A copper-red and silver-white metallic glaze of R_(2)O-RO-Al_(2)O_(3)-SiO_(2)-P_(2)O_(5)system was synthesized by adjusting the firing temperature and glaze components.The coloration mechanism of the metallic glaze wa...A copper-red and silver-white metallic glaze of R_(2)O-RO-Al_(2)O_(3)-SiO_(2)-P_(2)O_(5)system was synthesized by adjusting the firing temperature and glaze components.The coloration mechanism of the metallic glaze was revealed via investigation of the microstructure of the glaze.Our research reveals that the metallic glaze with different colors is mainly due to the amount of Fe_(2)O_(3).The metallic glaze shows a silver-white luster due to a structural color ofα-Fe_(2)O_(3)crystals with a good orientation when the sample contains 0.0939 mol of Fe_(2)O_(3),maintaining temperatures at 1150℃for 0.5 h.The metallic glaze is copper-red which is dominated by the coupling of chemical and structural color ofα-Fe_(2)O_(3)crystals when the sample contains 0.0783 mol of Fe_(2)O_(3).After testing the amount of SiO_(2),we find that 4.0499 mol is the optimal amount to form the ceramic network,and 0.27 mol AlPO_(4)is the best amount to promote phase separation.展开更多
Based on the premise that the addition of glass beads （GB） could hardly influence the linear viscoelasticity in low frequency （ω） region for homogeneous polymer systems, the dynamic rheological behaviors of unfil...Based on the premise that the addition of glass beads （GB） could hardly influence the linear viscoelasticity in low frequency （ω） region for homogeneous polymer systems, the dynamic rheological behaviors of unfilled and filled poly（methyl methyacrylate） （PMMA）/poly（styrene-co-acrylonitrile） （SAN） blends were studied in order to explore the effect of GB on the phase-separation of binary polymer matrix. Results show that GB has an induced effect on the phase-separation, which embodies that the phase-separation temperature （Ts） of PMMA/SAN blend filled with GB is lower than that of the unfilled system. The higher content of GB, the higher is the ＂secondary plateau＂ of ω in the terminal region of storage modulus （G＇） versus ω plot. The ＂secondary plateau＂ appearing in the terminal region is attributed to the phase-separation of PMMA/SAN blends and it becomes more fiat for filled polymer blends under the same conditions. However, it is suggested that this kind of ＂induced effect＂ is related to the GB content; the higher content of GB particles might enhance the interaction between the particles and polymer matrix. Moreover, it is found that the addition of GB also has an influence more or less on the morphology and domain size of polymer matrix. It is believed that the plot of dynamic viscosity （η＇） versus the loss viscosity （η＂） is sensitive to examine the effect induced by GB on the phase-separation of binary polymer matrix.展开更多
Aiming at the complex electromagnetic transient process of EMU passing by phase-separation with electric load in high-speed railway, mechanism of overvoltage caused by switching off, overvoltage caused by switching on...Aiming at the complex electromagnetic transient process of EMU passing by phase-separation with electric load in high-speed railway, mechanism of overvoltage caused by switching off, overvoltage caused by switching on and impact current is analyzed systematically in this article. π-type equivalent circuit of feeding section is put forward in the analysis of overvoltage mechanism. Overvoltage and overcurrent model of passing by phase-separation with electric load are also built. Correctness of mechanism was validated by simulation. In addition, the methods to solve the influence on substations, transformers and protection devices in this process are put forward, which provides a new idea on passing by phase-separation with electric load technology.展开更多
Occupants of highly glazed buildings often suffer from thermal discomfort during the mid-seasons when no shadings are used in such buildings,especially when inertial heating systems are used.The present study is devot...Occupants of highly glazed buildings often suffer from thermal discomfort during the mid-seasons when no shadings are used in such buildings,especially when inertial heating systems are used.The present study is devoted to evaluating the impact of long solar beam exposure on the internal thermal discomfort in glazed spaces when heating is implemented through a floor system.A comprehensive experimental study is carried out using an experimental bi-climatic chamber which is fully monitored and controlled,allowing realistic simulations of the dynamic movement of the sun patch on a heated slab.The findings show that a period of discomfort as long as 8 h can occur,and persist far after the sunbeam exposure stops.During this period,the heating slab’s surface temperature,considered from an average point of view,can attain 34°C while the indoor temperature reaches 26°C.Simulations conducted using a previously developed model display a good fit with the measurements.展开更多
基金Funded by the National Natural Science Foundation of China(No.52202231)the College Students Innovation and Entrepreneurship Training Program of Hubei University of Technology(No.202310500039)。
文摘A copper-red and silver-white metallic glaze of R_(2)O-RO-Al_(2)O_(3)-SiO_(2)-P_(2)O_(5)system was synthesized by adjusting the firing temperature and glaze components.The coloration mechanism of the metallic glaze was revealed via investigation of the microstructure of the glaze.Our research reveals that the metallic glaze with different colors is mainly due to the amount of Fe_(2)O_(3).The metallic glaze shows a silver-white luster due to a structural color ofα-Fe_(2)O_(3)crystals with a good orientation when the sample contains 0.0939 mol of Fe_(2)O_(3),maintaining temperatures at 1150℃for 0.5 h.The metallic glaze is copper-red which is dominated by the coupling of chemical and structural color ofα-Fe_(2)O_(3)crystals when the sample contains 0.0783 mol of Fe_(2)O_(3).After testing the amount of SiO_(2),we find that 4.0499 mol is the optimal amount to form the ceramic network,and 0.27 mol AlPO_(4)is the best amount to promote phase separation.
基金This project was supported by the National Natural Science Foundation of China(No.20304014)the Special Funds for National Science Funds for Distinguished Young Scholars(No.50125312).
文摘Based on the premise that the addition of glass beads （GB） could hardly influence the linear viscoelasticity in low frequency （ω） region for homogeneous polymer systems, the dynamic rheological behaviors of unfilled and filled poly（methyl methyacrylate） （PMMA）/poly（styrene-co-acrylonitrile） （SAN） blends were studied in order to explore the effect of GB on the phase-separation of binary polymer matrix. Results show that GB has an induced effect on the phase-separation, which embodies that the phase-separation temperature （Ts） of PMMA/SAN blend filled with GB is lower than that of the unfilled system. The higher content of GB, the higher is the ＂secondary plateau＂ of ω in the terminal region of storage modulus （G＇） versus ω plot. The ＂secondary plateau＂ appearing in the terminal region is attributed to the phase-separation of PMMA/SAN blends and it becomes more fiat for filled polymer blends under the same conditions. However, it is suggested that this kind of ＂induced effect＂ is related to the GB content; the higher content of GB particles might enhance the interaction between the particles and polymer matrix. Moreover, it is found that the addition of GB also has an influence more or less on the morphology and domain size of polymer matrix. It is believed that the plot of dynamic viscosity （η＇） versus the loss viscosity （η＂） is sensitive to examine the effect induced by GB on the phase-separation of binary polymer matrix.
文摘Aiming at the complex electromagnetic transient process of EMU passing by phase-separation with electric load in high-speed railway, mechanism of overvoltage caused by switching off, overvoltage caused by switching on and impact current is analyzed systematically in this article. π-type equivalent circuit of feeding section is put forward in the analysis of overvoltage mechanism. Overvoltage and overcurrent model of passing by phase-separation with electric load are also built. Correctness of mechanism was validated by simulation. In addition, the methods to solve the influence on substations, transformers and protection devices in this process are put forward, which provides a new idea on passing by phase-separation with electric load technology.
文摘Occupants of highly glazed buildings often suffer from thermal discomfort during the mid-seasons when no shadings are used in such buildings,especially when inertial heating systems are used.The present study is devoted to evaluating the impact of long solar beam exposure on the internal thermal discomfort in glazed spaces when heating is implemented through a floor system.A comprehensive experimental study is carried out using an experimental bi-climatic chamber which is fully monitored and controlled,allowing realistic simulations of the dynamic movement of the sun patch on a heated slab.The findings show that a period of discomfort as long as 8 h can occur,and persist far after the sunbeam exposure stops.During this period,the heating slab’s surface temperature,considered from an average point of view,can attain 34°C while the indoor temperature reaches 26°C.Simulations conducted using a previously developed model display a good fit with the measurements.
基金National Key Research and Development Project during the 14th Five-year Plan Period(2023YFF0905800)Science and Technology Program of Jiangxi Provincial Education Department(GJJ160879)。
