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Separation of Indium and Iron from Dilute Sulphate Solutions with a Phosphorous Mixer Extractant 被引量:4
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作者 xiulian Xu, Zhifeng Xu Department of Material Engineering, Southem Institute of Metallurgy,Ganzhou 341000, China 《Rare Metals》 SCIE EI CAS CSCD 2001年第3期152-156,共5页
The phosphorous mixer introduced could replace D2EHPA as an extractant applied in the extraction of indium. The extraction properties of the phosphorous mixer were studied. The influences of extractant concentration, ... The phosphorous mixer introduced could replace D2EHPA as an extractant applied in the extraction of indium. The extraction properties of the phosphorous mixer were studied. The influences of extractant concentration, organic/aqueous (O/A) phase ratio, equilibrium time, and pH value of the feed solutions on the extraction of indium, and separation of indium-iron were investigated experimentally. Under the best operating conditions, more than 98% of indium. was extracted through two-stage counter-current extraction. The optimizing condition of indium extraction is determined as follows: O/A = 1 : (9-12) in volume ratio; 30% PPD in sulphonated kerosene; pH of the feed, about 0.6; equilibrium time, 3-5 min. The extractant has good reusing and anti-aging properties. 展开更多
关键词 acidic phosphorous extractant indium-iron separation solvent extraction
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P204萃取分离催化剂母液中钴和锰 被引量:2
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作者 张征林 黄宁平 路春娥 《水处理技术》 CAS CSCD 北大核心 1993年第2期87-92,共6页
在25±2℃下研究了 D2EHPA—煤油从硫酸盐介质中革取分离钻(Ⅱ)、锰(Ⅱ)的工艺。考察了萃取剂浓度、平衡 pH 值,相比对萃取钻锰的影响,获得了较适宜的工艺条件,利用五级逆流萃取模拟试验将钻锰浓度比从1∶1.5提高到1000∶1。加入洗... 在25±2℃下研究了 D2EHPA—煤油从硫酸盐介质中革取分离钻(Ⅱ)、锰(Ⅱ)的工艺。考察了萃取剂浓度、平衡 pH 值,相比对萃取钻锰的影响,获得了较适宜的工艺条件,利用五级逆流萃取模拟试验将钻锰浓度比从1∶1.5提高到1000∶1。加入洗涤段后,可获得金属含量比为1000的纯钴、锰溶液。初步探索了用液膜萃取新技术从溶液中分别富集,分离钴(Ⅱ)、锰(Ⅱ)的方法,找出了体系 pH 值对液膜萃取的影响。提出了从 PTA 氧化母液中回收废催化剂、萃取分离钻、锰,再生制备醋酸钴、醋酸锰和其他含钴锰的精细化工产品的工艺。此方法可考虑用来处理含 Co、Mn 的废水。 展开更多
关键词 P204 萃取 催化剂 废水处理
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