Three new complexes TbL3dipy （H2O）2, TbL3phen （H2O） 2 and TbL2 （TPPO） 2NO3 were synthesized （L = phenylglyoxylate ion, dipy = 2, 2-dipyridine, phen = 1,10-phenanthmline, TPPO = Triphenyl phosphine oxide）. Elem...Three new complexes TbL3dipy （H2O）2, TbL3phen （H2O） 2 and TbL2 （TPPO） 2NO3 were synthesized （L = phenylglyoxylate ion, dipy = 2, 2-dipyridine, phen = 1,10-phenanthmline, TPPO = Triphenyl phosphine oxide）. Elemental analysis, conductivity, IR spectra, and ^1HNMR spectra studies were performed. IR spectra indicate that the carboxylate ion of phenylglyoxylate is coordinated to the Tb（Ⅲ） ion as an unidentate ligand. In ^1HNMR, the signals of different hydrogens in phenylglyoxylate ion shift upfield. The excitation and emission spectra of the three solid complexes were recorded at morn temperature, in which the optimum excitation wavelengths are, 361.0, 359.0 and 367.0 nm for these three complexes, respectively. Four emission bands due to the ^5D4-^7Fj（j = 6, 5, 4, 3） transitions were observed for TbL3dipy（H2O）2（489.0, 545.0, 584.0, 620.0 nm） and TbL3phen（H2O）2（490.0, 544.0, 583.0, 620.0 nm）. Under the same conditions, only one emission band due to the ^5D4-^7F5 transition was observed for the complex TbL2（TPPO）2NO3. The emission intensity of TbL3dipy（H2O）2 is the strongest among the three complexes.展开更多
Three new complexes TbL3dipy （H2O）2, TbL3phen （ H2O ）2 and TbL2 （ TPPO ）2NO3 have been synthesized （L = phenylglyoxylate ion, dipy = 2, 2- dipyfidine, phen = 1,10-phenanthroline, TPPO = Triphenyl phosphine oxi...Three new complexes TbL3dipy （H2O）2, TbL3phen （ H2O ）2 and TbL2 （ TPPO ）2NO3 have been synthesized （L = phenylglyoxylate ion, dipy = 2, 2- dipyfidine, phen = 1,10-phenanthroline, TPPO = Triphenyl phosphine oxide ）. Elemental analysis, conductivity, IR spectra and ^1HNMR spectra studies were performed on them. IR spectra indicate that carboxylate ions in the phenylglyoxylate are coordinated to Tb （Ⅲ） ions as unidentate ligands. In ^1HNMR, the signals of hydrogens in phenylglyoxylate shift upfield. The excitation and emission spectra of the three comolexes were recorded at room temoerature, the excitation spectra show that the optimum excitation wavelengths are 361.0, 359.0 and 367.0 nm, respectively. Four emission bands due to ^5D4-^7Fj （j = 6, 5, 4, 3 ） transitions were observed for TbLadipy （ H2O ）2 （489.0, 545. 0, 584.0,620.0 nm） and TbL3phen （H2O）2 （490. , 544.0, 583.0, 620.0 nm）. And under the same conditions, only one emission band due to ^5Da-^7F5 transition was observed for TbL2 （TPPO）ENO3. The emission intensity of TbLadipy （H2O）2 is the strongest among the three complexes.展开更多
文摘Three new complexes TbL3dipy （H2O）2, TbL3phen （H2O） 2 and TbL2 （TPPO） 2NO3 were synthesized （L = phenylglyoxylate ion, dipy = 2, 2-dipyridine, phen = 1,10-phenanthmline, TPPO = Triphenyl phosphine oxide）. Elemental analysis, conductivity, IR spectra, and ^1HNMR spectra studies were performed. IR spectra indicate that the carboxylate ion of phenylglyoxylate is coordinated to the Tb（Ⅲ） ion as an unidentate ligand. In ^1HNMR, the signals of different hydrogens in phenylglyoxylate ion shift upfield. The excitation and emission spectra of the three solid complexes were recorded at morn temperature, in which the optimum excitation wavelengths are, 361.0, 359.0 and 367.0 nm for these three complexes, respectively. Four emission bands due to the ^5D4-^7Fj（j = 6, 5, 4, 3） transitions were observed for TbL3dipy（H2O）2（489.0, 545.0, 584.0, 620.0 nm） and TbL3phen（H2O）2（490.0, 544.0, 583.0, 620.0 nm）. Under the same conditions, only one emission band due to the ^5D4-^7F5 transition was observed for the complex TbL2（TPPO）2NO3. The emission intensity of TbL3dipy（H2O）2 is the strongest among the three complexes.
文摘Three new complexes TbL3dipy （H2O）2, TbL3phen （ H2O ）2 and TbL2 （ TPPO ）2NO3 have been synthesized （L = phenylglyoxylate ion, dipy = 2, 2- dipyfidine, phen = 1,10-phenanthroline, TPPO = Triphenyl phosphine oxide ）. Elemental analysis, conductivity, IR spectra and ^1HNMR spectra studies were performed on them. IR spectra indicate that carboxylate ions in the phenylglyoxylate are coordinated to Tb （Ⅲ） ions as unidentate ligands. In ^1HNMR, the signals of hydrogens in phenylglyoxylate shift upfield. The excitation and emission spectra of the three comolexes were recorded at room temoerature, the excitation spectra show that the optimum excitation wavelengths are 361.0, 359.0 and 367.0 nm, respectively. Four emission bands due to ^5D4-^7Fj （j = 6, 5, 4, 3 ） transitions were observed for TbLadipy （ H2O ）2 （489.0, 545. 0, 584.0,620.0 nm） and TbL3phen （H2O）2 （490. , 544.0, 583.0, 620.0 nm）. And under the same conditions, only one emission band due to ^5Da-^7F5 transition was observed for TbL2 （TPPO）ENO3. The emission intensity of TbLadipy （H2O）2 is the strongest among the three complexes.
