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Elemental Composition Method in Thermodynamics of Multireaction Systems (II) Residual Properties, Property Changes of Mixing and Excess Properties Relations
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作者 林金清 李浩然 韩世钧 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2002年第4期464-468,共5页
Based on the concept of “element” and the fundamental thermodynamic principle,the relationships of the residual properties,the property changes of mixing,excess properties,fugacity coefficients and activity coeffici... Based on the concept of “element” and the fundamental thermodynamic principle,the relationships of the residual properties,the property changes of mixing,excess properties,fugacity coefficients and activity coefficients between the hypothetical solution of elemental species and the equilibrated solution of actual species were established.The hypothetical solution of elemental species provides a way of reducing the dimensionality of problem, simplifying the analysis and visualizing the phase behavior. 展开更多
关键词 elemental composition dimension reduction multireaction phaseequilibrium
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三水氯化镧与冠醚B15C5在乙腈中配合行为的半微量相平衡研究
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作者 张敬乐 任德厚 孙聚昌 《西北大学学报(自然科学版)》 CSCD 1996年第1期45-49,共5页
采用半微量相平衡方法研究了LaCl3·3H2O-B15C5-CH3CN三元体系在25℃时的溶解度,测定了各饱和溶液的折光率。该体系在25℃生成一种化学计量的三元配合物:LaCl3·B15C5·3H2O-C... 采用半微量相平衡方法研究了LaCl3·3H2O-B15C5-CH3CN三元体系在25℃时的溶解度,测定了各饱和溶液的折光率。该体系在25℃生成一种化学计量的三元配合物:LaCl3·B15C5·3H2O-CH3CN。经分离、洗涤制得了固态配合物,分别在80%H2SO4与98%H2SO4干燥器中干燥王恒重,经化学分析确定配合物的组成为:LaCl3·B15C5·3H2O与LaCl3·B15C5。用IR,DTG,TG,DSC以及x-射线衍射分析研究了配合物的组成与性质。 展开更多
关键词 三水氯化镧 冠醚 溶解度 相平衡 镧配合物
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