Geochronology and Petrogeochemistry of Metallogenic Intrusions in the Shanmen Large-scale Silver Deposit in the Siping Area of Jilin Province, NE China

The Shanmen deposit, located in the Siping area of Jilin Province, is one of large-scale silver deposits in Northeast(NE) China. Due to its high Ag grade, associated gold resources and special tectonic location, this deposit has important theoretical and ore-prospecting significance. To present new data on the ore genesis, mineralization time and tectonic settings, the relationship between silver mineralization and intrusions in this deposit has been studied and some analyses have been carried out, including LA-ICP-MS zircon U-Pb dating, whole-rock major and trace element analysis and Sr-Nd-Pb isotope analysis of the granitoids associated with silver mineralization. Studies on deposit geology indicate that the ore-hosting granodiorite and monzogranite have intimate genetic relationships with silver mineralization. LA-ICP-MS zircon U-Pb dating results of the both intrusions are 167.6 ± 1.9 Ma and 167.0 ± 1.5 Ma, respectively, implying that the two intrusions and associated silver mineralization in the Shanmen deposit formed during the Middle Jurassic. Major element analytical data suggest that the two intrusions are high-K calc–alkaline series I-type granites and belong to metaluminous and peraluminous rocks. Both intrusions have similar REE characteristics with regard to the relative enrichment of LREEs, depletion of HREEs, obvious fractionation of LREEs and HREEs(ΣLREE/ΣHREE = 8.68–14.09,(La/Yb)_N = 12.51–21.96), moderately negative Eu anomalies as well as weakly negative Ce anomalies(δEu = 0.56–0.71, δCe = 0.93–1.09). Moreover, the samples are generally enriched in LILEs and depleted in HFSEs. The rock assemblages and geochemical characteristics of granitoids in the Shanmen deposit suggest that they formed in an active continental margin associated with the Paleo-Pacific plate subduction. The Sr-Nd-Pb isotope compositions show that both the granodiorite and monzogranite have low Sr initial ratios and high Sm/Nd initial ratios. The ε_(Nd)(t) values and young Nd-model ages are-3.2 to-1.7 and 990 Ma to 1110 Ma, respectively. Considering the Sr-Nd isotope compositions, in conjunction with the relatively high ~(206)Pb, ~(207)Pb and ~(208)Pb, alongside the relatively low ~(204)Pb, it can be concluded that the Middle Jurassic intermediate-acidic magma represented by the studied monzogranite and granodiorite in the Shanmen deposit, was derived from the partial melting of juvenile lower crust enriched in mantle-derived materials and affected by the mixing of ancient crustal materials during the ascension and intrusion processes.

Geochronology and petrogeochemistry of Late Permian volcanic rocks in the B.Xiengnou area,Northwestern Laos:Petrogenesis and tectonic significance

The Nan Suture and Sukhothai Arc Terrane are products of the eastward subduction of the Paleotethyan Ocean during the Late Carboniferous to Triassic.However,their footprints in northwestern Laos are poorly constrained.New geochronological and geochemical data presented in this study demonstrate a Late Permian origin for the andesitic rocks in the B.Xiengnou area rather than Late Triassic.The breccia-bearing andesitic tuff in the B.On ultramafic complex yield a zircon U-Pb age of 260±1.4 Ma,geochemically displaying a MORB-like signature.The andesitic tuff in the B.Kiophoulan-B.Houayhak belt gave the U-Pb age of 254±1.3 Ma,with arc-like geochemical affinity.By combining geochronological and geochemical data from the Nan Suture and Sukhothai Arc Terrane,the authors suggest that the andesitic rocks in the B.On ultramafic complex formed in a back-arc basin background,which connected the Jinghong and Nan back-arc basin during the Permian;while the andesitic tuff in the B.Kiophoulan-B.Houayhak belt erupted in the Sukhothai continental arc setting.

Petrogeochemistry, geochronology and its geological significance of the granite from Baishipo Ag deposit, Dabie orogen

1 Introduction Granitoid magmas have been widely used as a natural probe for tracing the crustal evolution process(Martin et al.,2005).Mesozoic granitoids are widespread in the Dabie

Geochronology and Geochemistry of the Early Paleozoic Ore-host Volcanic Sequence in the Kalatag Area,East Tianshan,NW China:Implications for the Tectonic Evolution

The East Tianshan contains many late Paleozoic magmatic and polymetallic deposits.Recent studies demonstrate that the early Paleozoic volcanic rocks discovered in the northern region of East Tianshan can be subdivided into the Daliugou,Hongliuxia and Kalatag formations.Here,we report zircon U-Pb ages of volcanic rocks and quartz diorite porphyry,together with whole-rock geochemical and Sr-Nd isotope data of early Paleozoic volcanic rocks,in order to investigate their petrogenesis and geodynamic setting.Zircon U-Pb analyses of the rocks suggest that the Kalatag Formation formed at ca.438-413 Ma.Geochemical characteristics of the early Paleozoic volcanic rocks exhibit typical subduction-related features.They have high Mg^(#)(44-75),positiveε_(Nd)(t)values(0.25-7.88),low^(87)Sr/^(86)Sr ratios(0.70457 to 0.70588)and young two-stage Hf isotope model ages(551-446 Ma),consistent with a depleted mantle origin with limited crustal contamination.The basaltic andesite and andesite have relatively high MgO contents(6.1-9.4 wt%),suggesting that they belong to high-magnesian andesites.They were most likely derived from the partial melting of mantle peridotite caused by the addition of fluids released by subducted oceanic slab.Based on regional geology,geochemical characteristics and previous studies,we infer that the southward subduction of the Junggar Ocean slab resulted in the generation of early Paleozoic volcanic rocks and arc setting-related metallogenic systems in the Kalatag area.

Litho-Structural and Geochemistry Analysis of Granitoids from Mount Fouimba and Goma in Seguela Area (Central-Western Côte d’Ivoire)

The petrogeochemical analysis of the granitoids of Mount Fouimba and Mount Goma in the Seguela region (central-western C?te d’Ivoire) is the subject of this study. This analysis combines remote sensing, geophysics, petrography and geochemistry, in order to determine the major characteristics of the granitoids in the study area, and above all to participate in the detailed mapping of all the Ivorian terrains. The granitoids encountered in this region are essentially two-mica granites, granodiorites and porphyry basalts. Chemical analysis indicates that these granitoids are of the ferrous and magnesian type with peraluminous to weakly metaluminous characteristics. They originate from the mantle and were emplaced in an active continental margin context.

Geochronology, petrogenesis and tectonic significance of Dahongliutan pluton in Western Kunlun orogenic belt, NW China

The Dahongliutan granitic pluton,in the eastern part of the West Kunlun orogenic belt,provides significant insights for studying the tectonic evolution of West Kunlun.This paper presents a systematic study of LA-ICP-MS zircon U Pb age,major and trace elements,Sr-Nd-Hf isotopes,and the first detailed Li isotope analysis of the Dahongliutan pluton.LA-ICP-MS zircon U Pb dating shows that the Dahongliutan granites were emplaced in the Late Triassic((213±2.1)Ma).Geochemical data show relatively high SiO2 contents(68.45 wt%73.62 wt%)and aluminum saturation index(A/CNK=1.111.21)indicates peraluminous high-K calc-alkaline granite.The Dahongliutan granites are relatively high in light rare earth elements(LREE)and large ion lithophile elements(LILEs)(e.g.,Rb,K,Th),and relatively depleted in high field strength elements(HFSEs)(e.g.,Nb,Ta,P,Ti).TheεNd(t)values range from 8.71 to 4.73,and(87Sr/86Sr)i=0.70870.71574.Zircons from the pluton yield 176Hf/177Hf values of 0.2826181 to 0.2827683,andεHf(t)values are around 0;the two-stage Hf model ages range from 0.974 to 1.307 Ga.Theδ7Li values are 0.76‰3.25‰,with an average of 2.53‰.Isotopic compositions of the pluton suggest a mixed trend between the partial melting of the Middle Proterozoic ancient crustal material and a juvenile mantle-derived material.This study infers that the Dahongliutan rock mass is formed in the post-collisional extension environment,when the collision between South Kunlun and the Tianshuihai terranes results in the closure of the Palaeo-Tethys.The mantle-derived magma results in partial melting of the lower crust.

Geochemical Constrains on Petrogenesis and Tectonic Setting of Volcanic Rocks from the Baimianxia and Sanwan Formations in the Northern Margin of the Yangtze Plate

On the basis of petrogeochemical data, the volcanic lavas of the Baimianxia Formation can be classified into two units： high TiO2 and low TiO2. The TiO2 concentration of the former is generally higher than 1%, which occurs in the lower part with high-grade metamorphism, but the latter is less than 1% and crops out in the upper part with low-grade metamorphism. The high-TiO2 unit is dominated by tholeiitic lavas showing high rare earth element （REE） contents （~REE = 83.4-180.8 pg/ g）, high light/heavy REE （LREE/HREE） ratios （LREE/HREE=2.17-5.85） and weak negative Eu anomaly （Eu=0.79-1.01）. Its trace element patterns display weak Nb-Ta anomalies with respect to Th, K, La, Ce, showing within-plate basalt affinities. In contrast, the low-TiO2 unit is characterized by low REE contents, low LREE/HREE ratios, and pronounced Nb-Ta anomalies, indicating typical arc or continental arc signature. Chondrite-normalized REE patterns of basalts and andesites from the Sanwan Formation are flat or LREE depletion, which is very similar to normal mid-oceanic basalt. Therefore, we suggest that these lavas should be formed in a back-arc basin setting. Sr-Nd isotopic data of the basalt in the lower part suggest that the rocks would have been formed in ~1144 Ma. Based on the geochemical and isotopic features of the basalts, we suggest that these rocks in the low part of the Baimianxia Formation should originate from an asthenospheric oceanic-island basalt-like mantle source, which may be produced by partial melting of garnet lherzolite, and significantly underwent fractional crystallization and crustal or lithospheric mantle contamination en route to the surface. However, laser ablation inductively coupled plasma mass spectrometry zircon U-Pb dating of the basalt sample from the upper part of the Baimianxia Formation gives a 437 Ma, indicating a Early Paleozoic age. The geochemical analysis in this paper suggests that they may originate from an arc or continental arc in response to aqueous fluids or melt expelled from a subducting slab, and the partial melting occurred in the garnet stability field. The samples of basalts and andesites in the Sanwan Formation show they are derived from depleted mantle source similar to normal mid-oceanic basalt. Finally, we can conclude that the lavas in the lower part of the Baimianxia Formation represent the geological records of rift-related volcanism in the middle Proterozoic, which is commonly considered to be the precursor of continental breakup and followed by oceanic basin forming from Neoproterozoic to early Paleozoic. Whereas, the lavas in upper part of the Baimianxia Formation and Sanwan Formations may have been generated by the oceanic and continental conversion that occurred in the early Paleozoic.

Petrogenesis and tectonic implications of Late Triassic granitoids in the Alananshan,East Kunlun belt:evidence from geochemistry,geochronology,and zircon Hf isotopic compositions

The Qimantag in the East Kunlun Orogenic Belt has widespread Triassic magmatic rocks that have received scant attention,with an unresolved issue relating to its petrogenesis and geodynamics.In this paper,we used zircon U-Pb-Hf isotopes and whole-rock geochemistry to trace the petrogenesis and tectonic settings of the moyite and monzogranite from the Qimantag Alananshan,East Kunlun.The moyite and monzogranite are silicic(SiO_(2-)~69.9-76.41%),highly alkali(Na_(2)O+K_(2)O~7.29 to8.96 wt.%),with Mg^(#)about 10.4-30.34,indicative of a high-K calc-alkaline rock series.The rare earth element patterns diagram is right-leaning,with a negative Eu anomaly(δEu=0.31-0.68).They are enriched in Rb,K,and light rare earth elements but depleted in Nb,Ta,and Ti,with abundant amphibole,typical of I-type granites.U-Pb on zircon constrained the emplacement of the moyite at 223.9±2.6 Ma and monzogranite at 226.9±2.9 Ma.TheεHf(t)values range from-2.8 to+0.1 except for one outlier value of-7.0,corresponding two-stage model age of 1249-1437 Ma.Our combined geochemical and isotopic results indicate that the moyite and monzogranite were derived from partial melting of the lower thicken crust with the contribution from the older basement materials.These rocks formed in a post-collision setting that is transitional between compressive collision and extension orogeny.

Geochemistry,geochronology,and zircon Hf isotopic compositions of felsite porphyry in Xiangshan uranium orefield and its geological implication

Recently,a new kind of volcanic rock,felsite porphyry,has been revealed by drilling in Xiangshan area,Jiangxi Province,China.To better understand petrogenesis and magmatic evolution sequence of the Xiangshan volcanic-intrusive complex,we studied systematic petrology,geochemistry,LA-ICP-MS zircon U–Pb dating,and Hf isotope results of the felsite porphyry.Results show that the felsite porphyry has similar geochemical characteristics to the porphyroclastic rhyolite,which is the predominant lithology of Xiangshan uranium orefield.Felsite porphyry and porphyroclastic rhyolite have high SiO2,Al2O3,and K2O contents,low Na2O,and MgO contents,and slightly negative Eu anomalies.Moreover,these rocks are relatively depleted in large ion lithophile elements(K,Ba,and Sr)and are enriched in high field strength elements(Th,Zr,and Hf).LA-ICP-MS zircon U–Pb dating of the felsite porphyry yielded a crystallization age of 132.2±0.9 Ma,which is coeval to that of the porphyroclastic rhyolite.These ages signified that Xiangshan volcanic-intrusive complex formed in the Early Cretaceous,during which the entire South China was in the back-arc extension tectonic setting related to the subduction of the Pacific Plate under the Euroasian Plate.In-situ zircon Hf isotope data on a felsite porphyry sample show eHf(t)values from-8.82 to-5.11,while the Hf isotope two-stage model age(TDM2-Hf)ranges from 1513 to 1747 Ma.Combined with petrological,mineralogical,geochemistry,and geochronology results of the felsite porphyry,it is concluded that the felsite porphyry in Xiangshan might be originated from the partial melting of the Mesoproterozoic ancient metamorphic rocks,with possible input of small amounts of mantle materials.

Determination of properties of Proterozoic continental flood basalts of western part from North Qilian Mountains

Proterozoic volcanic rocks of the western part from the North Qilian Mountains are the products of continental rift volcanism, belonging to continental flood basalts, the petrogeochemistry of which apears to suggest that they are derived from sub-lithospheric mantle plume sources, but that they also show evidence of continental lithosphere components involvement. Their formation is the consequences of plume-lithosphere interactions and is precursive to the opening of the North Qilian Early-Paleozoic ocean basin.