The concrete molecule-fixed (MF) kinetic energy operator for penta-atomic molecules is expressed in terms of the parameter δ, the matrix element Gij, and angular momentum operatorj. The applications of the operator a...The concrete molecule-fixed (MF) kinetic energy operator for penta-atomic molecules is expressed in terms of the parameter δ, the matrix element Gij, and angular momentum operatorj. The applications of the operator are also discussed. Finally, a general compact form of kinetic energy operator suitable for calculating the rovibrational spectra of polyatomic molecules is presented.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 29573096)
文摘The concrete molecule-fixed (MF) kinetic energy operator for penta-atomic molecules is expressed in terms of the parameter δ, the matrix element Gij, and angular momentum operatorj. The applications of the operator are also discussed. Finally, a general compact form of kinetic energy operator suitable for calculating the rovibrational spectra of polyatomic molecules is presented.
