The nitrides of transient metals have a high hardness, thermal stability, remarkable wear resistance in aggressive chemical mediums, melted metals and alloys, high corrosion resistance, and low coefficient of electric...The nitrides of transient metals have a high hardness, thermal stability, remarkable wear resistance in aggressive chemical mediums, melted metals and alloys, high corrosion resistance, and low coefficient of electric resistance. Under the conditions of low-temperature argon plasma （LTP）, thermodynamic investigations were conducted in the process of obtaining of A1N, TiN and Si3N4 in a temperature range of 1000 K to 6000 K. To investigate the thermodynamic possibility of obtaining nitrides, a computer model was used which provided the equilibrium composition of gaseous and solid phases at different temperatures. The conditions for chemical equilibrium of the system were based on the minimization of Gibbs＇ energy.展开更多
This article presents a review on the physical-chemical properties and characteristics of plasma-chemically produced nanodispersed powders （NDP）, such as metals, oxides, nitrides, carbides, and catalysts. The plasma...This article presents a review on the physical-chemical properties and characteristics of plasma-chemically produced nanodispersed powders （NDP）, such as metals, oxides, nitrides, carbides, and catalysts. The plasma-chemical preparatior~ of the powders was carried out in thermal plasma （TP） created by means of high-current electric arcs, plasma jets, high-frequency （HF） discharges, etc. We also discuss certain properties and characteristics of the NDPs, which are determined largely by the conditions of preparation.展开更多
文摘The nitrides of transient metals have a high hardness, thermal stability, remarkable wear resistance in aggressive chemical mediums, melted metals and alloys, high corrosion resistance, and low coefficient of electric resistance. Under the conditions of low-temperature argon plasma （LTP）, thermodynamic investigations were conducted in the process of obtaining of A1N, TiN and Si3N4 in a temperature range of 1000 K to 6000 K. To investigate the thermodynamic possibility of obtaining nitrides, a computer model was used which provided the equilibrium composition of gaseous and solid phases at different temperatures. The conditions for chemical equilibrium of the system were based on the minimization of Gibbs＇ energy.
文摘This article presents a review on the physical-chemical properties and characteristics of plasma-chemically produced nanodispersed powders （NDP）, such as metals, oxides, nitrides, carbides, and catalysts. The plasma-chemical preparatior~ of the powders was carried out in thermal plasma （TP） created by means of high-current electric arcs, plasma jets, high-frequency （HF） discharges, etc. We also discuss certain properties and characteristics of the NDPs, which are determined largely by the conditions of preparation.
