Effective Elimination of Hazardous Chromium (VI) Using Periodic Elements and Contemporary Adsorption Methods by Using Magnesium Ferrite Nanoparticle: A Review

A well-known hazardous metal and top contaminant in wastewater is hexavalent chromium. The two forms of most commonly found chromium are chromate ( CrO 4 2− ) and dichromate ( Cr 2 O 7 2− ). Leather tanning, cooling tower blow-down, plating, electroplating, rinse water sources, anodizing baths etc. are the main sources of Cr (VI) contamination. The Cr (VI) is not only non-biodegradable in the environment but also carcinogenic to living population. It is still difficult to treat Cr contaminated waste water effectively, safely, eco-friendly, and economically. As a result, many techniques have been used to treat Cr (VI)-polluted wastewater, including adsorption, chemical precipitation, coagulation, ion-exchange, and filtration. Among these practices, the most practical method is adsorption for the removal of Cr (VI) from aqueous solutions, which has gained widespread acceptance due to the ease of use and affordability of the equipment and adsorbent. It has been revealed that Fe-based adsorbents’ oxides and hydroxides have high adsorptive potential to lower Cr (VI) content below the advised threshold. Fe-based adsorbents were also discovered to be relatively cheap and toxic-free in Cr (VI) treatment. Fe-based adsorbents are commonly utilized in industry. It has been discovered that nanoparticles of Fe-, Ti-, and Cu-based adsorbents have a better capacity to remove Cr (VI). Cr (VI) was effectively removed from contaminated water using mixed element-based adsorbents (Fe-Mn, Fe-Ti, Fe-Cu, Fe-Zr, Fe-Cu-Y, Fe-Mg, etc.). Initial findings suggest that Cr (VI) removal from wastewater may be accomplished by using magnesium ferrite nanomaterials as an efficient adsorbent.

Study on the methods to calculate the numbers of elements in every period in the periodic table

The previous methods of figuring the numbers of chemical elements is summed up in this paper. Based on that, another two creative calculative methods are introduced as well.

The Trace Elements are Bounded by Organic Functional Groups in Coal:A Studying Result Based on FTIR Analysis

The relationship between trace elements in coal and organic functional groups of coal, also some of aromatic structure, was investigated by using curve fitting of infrared spectra. Cluster analysis was also performed according to the degree of affinity of organic groups to the trace elements. The results show that there is a possibility that trace elements, especially LREE, were bound to peripheral organic functional groups of middle rank coal macromolecule. The most possible functional group that binds trace element is the hydroxyl, and to the less degree, the asymmetric -CH3 and 〉CH2 stretching, -CH3 stretching, etc. The degree of affinity of trace elements to different functional groups varies. The tendency obeys the natural structural changing law of trace elements-- the periodic law. The deviation of some trace elements from this regular trend is attributed to the deviation of intrinsic ＂confusion degree＂ （conventional molar entropy） of the matter system of coal basin, which is affected by the inner and outer factors during the evolution.

A Table That Produces Elements

How do elements originate, how atoms are formed, and what are the laws? According to the unified logic of “Tong Yi Lun Thought”, combined with the elements’ attributes and the atomic composition that have been discovered now, after determining that the mechanism of increasing yang in the atomic system is the increase of proton number, the Bian Zheng relationship among proton, neutron and electron determines that there are only 128 kinds of elements in the atomic system. At the same time, element atoms have corresponding logical relations when they are generated.

The periodic law of trace elements in coal——A case study of the 5~# coal from the Weibei Coalfield

To better understand the 5# coal （late Paleozoic） from the Weibei Coalfield, nine samples were collected in different locations of the 5# coal seam. The correlation coefficients between 51 trace elements including organic carbon, as well as ash, were calculated by statistical method. The variations of the squares of correlation coefficients with the first ionization energy, as well as ion radii of the corresponding elements, were comparatively investigated. The results show that the distribution law of the trace elements is in accordance with the chemical element periodic law and can be theoretically explained in detail. The distribution law is also suitable to the stable coal layer formed under the function of the coal accumulation, such as that in the Ordos Basin.

PERIODIC TABLE OF THE ELEMENTS

Table 4.1.Reviced 2011 by D.E.Groom（LBNL）,and E.Bergren.

Theoretical aspects of selecting repeated unit cell model in micromechanical analysis using displacement-based finite element method

Repeated Unit Cell（RUC）is a useful tool in micromechanical analysis of composites using Displacement-based Finite Element（DFE）method,and merely applying Periodic Displacement Boundary Conditions（PDBCs）to RUC is almost a standard practice to conduct such analysis.Two basic questions arising from this practice are whether Periodic Traction Boundary Conditions（PTBCs,also known as traction continuity conditions）are guaranteed and whether the solution is independent of selection of RUCs.This paper presents the theoretical aspects to tackle these questions,which unify the strong form,weak form and DFE method of the micromechanical problem together.Specifically,the solution’s independence of selection of RUCs is dealt with on the strong form side,PTBCs are derived from the weak form as natural boundary conditions,and the validity of merely applying PDBCs in micromechanical Finite Element（FE）analysis is proved by referring to its intrinsic connection to the strong form and weak form.Key points in the theoretical aspects are demonstrated by illustrative examples,and the merits of setting micromechanical FE analysis under the background of a clear theoretical framework are highlighted in the efficient selection of RUCs for Uni Directional（UD）fiber-reinforced composites.

Temperature stability of magnetic field for periodic permanent-magnet focusing system

In this study, finite element analysis based on an Ansoft Maxwell software was used to reveal the temperature stability of a magnet ring and the equivalent structural periodic permanent-magnet（PPM） focusing system. It is found that with the temperature increasing, the decrease rate of magnetic induction peak（Bz）maxof single magnet ring is greater than that of remanence Brof magnet in the range from room temperature to 200 °C, however,the PPM focusing system do have the same temperature characteristics of permanent-magnet materials. It indicates that the magnetic temperature properties of the PPM system can be effectively controlled by adjusting the temperature properties of the magnets. Moreover, the higher permeability of the magnets indicates the less Hcb, giving rise to lower magnetic induction peak （Bz）′max： Finally, it should be noted that the magnetic orientation deviation angle θ（／15°） of permanent magnets has little effect on the focusing magnetic field of the PPM system at different temperatures and the temperature stability. The obtained results are beneficial to the design and selection of permanent magnets for PPM focusing system.

Prediction of vibrations induced by trains on line 8 of Beijing metro

This paper mainly discusses the problem of ground-borne vibrations due to the planned line 8 of Beijing metro which passes under the National Measurement Laboratory.A lot of vibration sensitive equipments are placed in the laboratory.It is therefore necessary to study the impact of vibrations induced by metro trains on sensitive equipments and important to propound a feasible vibration mitigation measure.Based on the coupled periodic finite element-boundary element (FE-BE) method,a 3D dynamic track-tunnel-soil interaction model for metro line 8 has been used to predict vibrations in the free field induced by trains running at variable speeds between 30 km/h and 80 km/h.Four types of track structures commonly used on the Beijing metro network have been considered:(1) high resilience direct fixation fasteners,(2) Vanguard fasteners,(3) a floating slab track and (4) a floating ladder track.For each of these track types,the vibration isolation efficiency has been compared.The results of the numerical study can be used to predict vibrations in nearby buildings and to decide upon effective vibration countermeasures.

Effect of sample size on the response of DEM samples with a realistic grading

This paper shows that for DEM simulations of triaxial tests using samples with a grading that is repre- sentative of a real soil, the sample size significantly influences the observed material response. Four DEM samples with identical initial states were produced： three cylindrical samples bounded by rigid wails and one bounded by a cubical periodic cell, When subjected to triaxial loading, the samples with rigid boundaries were more dilative, stiffer and reached a higher peak stress ratio than the sample enclosed by periodic boundaries. For the rigid-wall samples, dilatancy increased and stiffness decreased with increasing sample size, The periodic sample was effectively homogeneous, The void ratio increased and the contact density decreased close to the rigid walls, This heterogeneity reduced with increasing sample size. The positions of the critical state lines （CSLs） of the overall response in e-log p＇ space were sensitive to the sample size, although no difference was observed between their slopes. The critical states of the interior regions of the rigid-wall-bounded samples approached that of the homogeneous periodic sample with increasing sample size. The ultimate strength of the material at the critical state is independent of sample size.

Multiaxial fatigue life prediction of composite materials

In order to analyze the stress and strain fields in the fibers and the matrix in composite materials,a fiber-scale unit cell model is established and the corresponding periodical boundary conditions are introduced.Assuming matrix cracking as the failure mode of composite materials,an energy-based fatigue damage parameter and a multiaxial fatigue life prediction method are established.This method only needs the material properties of the fibers and the matrix to be known.After the relationship between the fatigue damage parameter and the fatigue life under any arbitrary test condition is established,the multiaxial fatigue life under any other load condition can be predicted.The proposed method has been verified using two different kinds of load forms.One is unidirectional laminates subjected to cyclic off-axis loading,and the other is filament wound composites subjected to cyclic tension-torsion loading.The fatigue lives predicted using the proposed model are in good agreements with the experimental results for both kinds of load forms.