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Molten salt synthesis and luminescent properties of YVO_4:Eu nanocrystalline phosphors
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作者 王芳 刘成露 +2 位作者 周志强 贾佩云 林君 《Journal of Rare Earths》 SCIE EI CAS CSCD 2012年第3期202-204,共3页
YVO4:Eu nanocrystalline phosphors were successfully prepared at 400 oC in equal moles of NaNO3 and KNO3 molten salts. NaOH concentration and annealing temperature played important roles in phase purity and crystallin... YVO4:Eu nanocrystalline phosphors were successfully prepared at 400 oC in equal moles of NaNO3 and KNO3 molten salts. NaOH concentration and annealing temperature played important roles in phase purity and crystallinity of the nanocrystallines, and the optimum NaOH concentration and annealing temperature were 6:40 and 400 oC, respectively. The nanocrystallines were well crystallized with a cubic morphology in an average grain size of 18 nm. Upon excitation of the vanadate groups at 314 nm, YVO4:Eu nanocrystallines exhibited the characteristic emission of Eu3+, which indicated that there was an energy transfer from vanadate groups to Eu3+. Moreover, the influence of superficial effect, especially the dangling bonds on the structure and luminescent properties of the nanocrystallines was discussed in detail. 展开更多
关键词 nanocrystalline phosphor luminescence molten salt YVO4 rare earths
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