Durable hierarchical phosphorus‐doped biphase MoS_(2)electrocatalysts with enhanced H^(*)adsorption

Phase engineering is an efficient strategy for enhancing the kinetics of electrocatalytic reactions.Herein,phase engineering was employed to prepare high‐performance phosphorous‐doped biphase(1T/2H)MoS_(2)(P‐BMS)nanoflakes for hydrogen evolution reaction(HER).The doping of MoS_(2)with P atoms modifies its electronic structure and optimizes its electrocatalytic reaction kinetics,which significantly enhances its electrical conductivity and structural stability,which are verified by various characterization tools,including X‐ray photoelectron spectroscopy,high‐resolution transmission electron microscopy,X‐ray absorption near‐edge spectroscopy,and extended X‐ray absorption fine structure.Moreover,the hierarchically formed flakes of P‐BMS provide numerous catalytic surface‐active sites,which remarkably enhance its HER activity.The optimized P‐BMS electrocatalysts exhibit low overpotentials(60 and 72 mV at 10 mA cm^(−2))in H_(2)SO_(4)(0.5 M)and KOH(1.0 M),respectively.The mechanism of improving the HER activity of the material was systematically studied using density functional theory calculations and various electrochemical characterization techniques.This study has shown that phase engineering is a promising strategy for enhancing the H*adsorption of metal sulfides.

Pillar effect induced by ultrahigh phosphorous/nitrogen doping enables graphene/MXene film with excellent cycling stability for alkali metal ion storage

Graphene's large theoretical surface area and high conductivity make it an attractive anode material for potassium-ion batteries(PIBs).However,its practical application is hindered by small interlayer distance and long ion transfer distance.Herein,this paper aims to address the issue by introducing MXene through a simple and scalable method for assembling graphene and realizing ultrahigh P doping content.The findings reveal that MXene and P-C bonds have a "pillar effect" on the structure of graphene,and the P-C bond plays a primary role.In addition,N/P co-doping introduces abundant defects,providing more active sites for K^(+) storage and facilitating K^(+) adsorption.As expected,the developed ultrahigh phosphorous/nitrogen co-doped flexible reduced graphene oxide/MXene(NPrGM) electrode exhibits remarkable reversible discharge capacity(554 mA hg^(-1) at 0.05 A g^(-1)),impressive rate capability(178 mA h g^(-1) at 2 A g^(-1)),and robust cyclic stability(0.0005% decay per cycle after 10,000 cycles at 2 A g^(-1)).Furthermore,the assembled activated carbon‖NPrGM potassium-ion hybrid capacitor(PIHC) can deliver an impressive energy density of 131 W h kg^(-1) and stable cycling performance with 98.1% capacitance retention after5000 cycles at 1 A g^(-1).Such a new strategy will effectively promote the practical application of graphene materials in PIBs/PIHCs and open new avenues for the scalable development of flexible films based on two-dimensional materials for potential applications in energy storage,thermal interface,and electromagnetic shielding.

Controlled Synthesis and Application of α-Al_2O_3 for Lu_3Al_5O_(12): Ce^(3+) Green Spherical Phosphors

Al2O3 powders with different morphologies,namely fibrous,sheet-like,and spherical,were prepared by the hydrothermal-thermolysis method.Subsequently,polycrystalline,transparent cerium doped lutetium aluminum garnet（Lu3Al5O（12）：Ce^3＋）green phosphors were synthesized by high temperature solidstate method using commercial lutetium（III）oxide,cerium（III）oxide,and as-prepared Al2O3 powders with different morphologies.The phases,morphologies,and photoluminescent properties of the prepared phosphors were investigated by X-ray diffraction（XRD）,scanning electron microscopy（SEM）,and photoluminescence spectroscopy（PL）.Moreover,the influences of the morphologies ofα-Al2O3 on the types of crystal structure,morphologies,and photoluminescent properties of LuAG：Ce^3＋green phosphors were investigated.The results indicated that the morphologies and particle sizes of theα-Al2O3 powders could be controlled by the additives and parameters.Notably,the sphericalα-Al2O3 powders with good dispersibility were found to be the excellent base materials of LuAG：Ce^3＋green phosphors for white light emitting diodes.

Heteroatom Doped Multi-Layered Graphene Material for Hydrogen Storage Application

A variety of distinctive techniques have been developed to produce graphene sheets and their functionalized subsidiaries or composites. The production of graphene sheets by oxidative exfoliation of graphite can be a suitable route for the preparation of high volumes of graphene derivatives. P-substituted graphene material is developed for its application in hydrogen sorption in room temperature. Phosphorous doped graphene material with multi-layers of graphene shows a nearly ~2.2 wt% hydrogen sorption capacity at 298 K and 100 bar. This value is higher than that for reduced graphene oxide (RGO without phosphorous).

Bifunctional interstitial phosphorous doping strategy boosts platinum-zinc alloy for efficient ammonia oxidation reaction and hydrogen evolution reaction

It is still a lack of bifunctional catalysts for ammonia oxidation reaction(AOR)and hydrogen evolution reaction(HER)due to their different reaction mechanisms.In this work,P is doped into PtZn alloy by calcination with NaH_(2)PO_(2) as P source to induce the lattice tensile strain of Pt and the electronic interaction between P and Zn,which optimizes the AOR and HER activity simultaneously.The sample with the optimal P content can drive the AOR peak current density of 293.6 mA·mgPt^(-1),which is almost 2.7 times of Pt.For HER,the overpotential at^(-1)0 mA·cm^(-2) is only 23 mV with Tafel slope of 34.1 mV·dec^(-1).Furthermore,only 0.59 V is needed to obtain 50 mA·mgPt^(-1) for ammonia electrolysis under a two-electrode system.Therefore,this work shows an ingenious method to design bifunctional catalysts for ammonia electrolysis.

Enhancing electrical conductivity of single-atom doped Co_(3)O_(4) nanosheet arrays at grain boundary by phosphor doping strategy for efficient water splitting

High electrical conductivity guarantees a rapid electron transfer and thus plays an important role in electrocatalysis.In particular,for the single atom catalysts(SACs),to facilitate interaction between the single atom and supports,precisely engineering the conductivity represents a promising strategy to design SACs with high electrochemical efficiency.Here we show rhodium(Rh)SAC anchored on Co_(3)O_(4) nanosheets arrays on nickel foam(NF),which is modified by a facile phosphorus(P-doped Rh SACCo_(3)O_(4)/NF),possessing an appropriate electronic structure and high conductivity for electrocatalytic reaction.With the introduction of P atom in the lattice,the electrocatalyst demonstrates outstanding alkaline oxygen evolution reaction(OER)activity with 50 mA·cm^(−2) under overpotential of 268 mV,6 times higher than that of Ir/C/NF.More interestingly,the P-doped Rh SAC-Co_(3)O_(4)/NF can get 50 mA·cm^(−2) at only 1.77 V for overall water splitting.Both electrical conductivity studies and density functional theory(DFT)calculations reveal that the high conductivity at grain boundary improves the charge transfer efficiency of the Rh catalytic center.Furthermore,other noble-metal(Ir,Pd,and Ru)doped Co_(3)O_(4) nanosheets arrays are prepared to exhibit the general efficacy of the phosphorus doping strategy.

Modified silicon carbide whisker reinforced polybenzimidazole used for high temperature proton exchange membrane

Polybenzimidazole containing ether bond（OPBI） was reinforced with silicon carbide whisker（m Si C） modified by 3-aminopropyltriethoxysilane（KH550）, and then doped with phosphoric acid（PA） to obtain OPBI/m Si C/PA membranes. These OPBI/m Si C/PA membranes have excellent mechanical strength and oxidative stability and can be used for high temperature proton exchange membrane（HT-PEM）. The tensile strength of OPBI/m Si C/PA membranes ranges from 27.3 to 36.8 MPa, and it increases at first and then decreases with the increase of m Si C content. The high m Si C content and PA doping level contribute to improving the proton conductivity of membranes. The proton conductivity of PBI/m Si C-10/PA membrane is 27.1 m S cm-1 at 170℃ without humidity, with an increase of 55.7% compared with that of OPBI/PA membrane. These excellent properties make OPBI/m Si C/PA membranes promising membrane materials for HT-PEM applications.

Color-tunable hypersensitive temperature sensor based on metal organic framework doped with Eu^(3+)and Dy^(3+)via phonon-assisted energy transfer

In this work,catena-[(μ-benzene-1,3,5-tricarboxylato)-(1,10-phenanthroline)-(N,N-dimethylfo rmamide)-gadolinium(ⅲ)-N,N-dimethylformamide solvate](denoted as Gd-MOF)co-doped with Eu^(3+)and Dy^(3+)was successfully synthesized.The entire X-ray diffraction peaks of the sample match well with the GdMOF phase.A detailed characterization by inductively coupled plasma mass spectrometry(ICP-MS)shows that the actual concentration is basically consistent with the design concentration.The temperature sensing properties of Gd-MOF:Eu^(3+),Dy^(3+)were analyzed by temperature-dependent fluorescence spectra from 213 to 453 K.As temperature rises,the emission color of Gd-MOF:Eu^(3+),Dy^(3+)changes from yellow to red.The relative sensitivity reaches a maximum of 5.87%/K at 383 K in the Gd-MOF:1%Eu^(3+),30%Dy^(3+)sample.The high relative sensitivity of this MOF is due to the phonon-assisted energy transfer from Dy^(3+)to Eu^(3+),which is proved via fluorescence decay curves and fluoresce nce spectra.The major route of this energy transfer is^(4)F_(9/2)(Dy^(3+))→^(5)D_(1)(Eu^(3+)).

A tunable yellow emission from three-band emission of singly doped single-phased phosphor BaY_2S_4:Ho^(3+)

The establishment of an approach to design tunable yellow emission through singly doped single-phased phosphors to obtain white LED-based InGaN chip was reported. BaY2–xS4：xHo3＋ phosphors were prepared by the high temperature solid state reaction and characterized by X-ray diffraction and photoluminescence spectra. Under the excitation of 465 nm,the emission spectra of these phosphors exhibited three sharp emission lines peaked at about 492,543 and 661 nm of Ho3＋ corresponding to 5F3,5F4 （5S2） and 5F5→5I8 transitions,respectively,with comparable intensities,resulting in a yellow light emission. The luminescence mechanism for Ho3＋ in BaY2S4 was explained.

Plasmon-enhanced broad-band quantum-cutting of NaBaPO4:Eu^2+,Er^3+phosphors with silver nano-particles

NaBaPO4:Eu^2+,Er^3+phosphors and Ag nano-particles(NPs)were prepared by the solid-state reaction and chemical reduction method,respectively.The fluorescence spectra and decay curves demonstrate the effective energy transfer from Eu^2+to Er^3+and the existence of three-photon quantum-cutting through two-step cross-relaxation of Er^3+.The quantum-cutting emission is peaked at 1534 nm with a broad excitation band centered at 352 nm,Plasmon-enhanced quantum-cutting of NaBaPO4:Eu^2+,Er^3+phosphors was realized by decorating Ag NPs.The largest enhancement factor is 1.395.It is hopeful to improve the photovoltaic conversion efficiency of Ge solar cells by using this phosphor.

White light emission in Pr^(3+),Tb^(3+):CaYAlO_4 phosphor

In this work, the synthesis and photoluminescence characteristics of two new phosphors Pr3+: CaYAlO4(CYA) and Pr3+/Tb3+: CYA for light emitting diodes(LEDs) are investigated. 0.5%(atom percentage) Pr3+: CYA exhibits the largest bright yellow emission by varying the Pr3+ concentration, owing to the cross-relaxation process of 3P0 +3H4→ 1G4+1G4. The energy level diagram in Pr3+: CYA, especially the positions of 4f5 d level and 1S0 level, is discussed. By co-doping Tb3+ ions, the color coordinates of Pr3+/Tb3+: CYA phosphor can be tuned from yellow to white region. Finally, the strongest luminescence emission with color coordinates of(0.339, 0.364) located in the white region can be obtained in 0.3%Tb3+/0.5%Pr3+: CYA phosphor.

Luminescence properties of tunable red-green emitting phosphor Ba2Ca(BO3)2：Eu3＋,Tb3＋

A series of Eu^(3+) or Tb^(3+) doped Ba_2Ca(BO_3)_2 phosphors were synthesized by a high temperature solid state method, and the luminescence properties are investigated. Ba_2Ca(BO_3)_2:Tb^(3+) can show an obvious green emission, and the peak locates at 551 nm, which corresponds to the 5D34→7F5 transition of Tb^(3+). Ba_2Ca(BO_3)_2:Eu+ can present the characteristic emission of Eu^(3+), and the peak locates at 600 nm, which is ascribed to the 5D70→F2 transition of Eu^(3+). In order to achieve the emission-tunable phosphors, the Eu^(3+)/Tb^(3+) co-doped Ba_2Ca(BO_3)_2 are synthesized. When tuning the Eu^(3+) or Tb^(3+) concentration, Ba_2Ca(BO_3)_2:Eu^(3+), Tb^(3+) can both show the tunable emission, which may be induced by the energy transfer from Tb^(3+) to Eu^(3+).

Improved luminescent properties of SrZn_2(PO_4)_2:Sm^(3+) doped with Li^+, Na^+ and K^+ ions

SrZn2(PO4)2:Sm3+ phosphor was synthesized by a high temperature solid-state reaction in atmosphere. SrZn2(PO4)2:Sm3+ phosphor is efficiently excited by ultraviolet(UV) and blue light, and the emission peaks are assigned to the transitions of 4G5/2-6H5/2(563 nm), 4G5/2-6H7/2(597 nm and 605 nm) and 4G5/2-6H9/2(644 nm and 653 nm). The emission intensities of SrZn2(PO4)2:Sm3+ are influenced by Sm3+ concentration, and the concentration quenching effect of SrZn2(PO4)2:Sm3+ is also observed. When doping A+(A=Li, Na and K) ions, the emission intensity of SrZn2(PO4)2:Sm3+ can be obviously enhanced. The Commission Internationale de l'Eclairage(CIE) color coordinates of SrZn2(PO4)2:Sm3+ locate in the orange-red region. The results indicate that the phosphor has a potential application in white light emitting diodes(LEDs).