Highly efficient conversion of surplus electricity to hydrogen energy via polysulfides redox

Decoupled electrolysis of water is a promising strategy for peak load regulation of electricity.The key to developing this technology is to construct decoupled devices containing stable redox mediators and corresponding efficient catalysts,which remains a considerable challenge.Herein,we designed a high-performance device,using polysulfides as mediators and graphene-encapsulated CoNi as catalysts.It produced H2 with a low potential of 0.82 V at 100 mA/cm^(2),saving 60.2%more energy than direct water electrolysis.The capacity of H2 production reached 2.53105 mAh/cm^(2),which is the highest capacity reported so far.This device exhibited excellent cyclability in 15-day recycle tests,without any decay of performance.The calculation results revealed that the electronic structure of the graphene shell was modulated by the electron transfer from N-dopant and metal core,which significantly facilitated recycle of polysulfides on graphene surfaces.This study provides a promising method for constructing a smart grid by developing efficient decoupled devices.

Inverse Proportion Technique Based Scheduling Strategy for Energy Storage System Considering Load Demand Differences

The energy storage system(ESS)as a demand-side management(DSM)resource can effectively smooth the load power fluctuation of a power system.However,designing a more reasonable ESS operational strategy will be a prerequisite before incorporating the energy storage device into DSM.As different load levels have different demands for the real-time chargedischarge power of an ESS,this paper proposes a heuristic ESS operation scheduling strategy which can take into account the electrical load demand differences.In this paper,firstly,two demand degree concepts for charging power and discharging power are defined to describe the differentiated ESS demand under the condition of different electrical load levels.Secondly,an inverse proportion technique based ESS scheduling strategy,with the consideration of the load demand difference,is proposed in this paper.Thirdly,some evaluating indices are defined in this paper for describing the influence of the proposed strategy on the smoothing degree of the daily load curve.Finally,several case studies are designed to verify the validity and correctness of the proposed technique,and the results show that the proposed technique can effectively smooth the load curve and improve the ability of peak shaving and valley filling.