Due to their unique physicochemical properties,the anion radical and dianion of perylene diimide derivatives(PDIs)recently attracted significant attention for organic semiconductors.However,the impact of packing struc...Due to their unique physicochemical properties,the anion radical and dianion of perylene diimide derivatives(PDIs)recently attracted significant attention for organic semiconductors.However,the impact of packing structure and the radical content for carrier transport in the solid state still need to be determined.Bringing the electron-withdrawing groups is an effective strategy for enablingπ−πstacking distance.Here,bay-tetrachloro-substituted PDI(B-4Cl-PDI)anion radical and dianion films were fabricated quantitatively doped with N_(2)H_(4)·H_(2)O.The radical contents were quantitatively calculated by absorption spectra in different doping ratios.The X-ray powder diffraction patterns showed that the anion radical presented a crystalline structure,and dianion aggregates exhibited an amorphous structure.With precise manipulation of the radical content,the anion radical aggregates and dianion aggregates showed the maximum electrical conductivity value of 0.024 and 0.0018 S/cm,respectively.The experiment results show that doping level and aggregate structure play a crucial role in electronic transport properties.展开更多
Herein, we reported a new label-free and fluorescence turn-on biosensor based on cationic conjugated poly(9,9-bis(6'-N,N,N-trimethylammonium)hexyl)fluorine phenylene)(PFP) and perylene diimide derivatives(PDI...Herein, we reported a new label-free and fluorescence turn-on biosensor based on cationic conjugated poly(9,9-bis(6'-N,N,N-trimethylammonium)hexyl)fluorine phenylene)(PFP) and perylene diimide derivatives(PDI). Cationic PFP, single-stranded nucleic acid and PDI were used as signal reporter, probe and fluorescence quencher, respectively. In the presence of nucleic acids, they form complexes with PFP and PDI through strong electrostatic attraction interactions, resulting in PDI aggregating on nucleic acids and fluorescence of PFP being quenched. When nucleic acids are hydrolyzed by enzymes or their conformation is changed via recognizing targets, the effective aggregation of PDI is disrupted and the quenching ability is decreased. Thus the fluorescence of PFP recovers significantly. By taking advantage of the mechanism, we construct a new biosensor for endonuclease and small molecules detection. Here, S1 nuclease and bisphenol A are used as model systems. The detection limit of the SI nuclease and BPA are1.0×10^-6U/mL and 0.05 ng/mL, respectively. Our method is sensitive, cost-effective and simple, and provides a new platform for bioanalysis.展开更多
The perylene diimide derivatives(s-THBPDI and d-THBPDI) bearing oxygen bridged twisty heptatomic biphenyl in the bay positions of the perylene core through acetylene bond were designed and synthesized.The photophysi...The perylene diimide derivatives(s-THBPDI and d-THBPDI) bearing oxygen bridged twisty heptatomic biphenyl in the bay positions of the perylene core through acetylene bond were designed and synthesized.The photophysical properties of the functionalized dyes were investigated in solution and solid state by UV-vis and photoluminescence(PL) spectra.Their UV-vis and PL spectrum both exhibited the different concentration-dependent behaviors due to the difference of chemical structure.Moreover,cyclic voltammetry results indicated that the introduction of oxygen bridged twisted heptatomic biphenyl could decrease the LUMO energy level of the perylene diimide effectively and made it promising material in photoelectric devices.展开更多
基金National Key R&D Program of China(No.2020YFA0714604)National Natural Science Foundation of China(Nos.U20A6002,91833304,5152100222005107,52203221)+4 种基金Basic and Applied Basic Research Major Program of Guangdong Province,China(No.2019B030302007)Research and Development Funds for Science and Technology Program of Guangzhou,China(No.202007020004)Natural Science Foundation of Guangdong Province,China(Nos.2019B121205002,2022A1515010063)Fund of the Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates,China(No.2019B030301003)Funding by Science and Technology Projects in Guangzhou,China(Nos.202102020401,202102020561).
文摘Due to their unique physicochemical properties,the anion radical and dianion of perylene diimide derivatives(PDIs)recently attracted significant attention for organic semiconductors.However,the impact of packing structure and the radical content for carrier transport in the solid state still need to be determined.Bringing the electron-withdrawing groups is an effective strategy for enablingπ−πstacking distance.Here,bay-tetrachloro-substituted PDI(B-4Cl-PDI)anion radical and dianion films were fabricated quantitatively doped with N_(2)H_(4)·H_(2)O.The radical contents were quantitatively calculated by absorption spectra in different doping ratios.The X-ray powder diffraction patterns showed that the anion radical presented a crystalline structure,and dianion aggregates exhibited an amorphous structure.With precise manipulation of the radical content,the anion radical aggregates and dianion aggregates showed the maximum electrical conductivity value of 0.024 and 0.0018 S/cm,respectively.The experiment results show that doping level and aggregate structure play a crucial role in electronic transport properties.
基金the financial support from the National Natural Science Foundation of China(No. 21675106)the 111 Project(No. B14041)+2 种基金Natural Science Basic Research Plan in Shaanxi Province of China (No. 2017JM2019)the Program for Changjiang Scholars and Innovative Research Team in University (No. 14R33)the Program for Innovative Research Team in Shaanxi Province(No. 2014KCT-28)
文摘Herein, we reported a new label-free and fluorescence turn-on biosensor based on cationic conjugated poly(9,9-bis(6'-N,N,N-trimethylammonium)hexyl)fluorine phenylene)(PFP) and perylene diimide derivatives(PDI). Cationic PFP, single-stranded nucleic acid and PDI were used as signal reporter, probe and fluorescence quencher, respectively. In the presence of nucleic acids, they form complexes with PFP and PDI through strong electrostatic attraction interactions, resulting in PDI aggregating on nucleic acids and fluorescence of PFP being quenched. When nucleic acids are hydrolyzed by enzymes or their conformation is changed via recognizing targets, the effective aggregation of PDI is disrupted and the quenching ability is decreased. Thus the fluorescence of PFP recovers significantly. By taking advantage of the mechanism, we construct a new biosensor for endonuclease and small molecules detection. Here, S1 nuclease and bisphenol A are used as model systems. The detection limit of the SI nuclease and BPA are1.0×10^-6U/mL and 0.05 ng/mL, respectively. Our method is sensitive, cost-effective and simple, and provides a new platform for bioanalysis.
基金supported by the National Natural Science Foundation of China (Nos: 51173155,51472214)the Colleges and Universities Science and Technology Research Project of Hebei Province (No.QN20131070)
文摘The perylene diimide derivatives(s-THBPDI and d-THBPDI) bearing oxygen bridged twisty heptatomic biphenyl in the bay positions of the perylene core through acetylene bond were designed and synthesized.The photophysical properties of the functionalized dyes were investigated in solution and solid state by UV-vis and photoluminescence(PL) spectra.Their UV-vis and PL spectrum both exhibited the different concentration-dependent behaviors due to the difference of chemical structure.Moreover,cyclic voltammetry results indicated that the introduction of oxygen bridged twisted heptatomic biphenyl could decrease the LUMO energy level of the perylene diimide effectively and made it promising material in photoelectric devices.