Based on the concept of “element” and the fundamental thermodynamic principle,the relationships of the residual properties,the property changes of mixing,excess properties,fugacity coefficients and activity coeffici...Based on the concept of “element” and the fundamental thermodynamic principle,the relationships of the residual properties,the property changes of mixing,excess properties,fugacity coefficients and activity coefficients between the hypothetical solution of elemental species and the equilibrated solution of actual species were established.The hypothetical solution of elemental species provides a way of reducing the dimensionality of problem, simplifying the analysis and visualizing the phase behavior.展开更多
基金Supported by the National Natural Science Foundation of China (No. 29976035) and the Natural Science Foundation of Fujian Province (No. B9810011).
文摘Based on the concept of “element” and the fundamental thermodynamic principle,the relationships of the residual properties,the property changes of mixing,excess properties,fugacity coefficients and activity coefficients between the hypothetical solution of elemental species and the equilibrated solution of actual species were established.The hypothetical solution of elemental species provides a way of reducing the dimensionality of problem, simplifying the analysis and visualizing the phase behavior.