed bed packing with pentaphyllous particles has lower pressure drop and better heat/mass transfer performance, and it shows that this method can be used for the screening of particle shapes in a fixed bed.
基金This work is supported by the National Natural Science Foundation (50005016) and the foundation of Yangtze River Scholarship. Although all the calculation was carried out in China, the researching experience of ZFY in Cambridge University is acknowledged
文摘A phenomenological anisotropic model has been presented for the surface roughness modeling of pack rolling. The model is an assembly of grains in different orientations and sizes. The grain size is assumed to be in log-normal distribution. To model the macro anisotropic mechanical behavior of the grains induced by the slip deformation, the grains are assumed as isolated anisotropic units. The units have different mechanic behavior, and depend on the crystallographic orientations and the external loading as well as the interaction of the adjunctive grains. In the paper, the material properties of the grains are assumed as uniform distributions. The roughness of the contact surfaces depends on the distribution types and the scatters of the distributions. It is found that the initial roughness of the contact surfaces has a little influence on the surface roughness when the rolling deformation is large. The comparison between the phenomenological model and crystallographic model shows that the phenomenological model can also give out a reasonable result, while it only takes much less CPU time. The agreement between the single sheet model and the pack rolling model shows that in a certain degree the pack rolling model can be replaced by the single sheet model to decrease the CPU time.
基金supported by the National Science Foundation of the United States under a research grant (CMMI-1917238)
文摘Determination of the critical state line(CSL)is important to characterize engineering properties of granular soils.Grain size distribution(GSD)has a significant influence on the location of CSL.The influence of particle breakage on the CSL is mainly attributed to the change in GSD due to particle breakage.However,GSD has not been properly considered in modeling the CSL with influence of particle breakage.This study aims to propose a quantitative model to determine the CSL considering the effect of GSD.We hypothesize that the change of critical state void ratio with respect to GSD is caused by the same mechanism that influences of the change of minimum void ratio with respect to GSD.Consequently,the particle packing model for minimum void ratio proposed by Chang et al.(2017)is extended to predict critical state void ratio.The developed model is validated by experimental results of CSLs for several types of granular materials.Then the evolution of GSD due to particle breakage is incorporated into the model.The model is further evaluated using the experimental results on rockfill material,which illustrates the applicability of the model in predicting CSL for granular material with particle breakage.
基金supported by the National Natural Science Foundation of China (No.50704040, 20805060)the Natural Science Foundation Project of Chongqing Science & Technology Commission, China (No.CSTC,2009BB4197)
文摘The molten liquid flow inside a packed bed is a familiar momentum transportation phenomenon in a blast furnace. With regard to the reported mathematical models describing the liquid flow within a packed bed, there are some obstacles for their application in engineering design, or some limitations in the model itself. To overcome these problems, the forces from the packed bed to the liquid flow were divided into appropriate body and surface forces on the basis of three assumptions. Consequently, a new mathematical model was built to present the liquid flow inside the coke bed in a blast furnace. The mathematical model can predict the distribution of liquid flowrate and the liquid flowing range inside the packed bed at any time. The predicted results of this model accord well with the experimental data. The model will be applied considerably better in the simulation on the ironmaking process compared with the existent models.
基金Supported by the National Nature Science Foundation of China, under Grant No. 51179123 and No. 51279131 and the Special Research Program of Ministry of Industry and Information Technology of China
文摘In this study, we carried out model tests to investigate the ice failure process and the resistance experienced by a transport vessel navigating in the Arctic region in pack ice conditions. We tested different navigation velocities, ice plate sizes, and ice concentrations. During the tests, we closely observed several phenomena, including the modes of interaction of the ice ship and the moving and failure modes of ice. We also measured the vessel resistances under different conditions. The test results indicate that the navigation velocity is a significant determinant of the moving and failure modes of ice. Moreover, vessel resistance is remarkably dependent on the ice concentration and navigation velocity. The variances of the mean and maximum resistance are also compared and discussed in detail.
文摘A mathematical model for the process of removal of aerosols from gases in channels filled with packing is considered. Equations for transport of aerosol particles and results of their numerical solution are given. Influence of operating conditions and of design characteristics of the packed apparatus on gas purification efficiency is analyzed.
文摘Thermal Energy Storage is becoming a necessary component of sustainable energy production systems as it helps alleviate intrinsic limitations of Renewable Energy Sources, such as intermittent use and mismatch between power demand and supply. This paper discusses a packed bed thermocline tank as a thermal energy storage solution. Firstly, this paper presents the development of a numerical model calculating heat transfers within the tank, based on a discretization over several nodes and the nodal formulation of the heat balance equation. The model considers a filler material and a heat transferring fluid and uses the finite difference method to calculate the temperature evolution of the two media across the tank. The model was validated with two different packed bed systems from the literature during a discharging process, presenting a good fit with the experimental results. Secondly, the experimental packed bed is presented and characterized for a charging cycle from ambient temperature to approximately 180?C. The charging experiment was accurately reproduced with the numerical model requiring minimal computational time. Two additional charging modes were simulated with different inlet HTF conditions: constant temperature and varying temperature following the profile produced by a thermal solar collector field. The temperature profiles obtained from the three charging modes were analysed and compared to each other. The proposed numerical and experimental tools will be used in future studies for a better understanding of the design and operating conditions of packed bed thermal energy storage systems.
文摘A laboratory scale aerobic fixed film bioreactor packed with glass beads for biofilm growth was used to evaluate the removal efficiencies of COD and phenol for a carbohydrate—phenol mixture in wastewater. It was done by an indigenous mixed culture inoculums developed after collecting sludge from a return line of an activated sludge plant. The test result on continuous flow in the above biofilm reactor indicated an optimum hydraulic loading range of 4-6.4 m3day-1m-2 for attainment of reasonable amount of COD removal in case of carbohydrate substrate only. The COD removal efficiency, however, gradually depleted from 100% to 54% by gradual increase in organic loading (OLR) from 0.72-4.32 kgday-1m-3, beyond which removal was not significant. For the identical loading conditions, in presence of phenol in the substrate along with carbohydrate, the COD removal was observed varying from 100-40% in the above organic loading range. The COD removal kinetics in presence of phenol also shows a decreasing trend compared to data obtained without the presence of phenol in wastewater that reveals biological inhibition. The experimental data were fitted in a simple plug flow model for evaluating the zero order, first order and Monod form of rate equations to evaluate the kinetics. It was found that Monod type rate equations combining a zero and first order rate expression is the best fit for the above hydraulic and organic loading that gives a best fit half velocity constant value of 35 mgL-1 (R2 = 0.9612).
文摘为降低连续刚构桥跨中下挠幅度,针对弹性模量与徐变2种影响因素,提出一种基于骨料紧密堆积理论的配合比优化控制方法,并对比原配合比研究了优化控制方法对不同龄期与环境下的弹性模量与徐变的影响;结合SEM(scanning electron microscope)与MIP(mercury intrusion porosimetry)试验,从混凝土微观层面分析优化机理,以CEB-FIP(1990)模型为基础,提出考虑弹性模量成熟度的修正模型.结果表明:优化控制方法对早龄期混凝土弹性模量具有明显的控制效果,但界面过渡区面积的增加限制了后期弹性模量的发展;相同条件下,优化后混凝土徐变系数较原配合比降低了12%~23%;环境对混凝土徐变影响与优化控制方法相比占主导作用,不同环境下混凝土徐变变化幅度在45%~60%;混凝土徐变随加载龄期延长而减小,且优化后混凝土在较小加载龄期时,徐变仍比较大加载龄期的原配合比混凝土徐变降低3%~13%;优化后混凝土早龄期内部孔隙与微裂缝数量减少,改善了混凝土内部结构;修正后的CEB-FIP(1990)模型对徐变预测精度更高.
