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Assessment of bisphenols in children's toy and baby products in the Middle East
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作者 K.Martínez-Guijarro B.Gevao +8 位作者 M.Porcelli S.Al-Salem Saif Uddin M.Bahloul H.Taqi M.Hajeyah D.Krishnan S.Rajagopalan A.Boota 《Emerging Contaminants》 CSCD 2024年第3期336-342,共7页
A major concern from the scientific community has been raised since evidence of Bisphenol A(BP-A)can leach out from the products where they are incorporated as well as its endocrine disrupting effects observed in anim... A major concern from the scientific community has been raised since evidence of Bisphenol A(BP-A)can leach out from the products where they are incorporated as well as its endocrine disrupting effects observed in animals and humans.BP-A and several related chemicals such as Bisphenol AP(BP-AP),Bisphenol B(BPeB),Bisphenol S(BPeS),Bisphenol AF(BP-AF),Bisphenol(BPeP),Bisphenol Z(BP-Z)were analyzed in this study.BP-A and BP-S were the only bisphenols detected in the samples analyzed in this study.The median(range;mean)concentrations of BP-A found in this study was 321 ng/g(11-200932;4893 ng/g).The analysis was carried out by sonicating 0.1 g of a cryo-milled sample aliquot in methanol followed by UPLC-MS/MS determination.High concentrations of BP-A were found in several products labeled as BP-A free such as nursing bottles which are particularly problematic from the children's exposure point of view.This study presents the first reliable bisphenols in children's toys and baby products commercialized in the Middle East.There is,however,a need to continue monitoring these compounds,especially in low-cost toys,and the so-called BP-A-free products,which appear to have high levels of target contaminants and can pose an exposure risk for infants and children in the region. 展开更多
关键词 BIsPHENOLs Bisphenol A(BP-A) Bisphenol s(BPes) children toys
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顶空-气相色谱法测定乙烯-乙酸乙烯酯共聚物塑料儿童用品中甲酰胺含量 被引量:16
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作者 孙多志 禄春强 +1 位作者 左莹 秦紫明 《理化检验(化学分册)》 CAS CSCD 北大核心 2014年第2期199-201,共3页
应用顶空-气相色谱法测定了儿童用品乙烯-乙酸乙烯酯共聚物塑料中甲酰胺的含量。选择顶空平衡温度和时间分别为160℃和40min,用DB-Wax色谱柱(0.53mm×30m,1μm)分离,氢火焰离子化检测器检测。以N,N-二甲基甲酰胺为内标物。甲酰胺的... 应用顶空-气相色谱法测定了儿童用品乙烯-乙酸乙烯酯共聚物塑料中甲酰胺的含量。选择顶空平衡温度和时间分别为160℃和40min,用DB-Wax色谱柱(0.53mm×30m,1μm)分离,氢火焰离子化检测器检测。以N,N-二甲基甲酰胺为内标物。甲酰胺的线性范围为1~646μg。方法用于此类共聚物塑料地垫样品的分析,加标回收率在80.9%~82.8%之间,测定值的相对标准偏差(n=6)在4.1%~4.5%之间。 展开更多
关键词 顶空-气相色谱法 甲酰胺 乙烯-乙酸乙烯酯共聚物 塑料 儿童用品
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试论儿童文化的原初性与可塑性 被引量:2
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作者 邓琪瑛 《浙江师范大学学报(社会科学版)》 2010年第3期44-48,共5页
儿童文化,看似一个极为单纯的议题,不具备任何深邃的内涵可供讨论,殊不知它饱含能量,无时无刻不在等待着成人的关注与挖掘。可惜的是,成人世界向来对此不够重视。"原初性"与"可塑性"是儿童文化最珍贵的精髓,也是该... 儿童文化,看似一个极为单纯的议题,不具备任何深邃的内涵可供讨论,殊不知它饱含能量,无时无刻不在等待着成人的关注与挖掘。可惜的是,成人世界向来对此不够重视。"原初性"与"可塑性"是儿童文化最珍贵的精髓,也是该文化的价值核心与基本特征。儿童文化虽不直接带来经世致用的功能,但对它的探索,将有助于唤醒成人对儿童文化的尊重,且为儿童文化打开一条可供应用的思路。这对净化人心与创建和谐社会将起到一定的积极作用。 展开更多
关键词 儿童文化 原初性 可塑性
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