Application of an Organophosphorus Compound-DEPBT as Coupling Reagent in Liquid Phase Peptide Synthesis

DEPBT, a novel coupling reagent containing phosphorus, was used in synthesis of pentapeptide Boc-Ile-Asn-Met-Trp(For)-Gly.OMe by solution method.

Stability and multistability of synchronization in networks of coupled phase oscillators

Coupled phase oscillators usually achieve synchronization as the coupling strength among oscillators is increased beyond a critical value. The stability of synchronous state remains an open issue. In this paper, we study the stability of the synchronous state in coupled phase oscillators. It is found that numerical integration of differential equations of coupled phase oscillators with a finite time step may induce desynchronization at strong couplings. The mechanism behind this instability is that numerical accumulated errors in simulations may trigger the loss of stability of the synchronous state.Desynchronization critical couplings are found to increase and diverge as a power law with decreasing the integral time step. Theoretical analysis supports the local stability of the synchronized state. Globally the emergence of synchronous state depends on the initial conditions. Other metastable ordered states such as twisted states can coexist with the synchronous mode. These twisted states keep locally stable on a sparse network but lose their stability when the network becomes dense.

Comparative Assessment of Impacts of Future Climate Change on Runoff in Upper Daqinghe Basin,China

Assessing runoff changes is of great importance especially its responses to the projected future climate change on local scale basins because such analyses are generally done on global and regional scales which may lead to generalized conclusions rather than specific ones.Climate change affected the runoff variation in the past in the upper Daqinghe Basin,however,the climate was mainly considered uncertain and still needs further studies,especially its future impacts on runoff for better water resources management and planning.Integrated with a set of climate simulations,a daily conceptual hydrological model(MIKE11-NAM)was applied to assess the impact of climate change on runoff conditions in the Daomaguan,Fuping and Zijingguan basins in the upper Daqinghe Basin.Historical hydrological data(2008–2017)were used to evaluate the applicability of the MIKE11-NAM model.After bias correction,future projected climate change and its impacts on runoff(2025–2054)were analysed and compared to the baseline period(1985–2014)under three shared social economic pathways(SSP1-2.6,SSP2-4.5,and SSP5-8.5)scenarios from Coupled Model Intercomparison Project Phase 6(CMIP6)simulations.The MIKE-11 NAM model was applicable in all three Basins,with both R^(2)and Nash-Sutcliffe Efficiency coefficients greater than 0.6 at daily scale for both calibration(2009–2011)and validation(2012–2017)periods,respectively.Although uncertainties remain,temperature and precipitation are projected to increase compared to the baseline where higher increases in precipitation and temperature are projected to occur under SSP2-4.5 and SSP5-8.5 scenarios,respectively in all the basins.Precipitation changes will range between 12%–19%whereas temperature change will be 2.0℃–2.5℃ under the SSP2-4.5 and SSP5-8.5 scenarios,respectively.In addition,higher warming is projected to occur in colder months than in warmer months.Overall,the runoff of these three basins is projected to respond to projected climate changes differently because runoff is projected to only increase in the Fuping basin under SSP2-4.5 whereas decreases in both Daomaguan and Zijingguan Basins under all scenarios.This study’s findings could be important when setting mitigation strategies for climate change and water resources management.

Output mode characteristics of an in-phase locked gain waveguide array CO_2 laser

In this paper, experimental and theoretical studies of the output mode characteristics of an in-phase locked gain waveguide array CO2 laser are reported. The experimental results of the optical oscillation mode frequency, the far-field intensity distribution and the burnt pattern of the sliced waveguide array laser are obtained. A revised mode expression of the rectangle waveguide, which is suited for this waveguide array CO2 laser, is proposed. The theoretical simulation results based on the revised mode expression are shown to be in good agreement with the experimental results.

A CMIP6-based assessment of regional climate change in the Chinese Tianshan Mountains

Climate warming profoundly affects hydrological changes,agricultural production,and human society.Arid and semi-arid areas of China are currently displaying a marked trend of warming and wetting.The Chinese Tianshan Mountains(CTM)have a high climate sensitivity,rendering the region particularly vulnerable to the effects of climate warming.In this study,we used monthly average temperature and monthly precipitation data from the CN05.1 gridded dataset(1961-2014)and 24 global climate models(GCMs)of the Coupled Model Intercomparison Project Phase 6(CMIP6)to assess the applicability of the CMIP6 GCMs in the CTM at the regional scale.Based on this,we conducted a systematic review of the interannual trends,dry-wet transitions(based on the standardized precipitation index(SPI)),and spatial distribution patterns of climate change in the CTM during 1961-2014.We further projected future temperature and precipitation changes over three terms(near-term(2021-2040),mid-term(2041-2060),and long-term(2081-2100))relative to the historical period(1961-2014)under four shared socio-economic pathway(SSP)scenarios(i.e.,SSP1-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5).It was found that the CTM had experienced significant warming and wetting from 1961 to 2014,and will also experience warming in the future(2021-2100).Substantial warming in 1997 was captured by both the CN05.1 derived from interpolating meteorological station data and the multi-model ensemble(MME)from the CMIP6 GCMs.The MME simulation results indicated an apparent wetting in 2008,which occurred later than the wetting observed from the CN05.1 in 1989.The GCMs generally underestimated spring temperature and overestimated both winter temperature and spring precipitation in the CTM.Warming and wetting are more rapid in the northern part of the CTM.By the end of the 21st century,all the four SSP scenarios project warmer and wetter conditions in the CTM with multiple dry-wet transitions.However,the rise in precipitation fails to counterbalance the drought induced by escalating temperature in the future,so the nature of the drought in the CTM will not change at all.Additionally,the projected summer precipitation shows negative correlation with the radiative forcing.This study holds practical implications for the awareness of climate change and subsequent research in the CTM.

CMIP 6 models simulation of the connection between North/South Pacific Meridional Mode and ENSO

The subtropical North and South Pacific Meridional Modes(NPMM and SPMM)are well known precursors of El Niño-Southern Oscillation(ENSO).However,relationship between them is not constant.In the early 1980,the relationship experienced an interdecadal transition.Changes in this connection can be attributed mainly to the phase change of the Pacific decadal oscillation(PDO).During the positive phase of PDO,a shallower thermocline in the central Pacific is responsible for the stronger trade wind charging(TWC)mechanism,which leads to a stronger equatorial subsurface temperature evolution.This dynamic process strengthens the connection between NPMM and ENSO.Associated with the negative phase of PDO,a shallower thermocline over southeastern Pacific allows an enhanced wind-evaporation-SST(WES)feedback,strengthening the connection between SPMM and ENSO.Using 35 Coupled Model Intercomparison Project Phase 6(CMIP6)models,we examined the NPMM/SPMM performance and its connection with ENSO in the historical runs.The great majority of CMIP6 models can reproduce the pattern of NPMM and SPMM well,but they reveal discrepant ENSO and NPMM/SPMM relationship.The intermodal uncertainty for the connection of NPMM-ENSO is due to different TWC mechanism.A stronger TWC mechanism will enhance NPMM forcing.For SPMM,few models can simulate a good relationship with ENSO.The intermodel spread in the relationship of SPMM and ENSO owing to SST bias in the southeastern Pacific,as WES feedback is stronger when the southeastern Pacific is warmer.

Phase Control of Transient Optical Properties of Double Coupled Quantum-Dot Nanostructure via Gaussian Laser Beams

We theoretically analyze the transient properties of a probe field absorption and dispersion in a coupled semiconductor double-quantum-dot nanostructure.We show that in the presence of the Gaussian laser beams,absorption and dispersion of the probe field can be dramatically influenced by the relative phase between applied fields and intensity of the Gaussian laser beams.Transient and steady-state behaviors of the probe field absorption and dispersion are discussed to estimate the required switching time.The estimated range is between 5-8 ps for subluminal to superluminal light propagation.

The Ott-Antonsen Ansatz in Globally Coupled Phase Oscillators

The Ott-Antonsen ansatz provides a powerful tool in investigating synchronization among coupled phase oscil- lators. However, previous works using the ansatz only focused on the evolution of the order parameter and the information on desynchronized oscillators is less discussed. In this work, we show that the Ott-Antonsen ansatz can also be applied to investigate the desynchronous dynamics in coupled phase oscillators. Studying the original Kuramoto model and two of its variants, we find that the dynamics of α（ω）, the coefficient in the Fourier series of the probability density, can give most of the information on the synchronization, for example, the threshold of natural frequency delimiting the oscillators synchronized and desychronized by the mean field, the formulation of the effective frequency ωe （ω） of desynchronous oscillators, and the structure of the graph ωe （ω）.

Projected Regional 1.50℃and 2.00℃Warming Threshold-crossing Time Worldwide Using the CMIP6 Models

The Paris Agreement aims to limit global warming to well below 2.00℃and pursue efforts to limit the temperature increase to 1.50℃.However,the response of climate change to unbalanced global warming is affected by spatial and temporal sensitivities.To better understand the regional warming response to global warming at 1.50℃and 2.00℃,we detected the 1.50℃and 2.00℃warming threshold-crossing time(WTT)above pre-industrial levels globally using the Coupled Model Intercomparison Project phase 6(CMIP6)models.Our findings indicate that the 1.50℃or 2.00℃WTT differs substantially worldwide.The warming rate of land would be approximately 1.35–1.46 times that of the ocean between 60°N–60°S in 2015–2100.Consequently,the land would experience a 1.50℃(2.00℃)warming at least 10–20 yr earlier than the time when the global mean near-surface air temperature reaches 1.50℃(2.00℃)WTT.Meanwhile,the Southern Ocean between 0°and 60°S considerably slows down the global 1.50℃and 2.00℃WTT.In 2040–2060,over 98.70%(77.50%),99.70%(89.30%),99.80%(93.40%),and 100.00%(98.00%)of the land will have warmed by over 1.50℃(2.00℃)under SSP(Shared Socioeconomic Pathway)1–2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5,respectively.We conclude that regional 1.50℃(2.00℃)WTT should be fully considered,especially in vulnerable high-latitude and high-altitude regions.

GEAR CRACK EARLY DIAGNOSIS USING BISPECTRUM DIAGONAL SLICE

A study of bispectral analysis in gearbox condition monitoring is presented.The theory of bispectrum and quadratic phase coupling (QPC) is first introduced, and then equationsfor computing bispectrum slices are obtained. To meet the needs of online monitoring, a simplifiedmethod of computing bispectrum diagonal slice is adopted. Industrial gearbox vibration signalsmeasured from normal and tooth cracked conditions are analyzed using the above method. Experimentsresults indicate that bispectrum can effectively suppress the additive Gaussian noise andchracterize the QPC phenomenon. It is also shown that the 1-D bispectrum diagonal slice can capturethe non-Gaussian and nonlinear feature of gearbox vibration when crack occurred, hence, this methodcan be employed to gearbox real time monitoring and early diagnosis.

HIGHER ORDER SPECTRAL ANALYSIS IN FAULT DIAGNOSIS OF ROTORS

The nonlinear properties of rotating machinery vibration signals are presented. The relationship between faults and quadratic phase coupling is discussed. The mechanism that gives rise to quadratic phase coupling is analyzed, and the coupling models are summarized. As a result, higher order spectra analysis is introduced into fault diagnosis of rotors. A brief review of the properties of higher order spectra is presented. Furthermore, the bicoherence spectrum is employed to extract the features that signify the machinery condition. Experiments show that bicoherence spectrum patterns of different faults are quite different, so it is proposed to identify the faults in rotors.

Harmonic Retrieval in Colored ARMA Noise

We propose a new approach to harmonic retrieval in colored ARMA noise. A suitable filter is first used to remove all the sharp power spectrum peaks of the noisy observed process, then some kinds of cross correlation is employed to identify the noise characteristics. After filtering the noisy observed process with the identified noise characteristics again, SVD-TLS method can be applied to retrieve the harmonics. The proposed approach can be used to retrieve real-valued harmonic signals in colored ARMA noise with no restrictions on the phase coupling of harmonics and the distribution of the noise. Simulation examples show its effectiveness.

CMIP6模式对中国东部地区水循环的模拟能力评估

本文基于观测和再分析资料,采用Brubaker二元模型评估了第六次国际耦合模式比较计划(CMIP6)中19个模式对中国东部季风区气候态水循环过程的模拟能力,并分析了模拟误差来源。结果表明,CMIP6模式集合平均(MME)能够合理再现观测降水和蒸发的年平均气候态空间分布及年循环特征,与观测值的空间相关系数分别为0.92和0.87。较之观测,MME高估了华北地区降水(0.55 mm d^(−1)),低估了华南沿海地区降水(−0.3 mm d^(−1))。所有CMIP6模式均高估蒸发强度(偏差0.03~0.98 mm d^(−1)),使得模拟的降水与蒸发之差偏少。模式整体能够模拟出我国东部季风区降水再循环率及不同边界水汽来源的贡献率,但低估了由南边界进入季风区的水汽贡献,导致东亚季风区偏干。通过分析模式对影响水汽通量的两个气象要素(风速和大气比湿)的模拟能力,发现研究区南边界的风速大小决定了模式间水汽输送差异。南边界风速越大的模式,由南边界进入的水汽通量越大,模式模拟的降水越多。西北太平洋辐合带的东西位置是影响南边界南风速的重要系统之一,辐合带位置偏东的模式模拟的南风强度较弱,使得水汽输送偏弱、降水偏少;反之,南边界水汽输送偏强、降水偏多。本文通过评估最新一代CMIP6模式在东亚水循环方面的模拟性能,指出了当前气候模式在模拟西太平洋辐合带位置方面存在的偏差及其对东亚水循环的影响。

Global air-sea CO_(2) exchange fl ux since 1980s: results from CMIP6 Earth System Models

The ocean could profoundly modulate the ever-increasing atmospheric CO_(2) by air-sea CO_(2) exchange process,which is also able to cause signifi cant changes of physical and biogeochemical properties in return.In this study,we assessed the long-term average and spatial-temporal variability of global air-sea CO_(2) exchange fl ux(F CO_(2))since 1980s basing on the results of 18 Coupled Model Intercomparison Project Phase 6(CMIP6)Earth System Models(ESMs).Our fi ndings indicate that the CMIP6 ESMs simulated global CO_(2) sink in recent three decades ranges from 1.80 to 2.24 Pg C/a,which is coincidence with the results of cotemporaneous observations.What’s more,the CMIP6 ESMs consistently show that the global oceanic CO_(2) sink has gradually intensifi ed since 1980s as well as the observations.This study confi rms the simulated F CO_(2) could reach agreements with the observations in the aspect of primary climatological characteristics,however,the simulation skills of CIMP6 ESMs in diverse open-sea biomes are unevenness.None of the 18 CMIP6 ESMs could reproduce the observed F CO_(2) increasement in the central-eastern tropical Pacifi c and the midlatitude Southern Ocean.Defi ciencies of some CMIP6 ESMs in reproducing the atmospheric pressure systems of the Southern Hemisphere and the El Niño-Southern Oscillation(ENSO)mode of the tropical Pacifi c are probably the major causes.

An assessment of the CMIP5 models in simulating the Argo geostrophic meridional transport in the North Pacifi c Ocean

Eleven climate system models that participate in the Coupled Model Intercomparison Project phase 5(CMIP5)were evaluated based on an assessment of their simulated meridional transports in comparison with the Sverdrup transports.The analyses show that the simulated North Pacifi c Ocean circulation is essentially in Sverdrup balance in most of the 11 models while the Argo geostrophic meridional transports indicate signifi cant non-Sverdrup gyre circulation in the tropical North Pacifi c Ocean.The climate models overestimated the observed tropical and subtropical volume transports signifi cantly.The non-Sverdrup gyre circulation leads to non-Sverdrup heat and salt transports,the absence of which in the CMIP5 simulations suggests defi ciencies of the CMIP5 model dynamics in simulating the realistic meridional volume,heat,and salt transports of the ocean.

Nonvolatile control of transport and magnetic properties in magnetoelectric heterostructures by electric field

Nonvolatile manipulation of transport and magnetic properties by external electric field is significant for information storage. In this study, we investigate the electric field control of resistance and magnetization in a magnetoelectric heterostructure comprising an electronic phase-separated La0.325Pr0.3Ca0.375MnO3（LPCMO） thin film and a ferroelectric（011）-oriented 0.7Pb（Mg1/3Nb2/3）O3-0.3PbTiO3（PMN-PT） substrate. In a room-temperature poled sample, the metal-toinsulator transition temperature of an LPCMO film increases and the resistance decreases with variation in the effect of the remnant strain. Meanwhile, the increase in the magnetization of the sample is observed as well. This effect would be beneficial for the development of novel storage devices with low power consumption.

A comparison of the CMIP5 models on the historical simulation of the upper ocean heat content in the South China Sea

Seventeen models participating in the Coupled Model Intercomparison Project phase 5（CMIP5） activity are compared on their historical simulation of the South China Sea（SCS） ocean heat content（OHC） in the upper 300 m. Ishii＇s temperature data, based on the World Ocean Database 2005（WOD05） and World Ocean Atlas 2005（WOA05）, is used to assess the model performance by comparing the spatial patterns of seasonal OHC anomaly（OHCa） climatology, OHC climatology, monthly OHCa climatology, and interannual variability of OHCa. The spatial patterns in Ishii＇s data set show that the seasonal SCS OHCa climatology, both in winter and summer, is strongly affected by the wind stress and the current circulations in the SCS and its neighboring areas. However, the CMIP5 models present rather different spatial patterns and only a few models properly capture the dominant features in Ishii＇s pattern. Among them, GFDL-ESM2 G is of the best performance. The SCS OHC climatology in the upper 300 m varies greatly in different models. Most of them are much greater than those calculated from Ishii＇s data. However, the monthly OHCa climatology in each of the 17 CMIP5 models yields similar variation and magnitude as that in Ishii＇s. As for the interannual variability, the standard deviations of the OHCa time series in most of the models are somewhat larger than those in Ishii＇s. The correlation between the interannual time series of Ishii＇s OHCa and that from each of the 17 models is not satisfactory. Among them, BCC-CSM1.1 has the highest correlation to Ishii＇s, with a coefficient of about 0.6.

Spin–orbit coupled Bose–Einstein condensates with Rydberg-dressing interaction

Interaction between Rydberg atoms can be used to control the properties of interatomic interaction in ultracold gases by weakly dressing the atoms with a Rydberg state. Here we investigate the effect of the Rydberg-dressing interaction on the ground-state properties of a Bose–Einstein condensate imposed by Raman-induced spin–orbit coupling. We find that,in the case of SU（2）-invariant s-wave interactions, the gas is only in the plane-wave phase and the zero-momentum phase is absent. In particular, we also predict an unexpected magnetic stripe phase composed of two plane-wave components with unequal weight when s-wave interactions are non-symmetric, which originates from the Rydberg-dressing interaction.

EFFECT OF SUSPENDED PARTICLE ON STABILITY OF INTERFACE OF MOVING TWO PHASE JET

The stability equation of interface of moving two phase jet and the corresponding equation of particle gas disturbance velocity ration are derived by means of the continuum phase coupling model. The stability curves of interface of moving two phase jet for different particle properties and velocities of jetting device are given out through numerical computation. Further, sevral important conclusions on the effect of particle property and velocity of jetting device on the growth and propagation of disturbance of interface of moving two phase jet are reched on the basis of analyses of the obtained stability curves. These important conclusions can play a guiding role in studying development of moving two phase jet and executing artificial controls over it in practice.

Dynamics of clustering patterns in the Kuramoto model with unidirectional coupling

We study the synchronization transition in the Kuramoto model by considering a unidirectional cou- pling with a chain structure. The microscopic clustering features are characterized in the system. We identify several clustering patterns for the long-time evolution of the effective frequencies and reveal the phase transition between them. Theoretically, the recursive approach is developed in order to ob- tain analytical insights; the essential bifurcation schemes of the clustering patterns are clarified and the phase diagram is illustrated in order to depict the various phase transitions of the system. Fur- thermore, these recursive theories can be extended to a larger system. Our theoretical analysis is in agreement with the numerical simulations and can aid in understanding the clustering patterns in the Kuramoto model with a general structure.