The design and synthesis of photoactive macrocyclic molecules continue to attract attention because such species play important roles in supramolecular chemistry as well as photoelectronic applications.Donoracceptor(D...The design and synthesis of photoactive macrocyclic molecules continue to attract attention because such species play important roles in supramolecular chemistry as well as photoelectronic applications.Donoracceptor(D-A)conjugated macrocycles are an emerging class of photoactive molecules due to their D-A conjugated structural characteristics and tunable optical properties.In addition,the well-defined cavities in such D-A macrocycles endow them with versatile host-guest properties.In this review,we provide a comprehensive summary of D-A conjugated macrocycle chemistry,detailing recent progress in the area of synthetic methods,optical properties,host-guest chemistry and applications of the underlying chemistry to chemical sensors,bioimaging and photoelectronic devices.Our objective is to provide not only a review of the fundamental findings,but also to outline future research directions where D-A conjugated macrocycles and their constructs may have a role to play.展开更多
Van der Waals heterostructures,composed of individual two-dimensional material have been developing extremely fast.Synthesis of van der Waals heterostructures without the constraint of lattice matching and processing ...Van der Waals heterostructures,composed of individual two-dimensional material have been developing extremely fast.Synthesis of van der Waals heterostructures without the constraint of lattice matching and processing compatibility provides an ideal platform for fundamental research and new device exploitation.We review the approach of synthesis of van der Waals heterostructures,discuss the property of heterostructures and thoroughly illustrate the functional van der Waals heterostructures used in novel electronic and photoelectronic device.展开更多
基金supported by the National Natural Science Foundation of China(Nos.21971041 and 22001039)Natural Science Foundation of Fujian Province(No.2020J01447).
文摘The design and synthesis of photoactive macrocyclic molecules continue to attract attention because such species play important roles in supramolecular chemistry as well as photoelectronic applications.Donoracceptor(D-A)conjugated macrocycles are an emerging class of photoactive molecules due to their D-A conjugated structural characteristics and tunable optical properties.In addition,the well-defined cavities in such D-A macrocycles endow them with versatile host-guest properties.In this review,we provide a comprehensive summary of D-A conjugated macrocycle chemistry,detailing recent progress in the area of synthetic methods,optical properties,host-guest chemistry and applications of the underlying chemistry to chemical sensors,bioimaging and photoelectronic devices.Our objective is to provide not only a review of the fundamental findings,but also to outline future research directions where D-A conjugated macrocycles and their constructs may have a role to play.
基金Project supported by the National Key Research and Development Program(No.2016YFA0203900)the National Natural Science Foundation of China(Nos.61376093,61622401)
文摘Van der Waals heterostructures,composed of individual two-dimensional material have been developing extremely fast.Synthesis of van der Waals heterostructures without the constraint of lattice matching and processing compatibility provides an ideal platform for fundamental research and new device exploitation.We review the approach of synthesis of van der Waals heterostructures,discuss the property of heterostructures and thoroughly illustrate the functional van der Waals heterostructures used in novel electronic and photoelectronic device.
