Effect of ECAP processing on distribution of second phase particles,hardness and electrical conductivity of Cu-0.81Cr-0.07Zr alloy

The effect of equal-channel angular pressing(ECAP)processing at room temperature and 300℃on the distribution of the second phase particles and its influence on hardness and electrical conductivity of the commercial Cu-0.81Cr-0.07Zr alloy were investigated.Microstructural characterization indicated that the area fraction of coarse Cr-rich particles decreased after ECAP processing.This reduction was attributed to the Cr dissolution induced by plastic deformation.The electrical conductivity of the alloy decreased by 12%after 4 ECAP passes at room temperature due to the increase of electrons scattering caused by higher Cr content in solid solution and higher density of defects in the matrix.These results were supported by the reduction of the Cu lattice parameter and by the exothermic reactions,during differential scanning calorimetry(DSC)analysis,observed only in the samples subjected to ECAP processing.Aging heat treatment after ECAP processing promoted an additional hardening effect and the complete recuperation of the electrical conductivity,caused by the re-precipitation of the partially dissolved particles.The better combination of hardness(191 HV)and electrical conductivity(83.5%(IACS))was obtained after 4 ECAP passes at room temperature and subsequent aging at 380℃for 1 h.

Phase-field study of the second phase particle effect on texture evolution of polycrystalline material

The second phase particle effect on texture evolution of polycrystalline material is studied through phase-field method. A unique field variable is introduced into the phase-field model to represent the second phase particles. Elastic interaction between particles and grains is also considered. Results indicate that in the presence of second phase particles the average particle diameter turns smaller than in the absence of these particles and retards texture formation by pinning effect. The second phase particles change the strain energy profile, which tremendously influences the pinning effect.

Monte Carlo study on abnormal growth of Goss grains in Fe-3%Si steel induced by second-phase particles

The selective abnormal growth of Goss grains in magnetic sheets of Fe-3%Si （grade Hi-B） induced by second-phase particles （AlN and MnS） was studied using a modified Monte Carlo Ports model. The starting microstructures for the simulations were generated from electron backscatter diffraction （EBSD） orientation imaging maps of recrystallized samples. In the simulation, second-phase particles were assumed to be randomly distributed in the initial microstructures and the Zener drag effect of particles on Goss grain boundaries was assumed to be selectively invalid because of the unique properties of Goss grain boundaries. The simulation results suggest that normal growth of the matrix grains stagnates because of the pinning effect of particles on their boundaries. During the onset of abnormal grain growth, some Goss grains with concave boundaries in the initial microstructure grow fast abnormally and other Goss grains with convex boundaries shrink and eventually disappear.

Grain growth simulation with the second phase particle pinning for heat-affected zone of microalloyed steel welds

The second phase particle dispersed in microalloyed steel has different effects on grain growth depending on their size and volume fiaction of the second phase particles which will change during welding thermal cycles. The particle coarsening and dissolution kinetics model was analyzed for continuous heating and cooling. In addition, based on experimental data, the coupled equation of grain growth was established by introducing limited size of grain growth with the consideration of the second phase particles pinning effects. Using Monte Carlo method based on experimental data model, the grain growth simulation for heat-affected zone of microalloyed steel welds was achieved. The calculating results were well in agreement with that of experiments.

Effect of initial nickel particle size on stability of nickel catalysts for aqueous phase reforming

The deactivation behavior by crystallite growth of nickel nanoparticles on various supports（carbon nanofibers, zirconia, Si C, α-Al2O3 and γ-Al2O3） was investigated in the aqueous phase reforming of ethylene glycol. Supported Ni catalysts of ~10 wt% were prepared by impregnation of carbon nanofibers（CNF）,Zr O2, SiC, γ-Al2O3 and α-Al2O3. The extent of the Ni nanoparticle growth on various support materials follows the order CNF ~ ZrO2〉 SiC 〉 γ-Al2O3〉〉 α-Al2O3 which sequence, however, was determined by the initial Ni particle size. Based on the observed nickel leaching and the specific growth characteristics; the particle size distribution and the effect of loading on the growth rate, Ostwald ripening is suggested to be the main mechanism contributing to nickel particle growth. Remarkably, initially smaller Ni particles（~12 nm） supported on α-Al2O3 were found to outgrow Ni particles with initially larger size（~20 nm）. It is put forward that the higher susceptibility with respect to oxidation of the smaller Ni nanoparticles and differences in initial particle size distribution are responsible for this behavior.

EFFECT OF DISPERSED PHASE PARTICLES ON ELECTRICAL CONDUCTION OF PEO-NaSCN

Fast ionic conductors are one kind of solid state material with ionic conductivity as high as that of melten salts or liquid electrolytes.Ionic conductivity is one of the important parameters for characterizing a fast ionic conductor.For a long time materialists and chemists have made great efforts in search of new fast ionic conductors with high ionic conductivity.In view of structure,they have synthesised silver and copper fast ionic conductors with so called open structures.But it is not so successful for searching more applicable alkaline fast ionic conductors.Since polymer has flexibility for making thin film,it concentrates attention on the polymer-alkaline salt complex.Fenton et al.have first reported poly(ethylene oxide) (PEO)-alkaline salt complex.Later on Armard et al.have investigated the electrical property of PEO-NaSCN.

Motion of a Nonrelativistic Quantum Particle in Non-commutative Phase Space

The equation governing the motion of a quantum particle is considered in nonrelativistic non-commutative phase space. For this aim, we first study new Poisson brackets in non-commutative phase space and obtain the modified equations of motion. Next, using novel transformations, we solve the equation of motion and report the exact analytical solutions.

Determination of Particle Sizes and Crystalline Phases on Colloidal Silicon Nanoparticle Suspensions

Particle size and crystallinity of silicon nanoparticles were determined by analyzing the optical extinction spectra of colloidal suspensions. Experimental results from these colloids were anaiyzed using Mie theory in connection with effective medium theory, in order to determine particle sizes and their internal structure with the simple technique of optical transmission spectroscopy. By modeling an effective refractive index for the particles, the crystalline volume fraction can be extracted from extinction spectra in addition to information about the size. The crystalline volume fraction determined in this way were used to calibrate the ratio of the Raman cross sections for nanocrystalline and amorphous silicon, which was found to be σc./σa = 0.66

Self-assembly of Binary Particles with Electrostatic and van der Waals Interactions

Nanoparticles with competitive interactions in solution can aggregate into complex structures. In this work, the synergistic self-assembles of binary particles with electrostatic and van der Waals interactions are studied with the particle Langevin dynamics simulation using a simple coarse-grained particle model. Various aggregations such as spherical, stacking-disk and tube structures are observed by varying the particles size and the interaction strength. The aggregation structures are explained with the packing theories of amphiphilic molecules in solution and dibolck copolymers in bulk. When the opposite ions are introduced into solution, the distribution of structures in the phase diagram appears an obvious offset. The simulation result is helpful to deeply understand the formation mechanism of complex nanostructures of multicomponent particles in solution.

Nano-refinement of the face-centered cubic Zr(Fe,Cr)_(2)secondary phase particles in Zircaloy-4 alloy via localized-shearing/bending-driven fracture under high-temperature compression

Nanoparticles are extensively introduced to improve the mechanical,physical,and chemical properties of alloys.In the present study,the underlying nano-refinement mechanisms of face-centered cubic Zr(Fe,Cr)_(2)secondary phase particles(SPPs)that precipitated in Zircaloy-4 alloy under high-temperature compression were investigated in detail by utilizing high-resolution transmission electron microscopy(HRTEM)and conventional TEM techniques.The frequently observed Zr(Fe,Cr)_(2)SPPs were incoherent with the matrix and exhibited brittle fracture behaviors without measurable plasticity.HRTEM observations revealed two mechanisms underlying the nano-refinement of incoherent micro-sized SPPs via localized shear fracture on{11¯2}SPP and nanoprecipitate-assisted bending fracture,respectively.The latter was,for the first time,found to occur when the movements of large SPPs were blocked by nanometer-sized SPP during alloy deformation.Accordingly,two force models were proposed to visualize their potential nano-refinement processes.The knowledge attained from this study sheds new light on the deformation behaviors of Zr(Fe,Cr)_(2)SPPs and their associated size refinement mechanisms under high-temperature compression,and is expected to greatly benefit the process optimization of zirconium alloys to achieve precipitate nano-refinement.

Microstructure and mechanical properties of Mg-Gd-Y-Zr alloy processed by equal channel angular pressing

Microstructure evolution and texture development and their effects on mechanical properties of a Mg-Gd-Y-Zr alloy during equal channel angular pressing（ECAP） were investigated.It is found that the microstructure is still inhomogeneous after four passes,and two zones,namely the fine grain zone（FGZ） and the coarse grain zone（CGZ） are formed.The grain refinement occurs mainly by particle-stimulated nucleation（PSN） mechanism,which led to a more random texture after four passes of ECAP.In the ECAP-processed alloy,the strength did not increase while the ductility was enhanced dramatically compared with the as-received condition.The change of ductility of this alloy was discussed in terms of texture and second phase particles.

Pollution characteristics of 15 gas- and particle-phase phthalates in indoor and outdoor air in Hangzhou

Phthalate esters(PAEs),typical pollutants widely used as plasticizers,are ubiquitous in various indoor and outdoor environments.PAEs exist in both gas and particle phases,posing risks to human health.In the present study,we chose four typical kinds of indoor and outdoor environments with the longest average human residence times to assess the human exposure in Hangzhou,including newly decorated residences,ordinary residences,offices and outdoor air.In order to analyze the pollution levels and characteristics of 15 gasand particle-phase PAEs in indoor and outdoor environments,air and particulate samples were collected simultaneously.The total PAEs concentrations in the four types of environments were 25,396,25,466.8,15,388.8 and 3616.2 ng/m^3,respectively.DEHP and DEP were the most abundant,and DMPP was at the lowest level.Distinct variations in the distributions of indoor/outdoor,gas/particle-phase and different molecular weights of PAEs were observed,showing that indoor environments were the main sources of PAEs pollution.While most PAEs tended to exsit in indoor sites and gas-phase,the high-molecular-weight chemicals tended to exist in the particle-phase and were mainly found in PM2.5.PAEs were more likely adsorbed by small particles,especially for the indoor environments.There existed a good correlation between the particle matter concentrations and the PAEs levels.In addition,neither temperature nor humidity had obvious effects on the distributions of the PAEs concentrations.

Effect of cooling conditions on corrosion resistance of friction stir welded 2219-T62 aluminum alloy thick plate joint

Friction stir welding (FSW) with water cooling and air cooling was used to weld 2219-T62 aluminum alloy joints with a thickness of 20 mm. The effect of cooling conditions on the corrosion resistance of joints in 3.5% NaCl solution was investigated using the open circuit potential (OCP), the potentiodynamic polarization, and the corrosion morphology after immersing for different time. And the precipitates distribution was characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results reveal that the weld nugget zone (WNZ) owning positive potential, lower corrosion current density and fine and uniform precipitates, is much more difficult to corrode than the heat affected zone (HAZ) and the base metal (BM). Compared with air-cooled joint, the water-cooled joint has better corrosion resistance. In addition, the results of microstructure observation show that the potential, distribution and size of second phase particles determine the corrosion resistance of FSW AA2219 alloy joints in chlorine-contained solution.

Effects of rare earth Ce addition on microstructure and mechanical properties of impure copper containing Pb

The effects of rare earth Ce on the microstructure and mechanical properties of impure copper containing Pb were investigated using OM,SEM,EPMA,TEM and tensile testing.TEM and EDS analysis reveal that spherical CePb3 particles form after Ce addition.CePb3 particles,with average size of^3.6μm,homogenously distribute in the Cu matrix.Due to small lattice misfit(~4.62%)with Cu matrix,CePb3 particles can act as effective nucleation sites beneficial to the grain refinement.Pb at grain boundaries seriously deteriorates the mechanical properties of Cu.The tensile strength and the elongation of Cu-0.1 Pb are decreased by 43.1%and 56.7%compared with those of pure copper,respectively.Ce can purify grain boundaries,cause the precipitation of CePb3 particles and refine grain sizes,which contribute to significant improvement of the mechanical properties of Cu.Compared with Cu-0.1Pb,the tensile strength(179 MPa)and the elongation(38.5%)of Cu-0.1Pb-0.3Ce are increased by 117.6%and 151.6%,respectively.

Effects of microstructural heterogeneity on fatigue properties of cast aluminum alloys

Cast Al alloys are widely employed for engine components,structural parts,gear box,chassis,etc.and subjected to mechanical cyclic load during operation.The accurate fatigue life prediction of these alloys is essential for normal operation as fatigue cracks initiated during operation induce the lubrication oil leak and serious safety hazard.Microstructural heterogeneity,including shrinkage/gaspores and secondary phase particles,is the most detrimental factor that affects fatigue life of cast Al alloys.The approximate fatigue life cycles could be estimated based on the size distribution and locations of shrinkage pores/defects.The relationship between crack population and stress was reported by statistical distributions and the cumulative probability for cast Al alloys fail at a certain stress could be predicted by combination of Paris law and pore size distribution.Pore depth was found to dominate the stress field around the pore on the surface and the maximum stress increases sharply when the pore intercepted with the surface at its top.The microstructure of cast Al alloys usually is composed of primary Al dendrites,eutectic silicon,Fe-rich particles and other intermetallic particles are dependent upon alloy composition and heat treatment.The coalescence of microcracks initiated from the fractured secondary phases was clearly found and can accelerate the initiation and propagation of the fatigue cracks.A link between defect features and the fatigue strength needs to be established through a good understanding of the fatigue damage mechanisms associated with the microstructural features under specific loading conditions.This paper reviews the influences of shrinkage/gaspores and secondary phase particles,formed during casting process,on the fatigue life of Al-Si-Mg cast Al alloys.

Study of the morphology and properties of diamond joints brazed with carbide-reinforced Cu-Sn-Ti filler metal

Cu-Sn-Ti brazing filler is a new type of copper-based brazing filler for brazing diamond tools currently used in industry,but it suffers from poor wear resistance,high brazing temperature and low bond strength.This paper provides a way to improve the strength of dia-mond-brazed joints by adding zirconium carbide and tungsten carbide reinforcing phase particles to the Cu-Sn-Ti alloy,respectively.Dia-mond particles were attached to Q460 steel using Cu-Sn-Ti composite filler with the addition of the reinforcing phase,and experimental in-struments such as scanning electron microscope,X-ray diffractometer and energy spectrometer were used to investigate the brazed joint per-formance of the composite brazing material for brazing diamond.The results show that the addition of enhanced phase particles resulted in a metallurgical reaction at the joint of the composite brazed diamond,achieving a higher strength joint with no obvious cracks at the interface,while the addition of 15 wt.%WC resulted in excellent wear resistance and the highest hardness at the joint interface.

Experiment and Numerical Simulation of Free Water Jet by a Central-body Nozzle

The recent research about cavitation jet mainly focuses on the organ-pipe nozzle and triangular nozzle. The research content mainly includes the optimized design about the structure of nozzles, the observation and flow analysis about the cavitation jet in the water, and the theory of rock attacked by the cavitation jet, while the energy characteristic of the free jet is not studied yet. In China, the research about the central-body nozzle is almost empty. For the purpose of studying the energy characteristic and the structure of free water jet discharged from central-body nozzle, an experiment with phase Doppler particle anemometry（PDPA） technology is carried out to measure the free water jet flow, which is produced by a central-body nozzle under the jet pressure of 15 MPa. While five sections with different axial distances from the nozzle outlet are selected for data process and analysis, the axial and radial velocity and the droplets of the particle size are studied. Meanwhile, numerical calculation of corresponding flow field is conducted by using volume of fluid（VOF） multiphase model, and the jet flow feature is discussed. The experimental and calculating results show that the axial velocity of high speed jet flow dissipates slowly in the air, and the core area and diffused area are discovered. The diameter of droplet in the core area is small, and jet energy is concentrated, while in the diffusion area, water is mingled with ambient air and radial velocity is relatively large. Obvious low-pressure area exists behind the central body and potential cavitation may occur in that area. The proposed research reveals the energy characteristic of free jet discharged from central-body nozzle, provides the theoretical basis for preestimating erosion feature of the central-body nozzle and also the theoretical foundation for revealing the mechanism of erosion.

Kinetics of Precipitation Behavior of Second Phase Particles in Ferritic Ti-Mo Microalloyed Steel

Two types of stress relaxation tests were carried out to investigate the incubation time for incipient precipi-tation of Ti（C,N） in deformed austenite and （Ti,Mo）C in ferrite of ferritic Ti-Mo microalloyed steel The size dis-tribution, amount and chemical composition of precipitates were obtained by using physicochemical phase analysis, and calculated according to thermodynamics and kinetics. The experimental results demonstrated that the incubation time was reduced with increasing Ti content, and prolonged with the addition of Mo. After 30 % deformation at 850 ℃, the nucleation of strain-induced Ti（C,N） was a relatively slow process. On the other hand, the temperature where the nucleation rate of （Ti, Mo）C in ferrite was the highest descended first and then ascended with increasing Ti content, and so did the temperature where the incubation time was the shortest. The key point is that the tempera-ture of steel containing about 0.09 % Ti is the lowest. The mass fraction of MC-type particles with size smaller than 10 nm in steel containing 0.09% Ti and 0.2% Mo reached 73.7%. The size distributions of precipitates in steel containing 0.09% Ti were relatively concentrated compared with that in steel containing 0.07% Ti.

Influence of Self-excited Vibrating Cavity Structure on Droplet Diameter Characteristics of Twin-fluid Nozzle

It is a great challenge to find effective atomizing technology for reducing industrial pollution; the twin-fluid atomizing nozzle has drawn great attention in this field recently. Current studies on twin-fluid nozzles mainly focus on droplet breakup and single droplet characteristics. Research relating to the influences of structural parameters on the droplet diameter characteristics in the flow field is scarcely available. In this paper, the influence of a self-excited vibrating cavity structure on droplet diameter characteristics was investigated. Twin-fluid atomizing tests were performed by a self-built open atomizing test bench, which was based on a phase Doppler particle analyzer(PDPA). The atomizing flow field of the twin-fluid nozzle with a self-excited vibrating cavity and its absence were tested and analyzed. Then the atomizing flow field of the twin-fluid nozzle with different self-excited vibrating cavity structures was investigated.The experimental results show that the structural parameters of the self-excited vibrating cavity had a great effect on the breakup of large droplets. The Sauter mean diameter(SMD) increased with the increase of orifice diameter or orifice depth. Moreover, a smaller orifice diameter or orifice depth was beneficial to enhancing the turbulence around the outlet of nozzle and decreasing the SMD. The atomizing performance was better when the orifice diameter was2.0 mm or the orifice depth was 1.5 mm. Furthermore, the SMD increased first and then decreased with the increase of the distance between the nozzle outlet and self-excited vibrating cavity, and the SMD of more than half the atomizing flow field was under 35 μm when the distance was 5.0 mm. In addition, with the increase of axial and radial distance from the nozzle outlet, the SMD and arithmetic mean diameter(AMD) tend to increase. The research results provide some design parameters for the twin-fluid nozzle, and the experimental results could serve as a beneficial supplement to the twin-fluid nozzle study.

Modeling the influence of forced ventilation on the dispersion of droplets ejected from roadheader-mounted external sprayer

In order to reveal the influence of forced ventilation on the dispersion of droplets ejected from roadheader-mounted external sprayer,the paper studies the air-flowing field and the droplet distribution under the condition of gentle breeze and normal forced ventilation in heading face using the particle tracking technology of computational fluid dynamics(CFD).The results show that air-flowing tendency in the same section presents great comparability in the period of gentle breeze and forced ventilation,and the difference mainly embodies in the different wind velocity.The influence of ventilation on the dispersion of droplets is faint under the gentle breeze condition.The droplet can be evenly distributed around the cutting head.However,under the normal forced ventilation,a large number of droplets will drift to the return air side.At the same time,droplet clusters are predominantly presented in the lower part of windward side and the middle of the leeward side around the cutting head.In contrast,the droplet concentration in other parts around cutting head decreases a lot and the droplets are unable to form close-grained mist curtain.So the dust escape channel is formed.In addition,the simulation results also reveal that the disturbance of air flow on the droplet distribution can be effectively relieved when using ventilation duct with Coanda effect(VDCE).Field experiment results show that the dust suppression efficiency of total dust and respirable dust increases respectively by 10.5%and 9.3%when using VDCE,which proves that it can weaken the influence of airflow on droplet dispersion.