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Meter-Scale Thin-Walled Structure with Lattice Infill for Fuel Tank Supporting Component of Satellite:Multiscale Design and Experimental Verification
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作者 Xiaoyu Zhang Huizhong Zeng +6 位作者 Shaohui Zhang Yan Zhang Mi Xiao Liping Liu Hao Zhou Hongyou Chai Liang Gao 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第1期201-220,共20页
Lightweight thin-walled structures with lattice infill are widely desired in satellite for their high stiffness-to-weight ratio and superior buckling strength resulting fromthe sandwich effect.Such structures can be f... Lightweight thin-walled structures with lattice infill are widely desired in satellite for their high stiffness-to-weight ratio and superior buckling strength resulting fromthe sandwich effect.Such structures can be fabricated bymetallic additive manufacturing technique,such as selective laser melting(SLM).However,the maximum dimensions of actual structures are usually in a sub-meter scale,which results in restrictions on their appliance in aerospace and other fields.In this work,a meter-scale thin-walled structure with lattice infill is designed for the fuel tank supporting component of the satellite by integrating a self-supporting lattice into the thickness optimization of the thin-wall.The designed structure is fabricated by SLM of AlSi10Mg and cold metal transfer welding technique.Quasi-static mechanical tests and vibration tests are both conducted to verify the mechanical strength of the designed large-scale lattice thin-walled structure.The experimental results indicate that themeter-scale thin-walled structure with lattice infill could meet the dimension and lightweight requirements of most spacecrafts. 展开更多
关键词 Thin-walled structure lattice infill supporting component selective laser melting SATELLITE
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Numerical Simulation of Super-Resolution Structured Illumination Microscopy (SIM) Using Heintzmann-Cremer Algorithm with Non-Continuous Spatial Frequency Support
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作者 Mesfin Woldeyohannes William McCray Weiguo Yang 《Optics and Photonics Journal》 2024年第5期75-90,共16页
We report a comprehensive numerical study of super resolution (SR) structured illumination microscopy (SIM) utilizing the classic Heintzmann-Cremer SIM process and algorithm. In particular, we investigated the impact ... We report a comprehensive numerical study of super resolution (SR) structured illumination microscopy (SIM) utilizing the classic Heintzmann-Cremer SIM process and algorithm. In particular, we investigated the impact of the diffraction limit of the underlying imaging system on the optimal SIM grating frequency that can be used to obtain the highest SR enhancement with non-continuous spatial frequency support. Besides confirming the previous theoretical and experimental work that SR-SIM can achieve an enhancement close to 3 times the diffraction limit with grating pattern illuminations, we also observe and report a series of more subtle effects of SR-SIM with non-continuous spatial frequency support. Our simulations show that when the SIM grating frequency exceeds twice that of the diffraction limit, the higher SIM grating frequency can help achieve a higher SR enhancement for the underlying imaging systems whose diffraction limit is low, though this enhancement is obtained at the cost of losing resolution at some lower resolution targets. Our simulations also show that, for underlying imaging systems with high diffraction limits, however, SR-SIM grating frequencies above twice the diffraction limits tend to bring no significant extra enhancement. Furthermore, we observed that there exists a limit grating frequency above which the SR enhancement effect is lost, and the reconstructed images essentially have the same resolution as the one obtained directly from the underlying imaging system without using the SIM process. 展开更多
关键词 structured Illumination Microscopy Super Resolution Imaging Spatial Frequency support Diffraction Limit
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A multi-purpose prototype test system for mechanical behavior of tunnel supporting structure: Development and application 被引量:1
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作者 Hongbin Chen Xinhua You +1 位作者 Dajun Yuan Yang Ping 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第2期467-476,共10页
A multi-purpose prototype test system is developed to study the mechanical behavior of tunnel sup-porting structure,including a modular counterforce device,a powerful loading equipment,an advanced intelligent manageme... A multi-purpose prototype test system is developed to study the mechanical behavior of tunnel sup-porting structure,including a modular counterforce device,a powerful loading equipment,an advanced intelligent management system and an efficient noncontact deformation measurement system.The functions of the prototype test system are adjustable size and shape of the modular counterforce structure,sufficient load reserve and accurate loading,multi-connection linkage intelligent management,and high-precision and continuously positioned noncontact deformation measurement.The modular counterforce structure is currently the largest in the world,with an outer diameter of 20.5 m,an inner diameter of 16.5 m and a height of 6 m.The case application proves that the prototype test system can reproduce the mechanical behavior of the tunnel lining during load-bearing,deformation and failure processes in detail. 展开更多
关键词 Prototype test system Tunnel supporting structure Tunnel fire LINING Mechanical behavior
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Tunnel Support Structure System and Its Synergy
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作者 Xingxing Wang Wenke Zhao Senyang Wu 《Journal of World Architecture》 2023年第4期11-16,共6页
The tunnel support system is composed of lining,bolt,and steel frame.It is of great significance to effectively control the deformation of the surrounding rock of the tunnel,make full use of the characteristics of dif... The tunnel support system is composed of lining,bolt,and steel frame.It is of great significance to effectively control the deformation of the surrounding rock of the tunnel,make full use of the characteristics of different support methods,and formulate an economical and effective support plan to ensure the safe operation of the tunnel structure.This paper clarifies the synergistic relationship between the support structure and the surrounding rock based on their fundamental characteristics and functions.Various support structures and components are also discussed in this paper.Additionally,the paper presents an optimized design of the tunnel support structure system. 展开更多
关键词 Tunnel engineering support structure system SYNERGY support structure design
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Method of Establishing Object-Oriented System Structure for Decision Support System 被引量:2
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作者 曹元大 胡军 管春 《Journal of Beijing Institute of Technology》 EI CAS 2002年第3期311-315,共5页
In order to solve existing problems about the method of establishing traditional system structure of decision support system(DSS), O S chart is applied to describe object oriented system structure of general DSS, an... In order to solve existing problems about the method of establishing traditional system structure of decision support system(DSS), O S chart is applied to describe object oriented system structure of general DSS, and a new method of eight specific steps is proposed to establish object oriented system structure of DSS by using the method of O S chart, which is applied successfully to the development of the DSS for the energy system ecology engineering research of the Wangheqiu country. Supplying many scientific effective computing models, decision support ways and a lot of accurate reliable decision data, the DSS plays a critical part in helping engineering researchers to make correct decisions. Because the period for developing the DSS is relatively shorter, the new way improves the efficiency of establishing DSS greatly. It also makes the DSS of system structure more flexible and easy to expand. 展开更多
关键词 decision support system object oriented technology system structure
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Structure optimal design research on backfill hydraulic support 被引量:8
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作者 ZHANG Qiang ZHANG Ji-xiong +2 位作者 QI Wen-yue ZHOU Nan TAI Yang 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第7期1637-1646,共10页
Backfill hydraulic support is the key equipment in achieving coal mining and solid backfilling simultaneously in solid backfill mining technology.Based on the summary and analysis of main types,basic structural proper... Backfill hydraulic support is the key equipment in achieving coal mining and solid backfilling simultaneously in solid backfill mining technology.Based on the summary and analysis of main types,basic structural properties and filed application of backfill hydraulic support,this work has firstly proposed the basic principle of backfill hydraulic support optimization design and provided the method of optimal design of key structural components,like four-bar linkage,rear canopy and tamping structure;the method is further elaborated as changing hinging position of upper bar to optimize four-bar linkage,by lengthening or shortening the rear canopy to optimize length ratio of canopy;and by changing length and hinging position of tamping structure as well as suspension height of backfill scrape conveyor to realize optimization of tamping structure.On this basis,the process of optimal design of backfill hydraulic support is built.The optimal design case of ZC5200/14.5/30 six columns-four bar linkage used in 7203 W workface of Zhaizhen Coal Mine shows that the backfill properties like horizontal roof gap,vertical horizontal gap,tamping angle and tamping head gap are improved obviously through optimizing four-bar linkage,canopy length and tamping structure according to the optimal design method proposed in this work. 展开更多
关键词 BACKFILL hydraulic support structure optimal design four-bar LINKAGE REAR CANOPY TAMPING structure
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Strength failure of spatial reticulated structures under multi-support excitation 被引量:5
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作者 Ye Jihong Zhang Zhiqiang Chu Ye 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2011年第1期21-36,共16页
Under strong earthquakes, long-span spatial latticed structures may collapse due to dynamic instability or strength failure. The elasto-plastic dynamic behaviors of three spatial latticed structures, including two dou... Under strong earthquakes, long-span spatial latticed structures may collapse due to dynamic instability or strength failure. The elasto-plastic dynamic behaviors of three spatial latticed structures, including two double-layer cylindrical shells and one spherical shell constructed for the 2008 Olympic Games in Beijing, were quantitatively examined under multi-support excitation (MSE) and uniform support excitation (USE). In the numerical analyses, several important parameters were investigated such as the peak acceleration and displacement responses at key joints, the number and distribution of plastic members, and the deformation of the shell at the moment of collapse. Analysis results reveal the features and the failure mechanism of the spatial latticed structures under MSE and USE. In both scenarios, the double-layer reticulated shell collapses in the "overflow" mode, and the collapse is governed by the number of invalid plastic members rather than the total number of plastic members, beginning with damage to some of the local regions near the supports. By comparing the numbers and distributions of the plastic members under MSE to those under USE, it was observed that the plastic members spread more sufficiently and the internal forces are more uniform under MSE, especially in cases of lower apparent velocities in soils. Due to the effects of pseudo-static displacement, the stresses in the members near the supports under MSE are higher than those under USE. 展开更多
关键词 multiple support excitation (MSE) uniform support excitation (USE) ELASTOPLASTIC spatial latticed structure strength failure
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Sensor monitoring of a newly designed foundation pit supporting structure 被引量:3
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作者 杨宇友 吕建国 +1 位作者 黄学刚 涂晓明 《Journal of Central South University》 SCIE EI CAS 2013年第4期1064-1070,共7页
A new type of pit supporting structure, which was tested and verified using the sensor monitoring technology, was presented. The new supporting structure is assembled by prefabricated steel structural units. The adjac... A new type of pit supporting structure, which was tested and verified using the sensor monitoring technology, was presented. The new supporting structure is assembled by prefabricated steel structural units. The adjacent steel structural units are jointed with fasteners, and each steel structural unit has a certain radian and is welded by two steel tubes and one piece of steel disc. In order to test and verify the reliability of the new supporting structure, the field tests are designed. The main monitoring programs include the hoop stress of supporting structure, lateral earth pressure, and soil deformation. The monitoring data of the field tests show that the new supporting structure is convenient, reliable and safe. 展开更多
关键词 foundation pit supporting structure sensor monitoring earth pressure horizontal displacement
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Dynamic responses of K-type and inverted-K-type jacket support structures for offshore wind-turbines 被引量:1
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作者 LIAO Ying-di GUO Meng-yuan +2 位作者 WANG Na HOU Li-jun CHEN Da 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第4期947-956,共10页
The jacket structure has become more popular as the offshore wind-turbine support structure. K-type and inverted-K-type jacket support structures have superior potential due to their fewer joints and lower cost of man... The jacket structure has become more popular as the offshore wind-turbine support structure. K-type and inverted-K-type jacket support structures have superior potential due to their fewer joints and lower cost of manufacture and installation. A numerical study was presented on the dynamic responses of K-type and inverted-K-type jacket support structures subjected to different kinds of dynamic load. The results show that the inverted-K-type jacket structure has higher natural frequencies than the K-type. The wave force spectrum response shows that the maximum displacement of the K-type jacket structure is larger than that of the inverted-K-type. The time-history responses under wind and wave-current load indicate that the inverted-K-type jacket structure shows smaller displacement and stress compared with the K-type, and presents different stress concentration phenomena. The dynamic responses reveal that the inverted-K-type of jacket support structure has greater stiffness and superior mechanical properties, and thus is more applicable in the offshore area with relatively deep water. 展开更多
关键词 JACKET support structure K-type inverted-K-type FOUNDATION dynamic RESPONSES
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Support surface pore structures matter: Effects of support surface pore structures on the TFC gas separation membrane performance over a wide pressure range 被引量:1
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作者 Mengqi Shi Chenxi Dong +3 位作者 Zhi Wang Xinxia Tian Song Zhao Jixiao Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第8期1807-1816,共10页
In this work, the effects of support surface pore structures(including surface pore size, surface pore density and surface porosity) on the performance of thin film composite(TFC) gas separation membrane over a wide p... In this work, the effects of support surface pore structures(including surface pore size, surface pore density and surface porosity) on the performance of thin film composite(TFC) gas separation membrane over a wide pressure range(from 0.3 to 2.0 MPa) were studied. To fulfill it, the polysulfone(PSf) supports with different surface pore structures were prepared. Two kinds of wide-accepted polymeric membrane materials, i.e., polyvinylamine(PVAm) and Pebax 1657 copolymer, were used as skin layer materials. We pointed out for the first time that the support surface average pore size and pore density could affect the chain mobility of polymer of skin layer at the support surface pore entrance, then, can affect the TFC membrane performance. Besides, we also discussed the effects of support on the TFC membrane performance when the feed pressure changes for the first time. This work can provide guidance for choosing a suitable support for TFC gas separation membrane. 展开更多
关键词 support SURFACE PORE structures Thin film composite gas separation membrane Polymer mobility
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Failure Assessment of Aero-engine Support Structure due to Blade-off 被引量:1
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作者 Liu Shuangli Chen Wei Chen Minghao 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2018年第5期838-848,共11页
Aero-engine blade-off event could cause serious malfunction and endanger flight safety,which is an important issue widely concerned for a long period.This paper presents a comprehensive review on the regulation requir... Aero-engine blade-off event could cause serious malfunction and endanger flight safety,which is an important issue widely concerned for a long period.This paper presents a comprehensive review on the regulation requirements,the major research methods and status at home and abroad.Firstly,the relevant certification regulations and standards about aero-engine structure safety due to blade-off event were overviewed and the research gaps between the abroad and the domestic were compared.Then,the simulation and experimental methodologies on aero-engine supporting structures undertake abnormal load due to blade-off event were discussed as major issue.Finally,the safety certification verification technology system for aero-engine support structures during blade-off event was proposed. 展开更多
关键词 AERO-ENGINE blade-off AIRWORTHINESS certification standard support structure failure analysis safety assessment
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Mode of overlying rock roofing structure in large mining height coal face and analysis of support resistance 被引量:2
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作者 吴锋锋 刘长友 杨敬轩 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第12期3262-3272,共11页
The mining space of large mining height coal face is large,the range of movement and caving of rock strata is large and the stability of supports at coal face is low and damage rate of supports is high,which significa... The mining space of large mining height coal face is large,the range of movement and caving of rock strata is large and the stability of supports at coal face is low and damage rate of supports is high,which significantly affects the safe and efficient production of coal mines.By similar simulation experiment and theoretical analysis,the mode of fractured roofing structure of large mining height coal face and the method of determination of reasonable support resistance of the support was evaluated.Analysis shows that the structural mode of "combined cantilever beam – non-hinged roofing – hinged roofing" of the large mining height coal face appears at the roofing of large mining height coal face.The supporting factor of caved gangue at the gob is introduced,the calculating equations of the fractured step distance of roofing were derived and conventional calculating method of caved height of roofing was corrected and the method of determination of the length and height of each structural area of the roofing was provided.With reference to the excavating conditions at Jinhuagong coal mine in Datong minefield,the dimensions of structural areas of the roofing of the coal face were determined and analyzed,and reasonable support resistance of the height coal face was acquired.By selecting Model ZZ13000/28/60 support and with procedures of advanced pre-cracking blasting,the safe production of large mining height coal face was assured. 展开更多
关键词 large mining height roof structure roof model roof fracturing distance support resistance
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Roof structure theory and support resistance determination of longwall face in shallow seam 被引量:2
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作者 黄庆享 《Journal of Coal Science & Engineering(China)》 2003年第2期21-24,共4页
This paper presents the structure models founded in shallow seam, the roof asymmetry arch with three articulations in roof first weighting and the step voussoir beam in roof periodic weighting. These structure models ... This paper presents the structure models founded in shallow seam, the roof asymmetry arch with three articulations in roof first weighting and the step voussoir beam in roof periodic weighting. These structure models are differ from classic theory, it establishes the new roof control theory of instability structure roof, especially in shallow seam. Based on the new roof structure theory, the support working state of "given sliding load" is put forward, and the factor of load transmitting is introduced to determine the load on roof structure. Therefore, the proper and accurate calculating methods of support resistance are established. Based on this, the dynamic structure theory in shallow seam could be predicted. 展开更多
关键词 shallow seam roof structure support resistance load transmitting
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Thermal Structure of Glass Fiber Reinforce Plastic Support Structure 被引量:2
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作者 刘康 汪荣顺 +1 位作者 石玉美 顾安忠 《Journal of Shanghai Jiaotong university(Science)》 EI 2008年第3期370-374,共5页
The assembled form of thick-wall glass fiber reinforced plastics (GFRP) tube and 0Cr18Ni9 austenitic stainless steel pipes was designed as the radius thermal-insulating and load-supporting structure in cryogenic vesse... The assembled form of thick-wall glass fiber reinforced plastics (GFRP) tube and 0Cr18Ni9 austenitic stainless steel pipes was designed as the radius thermal-insulating and load-supporting structure in cryogenic vessels. In order to study the thermal leakage and gap changes on the support structure, as well as radius temperature and stress distribution on GFRP tube, an experimental investigation has been taken. The results indicate that the support structure is proved to fit well as thermal-insulating and load-supporting part in cryo-genic vessels, furthermore has high security during cryogenic applications. 展开更多
关键词 glass fiber reinforced plastics (GFRP) tube support structure CRYOGENIC temperature stress
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Reliability analysis on bolt support structure of coal roadway under the influence of mining 被引量:4
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作者 Zhang Daobing Luo Yixin Zhu Chuanqu 《Engineering Sciences》 EI 2008年第3期64-68,84,共6页
Based on the features of the serious deformation of coal roadway,many random variables of the mechanics of the surrounding rocks and the influence of mining, the reliability analysis model of the support structure of ... Based on the features of the serious deformation of coal roadway,many random variables of the mechanics of the surrounding rocks and the influence of mining, the reliability analysis model of the support structure of coal roadway under the influence of mining is established,and the calculating formulas of reliability of the support structure is obtained with the engineering structure reliability theory. And the reliability is calculated based on the method of Monte Carlo to the coal roadway which is exampled on the influence of mining or not. The relationship between support parameters and reliability, the mining influence coefficients and reliability is established, which provides theory foundations for the design of the coal roadway bolt support. 展开更多
关键词 coal roadway influence of mining bolt support structure reliability the method of Monte Carlo
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Internal Force Analysis Due to the Supporting Translation in Statically (Indeterminate) Structures for Different Elastic Modulus 被引量:1
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作者 姚文娟 叶志明 《Journal of Shanghai University(English Edition)》 CAS 2004年第3期274-280,共7页
For statically indeterminate structure, the internal force will be changed with the translation of the supports, because the internal force is related to the absolute value of the stiffness EI. When the tension is dif... For statically indeterminate structure, the internal force will be changed with the translation of the supports, because the internal force is related to the absolute value of the stiffness EI. When the tension is different with the compression modulus, EI is the function of internal force and is not constant any more that is different from classic mechanics. In the other words, it is a nonlinear problem to calculate the internal force. The expression for neutral axis of the statically indeterminate structure was derived in the paper. The iterative program for nonlinear internal force was compiled. One case study was presented to illustrate the difference between the results using the different modulus theory and the single modulus theory as in classical mechanics. Finally, some reasonable suggestions were made for the different modulus structures. 展开更多
关键词 different moduli in tension and compression statically indeterminate structure translation of support nonlinear internal force iteration.
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A Lower Rigid Support Structure for the HT-7U Vacuum Vessel 被引量:3
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作者 宋云涛 姚达毛 +1 位作者 武松涛 翁佩德 《Plasma Science and Technology》 SCIE EI CAS CSCD 2002年第3期1289-1296,共8页
Vacuum vessel of the HT-7U is a fully welded toroidal structure with a noncircular cross-section nested in the bore of the TF coils. According to the requirement of the physics design, sixteen horizontal ports on outb... Vacuum vessel of the HT-7U is a fully welded toroidal structure with a noncircular cross-section nested in the bore of the TF coils. According to the requirement of the physics design, sixteen horizontal ports on outboard mid-plane and thirty-two vertical ports on the top and bottom are designed for diagnostics, plasma heating, current driving, vacuum pumping and gas puffing. Bellows on these port necks are used for flexible components to absorb the relative displacement in radial and vertical directions due to external load, thermal expansion or contrac-tion and assembly tolerance, and also used for isolation of mechanical vibration. For the support system of vacuum vessel it should be not only strong enough to withstand forces acting on the vessel interior components and the vessel itself due to the dead weight and electromagnetic inter-actions during plasma disruption, but also sufficiently flexible to be suited to thermal expansion during baking. In order to solve this contradiction a new kind of low rigid support has been designed, which has a perfectly rigid in vertical direction and perfectly soft in radial direction. Some three-dimension finite element COSMOS models were performed to analyze their structural strength, stiffness and fatigue life, with an emphasis on the static stress analysis. The load spectra during vacuum vessel operation were also simulated on these models in the view of fatigue design. It was confirmed that the bellows and support had sufficient strength in the designed range of the load conditions. The results showed that the peak stress on bellows was 87 MPa and on the support system was 97 MPa. Now all kinds of bellows and support system have been designed. In order to accumulate some engineering experiences and probe into some molding die and welding technologies, prototypical bellows and support system have been fabricated. At the same time a mechanical testing apparatus was designed for proof tests on the prototypical bellows and support to verify their functional and structure capability. The experimental data indicated that the re-sults of finite element analysis were coincident with experimental test results. It has been proved that the present vacuum vessel's bellows and support system are reasonable and feasible. 展开更多
关键词 A Lower Rigid support structure for the HT-7U Vacuum Vessel HT
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Application of modified polypropylene (crude) fibers concrete to strengthen the support structures in deep mine roadway 被引量:1
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作者 BI Yuan-zhi ZHANG Da-lin HU Jin-hua 《Journal of Coal Science & Engineering(China)》 2012年第4期379-384,共6页
The an thors developed a new composite cement base material by mixing the high tenacity polypropylene (coarse) fiber in plain cement base for the cement-layer-spray technology. By studying the key parameters of the ... The an thors developed a new composite cement base material by mixing the high tenacity polypropylene (coarse) fiber in plain cement base for the cement-layer-spray technology. By studying the key parameters of the fiber dosage, the spray layer thickness, and the fiber reinforced concrete injection time, etc. It is found that the ideal volume ratio of polypropylene (crude) fiber is 0.8% (V/V), and the secondary lining fiber concrete spraying should start when the shrinkage rate is lower than 0.5 mm/d, and the optimal thickness of shotcrete is 120 mm. The supporting effects and the economic benefits were studied using a real project practice, and the result obtained can be a good reference for practical applications of this new supporting material in the future. 展开更多
关键词 deep mine roadway modified polypropylene (crude) fiber supporting structure mine stress
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Influence of earthquake ground motion incoherency on multi-support structures 被引量:9
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作者 杨庆山 M.Saiid Saiidi +1 位作者 王航 Ahmad Itani 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2002年第2期167-180,共14页
A linear response history analysis method is used to determine the influence of three factors:geometric incoherency,wave-passage,and local site characteristics on the response of lnulti-support structures subjected to... A linear response history analysis method is used to determine the influence of three factors:geometric incoherency,wave-passage,and local site characteristics on the response of lnulti-support structures subjected to differential ground motions.A one-span frame and a reduced model of a 24-span bridge,located in Las Vegas,Nevada are studied,in which the influence of each of the three factors and their combinations are analyzed.It is revealed that the incoherency of earthquake ground motion can have a dramatic influence on structural response by modifying the dynamics response to uniform excitation and inducing pseudo-static response,which does not exist in structures subjected to uniform excitation.The total response when all three sources of ground motion incoherency are included is generally larger than that of uniform excitation. 展开更多
关键词 EARTHQUAKE BRIDGES ground motion incoherency wave passage local site characteristics multi-support structures
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SMFs-supported Pd nanocatalysts in selective acetylene hydrogenation:Pore structure-dependent deactivation mechanism 被引量:5
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作者 Elaheh Esmaeili Ali Morad Rashidi +2 位作者 Yadollah Mortazavi Abbas Ali Khodadadi Mehdi Rashidzadeh 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2013年第5期717-725,共9页
In the present study,CNFs,ZnO and Al2O3 were deposited on the SMFs panels to investigate the deactivation mechanism of Pd-based catalysts in selective acetylene hydrogenation reaction.The examined supports were charac... In the present study,CNFs,ZnO and Al2O3 were deposited on the SMFs panels to investigate the deactivation mechanism of Pd-based catalysts in selective acetylene hydrogenation reaction.The examined supports were characterized by SEM,NH3-TPD and N2adsorption-desorption isotherms to indicate their intrinsic characteristics.Furthermore,in order to understand the mechanism of deactivation,the resulted green oil was characterized using FTIR and SIM DIS.FTIR results confirmed the presence of more unsaturated constituents and then,more branched hydrocarbons formed upon the reaction over alumina-supported catalyst in comparison with the ones supported on CNFs and ZnO,which in turn,could block the pores mouths.Besides the limited hydrogen transfer,N2 adsorption-desorption isotherms results supported that the lowest pore diameters of Al2O3/SMFs close to the surface led to fast deactivation,compared with the other catalysts,especially at higher temperatures. 展开更多
关键词 selective hydrogenation alloy formation acidic site pore structure SMFs-supported Pd nanocatalysts
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