Polymer Fiber Rigid Network with High Glass Transition Temperature Reinforces Stability of Organic Photovoltaics

Organic photovoltaics(OPVs)need to overcome limitations such as insufficient thermal stability to be commercialized.The reported approaches to improve stability either rely on the development of new materials or on tailoring the donor/acceptor morphology,however,exhibiting limited applicability.Therefore,it is timely to develop an easy method to enhance thermal stability without having to develop new donor/acceptor materials or donor–acceptor compatibilizers,or by introducing another third component.Herein,a unique approach is presented,based on constructing a polymer fiber rigid network with a high glass transition temperature(T_(g))to impede the movement of acceptor and donor molecules,to immobilize the active layer morphology,and thereby to improve thermal stability.A high-T_(g) one-dimensional aramid nanofiber(ANF)is utilized for network construction.Inverted OPVs with ANF network yield superior thermal stability compared to the ANF-free counterpart.The ANF network-incorporated active layer demonstrates significantly more stable morphology than the ANF-free counterpart,thereby leaving fundamental processes such as charge separation,transport,and collection,determining the device efficiency,largely unaltered.This strategy is also successfully applied to other photovoltaic systems.The strategy of incorporating a polymer fiber rigid network with high T_(g) offers a distinct perspective addressing the challenge of thermal instability with simplicity and universality.

Improving Heat Transfer in Parabolic Trough Solar Collectors by Magnetic Nanofluids

A parabolic trough solar collector(PTSC)converts solar radiation into thermal energy.However,low thermal efficiency of PTSC poses a hindrance to the deployment of solar thermal power plants.Thermal performance of PTSC is enhanced in this study by incorporating magnetic nanoparticles into the working fluid.The circular receiver pipe,with dimensions of 66 mm diameter,2 mm thickness,and 24 m length,is exposed to uniform temperature and velocity conditions.The working fluid,Therminol-66,is supplemented with Fe3O4 magnetic nanoparticles at concentrations ranging from 1%to 4%.The findings demonstrate that the inclusion of nanoparticles increases the convective heat transfer coefficient(HTC)of the PTSC,with higher nanoparticle volume fractions leading to greater heat transfer but increased pressure drop.The thermal enhancement factor(TEF)of the PTSC is positively affected by the volume fraction of nanoparticles,both with and without a magnetic field.Notably,the scenario with a 4%nanoparticle volume fraction and a magnetic field strength of 250 G exhibits the highest TEF,indicating superior thermal performance.These findings offer potential avenues for improving the efficiency of PTSCs in solar thermal plants by introducing magnetic nanoparticles into the working fluid.

Assessment of High Concentrated Photovoltaic/Thermal Collector in Hot Climate

This work investigates the performance of combined hybrid high concentrated photovoltaic/thermal collector (HCPV/T) in Kuwait harsh climate. The proposed system consists of triple junction solar cells (InGaP/InGaAs/Ge) attached to heat source to discharge thermal energy to cooling media. Published HCPV/T models do not consider the effect of shunt resistance which greatly affects the system performance. So, a single diode model employing five parameters including the effect of shunt resistance is adapted to analyze the proposed system. To analyze the thermal performance of the proposed system, a two-dimensional thermal model based on the technique of finite difference is introduced to determine the efficiency of the hybrid HCPV/T system. The present developed subroutines are integrated with other involved codes in TRNSYS software to calculate HCPV/T system efficiency. Electrical and thermal as well as the whole system efficiency at different weather circumstances are evaluated and assessed. The effect of different weather conditions, cell temperature, concentration ratio and the temperatures of the coolant fluid on system performance are studied. Current results indicate that the model of single diode is a reliable one rather than using the two-diode complex model. Compared to measurements provided by high concentrated PV manufacturer, the current results revealed a total root mean square error of approximately 1.94%. Present predictions show that PV cell temperature has logarithmic increase with the rise in concentration ratio but with low values till concentration ratio of 400 suns after that the rise is faster at higher concentration values up to 1500 suns. Results also revealed that hybrid HCPV/T system works effectively specially in severe hot climate where thermal efficiency increases with high surrounding temperature for higher values of concentration ratio. In addition, an increase of approximately 15% in thermal efficiency and 10% in total efficiency can be achieved by utilizing active cooling device in HCPV/T system.

Flow Characteristics Diagnosis and Optimization for Dust Collectors Inflow Duct in Thermal Power Plants

火电厂烟风道用于输送烟气、冷风等介质，其设计优化水平不但影响火电厂烟风系统阻力的大小，而且影响与烟风道直接相连的各个设备的运行状态。某600MW机组除尘器前烟道设计不合理，存在磨损严重、进入除尘器烟气分配不均等问题，文中采用标准缸￡模型，利用Fluent求解器对该部分烟道的流场进行数值计算，诊断分析其存在的主要问题，提出的3个改造方案均可使烟道阻力大幅度下降、烟道磨损减轻、进入除尘器烟气分配均匀。同时，研究了缓转半径及烟气流速对该段烟道阻力和烟气分配的影响情况，计算结果表明该段烟道缓转半径宜选在0．875以上，烟气流速对该段烟道的性能基本没有影响。

Heat Transfer Enhancement of the Absorber Tube in a Parabolic Trough Solar Collector through the Insertion of Novel Cylindrical Turbulators

This study includes an experimental and numerical analysis of the performances of a parabolic trough collector(PTC)with and without cylindrical turbulators.The PTC is designed with dimensions of 2.00 m in length and 1.00 m in width.The related reflector is made of lined sheets of aluminum,and the tubes are made of stainless steel used for the absorption of heat.They have an outer diameter of 0.051 m and a wall thickness of 0.002 m.Water,used as a heat transfer fluid(HTF),flows through the absorber tube at a mass flow rate of 0.7 kg/s.The dimensions of cylindrical turbulators are 0.04 m in length and 0.047 m in diameter.Simulations are performed using the ANSYS Fluent 2020 R2 software.The PTC performance is evaluated by comparing the experimental and numerical outcomes,namely,the outlet temperature,useful heat,and thermal efficiency for a modified tube(MT)(tube with novel cylindrical turbulators)and a plain tube(PT)(tube without novel cylindrical turbulators).According to the results,the experimental outlet temperatures recorded 63.2°C and 50.5°C for the MT and PT,respectively.The heat gain reaches 1137.5 Win the MT and 685.8 Win the PT.Compared to the PT collector,the PTC exhibited a(1.64 times)higher efficiency.

Proposal of a Solar Thermal Power Plant at Low Temperature Using Solar Thermal Collectors

To this day, only two types of solar power plants have been proposed and built: high temperature thermal solar one and photovoltaic one. It is here proposed a new type of solar thermal plant using glass-top flat surface solar collectors, so working at low temperature (i.e., below 100°C). This power plant is aimed at warm countries, i.e., the ones mainly located between -40° and 40° latitude, having available space along their coast. This land based plant, to install on the seashore, is technologically similar to the one used for OTEC (Ocean Thermal Energy Conversion). This plant, apart from supplying electricity with a much better thermodynamic efficiency than OTEC plants, has the main advantage of providing desalinated water for drinking and irrigation. This plant is designed to generate electricity (and desalinated water) night and day and all year round, by means of hot water storage, with just a variation of the power delivered depending on the season.

Energy and Life Cycle Assessment of Zinc/Water Nanofluid Based Photovoltaic Thermal System

Cooling the PV surface in a Photovoltaic Thermal system is a pivotal operational aspect to be taken into account to achieve optimized values of performance parameters in a Photovoltaic Thermal System.The experimental design used in this study facilitates the flow of varying concentrations of Zn-water nanofluid in serpentine copper tubing installed at the rear of the PV panel thereby preventing the PV surface temperature from increasing beyond the threshold value at which a decrease in electrical efficiency starts to occur.This fusion of solar thermal with PV devices leads to better electrical and thermal efficiency values resulting in decreased cell degradation over time and maximization of the lifespan of the PV module and the energy output from the PV system.Due to the superior thermal heat properties of nanofluids,their usage in such systems has become increasingly widespread.Life cycle metrics which include Energy Payback period,Energy Production Factor and life cycle conversion efficiency were evaluated for the PVT system by exhaustively chalking fundamental parameters such as embodied energy of the PVT setup and the total energy output from the PVT system.This research aims to be a major milestone in the evolutionary journey of Photovoltaic Thermal modules by guiding the engineers working on the theory,design and implementation of PVT systems towards its economic feasibility,environmental impact and energy sustainability.

Solar Thermal Systems Performances versus Flat Plate Solar Collectors Connected in Series

This paper shows the modeling of a solar collective heating system in order to predict the system performances. Two systems are proposed: 1) the first, Solar Direct Hot Water, which is composed of flat plate collectors and thermal storage tank, 2) the second, a Solar Indirect Hot Water in which we added an external heat exchanger of constant effectiveness to the first system. The mass flow rate by a collector is fixed to 0.04 Kg·s–1 and the total number of collectors is adjusted to 60. For the first system, the maximum average water temperature within the tank in a typical day in summer and annual performances are calculated by varying the number of collectors connected in series. For the second, this paper shows the detailed analysis of water temperature within the storage and annual performances by varying the mass flow rate on the cold side of the heat exchanger and the number of collectors in series on the hot side. It is shown that the stratification within the storage is strongly influenced by mass flow rate and the connections between collectors. It is also demonstrated that the number of collectors that can be connected in series is limited. The optimization of the mass flow rate on cold side of the heat exchanger is seen to be an important factor for the energy saving.

Performance on Power,Hot and Cold Water Generation of a Hybrid Photovoltaic Thermal Module

This paper proposed a new function of photovoltaic thermal(PVT)module to produce nocturnal cool water not just only generating electrical power and hot water during daytime.Experimental tests were carried out under Chiang Mai tropical climate with a 200 Wp monocrystalline PVT module having dimensions of 1.601 m×0.828 m connected with two water tanks each of 60 L taken for hot and cool water storages.The module was facing south with 18o inclination.The electrical load was a 200 W halogen lamp.From experiments,by taking the module as a nocturnal radiative cooling surface,the cool water temperature in the cool storage tank could be reduced 2℃–3℃each night and the temperature could be reduced from 31.5℃to 22.1℃within 4 consecutive days.The cool water at approximately 23℃was also used to cool down the PVT module from noon when the PVT module temperature was rather high,and then the module temperature immediately dropped around 5℃and approximately 10%increase of electrical power could be achieved.A set of mathematical models was also developed to predict the PVT module temperature and the hot water temperature including the cool water temperature in the storage tanks during daytime and nighttime.The simulated results agreed well with the experimental data.

Comprehensive Examination of Solar Panel Design: A Focus on Thermal Dynamics

In the 21st century, the deployment of ground-based Solar Photovoltaic (PV) Modules has seen exponential growth, driven by increasing demands for green, clean, and renewable energy sources. However, their usage is constrained by certain limitations. Notably, the efficiency of solar PV modules on the ground peaks at a maximum of 25%, and there are concerns regarding their long-term reliability, with an expected lifespan of approximately 25 years without failures. This study focuses on analyzing the thermal efficiency of PV Modules. We have investigated the temperature profile of PV Modules under varying environmental conditions, such as air velocity and ambient temperature, utilizing Computational Fluid Dynamics (CFD). This analysis is crucial as the efficiency of PV Modules is significantly impacted by changes in the temperature differential relative to the environment. Furthermore, the study highlights the effect of airflow over solar panels on their temperature. It is found that a decrease in the temperature of the PV Module increases Open Circuit Voltage, underlining the importance of thermal management in optimizing solar panel performance.

Thin Film Photovoltaic/Thermal Solar Panels

A solar panel is described,in which thin films of semiconductor are deposited onto a metal substrate.The semiconductor-metal combination forms a thin film photovoltaic cell,and also acts as a reflector-absorber tandem,which acts as a solar selective surface,thus enhancing the solar thermal performance of the collector plate.The use of thin films reduces the distance heat is required to flow from the absorbing surface to the metal plate and heat exchange conduits.Computer modelling demonstrated that,by suitable choice of materials,photovoltaic efficiency can be maintained,with thermal performance slightly reduced,compared to that for thermal-only panels.By grading the absorber layer-to reduce the band gap in the lower region-the thermal performance can be improved,approaching that for a thermal-only solar panel.

Contrastive Observation of Solar Thermal and Photovoltaic Resource

Solar thermal and photovoltaic applications are the most w idely used and the most successful w ay of commercial development in solar energy applications. Observation and assessment of solar thermal and photovoltaic resources are the basis and key of their large-scale development and utilization. Using the observational data carried out from Beijing southern suburbs observation station of China M eteorological Administration in summer of 2009,preliminary solar thermal and photovoltaic resources characteristics for different w eather conditions,different angle and different directions are analyzed. The results show that:(1) In sunny,cloudy or rainy w eather conditions,both of solar thermal and photovoltaic sensors daily irradiance have consistent change in trend. Solar thermal irradiance is larger than photovoltaic. Under sunny conditions,solar thermal global radiation has about 2.7%higher than the photovoltaic global radiation. Under cloudy w eather conditions,solar thermal global radiation has about 3. 9%higher than the photovoltaic. Under rainy w eather conditions,solar thermal global radiation has about 20% higher than the photovoltaic.(2) For different inclined plane daily global radiation,southern latitude-15 °incline is the maximum and southern vertical surface is the minimum. The order from large to small is southern latitude-15 ° incline,southern latitude incline,southern latitude+15 °incline,horizontal surface and southern vertical surface. Southern latitude-15 °incline global radiation has about 41% higher than the southern vertical surface.(3) For different orientation vertical surface daily global radiation,southern vertical surface is the maximum and w estern vertical surface is the minimum,w hich eastern vertical surface is in the middle. Southern vertical surface global radiation has about 20% higher than the w estern vertical surface.

Spectral Selectivity of CdTe Cells with Substrate Configuration for Photovoltaic/Thermal Applications

Existing photovoltaic cells with high infrared emissivity generate huge radiative heat loss in photovoltaic/thermal applications and degrade the photothermal performance.The purpose of this work is to evaluate the full spectral absorptivity of CdTe cells to find a spectrally selective photovoltaic cell for photovoltaic/thermal applications.To this end,the solar absorptivity and mid-infrared thermal emissivity of CdTe cells were tested by ellipsometry,UV-Vis-NIR spectrophotometer,and Fourier transform infrared spectrometer.The experimental results show that the AM 1.5 solar spectrum weighted absorptivity of the substrate configuration CdTe cell reaches 0.91,and the mid-infrared emissivity is only 0.29,while the superstrate configuration cell emissivity is as high as 0.9.Further research shows that substrate configuration with a transparent conductive layer on top can be flexibly grown on metal foils and has spectral selectivity with high solar absorptivity and low mid-infrared emissivity should be considered in the future for photovoltaic/thermal applications.

Performance analysis of a photovoltaic/thermal system with lunar regolith-based thermal storage for the lunar base

Powering a moon base,especially keeping it warm during the long lunar night,is a big challenge.This paper introduces a photovoltaic/thermal(PV/T)system incorporating regolith thermal storage to solve the challenge of power and heat provision for the lunar base simultaneously.The vacuum of space around the moon helps this system by reducing heat loss.During the moon's daytime,the system not only generates electricity but also captures heat.This stored heat in the regolith is then used at night,reducing the amount of equipment we need to send from Earth.The spectrally selective PV/T panels are designed to absorb a wide range of sunlight(0.3–2.5μm)while minimizing heat loss in the infrared range(3–30μm).Simulation results of the hybrid solar energy system indicate the average value of the overall efficiency is 45.9%,which relatively elevates 56.1%compared to the PV system.The launch mass of the proposed PV/T system is only 8.4%of a traditional photovoltaic-lithium battery system with the same amount of energy storage.And the total specific energy of the proposed system is 7.3 kWh kg^(-1),while that of the photovoltaic-lithium battery system is about 0.3 kWh kg^(-1).In summary,this study proposes an alternative combined heat and electricity supply system for the lunar base,which can greatly reduce the launch mass and free up load for other scientific research equipment.

Experimental evaluation of factors affecting performance of concentrating photovoltaic/thermal system integrated with phase‐change materials(PV/T‐CPCM)

The photovoltaic/thermal(PV/T)system is a promising option for countering energy shortages.To improve the performance of PV/T systems,compound parabolic concentrators(CPCs)and phase-change materials(PCMs)were jointly applied to construct a concentrating photovoltaic/thermal system integrated with phase-change materials(PV/T-CPCM).An open-air environment is used to analyze the effects of different parameters and the intermittent operation strategy on the system performance.The results indicate that the short-circuit current and open-circuit voltage are positively correlated with the solar irradiance,but the open-circuit voltage is negatively correlated with the temperature of the PV modules.When the solar irradiance is 500 W⋅m^(−2) and the temperature of the PV modules is 27.5℃,the short-circuit current and open-circuit voltage are 1.0 A and 44.5 V,respectively.Higher solar irradiance results in higher thermal power,whereas the thermal efficiency is under lower solar irradiance(136.2-167.1 W⋅m^(−2) is twice under higher solar irradiance(272.3-455.7 W⋅m^(−2))).In addition,a higher mass flow rate corresponds to a better cooling effect and greater pump energy consumption.When the mass flow rate increases from 0.01 to 0.02 kg⋅s^(-1),the temperature difference between the inlet and outlet decreases by 1.8℃,and the primary energy-saving efficiency decreases by 0.53%.The intermittent operation of a water pump can reduce the energy consumption of the system,and the combination of liquid cooling with PCMs provides better thermal regulation and energy-saving effects under various conditions.

Recent Advances to Understand Morphology Stability of Organic Photovoltaics

Organic photovoltaic devices are on the verge of commercialization with power conversion efficiencies exceeding 10 % in laboratory cells and above 8.5 % in modules. However, one of the main limitations hindering their mass scale production is the debatable inferior stability of organic photovoltaic devices in comparison to other technologies.Adequate donor/acceptor morphology of the active layer is required to provide carrier separation and transport to the electrodes. Unfortunately, the beneficial morphology for device performance is usually a kinetically frozen state which has not reached thermodynamic equilibrium. During the last 5 years, special efforts have been dedicated to isolate the effects related to morphology changes taking place within the active layer and compare to those affecting the interfaces with the external electrodes. The current review discusses some of the factors affecting the donor/acceptor morphology evolution as one of the major intrinsic degradation pathways. Special attention is paid to factors in the nano- and microscale domain.For example, phase segregation of the polymer and fullerene domains due to Ostwald ripening is a major factor in the microscale domain and is affected by the presence of additives, glass transition temperature of the polymers or use of crosslinkers in the active layer. Alternatively, the role of vertical segregation profile toward the external electrodes is key for device operation, being a clear case of nanoscale morphology evolution. For example, donor and acceptor molecules actually present at the external interfaces will determine the leakage current of the device, energy-level alignment, and interfacial recombination processes. Different techniques have been developed over the last few years to understand its relationship with the device efficiency. Of special interest are those techniques which enable in situ analysis being nondestructive as they can be used to study accelerated degradation experiments and some will be discussed here.

Correlation between the Low-Temperature Photoluminescence Spectra and Photovoltaic Properties of Thin Polycrystalline CdTe Films

A dominant intrinsic luminescence band, which is due to the surface potential barriers of crystalline grains, and an edge doublet, which arises as an LO-phonon repetition of the e-h band, has been revealed in the low-temperature photoluminescence spectra of fine-grained obliquely deposited films. Doping film with In impurity leads to quenching of the doublet band, while further thermal treatment causes activation of the intrinsic band, the half-width and the blue shift of the red edge of which correlates with the maximum value of anomalously high photovoltage generated by the film.

Improving the Performance of Photovoltaic Power Plants with Determinative Module for the Cooling System

The objective of this work is to analyze and evaluate the impact of cooling systems on photovoltaic modules (for electricity generation), applied at a pilot Testing Facility. The results obtained during this step are used as input in order to determine the best model to be applied at a real-scale Photovoltaic Power Plant (PVPP). This methodology is based on the monitoring and supervision of the operating temperature of commercial photovoltaic modules (PV), both with and without cooling systems, as well as on the study of the water supply design of the cooling system applied on a micro photovoltaic power plant which is connected to the commercial network. Through the analysis of the data, we observed that photovoltaic modules with cooling systems always operate at lower temperatures than the ones without cooling systems. During the testing period, the operating temperatures of the photovoltaic modules without cooling systems were above 60oC (with a maximum temperature equaling 68.06oC), whereas the maximum temperatures registered on the sensors of the model “A” were 43.55oC and 44.75oC, and the ones registered on the sensors of the model “B” were 46.76 and 48.33oC. Therefore, we conclude that the photovoltaic module with the cooling system model “A” is the most suitable for large-scale application, since it was the only model to present temperatures lower than the nominal operating condition temperature (NOCT) of the cell (47oC ± 2oC).

Adapting Integrated High Concentrated PV Modules and Evacuated Tube Collectors to Minimize Building Energy Consumption in Hot Climate

Energy consumption in buildings is considered a significant portion of gross power dissipation, so a great effort is required to design efficient construction. In severe hot weather conditions as Kuwait, energy required for building cooling and heating results in a huge energy loads and consumption and accordingly high emission rates of carbon dioxide. So, the main purpose of the current work is to convert the existing institutional building to near net-zero energy building (nNZEB) or into a net-zero energy building (NZEB). A combination of integrated high concentrated photovoltaic (HCPV) solar modules and evacuated tube collectors (ETC) are proposed to provide domestic water heating, electricity load as well as cooling consumption of an institutional facility. An equivalent circuit model for single diode is implemented to evaluate triple junction HCPV modules efficiency considering concentration level and temperature effects. A code compatible with TRNSYS subroutines is introduced to optimize evacuated tube collector efficiency. The developed models are validated through comparison with experimental data available from literature. The efficiency of integrated HCPV-ETC unit is optimized by varying the different system parameters. Transient simulation program (TRNSYS) is adapted to determine the performance of various parts of HCPV-ETC system. Furthermore, a theoretical code is introduced to evaluate the environmental effects of the proposed building when integrated with renewable energy systems. The integrated HCPV-ETC fully satisfies the energy required for building lighting and equipment. Utilizing HCPV modules of orientation 25? accomplishes a minimum energy payback time of about 8 years. Integrated solar absorption chiller provides about 64% of the annual air conditioning consumption needed for the studied building. The energy payback period (EPT) or solar cooling system is about 18 years which is significantly larger than that corresponding to HCPV due to the extra expenses of solar absorption system. The life cycle savings (LCS) of solar cooling absorption system is approximately $2400/year. Furthermore, levelized cost of energy of solar absorption cooling is $0.21/kWh. Hence, the net cost of the solar system after subtracting the CO2 emission cost will be close to the present price of conventional generation in Kuwait (about $0.17/kWh). Finally, the yearly CO2 emission avoided is approximately 543 ton verifying the environmental benefits of integrated HCPV-ETC arrangements in Kuwait.

Performance and Optimization of a Small Hybrid Solar-Thermal Collector

A hybrid solar collector was designed to investigate the effects of combining two different solar collector techniques on the overall collector’s effectiveness. While most solar collectors focus only on one solar collection method, the small hybrid system uses a flat plate collector in conjunction with five evacuated tubes to absorb the most energy possible from both direct and diffuse solar radiation. Data was collected over four months while the system operated at different flow rates and with various levels of available insolation from the sun to evaluate the performance of the solar collector. To understand the relative contribution of the flat plate collector and the evacuated tubes, temperature differences across each part of the system were measured. The results indicate the average first law efficiency of the hybrid system is 43.3%, significantly higher than the performance of the flat plate alone. An exergy analysis was performed for this system to assess the performance of the flat plate system by itself. Results of the second law analysis were comparable to the exergetic efficiencies of other experimental collectors, around 4%. Though the efficiencies were in the expected range, they reveal that further improvements to the system are possible.