Fe (III) 2,9,16,23 tertracarboxy phthalocyanine (Fe (III) taPc) was synthesized, and bonded to polystyrene (PS) with covalence by Friedel Crafts reaction to form a new polymer (Fe (III) taPc PS) (polymer (II))....Fe (III) 2,9,16,23 tertracarboxy phthalocyanine (Fe (III) taPc) was synthesized, and bonded to polystyrene (PS) with covalence by Friedel Crafts reaction to form a new polymer (Fe (III) taPc PS) (polymer (II)). UV VIS and Infrared spectra indicated that Fe (III) taPc was successfully bonded to PS. A photoreceptor device of sandwich structure consisting of alternate layers of polymer (II) and fullerene (C 60 ) was prepared. The experiment results show that the photoconductivity of the photoreceptor is higher than that of the single layer film of polymer (II) or C 60 , because of the charge transfer effect between the layers.展开更多
文摘Fe (III) 2,9,16,23 tertracarboxy phthalocyanine (Fe (III) taPc) was synthesized, and bonded to polystyrene (PS) with covalence by Friedel Crafts reaction to form a new polymer (Fe (III) taPc PS) (polymer (II)). UV VIS and Infrared spectra indicated that Fe (III) taPc was successfully bonded to PS. A photoreceptor device of sandwich structure consisting of alternate layers of polymer (II) and fullerene (C 60 ) was prepared. The experiment results show that the photoconductivity of the photoreceptor is higher than that of the single layer film of polymer (II) or C 60 , because of the charge transfer effect between the layers.