Solvent Effects on Two-Photon Absorption of Alkyne and Alkene π-bridging Chromophores

The present work concerns the study of solvent effects on the geometrical structures, as well as one- and two-photon absorption （TPA） processes, for two series of alkyne and alkene π-bridging molecules, within the framework of the polarization continuum model. Particular emphasis was put on the characterization of solvent effects on the molecular geometrical structures and geometric distortion, which were measured by the bond-length-alternation parameter. The π centres in the compounds are seen to play a decisive role in increasing the TPA cross section and nonlinear optical properties. All studied molecules have relatively strong TPA characteristics, while the alkyne π-bridging ones yield larger TPA cross sections.

Perfect photon absorption based on the optical parametric process

The perfect photon absorption is studied in a cavity quantum electrodynamics(CQED) system, in which an optical parameter amplifier(OPA) is coupled to the cavity mode. This makes it possible to control the optical phase to realize the perfect photon absorption. It is found that in the presence of one and two injected fields, the perfect photon absorption is present in these two cases and can be controlled by adjusting the parametric phase. Moreover, different from the previous predictions of perfect photon absorption in atomic CQED systems, the perfect photon absorption can be changed significantly by the relative phase. Our work provides a new platform to use the parametric processes to make an available way to control the behaviors of photons and to take advantage of the optical phase to achieve the perfect photon absorption.

General formula for phonon-assisted n-photon absorption in solids

A general formula for phonon-assisted n-photon absorption in solids is obtained by （n ＋ 1）-th order perturbation technique. The complicated calculation process for transition element of n-photon absorption is simply demonstrated by a diagram approach that is proposed in this work. We find that the transition element for the n-photon absorption has a simple form, i.e., it is just the first term of the n-th order fist kind Bessel function.

Recent strategies to enhance the efficiency of hematite photoanodes in photoelectrochemical water splitting

Photoelectrochemical(PEC)water splitting is one of the most promising approaches toward achieving the conversion of solar energy to hydrogen.Hematite is a widely applied photoanode material in PEC water splitting because of its appropriate band structure,non-toxicity,high stability,and low cost.Nevertheless,its relatively low photochemical conversion efficiency limits its application,and enhancing its PEC water splitting efficiency remains a challenge.Consequently,increasing efforts have been rendered toward improving the performance of hematite photoanodes.The entire PEC water splitting efficiency typically includes three parts:the photon absorption efficiency,the separation efficiency of the semiconductor bulk,and the surface injection efficiency.This review briefly discusses the recent advances in studies on hematite photoanodes for water splitting,and through the enhancement of the three above-mentioned efficiencies,the corresponding strategies toward improving the PEC performance of hematite are comprehensively discussed and summarized.

The Study of Changes in the Element Compositions of Pd and Re Specimens Irradiated in Dense Gaseous Deuterium by y-Quanta with Boundary Energy up to 23 MeV

The element compositions of palladium and rhenium specimens irradiated in dense gaseous deuterium by y-quanta with the threshold energy 23 MeV were studies. Strong anomalies are found in the structure and element composition of the irradiated Pd and Re specimens.

Semi-integer harmonic generation from an argon atom by bichromatic counter-rotating circularly polarized laser field

We theoretically investigated the properties of the high-order harmonic generation from an argon atom by bichromatic counter-rotating circularly polarized(BCCP)laser field.The harmonic emission processes have been illustrated by numerically solving the two-dimensional time-dependent Schr¨odinger equation of an atom in intense laser fields.It is found that with the decrease of the right-circularly polarized laser wavelength,the harmonic spectra are gradually splitting and the harmonic orders move towards the higher frequency.Meanwhile,the integer and semi-integer harmonic emission will be generated when the frequency ratios of right-and left-circularly polarized lasers are semi-integer.The emission mechanism of the semi-integer-order harmonics has been investigated by using the rules of photon absorption and emission.

Collectively induced transparency and absorption in waveguide quantum electrodynamics with Bragg atom arrays

Collective quantum states, such as subradiant and superradiant states, are useful for controlling optical responses in many-body quantum systems. In this work, we study novel collective quantum phenomena in waveguide-coupled Bragg atom arrays with inhomogeneous frequencies.For atoms without free-space dissipation, collectively induced transparency is produced by destructive quantum interference between subradiant and superradiant states. In a large Bragg atom array, multi-frequency photon transparency can be obtained by considering atoms with different frequencies. Interestingly, we find collectively induced absorption(CIA) by studying the influence of free-space dissipation on photon transport. Tunable atomic frequencies nontrivially modify decay rates of subradiant states. When the decay rate of a subradiant state equals to the free-space dissipation, photon absorption can reach a limit at a certain frequency. In other words, photon absorption is enhanced with low free-space dissipation, distinct from previous photon detection schemes. We also show multi-frequency CIA by properly adjusting atomic frequencies. Our work presents a way to manipulate collective quantum states and exotic optical properties in waveguide quantum electrodynamics(QED) systems.

Study of Differential Cross-Section and S-Matrix Using Volkov Function and Taylor Series Expansion for Elastic Scattering

This paper deals with S-matrix, born first approximation, amplitude, and differential cross-section (DCS), using Volkov function and Taylor series expansion in laser field, scattering. Equation (30) copes-with DCS and Equation (36) deals with S-matrix, with different parameters, moreover, both equations contain real and imaginary parts. The DCS increases with increasing angle and polarizabilities, constant with dipole distance for both emission and absorption of single-photon. The DCS for both emission and absorption is responded to low incidence energy (30 eV - 60 eV) and photon energy (15 eV) while at high energy only emission and absorption are responded for DCS. The DCS between absorption and emission of a photon with angle variation, dipole distance, and atomic polarizabilities was found 1.098 a.u.2 and at high incidence, energies were found 0.1 a.u.2.