Particle effects on the hydrodynamics in slurry bubble column reactors:A review from multiscale mechanisms Author links open overlay panel

Particles can appear as catalyst,reactant or product in various gas-liquid-solid three-phase production processes.Slurry bubble column reactors(SBCRs),as a kind of three-phase reactors,are preferred for phase contacting and mixing.However,literature studies concerning the effects of particles on the hydrodynamics of SBCRs are manifold and inconsistent in conclusions.Essentially,the multiscale interactions between particles,turbulent eddies and bubbles determine the reactor performance.This review focuses on revealing the particle effects in SBCRs from the perspective of multiscale mechanisms.Macroscopic hydrodynamic changes due to particle effects in literature are summarized.Dimensionless parameters,including the Stokes number,the solid-to-liquid density ratio,the ratio of particle and liquid characteristic lengths,the contact angle and the particle volume fraction are adopted to evaluate the characteristics of gas-liquid-solid flows.The relationships between particle influencing mechanisms and these parameters are analyzed and determined.Inconsistent experimental results are explained by different ranges of these dimensionless parameters.Moreover,particle effects at the mesoscale and microscale,such as the influence on the bubble dynamics and the pivoting effect on the turbulence energy spectrum,are elaborated.Finally,progress in modeling the SBCRs with consideration of particles effects using the Euler method are introduced.This review aims to improve the overall understanding of the complex hydrodynamics in the SBCRs.

Effects of Ni particle size on amination of monoethanolamine over Ni-Re/SiO_2 catalysts

Ni-Re/SiO2 catalysts with controllable Ni particle sizes(4.5–18.0 nm)were synthesized to investigate the effects of the particle size on the amination of monoethanolamine(MEA).The catalysts were characterized by various techniques and evaluated for the amination reaction in a trickle bed reactor at 170℃,8.0 MPa,and 0.5 h^-1 liquid hourly space velocity of MEA(LHSVMEA)in NH3/H2 atmosphere.The Ni-Re/SiO2 catalyst with the lowest Ni particle size(4.5 nm)exhibited the highest yield(66.4%)of the desired amines(ethylenediamine(EDA)and piperazine(PIP)).The results of the analysis show that the turnover frequency of MEA increased slightly(from 193 to 253 h^-1)as the Ni particle sizes of the Ni-Re/SiO2 catalysts increased from 4.5 to 18.0 nm.Moreover,the product distribution could be adjusted by varying the Ni particle size.The ratio of primary to secondary amines increased from 1.0 to 2.0 upon increasing the Ni particle size from 4.5 to 18.0 nm.Further analyses reveal that the Ni particle size influenced the electronic properties of surface Ni,which in turn affected the adsorption of MEA and the reaction pathway of MEA amination.Compared to those of small Ni particles,large particles possessed a higher proportion of high-coordinated terrace Ni sites and a higher surface electron density,which favored the amination of MEA and NH3 to form EDA.

Effect of In_(2)O_(3)particle size on CO_(2) hydrogenation to lower olefins over bifunctional catalysts

A reaction-coupling strategy is often employed for CO_(2)hydrogenation to produce fuels and chemicals using oxide/zeolite bifunctional catalysts.Because the oxide components are responsible for CO_(2)activation,understanding the structural effects of these oxides is crucial,however,these effects still remain unclear.In this study,we combined In_(2)O_(3),with varying particle sizes,and SAPO‐34 as bifunctional catalysts for CO_(2)hydrogenation.The CO_(2)conversion and selectivity of the lower olefins increased as the average In_(2)O_(3)crystallite size decreased from 29 to 19 nm;this trend mainly due to the increasing number of oxygen vacancies responsible for CO_(2) and H_(2) activation.However,In_(2)O_(3)particles smaller than 19 nm are more prone to sintering than those with other sizes.The results suggest that 19 nm is the optimal size of In_(2)O_(3)for CO_(2)hydrogenation to lower olefins and that the oxide particle size is crucial for designing catalysts with high activity,high selectivity,and high stability.

Particle concentration effect in adsorption/desorption of Zn(Ⅱ) on anatase type nano TiO_2

Adsorption/desorption in a new Zn（Ⅱ）-TiO2 adsorption system was investigated at different particle concentrations （Cp）. TEM, SEM and XRD analyses revealed that the TiO2 particles were an aggregation of nano-sized （approximately 10 nm） pure anatase-type TiO2. Adsorption experiments were carried out with particle concentrations of 100, 400 and 1000 mg/L, and their adsorption isotherms were found to decline successively, showing an obvious Cp effect. Desorption experiments indicated that adsorption in this system was irreversible, and the irreversibility increased with increasing Cp. These phenomena could be explained by the MEA （metastable equilibrium adsorption） theory and the Cp effect could be modeled well with an MEA-Freundlich-type Cp effect isotherm equation. This study may heln understand environmental behavior of contaminants on ultrafine natural particles.

Effect of Ni particle size on the production of renewable methane from CO_(2) over Ni/CeO_(2) catalyst

Production of’renewable Methane’has attracted renewed research interest as a fundamental probe reaction and process for CO_(2)utilization through potential use in Cl fuel production and even for future space exploration technologies.CO_(2)methanation is a structure sensitive reaction on Ni/CeO_(2)catalysts.To precisely elucidate the size effect of the Ni metal center on the CO_(2)methanation performance,we prepared2%Ni/CeO_(2)catalysts with pre-synthesized uniform Ni particles(2,4 and 8 nm)on a high surface area CeO_(2)support.Transmission electron microscopy(TEM)and ambient pressure X-ray photo spectroscopy(AP-XPS)characterization have confirmed that the catalyst structure and chemical state was uniform and stable under reaction conditions.The 8 nm sized catalyst showed superior methanation selectivity over the 4 and 2 nm counterparts,and the methanation activity in term of TOF is 10 times and 70 times higher than for the 4 and 2 nm counterparts,respectively.The DRIFTS studies revealed that the larger Ni(8 nm particles)over CeO_(2)efficiently facilitated the hydrogenation of the surface formate intermediates,which is proposed as the rate determining step accounting for the excellent CO_(2)methanation performance.

Effect of initial nickel particle size on stability of nickel catalysts for aqueous phase reforming

The deactivation behavior by crystallite growth of nickel nanoparticles on various supports（carbon nanofibers, zirconia, Si C, α-Al2O3 and γ-Al2O3） was investigated in the aqueous phase reforming of ethylene glycol. Supported Ni catalysts of ~10 wt% were prepared by impregnation of carbon nanofibers（CNF）,Zr O2, SiC, γ-Al2O3 and α-Al2O3. The extent of the Ni nanoparticle growth on various support materials follows the order CNF ~ ZrO2〉 SiC 〉 γ-Al2O3〉〉 α-Al2O3 which sequence, however, was determined by the initial Ni particle size. Based on the observed nickel leaching and the specific growth characteristics; the particle size distribution and the effect of loading on the growth rate, Ostwald ripening is suggested to be the main mechanism contributing to nickel particle growth. Remarkably, initially smaller Ni particles（~12 nm） supported on α-Al2O3 were found to outgrow Ni particles with initially larger size（~20 nm）. It is put forward that the higher susceptibility with respect to oxidation of the smaller Ni nanoparticles and differences in initial particle size distribution are responsible for this behavior.

Mssbauer Effect in Ultrafine Particles with Fe-C Solid Solution,γ-Fe and Fe_3C Phases

Ultrafine particles prepared by evaporating pure Fe in CH4 atmosphere using arc-dischargeheating method, were found to consist of Fe-C solid solution, γ-Fe and Fe3C phases. EfFect of annealing temperature on phase transformation and hyperfine interactions has been investigated by Mossbauer spectroscopy, X-ray diffraction (XRD), differential thermal analysis and thermogravimetry (DTA-TG), transmission electron microscopy (TEM), oxygen determination and vibrating sample magnetometer (VSM) measurements. It was observed that phase transformation of γ-Fe to α-Fe occurs during annealing in vacuum. The mechanism causing the change of hyperfine interactions with annealing temperature differs for Fe-C solution and interstitial compounds. DifFerence of hyperfine interactions of Fe-C solid solution in the starting sample and its annealed samples is ascribed to the improvement of activation of interstitial carbon atoms. Stress-relieving in structure of annealed Fe3C particle can result in a weak influence on hyperfine interactions. Parameters fitted to the Mossbauer spectra show the existence of superparamagnetism in all the samples. Absorbed and combined oxygen on particle surface of the starting sample were determined.

Particle Size Distribution,Powder Agglomerates and Their Effects on Sinterability of Ultrafine Alumina Powders

An intensive study of the particle size distribution of four commercial ultrafine alumina powders to obtain information about the powder agglomeration and relate them to the compactibility and the sinterability has been made.

Gold/Mg-Al mixed oxides catalysts for oxidative esterification of methacrolein:Effects of support size and composition on gold loading

Gold catalysts supported on Mg-Al mixed oxides for oxidative esterification of methacrolein are prepared by impregnation.Effects of the support particle size,concentration of HAuCl4 solution and Mg/Al ratio on gold loading and catalytic properties are investigated.The catalysts are characterized by CO_(2)-TPD,EDS,XPS,STEM and XRD techniques.Catalysts with smaller support particle size show more uniform gold distribution and higher gold dispersion,resulting in a higher catalytic performance,and the uniformity of gold and the activity of the catalysts with larger support particle size can be improved by decreasing the concentration of HAuCl4 solution.The Mg/Al molar ratio has significant effect on the uniformity of gold and the activity of the catalyst,and the optimum Mg/Al molar ratio is 0.1–0.2.This study underlines the importance of engineering support particle size,concentration of HAuCl4 solution and density of adsorption sites for efficient gold loading on support by impregnation.

EFFECT OF PARTICLE SIZE ON THE FILMING PROCESS OF POLYSTYRENE LATEX STUDIED BY AFM

The film formation process of micro-PS particles (diameter 742 nm) and nano-PS particles (diameter 29 nm) was studied by atomic force microscopy and differential scanning calorimetry. During a step heating process, the particles were annealed for 0.5 h at each selected temperature. It was found that the deformation and interdiffusion temperatures of the micro-PS particles are ca. 120-130degreesC and 140-150degreesC, that of the nano-PS particles are 90degreesC and 100-110degreesC respectively. The DSC traces of nano-PS particles showed that there was an exothermic peak near T-g after annealing for 0.5 h at the selected temperatures below 90degreesC; otherwise, the exothermic peak disappeared after annealing at 100degreesC or above. Compared with the micro-PS particles, the sintering process of nano-PS particles occurs at much lower temperature determined by the confined state of polymer chains with higher conformational energy in nano-particles, and completes in a much narrower temperature range driven mainly by the larger total surface energy.

EFFECT OF DISPERSED PHASE PARTICLES ON ELECTRICAL CONDUCTION OF PEO-NaSCN

Fast ionic conductors are one kind of solid state material with ionic conductivity as high as that of melten salts or liquid electrolytes.Ionic conductivity is one of the important parameters for characterizing a fast ionic conductor.For a long time materialists and chemists have made great efforts in search of new fast ionic conductors with high ionic conductivity.In view of structure,they have synthesised silver and copper fast ionic conductors with so called open structures.But it is not so successful for searching more applicable alkaline fast ionic conductors.Since polymer has flexibility for making thin film,it concentrates attention on the polymer-alkaline salt complex.Fenton et al.have first reported poly(ethylene oxide) (PEO)-alkaline salt complex.Later on Armard et al.have investigated the electrical property of PEO-NaSCN.

Effect of Particle Number Density on Wave Dispersion in a Two-Dimensional Yukawa System

Effect of the particle number density on the dispersion properties of longitudinal and transverse lattice waves in a two-dimensional Yukawa charged-dust system is investigated using molecular dynamics simulation. The dispersion relations for the waves are obtained. It is found that the frequencies of both the longitudinal and transverse dust waves increase with the density and when the density is sufficiently high a cutoff region appears at the short wavelength. With the increase of the particle number density, the common frequency tends to increase, and the sound speed of the longitudinal wave also increases, but that of the transverse wave remains low.

THE SIZE EFFECT ON THE DISPERSION OF A PARTICLE IN A HOMOGENEOUS ISOTROPIC TURBULENCE

The mechanism of the response motion of a suspended particle to turbulent motion of its surrounding fluid is different according to si:e of turbulent eddies. The particle is dragged by the viscous force of large eddies, and meanwhile driven randomly by small eddies. Based on this understanding, the dispersion of a particle with finite size in a homogeneous isotropic turbulence is calculated in this study. Results show that there are two competing effects: when enhanced by the inertia of a particle, the long-term particle diffusivity is reduced by the finite size of the particle.

Effect of the Ni size on CH4/CO2 reforming over Ni/MgO catalyst：A DFT study

Carbon deposition is sensitive to the metal particle sizes of supported Ni catalysts in CH_4/CO_2 reforming.To explore the reason of this phenomenon,Ni4,Ni8,and Ni12 which re flect the different cluster thicknesses supported on the MgO(100) slabs,have been employed to simulate Ni/MgO catalysts,and the reaction pathways of CH_4/CO_2 reforming on Nix/MgO(100) models are investigated by density functional theory.The reforming mechanisms of CH_4/CO_2 on different Nix/MgO(100) indicate the energy barriers of CH_4 dissociated adsorption,CH dissociation,and C oxidation three factors are all declining with the decrease of the Ni cluster sizes.The Hirshfeld charges analyses of three steps as described above show only Ni atoms in bottom two layers can obtain electrons from the MgO supporters,and the main electron transfer occurs between adsorbed species and their directly contacted Ni atoms.Due to more electron-rich Ni atoms in contact with the MgO supporters,the Ni/MgO catalysts with small Ni particles have a strong metal particle size effect and lead to its better catalytic activity.

Transition and self-sustained turbulence in dilute suspensions of finite-size particles

We study the transition to turbulence of channel flow of finite-size particle suspensions at low volume fraction, i.e., φ ≈0.001. The critical Reynolds number above which turbulence is sustained reduces to Re ≈ 1675, in the presence of few particles, independently of the initial condition, a value lower than that of the corresponding single-phase flow, i.e., Re ≈1775. In the dilute suspension, the initial arrangement of the particles is important to trigger the transition at a fixed Reynolds number and particle volume fraction. As in single phase flows, streamwise elongated disturbances are initially induced in the flow. If particles can induce oblique disturbances with high enough energy within a certain time, the streaks breakdown, flow experiences the transition to turbulence and the particle trajectories become chaotic, Otherwise, the streaks decay in time and the particles immigrate towards the channel core in a laminar flow.

Numerical analysis of submarine landslides using a smoothed particle hydrodynamics depth integral model

Submarine landslides can cause severe damage to marine engineering structures. Their sliding velocity and runout distance are two major parameters for quantifying and analyzing the risk of submarine landslides.Currently, commercial calculation programs such as BING have limitations in simulating underwater soil movements. All of these processes can be consistently simulated through a smoothed particle hydrodynamics（SPH） depth integrated model. The basis of the model is a control equation that was developed to take into account the effects of soil consolidation and erosion. In this work, the frictional rheological mode has been used to perform a simulation study of submarine landslides. Time-history curves of the sliding body＇s velocity, height,and length under various conditions of water depth, slope gradient, contact friction coefficient, and erosion rate are compared; the maximum sliding distance and velocity are calculated; and patterns of variation are discussed.The findings of this study can provide a reference for disaster warnings and pipeline route selection.

Solid Particles Injection in Gas Turbulent Channel Flow

This paper represents a review of the recent researches that investigate the behavior of the gas turbulent flow laden with solid particles. The significant parameters that influence the interactions between the both phases, such as particle size, loading ratio and the gas velocity, have been extensively reviewed. Those parameters are presented in dimensionless numbers in which the applicability of studying its effect in terms of all circumstances of the gas turbulent channel flow at different condition is possible. The represented results show that the turbulence degree is proportional to the particle size. It was found that at the most flow conditions even at low mass ratio, the particle shape, density and size significantly alter the turbulence characteristics. However, the results demonstrate that the particle Reynolds number is a vital sign: the turbulence field becomes weaker if particle Reynolds number is lower than the critical limit and vies verse. The gas velocity has a strong effect on the particles settling along the channel flow and as a result, the pressure drop will be affected.

Size effect of Pt nanoparticles in acid-assisted soot oxidation in the presence of NO

Pt/Al2O3 catalysts with mean Pt particle size ranged from 2.7 to 7.1 nm were synthesized by chemical reduction method,and the sulfated counterparts were prepared by impregnation of sulfuric acid.The turnover frequency of platinum for soot oxidation under loose contact conditions in a feed flow containing NO and O2 are positively correlated with the size of platinum.The sulfated Pt/Al2O3 exhibits higher catalytic activity for soot oxidation in the presence of NO despite their reduced ability for NO2 production.Such a contradiction is more significant for those catalysts with smaller platinum particles.Herein,the catalysts were characterized by X-ray diffraction(XRD),Brunauer-Emmett-Teller(BET),transmission electron microscopy(TEM),inductive coupled plasma(ICP)emission spectrometry,CO chemisorption,thermogravimetric analysis(TGA),NH3 temperature-programmed desorption(NH 3-TPD),NO temperature-programmed oxidation(TPO)and NO x temperatureprogrammed desorption(TPD).Possible effect of Pt particle size for the catalytic oxidation of soot in the presence of NO was presented based primarily on the promoted NO2 transfer efficiency onto the soot pushed by the acidic catalysts.

Determining the relationship between chemical composition and size, shape and effective density of airborne fine particles through concurrent use of inertial and optical based measurements

This study presents the development of a medium flow, multiple slit based PM2.5 （particle aerodynamic diameter 〈2.5 μm） inertial impactor. Its performance was compared with that of a light scattering based optical particle sizer in a field study and in controlled lab based experiments using polydisperse dolomite powder as test aerosol. The impactor＇s optimum nozzle configuration had a cutoff size of 2.51 μm （aero- dynamic diameter） at an operating flow rate of 215 L/rain with a pressure drop of 0.35 kPa across the impactor stage. Because the apparent particle density of an ambient aerosol depends on the physical properties and the chemical composition of the particles, the PM2.5 mass concentration was measured with an optical particle sizer and an inertial impactor over a weekday and a weekend day in a field study during which the effective particle shape factor and density were in tandem modified in order to com- pare the results from the two sampling techniques. The correlation of the two instrument results tended towards 1：1 with increasing values of shape factor （irregular shaped） and effective particle density. This observation was supported through chemical investigations of the collected mass, which showed a higher percentage contribution from elements which are mostly of crustal nature （namely, Ca, Fe, and Mg）.

Effects of an odd particle on shape phase transitions in odd-even systems

A scheme to solve the Hamiltonian in the interacting boson-fermion model in terms of the SU(3)coupling basis is introduced,through which the effects of an odd particle on shape phase transitions(SPTs)in odd-A nuclei are examined by comparing the critical behaviors of some selected quantities in odd-even and even-even systems.The results indicate that the spherical to prolate(U(5)-SU(3))SPT and spherical to γ-soft (U(5)-O(6))SPT may clearly occur in the odd-even system with the SPT signatures revealed by various quantities including the excitation energies,energy ratio,B(E2)ratio,quadrupole moments,and one-particle-transfer spectroscopic intensities.In particular,the results indicate that the spherical to prolate SPT in the odd-even system can even be strengthened by the effects of the odd particle with the large fluctuations of the quadrupole deformations appearing near the critical point.