Fluorite Ce0.8Sm0.2O2-δ（SDC） nanopowder with a crystallite size of 15 nm was synthesized by a co-precipitation method. An SDC porous layer was coated onto a BaCo0.7Fe0.2Nb0.1O3-δ（BCFN） mixed conductor to improve...Fluorite Ce0.8Sm0.2O2-δ（SDC） nanopowder with a crystallite size of 15 nm was synthesized by a co-precipitation method. An SDC porous layer was coated onto a BaCo0.7Fe0.2Nb0.1O3-δ（BCFN） mixed conductor to improve its oxygen transport behavior. The results show that the SDC-coated BCFN membrane exhibits a remarkably higher oxygen permeation flux（JO2） than the uncoated BCFN in the partial oxidation of coke oven gas（COG）. The maximum JO2 value of the SDC-coated BCFN is 18.28 mL ·min^-1·cm^-2 under a COG/air flux of 177 mL ·min^-1/353 mL ·min^-1 at 875℃ when the thickness of the BCFN membrane is 1 mm; this JO2 value is 23% higher than that of the uncoated BCFN membrane. This enhancement is likely because of the higher oxygen ionic conductivity of SDC, which supplies oxygen vacancies and accelerates oxygen exchange on the membrane/coating layer/gas three-phase boundary.展开更多
To evaluate the property of the organic coatings in oil and gas plants, the aging process was studied in high temperature and high CO_2 partial pressure environment. Correlations were developed between the macroscopic...To evaluate the property of the organic coatings in oil and gas plants, the aging process was studied in high temperature and high CO_2 partial pressure environment. Correlations were developed between the macroscopic properties and microstructure of the organic coatings. The surface appearance, mechanical properties, and permeability of the organic coatings were measured. Furthermore, the crystal structure of the organic coatings was investigated through synchrotron radiation grazing incidence X-ray diffraction（GIXRD） on the BL14B1 beam line in Shanghai Synchrotron Radiation Facility. Combined with the Fourier transform infrared spectroscopy, the molecular structure of the organic coatings was investigated. The experimental results indicate that the thickness variation and weight loss of the organic coatings increase with the immersion time, and the penetration resistance of the coating obviously decreases as the temperature rises. Moreover, the degradation of the organic coatings with immersion time in high temperature and high CO_2 partial pressure environment is caused by the amorphization of the organic coatings as the groups and bonds of the organic coatings were not damaged.展开更多
Controlled-release urea was fabricated by coating urea particles with a polymer latex in a fluidized bed. The latex film coated on the urea particle surface was hydrophilic and swelled in water. The film swelling in w...Controlled-release urea was fabricated by coating urea particles with a polymer latex in a fluidized bed. The latex film coated on the urea particle surface was hydrophilic and swelled in water. The film swelling in water and urea solution and properties of the swollen film were studied. The film swelling in urea solution followed the Lagergren＇s pseudo-first order kinetics with the swelling coefficient depending on the film material and experimental conditions. The effects of swelling on film structure and permeability were studied. The film permeability coefficient decreased with increasing swelling ratio with an approx- imately linear relationship. Based on the film formation process and structure of the swollen film. a film structure model consisting of dense and swollen phases was proposed. The permeability coefficient of the spherical film and cumulative release of urea from the coated particles were calculated from the swelling ratio of the spherical film. which was determined from the expansion curve of the coated particle during the release process, The calculated and measured release curves agreed well, This research indicates that the swelling of the hydrophilic film and the controlled-release mechanism are important factors in the development of controlled-release urea.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. 51472156, 51072112, and 51311130110)the Innovation Foundation of Shanghai University (No. sdcx2012033)the Training Funding Project for Young College Teachers of Shanghai
文摘Fluorite Ce0.8Sm0.2O2-δ（SDC） nanopowder with a crystallite size of 15 nm was synthesized by a co-precipitation method. An SDC porous layer was coated onto a BaCo0.7Fe0.2Nb0.1O3-δ（BCFN） mixed conductor to improve its oxygen transport behavior. The results show that the SDC-coated BCFN membrane exhibits a remarkably higher oxygen permeation flux（JO2） than the uncoated BCFN in the partial oxidation of coke oven gas（COG）. The maximum JO2 value of the SDC-coated BCFN is 18.28 mL ·min^-1·cm^-2 under a COG/air flux of 177 mL ·min^-1/353 mL ·min^-1 at 875℃ when the thickness of the BCFN membrane is 1 mm; this JO2 value is 23% higher than that of the uncoated BCFN membrane. This enhancement is likely because of the higher oxygen ionic conductivity of SDC, which supplies oxygen vacancies and accelerates oxygen exchange on the membrane/coating layer/gas three-phase boundary.
基金Funded by the National Science and Technology Major Project(2011ZX05022-013)
文摘To evaluate the property of the organic coatings in oil and gas plants, the aging process was studied in high temperature and high CO_2 partial pressure environment. Correlations were developed between the macroscopic properties and microstructure of the organic coatings. The surface appearance, mechanical properties, and permeability of the organic coatings were measured. Furthermore, the crystal structure of the organic coatings was investigated through synchrotron radiation grazing incidence X-ray diffraction（GIXRD） on the BL14B1 beam line in Shanghai Synchrotron Radiation Facility. Combined with the Fourier transform infrared spectroscopy, the molecular structure of the organic coatings was investigated. The experimental results indicate that the thickness variation and weight loss of the organic coatings increase with the immersion time, and the penetration resistance of the coating obviously decreases as the temperature rises. Moreover, the degradation of the organic coatings with immersion time in high temperature and high CO_2 partial pressure environment is caused by the amorphization of the organic coatings as the groups and bonds of the organic coatings were not damaged.
基金The authors express their gratitude for the financial support of this study by the National Natural Science Foundation of China （NSFC No. 20876085）.
文摘Controlled-release urea was fabricated by coating urea particles with a polymer latex in a fluidized bed. The latex film coated on the urea particle surface was hydrophilic and swelled in water. The film swelling in water and urea solution and properties of the swollen film were studied. The film swelling in urea solution followed the Lagergren＇s pseudo-first order kinetics with the swelling coefficient depending on the film material and experimental conditions. The effects of swelling on film structure and permeability were studied. The film permeability coefficient decreased with increasing swelling ratio with an approx- imately linear relationship. Based on the film formation process and structure of the swollen film. a film structure model consisting of dense and swollen phases was proposed. The permeability coefficient of the spherical film and cumulative release of urea from the coated particles were calculated from the swelling ratio of the spherical film. which was determined from the expansion curve of the coated particle during the release process, The calculated and measured release curves agreed well, This research indicates that the swelling of the hydrophilic film and the controlled-release mechanism are important factors in the development of controlled-release urea.
