The great spatial and temporal variability in hydrological conditions and nitrogen(N)processing introduces large uncertainties to the identification of N sources and quantifying N cycles in plain river network regio...The great spatial and temporal variability in hydrological conditions and nitrogen(N)processing introduces large uncertainties to the identification of N sources and quantifying N cycles in plain river network regions. By combining isotopic data with chemical and hydrologic measurements, we determined the relative importance of N sources and biogeochemical N processes in the Taige River in the East Plain Region of China. The river was polluted more seriously by anthropogenic inputs in winter than in summer. Manure and urban sewage effluent were the main nitrate(NO-3) sources, with the nitrification of N-containing organic materials serving as another important source of NO-3. In the downstream, with minor variations in hydrological conditions, nitrification played a more important role than assimilation for the decreasing ammonium(NH+4-N) concentrations.The N isotopic enrichment factors(ε) during NH+4utilization ranged from- 13.88‰ in March to- 29.00‰ in July. The ratio of the increase in δ^18O and δ^15N of river NO-3in the downstream was 1.04 in January and 0.92 in March. This ratio indicated that NO-3assimilation by phytoplankton was responsible for the increasing δ^15N and δ^18O values of NO-3in winter. The relationships between δ^15N of particulate organic nitrogen and isotopic compositions of dissolved inorganic nitrogen indicated that the phytoplankton in the Taige River probably utilized NH+4preferentially and mainly in summer, while in winter, NO-3assimilation by phytoplankton was dominant.展开更多
Methane (CH4) and nitrous oxide (N2O) saturation concentration and gas-water interface emission flux in surface water of the Yangtze Delta plain river net were investigated in summer at representative sites including ...Methane (CH4) and nitrous oxide (N2O) saturation concentration and gas-water interface emission flux in surface water of the Yangtze Delta plain river net were investigated in summer at representative sites including the upper reaches of the Huangpu River and the rivers in the Chongming Island. The results show that the CH4 concentration in river water ranged from 0.30±0.03 to 6.66±0.14 μmol.L-1, and N2O concentration ranged from 13.8±2.33 to 435±116 nmol.L-1. River surface water had a very high satura- tion level of CH4 (from 468±49.0% to 11560±235%) and that of N2O (from 175±29.5% to 4914±1304%). Dissolved oxygen (DO) was the primary factor controlling the CH4 concentration in water. N2O concentration had significant negative correlation with salinity and a significant positive correlation with nitrate (NO3-), nitrite (NO2-), chemical oxygen demand (CODcr) concentration and pH of river water. CH4 and N2O of river water were brought about mainly by methanogenesis and denitrification in river bottom sediment that diffused through sediment-water interface into the water body and then into atmosphere through the gas-water interface. The emission flux of CH4 and N2O at river gas-water interface reached 778±59.8 and 236±63.6 μmol.m-2.h-1, respectively in summer. The river net was a potential source of atmospheric CH4 and N2O because of eutrophication of the water body.展开更多
The land area in a river network is divided into certain-scale square cells for the sake of precision, and, based on the physical mechanisms of rainfall-runoff processes and runoff pollution, the non-point source poll...The land area in a river network is divided into certain-scale square cells for the sake of precision, and, based on the physical mechanisms of rainfall-runoff processes and runoff pollution, the non-point source pollution from cells is estimated using the export coefficients of different land use types. The non-point source pollution from a land cell should all go into the closest fiver reach, so it is distributed according to the terrain of the plain river network area and the positions of land cells and river network reaches. A relationship between a single land cell and its pollution-receiving reach can be determined using this system. In view of the above, a spatial distribution model of the rainfall runoff and non-point source pollution in reaches of a plain river network area was established. This model can provide technological support for further research on the dynamic effects of non-point source pollution on water quality.展开更多
Complex water movement and insufficient observation stations are the unfavorable factors in improving the accuracy of flow calculation of river networks. A water level updating model for river networks was set up base...Complex water movement and insufficient observation stations are the unfavorable factors in improving the accuracy of flow calculation of river networks. A water level updating model for river networks was set up based on a three-step method at key nodes, and model correction values were collected from gauge stations. To improve the accuracy of water level and discharge forecasts for the entire network, the discrete coefficients of the Saint-Venant equations for river sections were regarded as the media carrying the correction values from observation locations to other cross-sections of the river network system. To examine the applicability, the updating model was applied to flow calculation of an ideal river network and the Chengtong section of the Yangtze River. Comparison of the forecast results with the observed data demonstrates that this updating model can improve the forecast accuracy in both ideal and real river networks.展开更多
Based on the special hydrogeological conditions of the Dahei River Plain in the Inner Mongolia area, assessment of shallow groundwater vulnerability is conducted based on DRASTIC model. Each evaluation indicator weigh...Based on the special hydrogeological conditions of the Dahei River Plain in the Inner Mongolia area, assessment of shallow groundwater vulnerability is conducted based on DRASTIC model. Each evaluation indicator weight is determined by using analytic hierarchy process(AHP). The most important indicators are lithology in soil media and vadose zone. Assessment model of shallow groundwater vulnerability of the Dahei River plain is constructed. Distribution map of vulnerability index in this area is made with the spatial analysis function of ARCGIS. The results show that the particularly sensitive area is the piedmont of the Daqing Mountain, where the upstream place of the groundwater and the south-central place of the plain has the lowest vulnerability. The assessment results are more in accordance with the actual vulnerability conditions of this area by using analytic hierarchy process, and is helpful for groundwater protection.展开更多
The Hutuo River alluvial-proluvial fan is located in North China Plain, and groundwater is the main source of water supply for agriculture and domestic water. Shijiazhuang depression funnels due to the long-term exces...The Hutuo River alluvial-proluvial fan is located in North China Plain, and groundwater is the main source of water supply for agriculture and domestic water. Shijiazhuang depression funnels due to the long-term excessive exploitation are the bottleneck of the regional economic development. Analyzing the chemical characteristics of groundwater under the condition of strong human activities, can provide a scientific basis for further study of strong groundwater mining area environmental change. 143 groups of shallow groundwater samples are collected during the period of 2007-2008. In this paper, the hydrochemical characteristics of groundwater in the Hutuo River Plain area are analyzed systematically, using hydrogeochemical theory, combined with statistical methods and hydrochemical methods. Results are shown as follows: HCO_3^- and Ca^(2+) are major anion and cation. The variation coefficients of K^+, Ca^(2+), Mg^(2+) and HCO_3^- between 0.25 and 0.52, which means small and stable relatively. The variation coefficient of are Na^+, NO_3^-, Cl-, SO2-4 were large(0.89-1.01). They are sensitive and vulnerable to environmental change affect. Due to the impact of human activities, from the top to the edge of the alluvial-proluvial fan, the hydrochemical types of groundwater change from single to multiple, followed by HCO_3^-Ca·Mg, HCO_3·SO_4-Ca·Mg, HCO_3·SO_4·Cl-Ca·Mg, HCO_3·Cl-Ca·Mg and other types.展开更多
The Snake River in northwestern United States is 1735 km long, the largest tributary of the Columbia River and is the 13<sup>th</sup> longest river in the United States. The Snake River drainage basin incl...The Snake River in northwestern United States is 1735 km long, the largest tributary of the Columbia River and is the 13<sup>th</sup> longest river in the United States. The Snake River drainage basin includes parts of six U.S. states. The Snake River Plain was created by a volcanic hotspot that lies beneath Yellow-stone National Park. The previous Ice Age carved out canyons, cliffs and waterfalls along the middle and lower Snake River. The Missoula Flood was to the north and Bonneville Flood to the south altered the Snake River and surrounding landscape. The Snake River has a drainage basin of 282,000 km<sup>2</sup> in the states of Oregon, Washington, Utah, Nevada and Idaho. The Snake River drops from mountain elevations of 3000 m to its confluence with the Columbia River. The river is one of the most biologically diverse freshwater systems in the United States with trails designed to promote recreational tourism, increase use of the Snake River and create generations of people who care about the river and are willing to protect and provide environmental stewardship of the river watershed resources.展开更多
Due to the combined effect of sluices and sea tide,the sluice-controlled coastal plain river would be characterized by both trophic state and salinity gradients,affecting the spatiotemporal optical properties of disso...Due to the combined effect of sluices and sea tide,the sluice-controlled coastal plain river would be characterized by both trophic state and salinity gradients,affecting the spatiotemporal optical properties of dissolved organicmatter(DOM).In this study,we investigated the spatiotemporal variation of water quality parameters and optical properties of DOM in the Haihe River,a representative sluice-controlled coastal plain river in Tianjin,China.A significant salinity gradient and four trophic states were observed in the water body of the Haihe River.Two humic-and one protein-like substances were identified from the DOM by the three-dimensional fluorescence spectra combined with the parallel factor(PARAFAC)analysis.Pearson’s correlation analysis and redundancy analysis(RDA)showed that the salinity significantly affected the abundance of chromophoric DOM(CDOM)but did not cause significant changes in the fluorescence optical characteristics.In addition,the effect of Trophic state index(TSI)on the CDOM abundance was greater than that on the fluorescence intensity of fluorescent dissolved organic matter(FDOM).In the water body with both salinity and trophic state gradients,TSI posed a greater influence than salinity on the CDOM abundance.Our results fill the research gap in spatiotemporal DOM characteristics and water quality variation in water bodies with both salinity and trophic state gradients.These results are beneficial for clarifying the joint influence of saline intrusion and sluices on the DOM characteristics and water quality in sluice-controlled coastal plain rivers.展开更多
基金supported by the Mega-projects of Science Research for Water Environment Improvement (No. 2012ZX07101)
文摘The great spatial and temporal variability in hydrological conditions and nitrogen(N)processing introduces large uncertainties to the identification of N sources and quantifying N cycles in plain river network regions. By combining isotopic data with chemical and hydrologic measurements, we determined the relative importance of N sources and biogeochemical N processes in the Taige River in the East Plain Region of China. The river was polluted more seriously by anthropogenic inputs in winter than in summer. Manure and urban sewage effluent were the main nitrate(NO-3) sources, with the nitrification of N-containing organic materials serving as another important source of NO-3. In the downstream, with minor variations in hydrological conditions, nitrification played a more important role than assimilation for the decreasing ammonium(NH+4-N) concentrations.The N isotopic enrichment factors(ε) during NH+4utilization ranged from- 13.88‰ in March to- 29.00‰ in July. The ratio of the increase in δ^18O and δ^15N of river NO-3in the downstream was 1.04 in January and 0.92 in March. This ratio indicated that NO-3assimilation by phytoplankton was responsible for the increasing δ^15N and δ^18O values of NO-3in winter. The relationships between δ^15N of particulate organic nitrogen and isotopic compositions of dissolved inorganic nitrogen indicated that the phytoplankton in the Taige River probably utilized NH+4preferentially and mainly in summer, while in winter, NO-3assimilation by phytoplankton was dominant.
基金Supported by the National Natural Science Foundation of China (Grant No. 40730526)the Science & Technology Department of Shanghai (Grant No. 07DZ12037)+1 种基金the National Great Water Issue Project of China (Grant No. 2008ZX07317-006)China Postdoctoral Science Foundation (Grant No. 20060400635)
文摘Methane (CH4) and nitrous oxide (N2O) saturation concentration and gas-water interface emission flux in surface water of the Yangtze Delta plain river net were investigated in summer at representative sites including the upper reaches of the Huangpu River and the rivers in the Chongming Island. The results show that the CH4 concentration in river water ranged from 0.30±0.03 to 6.66±0.14 μmol.L-1, and N2O concentration ranged from 13.8±2.33 to 435±116 nmol.L-1. River surface water had a very high satura- tion level of CH4 (from 468±49.0% to 11560±235%) and that of N2O (from 175±29.5% to 4914±1304%). Dissolved oxygen (DO) was the primary factor controlling the CH4 concentration in water. N2O concentration had significant negative correlation with salinity and a significant positive correlation with nitrate (NO3-), nitrite (NO2-), chemical oxygen demand (CODcr) concentration and pH of river water. CH4 and N2O of river water were brought about mainly by methanogenesis and denitrification in river bottom sediment that diffused through sediment-water interface into the water body and then into atmosphere through the gas-water interface. The emission flux of CH4 and N2O at river gas-water interface reached 778±59.8 and 236±63.6 μmol.m-2.h-1, respectively in summer. The river net was a potential source of atmospheric CH4 and N2O because of eutrophication of the water body.
基金supported by the Major Science and Technology Program for Water Pollution Control and Treatment in China (Grant No. 2008X07101-005)
文摘The land area in a river network is divided into certain-scale square cells for the sake of precision, and, based on the physical mechanisms of rainfall-runoff processes and runoff pollution, the non-point source pollution from cells is estimated using the export coefficients of different land use types. The non-point source pollution from a land cell should all go into the closest fiver reach, so it is distributed according to the terrain of the plain river network area and the positions of land cells and river network reaches. A relationship between a single land cell and its pollution-receiving reach can be determined using this system. In view of the above, a spatial distribution model of the rainfall runoff and non-point source pollution in reaches of a plain river network area was established. This model can provide technological support for further research on the dynamic effects of non-point source pollution on water quality.
基金supported by the Major Program of the National Natural Science Foundation of China(Grant No.51190091)the National Natural Science Foundation of China(Grant No.51009045)the Open Research Fund Program of the State Key Laboratory of Water Resources and Hydropower Engineering Science of Wuhan University(Grant No.2012B094)
文摘Complex water movement and insufficient observation stations are the unfavorable factors in improving the accuracy of flow calculation of river networks. A water level updating model for river networks was set up based on a three-step method at key nodes, and model correction values were collected from gauge stations. To improve the accuracy of water level and discharge forecasts for the entire network, the discrete coefficients of the Saint-Venant equations for river sections were regarded as the media carrying the correction values from observation locations to other cross-sections of the river network system. To examine the applicability, the updating model was applied to flow calculation of an ideal river network and the Chengtong section of the Yangtze River. Comparison of the forecast results with the observed data demonstrates that this updating model can improve the forecast accuracy in both ideal and real river networks.
基金Basic Scientific Research Operating Expense Project of the Chinese Academy of Geological Sciences“Leaky System Numerical Modeling and Progressive Parameter Inversion Study”(YYWF201626)Geological survey project“1/50 000 Hydrogeological Survey of the Hutuo River-Fuyang River Basin Plain”(DD20160238)
文摘Based on the special hydrogeological conditions of the Dahei River Plain in the Inner Mongolia area, assessment of shallow groundwater vulnerability is conducted based on DRASTIC model. Each evaluation indicator weight is determined by using analytic hierarchy process(AHP). The most important indicators are lithology in soil media and vadose zone. Assessment model of shallow groundwater vulnerability of the Dahei River plain is constructed. Distribution map of vulnerability index in this area is made with the spatial analysis function of ARCGIS. The results show that the particularly sensitive area is the piedmont of the Daqing Mountain, where the upstream place of the groundwater and the south-central place of the plain has the lowest vulnerability. The assessment results are more in accordance with the actual vulnerability conditions of this area by using analytic hierarchy process, and is helpful for groundwater protection.
基金supported by Public Welfare Project of Ministry of Water Resources (201501008)Natural Science Foundation of Hebei Province (D2015504019)
文摘The Hutuo River alluvial-proluvial fan is located in North China Plain, and groundwater is the main source of water supply for agriculture and domestic water. Shijiazhuang depression funnels due to the long-term excessive exploitation are the bottleneck of the regional economic development. Analyzing the chemical characteristics of groundwater under the condition of strong human activities, can provide a scientific basis for further study of strong groundwater mining area environmental change. 143 groups of shallow groundwater samples are collected during the period of 2007-2008. In this paper, the hydrochemical characteristics of groundwater in the Hutuo River Plain area are analyzed systematically, using hydrogeochemical theory, combined with statistical methods and hydrochemical methods. Results are shown as follows: HCO_3^- and Ca^(2+) are major anion and cation. The variation coefficients of K^+, Ca^(2+), Mg^(2+) and HCO_3^- between 0.25 and 0.52, which means small and stable relatively. The variation coefficient of are Na^+, NO_3^-, Cl-, SO2-4 were large(0.89-1.01). They are sensitive and vulnerable to environmental change affect. Due to the impact of human activities, from the top to the edge of the alluvial-proluvial fan, the hydrochemical types of groundwater change from single to multiple, followed by HCO_3^-Ca·Mg, HCO_3·SO_4-Ca·Mg, HCO_3·SO_4·Cl-Ca·Mg, HCO_3·Cl-Ca·Mg and other types.
文摘The Snake River in northwestern United States is 1735 km long, the largest tributary of the Columbia River and is the 13<sup>th</sup> longest river in the United States. The Snake River drainage basin includes parts of six U.S. states. The Snake River Plain was created by a volcanic hotspot that lies beneath Yellow-stone National Park. The previous Ice Age carved out canyons, cliffs and waterfalls along the middle and lower Snake River. The Missoula Flood was to the north and Bonneville Flood to the south altered the Snake River and surrounding landscape. The Snake River has a drainage basin of 282,000 km<sup>2</sup> in the states of Oregon, Washington, Utah, Nevada and Idaho. The Snake River drops from mountain elevations of 3000 m to its confluence with the Columbia River. The river is one of the most biologically diverse freshwater systems in the United States with trails designed to promote recreational tourism, increase use of the Snake River and create generations of people who care about the river and are willing to protect and provide environmental stewardship of the river watershed resources.
基金This work was supported by the National Science Foundation of China(No.41807386).The authors gratefully acknowledge the warm help from Prof.Baoli Wang and PhD studentWanzhu Li during themeasurement of chlorophyll a.We greatly appreciate Prof.Wei He for his help in the use of the efc toolbox.We are deeply grateful to Prof.Jinyu Yang for her warm suggestion in the statistical analysis.We thank all staff and students that helped with sample collection and measurements.Scientific compass(www.shiyanjia.com)is gratefully appreciated for their service in the polish of manuscript.
文摘Due to the combined effect of sluices and sea tide,the sluice-controlled coastal plain river would be characterized by both trophic state and salinity gradients,affecting the spatiotemporal optical properties of dissolved organicmatter(DOM).In this study,we investigated the spatiotemporal variation of water quality parameters and optical properties of DOM in the Haihe River,a representative sluice-controlled coastal plain river in Tianjin,China.A significant salinity gradient and four trophic states were observed in the water body of the Haihe River.Two humic-and one protein-like substances were identified from the DOM by the three-dimensional fluorescence spectra combined with the parallel factor(PARAFAC)analysis.Pearson’s correlation analysis and redundancy analysis(RDA)showed that the salinity significantly affected the abundance of chromophoric DOM(CDOM)but did not cause significant changes in the fluorescence optical characteristics.In addition,the effect of Trophic state index(TSI)on the CDOM abundance was greater than that on the fluorescence intensity of fluorescent dissolved organic matter(FDOM).In the water body with both salinity and trophic state gradients,TSI posed a greater influence than salinity on the CDOM abundance.Our results fill the research gap in spatiotemporal DOM characteristics and water quality variation in water bodies with both salinity and trophic state gradients.These results are beneficial for clarifying the joint influence of saline intrusion and sluices on the DOM characteristics and water quality in sluice-controlled coastal plain rivers.