期刊文献+
共找到308篇文章
< 1 2 16 >
每页显示 20 50 100
Direct extraction of Mo(VI) from acidic leach solution of molybdenite ore by ion exchange resin:Batch and column adsorption studies 被引量:15
1
作者 Yun-feng FU Qing-gui XIAO +3 位作者 Yi-ying GAO Peng-ge NING Hong-bin XU Yi ZHANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第8期1660-1669,共10页
The adsorption behavior of ion exchange resin D301 in the extraction of hexavalent molybdenum from high acidic leach solution was investigated. SEM, EDS and Raman spectra analyses were applied to studying the adsorpti... The adsorption behavior of ion exchange resin D301 in the extraction of hexavalent molybdenum from high acidic leach solution was investigated. SEM, EDS and Raman spectra analyses were applied to studying the adsorption capacity, reaction kinetics and possible adsorption mechanism in detail. Results showed that the adsorption capacity of D301 resin for molybdenum from high acidic leach solution was up to 463.63 mg/g. Results of the kinetic analysis indicated that the adsorption process was controlled by the particle diffusion with the activation energy 25.47 k J/mol(0.9-1.2 mm) and 20.38 k J/mol(0.6-0.9 mm). Furthermore, the molybdenum loaded on the resin could be eluted by using 2 mol/L ammonia hydroxide solution. Besides, dynamic continuous column experiments verified direct extraction of molybdenum from acidic leach solutions by ion exchange resin D301 and the upstream flow improved dynamic continuous absorption. 展开更多
关键词 molybdenum acidic leach solution ion exchange resin kinetics continuous column adsorption
下载PDF
Study on the influence of humic acid of different molecular weight on basic ion exchange resin's adsorption capacity 被引量:8
2
作者 Jin Nan Wang Ai Min Li Yang Zhou Li Xu 《Chinese Chemical Letters》 SCIE CAS CSCD 2009年第12期1478-1482,共5页
In this paper, humic acid (HA) was ultra-filtered into different molecular weight sections and was characterized by multielement analysis, UV254/TOC, FT-IR and three-dimensional fluorescence spectrometric. Since hum... In this paper, humic acid (HA) was ultra-filtered into different molecular weight sections and was characterized by multielement analysis, UV254/TOC, FT-IR and three-dimensional fluorescence spectrometric. Since humic acids of different molecular weights have different hydrophilic and molecular size, the maximum adsorption capacity of basic ion exchange resins appears on the humic acid whose molecular weight ranges from 6000 to 10,000 Da. 展开更多
关键词 Humic acid Molecular weight Basic ion exchange resin ADSORPTion
下载PDF
Kinetic Study of Esterification of Lactic Acid with Isobutanol and n-Butanol Catalyzed by Ion-exchange Resins 被引量:3
3
作者 屈一新 彭少君 +2 位作者 王水 张志强 王际东 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第5期773-780,共8页
The esterification reactions of lactic acid with isobutanol and n-butanol have been studied in the presence of acid ion-exchange resin Weblyst D009. The influences of catalyst loading, stirrer speed, catalyst particle... The esterification reactions of lactic acid with isobutanol and n-butanol have been studied in the presence of acid ion-exchange resin Weblyst D009. The influences of catalyst loading, stirrer speed, catalyst particle size, initial reactant molar ratio and temperature on the reaction rate have been examined. Experimental kinetic data were correlated by using the pseudo-homogeneous, Langnluir-Hinshelwood and Eley-Rideal models. Nonideality of the liquid phase was taken into account by using activities instead of molar fractions. The activity coefficients were calculated according to the group contribution method UNIFAC. Provided that the nonideality of the liquid is taken into account, the esterification kinetics of lactic acid with isobutanol and n-butanol catalyzed by the acid ion-exchange resin can be described using all threemodels with reasonable errors. 展开更多
关键词 KINETICS ESTERIFICATion lactic acid ISOBUTANOL N-BUTANOL ion exchange resin
下载PDF
Cleaning the Ion Exchange Resin Sorption of Uranium from Silicic Acid Solution "Ayanat"
4
作者 Aibassov Erkin Zhakenovich Yemelyanova Valentina Stepanovna Shakieva Tatyana Tussupbaev Nessipbay Bulenbaiev Maxat Blagikh Evgeniy 《Journal of Chemistry and Chemical Engineering》 2015年第3期199-202,共4页
The authors discovered a new way to clean the ion exchange resin sorption of uranium from silicic acid used solution "Ayanat". The method reduces the costs of regeneration of ion exchange resin and its reuse in the ... The authors discovered a new way to clean the ion exchange resin sorption of uranium from silicic acid used solution "Ayanat". The method reduces the costs of regeneration of ion exchange resin and its reuse in the sorption of uranium. 展开更多
关键词 ion exchange resin sorption of uranium silicic acid cleaning.
下载PDF
Elution Behaviour of Monocarboxylic Acids on a Cation-exchange Resin Column
5
作者 Zhao Guoliang and Liu Zhiguang (Department of Chemistry, Mian University of Technology, Dalian) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1989年第3期237-243,共7页
The retention mechanism of monocarboxylic acids on a cation-exchange resin column was investigated. It was assumed that both Donnan membrane equilibrium and adsorption equilibrium were involved in the chromatographic ... The retention mechanism of monocarboxylic acids on a cation-exchange resin column was investigated. It was assumed that both Donnan membrane equilibrium and adsorption equilibrium were involved in the chromatographic process. On the basis of the proposed mechanism, an equation was derived for correlating distribution coefficient, Kd, dissociation constant, Aa, and adsorption equilibrium constant, K, of the analyzed acid. By this approach, retention data for some aliphatic acids under different operating conditions were predicted. Results are reasonably in agreement with experiment. 展开更多
关键词 ion exclusion chromatography Monocarboxylic acids Cation-exchange resin
下载PDF
Atmospheric Sulfur and Nitrogen Deposition in Five Nature Reserves of Sichuan Basin to Qinghai-Tibetan Plateau Transect Region,Southwest-ern China
6
作者 XU Zhongjun SHU Xi +5 位作者 YANG Han FU Liqiang LIU Tingting XIA Zhonglin QIAO Xue TANG Ya 《Chinese Geographical Science》 SCIE CSCD 2024年第6期1060-1072,共13页
Enhanced sulfur and nitrogen deposition has been observed in many transect regions worldwide,from urban/agricultural areas to mountains.The Sichuan Basin(SCB),with 18 prefectural cities,is the most economically-develo... Enhanced sulfur and nitrogen deposition has been observed in many transect regions worldwide,from urban/agricultural areas to mountains.The Sichuan Basin(SCB),with 18 prefectural cities,is the most economically-developed region in western China,while the rural Qinghai-Tibetan Plateau(QTP)lies west of the SCB.Previous regional and national atmospheric modeling studies have sug-gested that large areas in the SCB-to-QTP transect region experience excessive deposition of sulfur and nitrogen.In this study,we ap-plied a passive monitoring method at 1l sites(one in urban Chengdu and 10 from fivenature reserves)in this transect region from September 2021 to October 2022 to confirm the high sulfur and nitrogen deposition fluxes and to understand the gaps between the mod-eling and observation results for this transect region.These observations suggest that the five reserves are under eutrophication risk,and only two reserves are partially under acidification risk.Owing to the complex topography and landscapes,both sulfur and nitrogen de-position and critical loads exhibit large spatial variations within a reserve,such as Mount Emei.Regional atmospheric modeling may not accurately capture the spatial variations in deposition fluxes within a reserve;however,it can capture general spatial patterns over the entire transect.This study demonstrates that a combination of state-of-the-art atmospheric chemical models and low-cost monitoring methods is helpful for ecological risk assessments at a regional scale. 展开更多
关键词 acid deposition ion exchange resin critical load acidIFICATion EUTROPHICATion Sichuan Basin to Qinghai-Tibetan Plateau transect region China
下载PDF
Removal of Co(Ⅱ) from aqueous solutions by NKC-9 strong acid resin
7
作者 熊春华 冯宇杰 +1 位作者 姚彩萍 沈忱 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第6期1141-1147,共7页
A strong acidic ion exchange resin(NKC-9)was used as a new adsorbent material for the removal of Co(Ⅱ)from aqueous solutions.The adsorption isotherm follows the Langmuir model.The maximum adsorption capacity of the r... A strong acidic ion exchange resin(NKC-9)was used as a new adsorbent material for the removal of Co(Ⅱ)from aqueous solutions.The adsorption isotherm follows the Langmuir model.The maximum adsorption capacity of the resin for Co(Ⅱ)is evaluated to be 361.0 mg/g by the Langmuir model.It is found that 0.5 mol/L HCl solution provides effectiveness of the desorption of Co(Ⅱ)from the resin.The adsorption rate constants determined at 288,298 and 308 K are 7.12×10-5,8.51×10-5and 9.85×10-5s-1, respectively.The apparent activation energy(Ea)is 12.0 kJ/mol and the adsorption parameters of thermodynamic are-H Θ=16.1 kJ/mol,-SΘ=163.4 J/(mol·K),-G Θ 298 K=-32.6 kJ/mol,respectively.The adsorption of Co(Ⅱ)on the resin is found to be endothermic in nature.Column experiments show that it is possible to remove Co(Ⅱ)ions from aqueous medium dynamically by NKC-9 resin. 展开更多
关键词 strong acid resin ion exchange Co(Ⅱ) adsorption isotherm
下载PDF
Improved Performance of W/HZSM-5 Catalysts for Dehydroaromatization of Methane
8
作者 Nor Aishah Saidina Amin Kusmiyati 《Journal of Natural Gas Chemistry》 CAS CSCD 2004年第3期148-159,共12页
The dehydroaramatization of methane over W-supported ZSM-5 with varying degrees of Li+ ion-exchanged catalysts was studied with and without oxygen at 1073 K and atmospheric pressure. Catalyst activity and stability we... The dehydroaramatization of methane over W-supported ZSM-5 with varying degrees of Li+ ion-exchanged catalysts was studied with and without oxygen at 1073 K and atmospheric pressure. Catalyst activity and stability were found to be influenced by the catalyst acidity related to Bronsted acid sites and by the presence of oxygen in the feed. The NH3-TPD and FTIR-pyridine results demonstrated that partially exchanged of H+ ions by Li+ into the W/HZSM-5 catalysts could be used to control the amount of strong acid sites on the catalyst surface. Without oxygen, the 3WHLi-Z (5:1) catalyst that has strong acid sites equal to nearly 74% of the original strong acid sites in the parent HZSM-5 exhibited the highest methane conversion and selectivity towards aromatics. However, the catalyst deactivated in a five hour period. In the presence of oxygen, the catalyst activity and stability could be improved further. The results of this study revealed that a suitable amount of strong Bronsted acid sites as well as oxygen addition in the feed increased the catalyst activity and stability. The 3WHLi-Z(5:1) catalyst exhibited improved performance in the dehydroaromatization of methane. 展开更多
关键词 DEHYDROAROMATIZATion METHANE W-supported ZSM-5 partial ion exchange H+ ion Li ion catalyst activity catalyst stability catalyst acidity oxygen presence improved performance
下载PDF
酸性矿山废水中多种有价金属的高效分离
9
作者 许昊洋 宁寻安 +4 位作者 陈涛 廖正家 张艳林 庄小薇 张灌源 《环境保护科学》 CAS 2024年第3期119-127,共9页
酸性矿山废水(AMD)中多种有价金属的高效分离回收,是重金属减排和资源化利用的关键。文章通过中和沉淀实验和静态吸附实验探究回收有价金属的最佳沉淀和吸附pH,成功开发了中和沉淀—离子交换—中和沉淀组合工艺,并应用于大宝山AMD的处... 酸性矿山废水(AMD)中多种有价金属的高效分离回收,是重金属减排和资源化利用的关键。文章通过中和沉淀实验和静态吸附实验探究回收有价金属的最佳沉淀和吸附pH,成功开发了中和沉淀—离子交换—中和沉淀组合工艺,并应用于大宝山AMD的处理。结果表明,AMD在pH为3.00和9.80中和沉淀时,分别沉获64%的Fe_(2)O_(3)富铁渣和51%的Mn O富锰渣。采用离子交换树脂分别在pH 3.95和6.10条件下对AMD中的Cu和Zn进行吸附,得到质量浓度为Cu^(2+)11~26 g/L,Zn^(2+)10~20 g/L的两种解吸液。通过该组合工艺,AMD中的各金属Fe、Cu、Zn和Mn的回收率分别为:96%、81%、70%和60%,实现了有价金属的高效分离回收。若采用此工艺回收大宝山2000 m^(3)/d的AMD中的铜、锌、锰硫酸盐,每年的利润为119万元,经济效益非常显著。此处理工艺为酸性矿山废水的高效资源化利用提供了新路径。 展开更多
关键词 酸性矿山废水 CU ZN 金属回收 离子交换树脂 废水处理
下载PDF
增强型离子交换树脂催化醚化汽油TAME的合成
10
作者 蔡慧芳 程正载 孔君燃 《化工技术与开发》 CAS 2024年第1期35-39,共5页
在高压釜式反应器中,以甲醇和异戊烯为原料,增强型离子交换树脂Amberlyst为催化剂,制备了高辛烷值醚化汽油组分TAME。改变反应温度、催化剂用量等单一实验变量,探索得到了最佳工艺条件:反应温度70℃,催化剂用量为20%,醇/烯比为2。在最... 在高压釜式反应器中,以甲醇和异戊烯为原料,增强型离子交换树脂Amberlyst为催化剂,制备了高辛烷值醚化汽油组分TAME。改变反应温度、催化剂用量等单一实验变量,探索得到了最佳工艺条件:反应温度70℃,催化剂用量为20%,醇/烯比为2。在最优条件下,该催化反应只需进行4.5h,TAME的摩尔产率就达到70%。 展开更多
关键词 酸性离子交换树脂 甲基叔戊基醚TAME 高辛烷值 汽油组分
下载PDF
The Synthesis of Cyclic Amino Acids 被引量:2
11
作者 Shrong Shi LIN 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第9期883-884,共2页
Several cyclic amino acids (1-4) were synthesized from glycine. Isocyanate ester was prepared as the key intermediate and reacted with dibromoalkanes to afford the target compounds.
关键词 Cyclic amino acid isocyanate ester dibromoalkane ion exchange resin.
下载PDF
Removal of Copper from Acid Mine Drainage (AMD) or Acid Rock Drainage (ARD) 被引量:1
12
作者 Agabu Shane Xinyang Xu +7 位作者 John Siame Alick Nguvulu Tewodros Mitiku Tena Musango Lungu Sydney Chinyanta Jackson Kawala Victor Mwango Bowa Brian Chirambo 《Journal of Water Resource and Protection》 2021年第7期435-454,共20页
Acid mine drainage is wastewater from a mine having a low pH and an elevated level of dissolved heavy metals. These metals are harmful to aquatic, animal and human life. This paper looks at the removal of copper from ... Acid mine drainage is wastewater from a mine having a low pH and an elevated level of dissolved heavy metals. These metals are harmful to aquatic, animal and human life. This paper looks at the removal of copper from acid mine drainage using ion exchange to less than 1 mg/l. A weak acidic cation resin was used. Spectrophotometric determination of copper with sodium diethyldithiocarbamate was used to determine the copper concentrations in the treated water. Using regression analysis, the experimental results gave a correlation coefficient of 0.977 and a coefficient of determination of 99.5%. Results indicated that the higher the flows rate the shorter the period after which the copper concentration in the treated water reaches 1 mg/l. At pH 3.85 and 5.09, the resin performed better and at pH above 6.62 and between pH 3.0 and below the resin’s does not perform well. The higher the resin height the greater is the resin exchange capacity and the longer it takes for the copper concentration to reach 1 mg/l in the treated water. The higher the wastewater copper concentration the shorter the time it takes the resin to reach 1 mg/l. The results for this experiment indicated that acid mine drainage can be treated well by ion exchange resins, but it is also very important to establish suitable operating conditions. 展开更多
关键词 acid Mine Drainage COPPER ion exchange resin and Spectrophotometry
下载PDF
基于载铀树脂饱和再吸附-淋洗一体化工艺的U型塔设计研究
13
作者 程威 苏学斌 +3 位作者 阙为民 陈希 李建华 杜志明 《湿法冶金》 CAS 北大核心 2023年第3期312-316,共5页
针对部分酸法地浸铀矿工艺在浸出中后期存在的浸出液铀浓度偏低、HSO_(4)^(-)离子竞争吸附、吸附饱和树脂容量低、固定床淋洗合格液铀浓度低等问题,设计了一种离子交换设备U型塔,研究了采用饱和再吸附与淋洗一体化工艺处理载铀树脂,考... 针对部分酸法地浸铀矿工艺在浸出中后期存在的浸出液铀浓度偏低、HSO_(4)^(-)离子竞争吸附、吸附饱和树脂容量低、固定床淋洗合格液铀浓度低等问题,设计了一种离子交换设备U型塔,研究了采用饱和再吸附与淋洗一体化工艺处理载铀树脂,考察了处理后淋洗液中铀浓度的变化。结果表明:经U型塔一体化工艺处理后,淋洗合格液中铀质量浓度升至43~50 g/L;U型塔运行稳定,树脂运移顺畅,塔内铀浓度梯度分布合理。该设备适用于地浸采铀浸出液处理过程,有一定的推广应用价值。 展开更多
关键词 酸法地浸 载铀树脂 U型塔 饱和再吸附 离子交换 设计
下载PDF
离子交换树脂回收酸性溶液中钨的试验研究 被引量:1
14
作者 陈宗艺 张勇 +4 位作者 任嗣利 钱汉麟 马爱顺 曾广聪 龚丹丹 《稀有金属与硬质合金》 CAS CSCD 北大核心 2023年第6期8-15,22,共9页
白钨矿酸浸过程钨以钨同多酸形式产出,此分解方法为白钨矿冶炼提供了新的途径,但后续从钨同多酸浸出液中回收钨是关键。本文比较了不同阴离子交换树脂对钨同多酸溶液的吸附行为,确定大孔弱碱性阴离子交换树脂D301为最佳树脂。主要考察了... 白钨矿酸浸过程钨以钨同多酸形式产出,此分解方法为白钨矿冶炼提供了新的途径,但后续从钨同多酸浸出液中回收钨是关键。本文比较了不同阴离子交换树脂对钨同多酸溶液的吸附行为,确定大孔弱碱性阴离子交换树脂D301为最佳树脂。主要考察了D301树脂用量、溶液pH值、吸附温度、钨浓度和吸附时间对树脂吸附钨的影响。结果表明,在树脂用量为5倍理论量,溶液pH值为2~3,吸附温度为40℃,钨(WO_(3))浓度为50~100g/L,吸附时间为240min的条件下,D301树脂对钨同多酸溶液中的钨吸附率达99.4%以上。同时,研究了载钨树脂的解吸行为,结果表明,对D301载钨树脂解吸效果最好的解吸剂种类为NaOH溶液,在NaOH溶液用量20mL、浓度4mol/L以及解吸温度50℃、时间60min的条件下,钨的解吸率可达97.94%。 展开更多
关键词 白钨矿 酸浸液 钨同多酸 离子交换 树脂 吸附 解吸
下载PDF
酸盐分离技术在镍电积阳极液中的应用
15
作者 肖乐乐 卫媛 +5 位作者 李瑞杰 张雯雯 闫刚刚 王轩 刘涛 莫亚文 《有色金属(冶炼部分)》 CAS 北大核心 2023年第5期5-12,共8页
目前酸盐分离技术主要有树脂吸附法、离子交换法和膜分离技术三大类,但将其应用于镍湿法冶炼中镍电积阳极液的报道较少。总结了三大类酸盐分离技术的原理和应用,并分别采用树脂吸附法、扩散渗析法、特种纳滤膜和电渗析结合的方法对镍电... 目前酸盐分离技术主要有树脂吸附法、离子交换法和膜分离技术三大类,但将其应用于镍湿法冶炼中镍电积阳极液的报道较少。总结了三大类酸盐分离技术的原理和应用,并分别采用树脂吸附法、扩散渗析法、特种纳滤膜和电渗析结合的方法对镍电积阳极液进行酸盐分离试验。结果表明,三种方法对镍电积阳极液均有一定的分离效果,其中树脂吸附法易饱和,需反洗再生,造成体积膨胀;扩散渗析法对硫酸的回收率在80%以上,镍的截留率在90%以上,但回收的硫酸浓度较低,同样存在体积膨胀问题;特种纳滤膜和电渗析结合法对镍离子的截留率可达90%以上,氢离子去除率可达70%以上,同时浓缩后的氢离子浓度可提高400%以上,镍离子浓度可提高500%以上,淡化液中各种离子浓度小于50 mg/L,可用作纯水,并且该方法不会造成系统体积膨胀,具有工业化应用价值。 展开更多
关键词 酸盐分离 镍电积阳极液 膜分离 树脂吸附 离子交换
下载PDF
利用D309树脂从含砷钨杂多酸溶液中回收钨的研究 被引量:1
16
作者 刘佳勋 丁伟 +4 位作者 霍广生 陈平 曾璐琦 廖承钢 敖想 《稀有金属与硬质合金》 CAS CSCD 北大核心 2023年第2期1-7,共7页
采用D309大孔弱碱性阴离子交换树脂从含砷钨杂多酸的白钨矿盐酸浸出液中回收钨并将其转型为钨酸铵溶液,研究了D309树脂对[AsW_(12)O_(40)]^(3-)的吸附等温线、吸附动力学、吸附和解吸的工艺条件。结果表明:D309树脂对[AsW_(12)O_(40)]^(... 采用D309大孔弱碱性阴离子交换树脂从含砷钨杂多酸的白钨矿盐酸浸出液中回收钨并将其转型为钨酸铵溶液,研究了D309树脂对[AsW_(12)O_(40)]^(3-)的吸附等温线、吸附动力学、吸附和解吸的工艺条件。结果表明:D309树脂对[AsW_(12)O_(40)]^(3-)的吸附过程遵循Langmuir等温方程,为单分子层吸附;吸附过程的控制步骤为颗粒扩散;在温度55℃、反应时间1 h、液固比2.5∶1的最佳条件下,钨的吸附率可达99.90%;在温度55℃、反应时间3 h、氨水浓度210 g/L、液固比1.25∶1的最佳条件下,钨的解吸率为91.78%。 展开更多
关键词 砷钨杂多酸 钨回收 D309树脂 离子交换 动力学 吸附等温线 氨水解吸
下载PDF
可见光-过一硫酸盐-磁性离子交换树脂协同工艺去除水中腐植酸的效能与机理
17
作者 杨生巧 孙东晓 +3 位作者 丁磊 何海涛 叶港归 董志强 《净水技术》 CAS 2023年第10期95-104,共10页
文中研究了可见光(VI)-过一硫酸盐(PMS)-磁性离子交换(MIEX)树脂体系协同处理水中腐植酸(HA)的效能、活性氧化物质(ROS)种类及活化机理、HA的去除机理以及影响HA去除的因素。结果表明,该体系对水中HA有较好的去除效果,反应90 min后,HA... 文中研究了可见光(VI)-过一硫酸盐(PMS)-磁性离子交换(MIEX)树脂体系协同处理水中腐植酸(HA)的效能、活性氧化物质(ROS)种类及活化机理、HA的去除机理以及影响HA去除的因素。结果表明,该体系对水中HA有较好的去除效果,反应90 min后,HA的去除率达到52.9%,显示了三者的协同促进作用。树脂母体中的铁氧化物协同VI,可有效活化PMS,产生硫酸根自由基和羟基自由基等活性物质。HA的去除主要是ROS氧化HA强化MIEX树脂的吸附作用,而非自由基的矿化降解。MIEX树脂投加量以及PMS浓度的增加可促进HA的去除,而温度在298 K以上时,影响不明显。该体系在有效去除水中HA的同时,可有效去除反应过程中的副产物SO_(4)^(2-),显示了良好的应用前景。 展开更多
关键词 可见光(VI) 过一硫酸盐(PMS) 磁性离子交换(MIEX)树脂 腐植酸(HA) 高级氧化工艺
下载PDF
用低交换容量聚苯乙烯型强酸性阳离子交换树脂柱色谱分离中性氨基酸 被引量:17
18
作者 刘菊湘 刘国栋 +4 位作者 阎虎生 程晓辉 何炳林 姜根华 杨国英 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第12期2100-2103,共4页
通过磺化苯乙烯 -二乙烯苯共聚物或商品化的聚苯乙烯型强酸性阳离子交换树脂 ( 0 0 1× 7)的逆磺化反应 ,得到一系列不同交换容量的聚苯乙烯型强酸性阳离子交换树脂 .研究了丙氨酸和缬氨酸及缬氨酸和亮氨酸在这些树脂柱上的色谱分... 通过磺化苯乙烯 -二乙烯苯共聚物或商品化的聚苯乙烯型强酸性阳离子交换树脂 ( 0 0 1× 7)的逆磺化反应 ,得到一系列不同交换容量的聚苯乙烯型强酸性阳离子交换树脂 .研究了丙氨酸和缬氨酸及缬氨酸和亮氨酸在这些树脂柱上的色谱分离 .结果表明 ,用两种方法得到的树脂对丙氨酸和缬氨酸的色谱分离性能基本相同 ;同时中性氨基酸与聚苯乙烯型强酸性阳离子交换树脂之间的作用包括离子作用和疏水作用 ,且二者之间存在协同作用 . 展开更多
关键词 氨基酸 阳离子交换树脂 疏水作用 色谱 聚苯乙烯 分离 性能 色谱柱 蛋白质水解液
下载PDF
酸性离子交换树脂催化酯化改质生物油的研究 被引量:20
19
作者 熊万明 傅尧 +1 位作者 来大明 郭庆祥 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2009年第9期1754-1758,共5页
以磺酸型离子交换树脂为催化剂,在模型反应的基础上,探讨了该催化剂在稻壳裂解油及其轻质馏分的催化酯化改质过程中的活性和效果,并通过气-质联用仪对酯化前后的生物油进行了成分分析.结果表明,酯化过程中采用的催化剂可以方便地分离和... 以磺酸型离子交换树脂为催化剂,在模型反应的基础上,探讨了该催化剂在稻壳裂解油及其轻质馏分的催化酯化改质过程中的活性和效果,并通过气-质联用仪对酯化前后的生物油进行了成分分析.结果表明,酯化过程中采用的催化剂可以方便地分离和循环使用;生物油中的有机酸顺利地转化为相应的酯类(主要为乙酸乙酯).通过催化酯化改质后,两种生物油的理化特性均得到了有效改善,热值分别由16.80和12.76MJ/kg提高到20.08和18.33MJ/kg,相应提高了19.5%和43.6%;黏度分别由11.83和1.42mm2/s,下降到3.77和1.12mm2/s;水分分别为23.7%和28.4%,流动性明显增强,理化特性得到了明显提高.为生物油的精制加工提供了一种有效方法. 展开更多
关键词 生物油 固体酸 离子交换树脂 酯化
下载PDF
离子交换纤维对阿魏酸的吸附和解吸研究 被引量:22
20
作者 李明愉 曾庆轩 +2 位作者 冯长根 李凯 孙伟娜 《中国药学杂志》 EI CAS CSCD 北大核心 2005年第1期40-43,共4页
目的 测定自制的强碱性离子交换纤维对阿魏酸的吸附和解吸的性能。方法 采用测定静态吸附速率曲线及测定30. 8K的吸附等温线的方法 ,并对不同入口浓度和不同流速下 ,阿魏酸在固定床吸附柱上的动态吸附过程进行了研究。结果 离子交换... 目的 测定自制的强碱性离子交换纤维对阿魏酸的吸附和解吸的性能。方法 采用测定静态吸附速率曲线及测定30. 8K的吸附等温线的方法 ,并对不同入口浓度和不同流速下 ,阿魏酸在固定床吸附柱上的动态吸附过程进行了研究。结果 离子交换纤维对阿魏酸的静态饱和吸附量为 180 . 4mg·g-1(干纤维 ) ,用少量甲醇和稀盐酸即可将吸附在纤维上的阿魏酸完全解吸。结论 离子交换纤维对阿魏酸的吸附速率远大于D2. 96离子交换树脂对阿魏酸的吸附速率 ,是提纯和分离阿魏酸的一种新型离子交换剂。 展开更多
关键词 离子交换纤维 阿魏酸 吸附 解吸
下载PDF
上一页 1 2 16 下一页 到第
使用帮助 返回顶部