In an earlier paper, the authors reported the solid and liquid phase equilibria in mix-tures of tetrachloromethane with oxygen-containing compounds. This note reports the solidand liquld phase equilibria for mixtures ...In an earlier paper, the authors reported the solid and liquid phase equilibria in mix-tures of tetrachloromethane with oxygen-containing compounds. This note reports the solidand liquld phase equilibria for mixtures of tetrachloromethane with nitrogen-containing com-pounds. The solid intermolecular compound forms in mixture of tetrachloromethane withbenzene, the intermolecular bonding in compound has been assumed to be charge transfer.The intermolecula compounds form easily in mixtures in which the electron density of thebenzene ring has been increased in the presence of electron-excluding substituents in展开更多
We have reported the solid and liquid phase diagrams for tetrachloromethane+cyclopentanone, +4-butyrolactone, and +1-methyl-2-pyrrolidinone.The solid compounds are formed in all the three systems. The second component...We have reported the solid and liquid phase diagrams for tetrachloromethane+cyclopentanone, +4-butyrolactone, and +1-methyl-2-pyrrolidinone.The solid compounds are formed in all the three systems. The second component in the three tetrachloromethane mixtures have cyclic structure. Ref. [2] pointed out that the cyclic structure of the second component is very important during the compound formation in展开更多
IN refs.[1,2],we studied the solid and liquid phase equilibria in mixtures of tetra-chloromethane with oxygen and nitrogen-containing compounds,intermolecular interactionswith the formation of solid molecular addition...IN refs.[1,2],we studied the solid and liquid phase equilibria in mixtures of tetra-chloromethane with oxygen and nitrogen-containing compounds,intermolecular interactionswith the formation of solid molecular addition compounds.The nitrogen atom linking withthree carbon atoms is a strong electron donor,so is N,N-dimethylacetamide(DMA).展开更多
Solid and liquid phase diagrams have been constructed for {water+triethylamine,or+N,N-dimethylformamide(DMF) or+N,N-dimethlacetamide (DMA)} Solid-hydrates form with the empirical formulae N(C2H5)3 3H2O,DMF 3H2O,DMF 2H...Solid and liquid phase diagrams have been constructed for {water+triethylamine,or+N,N-dimethylformamide(DMF) or+N,N-dimethlacetamide (DMA)} Solid-hydrates form with the empirical formulae N(C2H5)3 3H2O,DMF 3H2O,DMF 2H2O,DMA 3H2O and (DMA)2 3H2O.All are congruently melting except the first which melts incongruently.The solid-hydrate formation is attributed to hydrogen bond.The results are compared with the references展开更多
文摘In an earlier paper, the authors reported the solid and liquid phase equilibria in mix-tures of tetrachloromethane with oxygen-containing compounds. This note reports the solidand liquld phase equilibria for mixtures of tetrachloromethane with nitrogen-containing com-pounds. The solid intermolecular compound forms in mixture of tetrachloromethane withbenzene, the intermolecular bonding in compound has been assumed to be charge transfer.The intermolecula compounds form easily in mixtures in which the electron density of thebenzene ring has been increased in the presence of electron-excluding substituents in
基金Project supported by the National Natural Science Foundation of China
文摘We have reported the solid and liquid phase diagrams for tetrachloromethane+cyclopentanone, +4-butyrolactone, and +1-methyl-2-pyrrolidinone.The solid compounds are formed in all the three systems. The second component in the three tetrachloromethane mixtures have cyclic structure. Ref. [2] pointed out that the cyclic structure of the second component is very important during the compound formation in
文摘IN refs.[1,2],we studied the solid and liquid phase equilibria in mixtures of tetra-chloromethane with oxygen and nitrogen-containing compounds,intermolecular interactionswith the formation of solid molecular addition compounds.The nitrogen atom linking withthree carbon atoms is a strong electron donor,so is N,N-dimethylacetamide(DMA).
基金Project supported by the National Natural Science Foundation of China
文摘Solid and liquid phase diagrams have been constructed for {water+triethylamine,or+N,N-dimethylformamide(DMF) or+N,N-dimethlacetamide (DMA)} Solid-hydrates form with the empirical formulae N(C2H5)3 3H2O,DMF 3H2O,DMF 2H2O,DMA 3H2O and (DMA)2 3H2O.All are congruently melting except the first which melts incongruently.The solid-hydrate formation is attributed to hydrogen bond.The results are compared with the references
