Visible photoluminescence （PL） has been observed from rare earth （Tm, Sm and Dy）-doped AlN films grown by radio-frequency magnetron reactive sputtering. X-ray diffraction indicates that the films are c-axis-orient...Visible photoluminescence （PL） has been observed from rare earth （Tm, Sm and Dy）-doped AlN films grown by radio-frequency magnetron reactive sputtering. X-ray diffraction indicates that the films are c-axis-oriented hexagonal wurtzite type structure with an average crystal size of about 80-110 nm. Room-temperature PL spectra indicate that the blue emission is due to the transition of ^1D2 to ^3F4 and ^1G4 to ^3H6 intra 4f electron of Tm^3＋, the yellow emissions of AlN：Sm are due to ^4G5/2 to the ^6HJ （J=5/2, 7/2, 9/2, 11/2） and the reddish emissions of AlN：Dy correspond to the ^4F9/2 to ^6HJ （J=5/2, 13/2, 11/2 and 9/2） and ^6Fll/2 transitions.展开更多
基金Project supported by the National Natural Science Foundation of China （Grant No 50372082）.
文摘Visible photoluminescence （PL） has been observed from rare earth （Tm, Sm and Dy）-doped AlN films grown by radio-frequency magnetron reactive sputtering. X-ray diffraction indicates that the films are c-axis-oriented hexagonal wurtzite type structure with an average crystal size of about 80-110 nm. Room-temperature PL spectra indicate that the blue emission is due to the transition of ^1D2 to ^3F4 and ^1G4 to ^3H6 intra 4f electron of Tm^3＋, the yellow emissions of AlN：Sm are due to ^4G5/2 to the ^6HJ （J=5/2, 7/2, 9/2, 11/2） and the reddish emissions of AlN：Dy correspond to the ^4F9/2 to ^6HJ （J=5/2, 13/2, 11/2 and 9/2） and ^6Fll/2 transitions.
