The extraction of Nd^3＋ and Sm^3＋, including the extraction and stripping capability as well as the separation effect of Nd^3＋ or Sm^3＋, from a sulfuric acid medium, by mixtures of di-（2-ethylhexyl） phosphoric a...The extraction of Nd^3＋ and Sm^3＋, including the extraction and stripping capability as well as the separation effect of Nd^3＋ or Sm^3＋, from a sulfuric acid medium, by mixtures of di-（2-ethylhexyl） phosphoric acid （HDEHP, H2A2（0）） and 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester （HEH/EHP, H2L2（0）） were studied. The distribution ratios and synergistic coefficients of Nd^3＋ and Sm^3＋ in different acidities were also determined. A synergistic extractive effect was found when HDEHP and HEH/EHP were used as mixed extractants for Sm^3＋ or Nd^3＋. The chemical compositions of the extracted complex were determined as Nd.（HA2）2-HL2 and Sm.（HA2）2-HL2. The extraction equilibrium constants, enthalpy change, and entropy change of the extraction reaction were also determined.展开更多
Stripping dispersion hollow fiber liquid membrane system（SDHFLM） containing feed phase adding acetate buffer solution and dispersion solution with HNO_3 solution as the stripping solution and membrane solution of 2-...Stripping dispersion hollow fiber liquid membrane system（SDHFLM） containing feed phase adding acetate buffer solution and dispersion solution with HNO_3 solution as the stripping solution and membrane solution of 2-ethyl hexyl phosphoric acid-mono-2-ethylhexyl ester（PC-88A） dissolved in kerosene,has been studied for the extraction of Sm^（3＋）.Many factors including pH value, volume ratio of membrane solution to stripping solution（OAV） and carrier concentration on Sm^（3＋） extraction were investigated. Experimental results indicate that the optimum extraction conditions of Sm^（3＋） were obtained as that PC-88A concentration was 0.120 mol/L,and OAV was 1.00 in the dispersion phase,and pH value was 4.80 in the feed phase.When initial Sm^（3＋） concentration was 1.20×10^（-4） mol/L,the extraction percentage of Sm^（3＋） was up to 92.8%in 160 min.展开更多
A synergistic rhodium（Ⅱ）/phosphoric acid catalyzed three component reaction of 3-diazooxindoles,alcohols and N-benzhydryl-α-imino ester is developed for the efficient construction of chiral β-alkoxy C-β-tetrasub...A synergistic rhodium（Ⅱ）/phosphoric acid catalyzed three component reaction of 3-diazooxindoles,alcohols and N-benzhydryl-α-imino ester is developed for the efficient construction of chiral β-alkoxy C-β-tetrasubstituted α-amino acid derivatives in good yields and with excellent diastereoselectivities and high enantioselectivities.The synthetic application of the resulting products was illustrated by reducing with Pd/C under H_2 atmosphere followed reacting with CSCl_2 at room temperature to rapid afford 3-spirocyclic oxindole in a good yield with a chirality retainment.The three-component reaction is proposed to proceed through an electrophilic trapping of the oxonium ylides by N-benzhydryl-α-imino ester.展开更多
基金the National Natural Science Foundation of China (50674016)the National High Technology Research and Develop-ment Program of China (863 Program) ( 2006AA06Z123)
文摘The extraction of Nd^3＋ and Sm^3＋, including the extraction and stripping capability as well as the separation effect of Nd^3＋ or Sm^3＋, from a sulfuric acid medium, by mixtures of di-（2-ethylhexyl） phosphoric acid （HDEHP, H2A2（0）） and 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester （HEH/EHP, H2L2（0）） were studied. The distribution ratios and synergistic coefficients of Nd^3＋ and Sm^3＋ in different acidities were also determined. A synergistic extractive effect was found when HDEHP and HEH/EHP were used as mixed extractants for Sm^3＋ or Nd^3＋. The chemical compositions of the extracted complex were determined as Nd.（HA2）2-HL2 and Sm.（HA2）2-HL2. The extraction equilibrium constants, enthalpy change, and entropy change of the extraction reaction were also determined.
基金financially supported by the National Natural Science Foundation of China for Young Scientists(Nos. 51109197 and 51009126)the Action Plan for the Development of Western China of the Chinese Academy of Sciences (No.KZCX2-XB2-13)+1 种基金the Knowledge Innovation Program of the Chinese Academy of Sciences(No.KSCX2-YW-N -003)Research Fund for Excellent Doctoral Thesis of Xi'an University of Technology(Nos.602-210805 and 602-210804)
文摘Stripping dispersion hollow fiber liquid membrane system（SDHFLM） containing feed phase adding acetate buffer solution and dispersion solution with HNO_3 solution as the stripping solution and membrane solution of 2-ethyl hexyl phosphoric acid-mono-2-ethylhexyl ester（PC-88A） dissolved in kerosene,has been studied for the extraction of Sm^（3＋）.Many factors including pH value, volume ratio of membrane solution to stripping solution（OAV） and carrier concentration on Sm^（3＋） extraction were investigated. Experimental results indicate that the optimum extraction conditions of Sm^（3＋） were obtained as that PC-88A concentration was 0.120 mol/L,and OAV was 1.00 in the dispersion phase,and pH value was 4.80 in the feed phase.When initial Sm^（3＋） concentration was 1.20×10^（-4） mol/L,the extraction percentage of Sm^（3＋） was up to 92.8%in 160 min.
基金NSFC (No. 21332003)STCSM (No. 15ZR1411000)Stake Key Laboratory of Advanced Technology for Materials Synthesis and Processing (2015-KF-11) for financial support
文摘A synergistic rhodium（Ⅱ）/phosphoric acid catalyzed three component reaction of 3-diazooxindoles,alcohols and N-benzhydryl-α-imino ester is developed for the efficient construction of chiral β-alkoxy C-β-tetrasubstituted α-amino acid derivatives in good yields and with excellent diastereoselectivities and high enantioselectivities.The synthetic application of the resulting products was illustrated by reducing with Pd/C under H_2 atmosphere followed reacting with CSCl_2 at room temperature to rapid afford 3-spirocyclic oxindole in a good yield with a chirality retainment.The three-component reaction is proposed to proceed through an electrophilic trapping of the oxonium ylides by N-benzhydryl-α-imino ester.
