Graphite-phase polymeric carbon nitride （CN） was reported to be a promising material in photoelectrochemical solar energy conversion. However, its high recombination rate of photogenerated carriers limits its potent...Graphite-phase polymeric carbon nitride （CN） was reported to be a promising material in photoelectrochemical solar energy conversion. However, its high recombination rate of photogenerated carriers limits its potential applications. In this article, a heterojunction of CN and sulfur-doped CN （CNS） was constructed through a solution-based processing way. Interestingly, it was observed that the photocatalytic hydrogen production of the as-prepared composite was 32.6 times higher than that of bulk carbon nitride and 2.3 times higher than that of the composites by conventional impregnating method. This study opens a new avenue to construct heterojunction of CN for large-scale industrial applications in environmental remediation.展开更多
基金financially supported in part by the National Natural Science Foundation of China(No. 21305065)Natural Science Foundation of Jiangsu Province(Nos. BK20160028, BK20170084)+1 种基金the Open Funds of the State Key Laboratory of Electroanalytical Chemistry (No. SKLEAC201703)the Fundamental Research Funds for the Central Universities
文摘Graphite-phase polymeric carbon nitride （CN） was reported to be a promising material in photoelectrochemical solar energy conversion. However, its high recombination rate of photogenerated carriers limits its potential applications. In this article, a heterojunction of CN and sulfur-doped CN （CNS） was constructed through a solution-based processing way. Interestingly, it was observed that the photocatalytic hydrogen production of the as-prepared composite was 32.6 times higher than that of bulk carbon nitride and 2.3 times higher than that of the composites by conventional impregnating method. This study opens a new avenue to construct heterojunction of CN for large-scale industrial applications in environmental remediation.
