Phase Regulation and Defect Passivation Enabled by Phosphoryl Chloride Molecules for Efficient Quasi‑2D Perovskite Light‑Emitting Diodes

Quasi-2D perovskites have attracted tremendous interest for application as lightemission layers in light-emitting diodes(LEDs).However,the heterogeneous n phase and non-uniform distribution still severely limit the further development of quasi-2D perovskite LEDs(Pero-LEDs).Meanwhile,the increased defect density caused by the reduced dimension and grain size induces non-radiative recombination and further deteriorates the device performance.Here,we found that a series of molecules containing phosphoryl chloride functional groups have noticeable enhancement effects on the device performance of quasi-2D Pero-LEDs.Then,we studied the modification mechanism by focusing on the bis(2-oxo-3-oxazolidinyl)phosphinic chloride(BOPCl).It is concluded that the BOPCl can not only regulate the phase distribution by decreasing the crystallization rate but also remain in the grain boundaries and passivate the defects.As a result,the corresponding quasi-2D Pero-LEDs obtained a maximum external quantum efficiency(EQE_(max))of 20.82%and an average EQE(EQE_(ave))of around 20%on the optimal 50 devices,proving excellent reproducibility.Our work provides a new selection of molecular types for regulating the crystallization and passivating the defects of quasi-2D perovskite films.

Phase-controlled coherent population trapping in superconducting quantum circuits

We investigate the influences of the-applied-field phases and amplitudes on the coherent population trapping behavior in superconducting quantum circuits. Based on the interactions of the microwave fields with a single A-type three-level fluxonium qubit, the coherent population trapping could be obtainable and it is very sensitive to the relative phase and amplitudes of the applied fields. When the relative phase is tuned to 0 or π, the maximal atomic coherence is present and coherent population trapping occurs. While for the choice of π/2, the atomic coherence becomes weak. Meanwhile, for the fixed relative phase π/2, the value of coherence would decrease with the increase of Rabi frequency of the external field coupled with two lower levels. The responsible physical mechanism is quantum interference induced by the control fields, which is indicated in the dressed-state representation. The microwave coherent phenomenon is present in our scheme, which will have potential applications in optical communication and nonlinear optics in solid-state devices.

Direct implementation of a scalable non-local multi-qubit controlled phase gate via optical fibres and adiabatic passage

This paper presents a direct implementation scheme of the non-local multi-qubit controlled phase gate by using optical fibres and adiabatic passage. The smaller operation number for implementing the multi-qubit controlled phase gate and needlessness for addressing individually save physical resource and lower the difficulties of experiment. Mean- while, the scheme is immune from some decoherence effects such as the atomic spontaneous emission and fibre loss. In principle, it is scalable.

Highly active mixed-phase TiO_2 photocatalysts fabricated at low temperature and the correlation between phase composition and photocatalytic activity

The idea of varying volume ratio of water to ethanol in solvent was firstly employed to yield phase composition controllable mixed- phase titanium dioxide (TiO2) photocatalysts via a low temperature solvothermal route at 353 K. It was found that anatase contents increase from 0 to 100% with increase of ethanol contents in solvent. The mixed-phase TiO2 with 60% anatase content exhibited the best photocatalytic activity in photodecomposing formaldehyde (FAD) under UV light irradiation, which increases by abou...

Phase control in an open A-type system with spontaneously generated coherence

This paper investigates the control role of the relative phase between the probe and driving fields on the gain, dispersion and populations in an open A system with spontaneously generated coherence （SGC）. It shows that by adjusting the value of the relative phase, a change from lasing with inversion to lasing without inversion can be realized; the values and frequency spectrum regions of the inversionless gain and dispersion can be obviously varied; high refractive index with zero absorption and electromagnetically induced transparency can be achieved. It is also found that when the driving field is resonant, the shapes of the dispersion and the gain curves versus the probe detuning are very similar if the relative phase of the dispersion lags π/2 than that of the gain, however for the off-resonant driving field the similarity will disappear; the gain, dispersion and populations are periodical functions of the relative phase, the modulation period is always 2π; the contribution of SGC to the inversionless gain and dispersion is much larger than that of the dynamically induced coherence.

Phase Control of Transient Optical Properties of Double Coupled Quantum-Dot Nanostructure via Gaussian Laser Beams

We theoretically analyze the transient properties of a probe field absorption and dispersion in a coupled semiconductor double-quantum-dot nanostructure.We show that in the presence of the Gaussian laser beams,absorption and dispersion of the probe field can be dramatically influenced by the relative phase between applied fields and intensity of the Gaussian laser beams.Transient and steady-state behaviors of the probe field absorption and dispersion are discussed to estimate the required switching time.The estimated range is between 5-8 ps for subluminal to superluminal light propagation.

Quantitative feedback theory and zero phase error tracking control combined robust control for radar truck leveling simulator

Radar leveling system is the key equipment for improving the radar mobility and survival capability. A combined quantitative feedback theory (QFT) controller is designed for the radar truck leveling simulator in this paper, which suffers from strong nonlinearities and system parameter uncertainties. QFT can reduce the plant uncertainties and stabilize the system, but it fails to obtain high-precision tracking. This drawback can be solved by a robust QFT control scheme based on zero phase error tracking control (ZPETC) compensation. The combined controller not only possesses high robustness, but greatly improves the system performance. To verify the effiectiveness and the potential of the proposed controller, a series of experiments have been carried out. Experimental results have demonstrated its robustness against a large range of parameters variation and high tracking precision performance, as well as its capability of restraining the load coupling among channels. The combined QFT controller can drive the radar truck leveling platform accurately, quickly and stably.

Coherent phase control in electron argon scattering in a bichromatic laser field

This paper theoretically investigates the coherent phase control in electron-argon scattering assisted by a bichro- matic laser field. The laser field is composed of a fundamental component and its second harmonic. The incoming and out going states of electron are described by the Volkov wave functions, and the electron-target interaction is treated as a screening potential. Numerical results for differential cross section of multiphoton processes vs the phase difference between the two components of laser field are discussed for several scattering angles and impact energies.

Phase control and stabilization of 1T-MoS_(2) via black TiO_(2-x)nanotube arrays supporting for electrocatalytic hydrogen evolution

1T phase MoS_(2)(1T-MoS_(2)) is a promising substitute of platinum electrocatalyst for hydrogen evolution reaction(HER)due to its high intrinsic activity but suffering from thermodynamical instability.Although great efforts have been made to synthesize 1T-MoS_(2) and enhance its stability,it remains a big challenge to realize the phase control and stabilization of 1T-MoS_(2).Herein,based on crystal field theory analysis,we propose a new solution by designing an electrocatalyst of 1T-MoS_(2) nanosheets anchoring on black TiO2-xnanotube arrays in-situ grown on Ti plate(1T-MoS_(2)/TiO_(2-x)@Ti).The black TiO_(2-x)substrate is expected to play as electron donors to increase the charge in Mo 4 d orbits of 1T-MoS_(2) and thus weaken the asymmetric occupation of electrons in the Mo 4 d orbits.Experimental results demonstrate that black TiO_(2-x)nanotubes shift electrons to MoS_(2) and induce MoS_(2) to generate more 1 T phase due to stabilizing the 1T-MoS_(2) nanosheets compared with a Ti substrate.Thus 1T-MoS_(2/)TiO_(2-x)@Ti shows much improved HER performance with a small Tafel slope of 42 m V dec^(-1) and excellent catalytic stability with negligible degradation for 24 h.Theoretical calculations confirm that the black TiO_(2-x)substrate can effectively stabilize metastable 1T-MoS_(2) due to electrons transferring from black TiO_(2-x)to Mo 4 d orbits.This work sheds light on the instability of 1T-MoS_(2) and provides an essential method to stabilize and efficiently utilize 1T-MoS_(2) for HER.

Coherent beam combining of hybrid phase control in master oscillator-power amplifier configuration

A novel scalable architecture for coherent beam combining with hybrid phase control involving passive phasing and active phasing in master oscillator-power amplifier configuration is presented. Wide-linewidth mutually injected passive phasing fibre laser arrays serve as master oscillators for the power amplifiers, and the active phasing using stochastic parallel gradient descent algorithm is induced. Wide-linewidth seed laser can suppress the stimulated Brillouin scattering effectively and improve the output power of the fibre laser amplifier, while hybrid phase control provides a robust way for in-phase mode coherent beam combining simultaneously. Experiment is performed by active phasing fibre laser amplifiers with passive phasing fibre ring laser array seed lasers. Power encircled in the main-lobe increases1.57 times and long-exposure fringe contrast is obtained to be 78% when the system evolves from passive phasing to hybrid phasing.

Optical phase front control in a metallic grating with equally spaced alternately tapered slits

A technique capable of focusing and bending electromagnetic （EM） waves through plasmonic gratings with equally spaced alternately tapered slits has been introduced. Phase resonances are observed in the optical response of transmission gratings, and the EM wave passes through the tuning slits in the form of surface plasmon polaritons （SPPs） and obtains the required phase retardation to focus at the focal plane. The bending effect is achieved by constructing an asymmetric phase front which results from the tapered slits and gradient refractive index （GRIN） distribution of the dielectric material. Rigorous electromagnetic analysis by using the two-dimensional （2D） finite difference time domain （FDTD） method is employed to verify our proposed designs. When the EM waves are incident at an angle on the optical axis, the beam splitting effect can also be achieved. These index-modulated slits are demonstrated to have unique advantages in beam manipulation compared with the width-modulated ones. In combination with previous studies, it is expected that our results could lead to the realization of ootimum designs for plasmonic nanolenses.

Analysis of a novel phase-shifted soft switch converter

In this paper, on the basis of the phase shifted controlled zero voltage switch (ZVS) full bridge converter with pulse width modulation (PWM), a novel zero voltage and zero current switch (ZVZCS) PWM converter using a simple auxiliary circuit was designed. The ZVZCS soft switch is achieved by the resonance among the resisting electromagnetic deflection capacitor, the capacitor of the simple auxiliary network and the leakage inductor of transformer. There are no dissipation devices of the saturation inductor and the auxiliary switch in the converter, meantime the capacitor of the auxiliary circuit is also used to clamp the voltage of the rectifier, and there is no additional clamped circuit. There is no big circulating current in the converter, all the active and passive devices work on the condition of the low current and voltage stress, and the proposed converter has wide load range and small duty loss.

Direct Digital Frequency Control Based on the Phase Step Change Characteristic between Signals

We present a new digital phase lock technology to achieve the frequency control and transformation through high precision multi-cycle group synchronization between signals without the frequency transformation circuit. In the case of digital sampling, the passing zero point of the phase of the controlled signal has the phase step characteristic, the phase step of the passing zero point is monotonic continuous with high resolution in the phase lock process, and using the border effect of digital fuzzy area, the gate can synchronize with the two signals, the quantization error is reduced. This technique is quite different from the existing methods of frequency transformation and frequency synthesis, the phase change characteristic between the periodic signals with different nominal is used. The phase change has the periodic phenomenon, and it has the high resolution step value. With the application of the physical law, the noise is reduced because of simplifying frequency transformation circuits, and the phase is locked with high precision. The regular phase change between frequency signals is only used for frequency measurement, and the change has evident randomness, but this randomness is greatly reduced in frequency control, and the certainty of the process result is clear. The experiment shows that the short term frequency stability can reach 10-12/s orders of magnitude.

Crystal phase control and ignition properties of HNS/CL-20 composite microspheres prepared by microfluidics combined with emulsification techniques

Improved controllability and energy density of ignition agents are of great significance for the devel-opment of energetic composite materials.In this study,droplet microfluidics and emulsification tech-niques were combined to prepare HNS/CL-20 composite microspheres with polyglycidyl azide polymer(GAP)as the binder.The influence of binder content on the morphology of microspheres was investi-gated,and the microspheres were characterized and tested for particle size,crystal structure,thermal decomposition,dispersibility,mechanical sensitivity,combustion behavior and detonation performance.The results showed that microspheres prepared with a binder content of 3%had higher sphericity and particle size uniformity.The microspheres retained the crystal structure of both HNS and CL-20(ε-type).Compared with raw HNS,the microspheres had higher apparent activation energy,better safety per-formance,and good dispersibility.The ignition experiments and detonation performance tests show that HNS/CL-20 composite microspheres have excellent ignition performance,obvious combustion flame,and significant energy release effects,which are expected to achieve high energy and high-speed response of the igniter,thus improving the ignition reliability in special environments or systems.

Complete hyperentangled Greenberger–Horne–Zeilinger state analysis for polarization and time-bin hyperentanglement

We present an efficient scheme for the complete analysis of hyperentangled Greenberger–Horne–Zeilinger(GHZ)state in polarization and time-bin degrees of freedom with two steps. Firstly, the polarization GHZ state is distinguished completely and nondestructively, resorting to the controlled phase flip(CPF) gate constructed by the cavity-assisted interaction. Subsequently, the time-bin GHZ state is analyzed by using the preserved polarization entanglement. With the help of CPF gate and self-assisted mechanism, our scheme can be directly generalized to the complete N-photon hyperentangled GHZ state analysis, and it may have potential applications in the hyperentanglement-based quantum communication.

Scheme for teleportation of an unknown atomic state via a cluster state in cavity QED

This paper proposes an experimentally feasible scheme for teleportation of an unknown two-atom entangled state, where a cluster state is used as the quantum channel. This scheme does not need any joint measurement. In addition, the successful probability and fidelity of teleportation can both reach 1.0. The current scheme can be realized within the current experimental technology.

VARIABLE STRUCTURE CONTROL APPLIED IN ELECTRO-HYDRAULIC SERVO SYSTEM WITH ANN

The variable structure control （VSC） theory is applied to the electro-hydraulic servo system here. The VSC control law is achieved using Lyapunov method and pole placement. To eliminate the chattering phenomena, a saturation function is adopted. The proposed VSC approach is fairly robust to load disturbance and system parameter variation. Since the distortion. including phase lag and amplitude attenuation occurs in the system sinusoid response, the amplitude and phase control （APC） algorithm, based on Adaline neural network and using LMS algorithm, is developed for distortion cancellation. The APC controller is simple and can on-line adjust, thus it gives accurate tracking.

Electromagnetically induced transparency in a three-mode optomechanical system

We study a three-mode double-cavity optomechanical system in which an oscillating membrane of perfect reflection is inserted between two fixed mirrors of partial transmission. We find that electromagnetically induced transparency （EIT） can be realized and controlled in this optomechanical system by adjusting the relative intensity and the relative phase between left-hand and right-hand input （probe and coupling） fields. In particular, one perfect EIT window is seen to occur when the two probe fields are exactly out of phase and the EIT window＇s width is very sensitive to the relative intensity of two coupling fields. Our numerical findings may be extended to achieve optomechanical storage and switching schemes applicable in quantum information processing.

Disturbance observer based time-varying sliding mode control for uncertain mechanical system

It is now well known that the time-varying sliding mode control （TVSMC） is characterized by its global robustness against matched model uncertainties and disturbances. The accurate tracking problem of the mechanical system in the presence of the parametric uncertainty and external disturbance is addressed in the TVSMC framework. Firstly, an exponential TVSMC algorithm is designed and the main features are analyzed. Especially, the control parameter is obtained by solving an optimal problem. Subsequently, the global chattering problem in TVSMC is considered. To reduce the static error resulting from the continuous TVSMC algorithm, a disturbance observer based time-varying sliding mode control （DOTVSMC） algorithm is presented. The detailed design principle and the stability of the closed-loop system under the composite controller are provided. Simulation results verify the effectiveness of the proposed algorithm.

Trace determination of hexabromocyclododecane diastereomers in water samples with temperature controlled ionic liquid dispersive liquid phase microextraction

A novel temperature controlled ionic liquid dispersive liquid phase microextracfion （TCIL-DLPME） coupled with rapid resolution liquid chromatography-electrospray tandem mass spectrometry （RRLC-ESI-MS-MS） has been developed for the enrichment and determination of three hexabromocyclododecane diastereomers （HBCDs） in water samples. Green solvent ionic liquid （IL） was used as extraction solvent instead of toxic organic solvents. This technique also avoided the usage of dispersive solvent. Some important parameters that might affect the extraction efficiency were optimized. Under the optimum conditions, good linear relationship, sensitivity and reproducibility were obtained. All the limits of detection for the three diastereomers were 0.1 ng/ mL. The linear range was obtained in the range of 1-100 ng/mL for the total amount of three HBCD diastereomers. It was satisfactory to analyze real environmental water samples with the recoveries ranging from 77.2% to 99.3%. The main advantage of the method is toxic organic solvent-free.