The problem of ship hull plate processing surface fairing with constraints based on B-spline is solved in this paper. The algorithm for B-spline curve fairing with constraints is one of the most common methods in plan...The problem of ship hull plate processing surface fairing with constraints based on B-spline is solved in this paper. The algorithm for B-spline curve fairing with constraints is one of the most common methods in plane curve fairing. The algorithm can be applied to global and local curve fairing. It can constrain the perturbation range of the control points and the shape variation of the curve, and get a better fairing result in plane curves. In this paper, a new fairing algorithm with constraints for curves and surfaces in space is presented. Then this method is applied to the experiments of ship hull plate processing surface. Finally numerical results are obtained to show the efficiency of this method.展开更多
The kinematics and dynamics of plate tectonics are frontal subjects in geosciences and the strong earthquake occurred along the plate boundary result directly from plate movement. By analyzing Ibaraki earthquake seque...The kinematics and dynamics of plate tectonics are frontal subjects in geosciences and the strong earthquake occurred along the plate boundary result directly from plate movement. By analyzing Ibaraki earthquake sequence, it has been found that the focal fault plane shows a special image of grading expansion along the direction of strike and adjustment along the dip direction respectively. With the consideration of strike, dip and slip directions of focal mechanism, we have confirmed that Ibaraki earthquake belongs to a thrust fault earthquake occurred under the Japan Trench. The cause of the earthquake sequence is discussed in the paper. The study on the temporal-spatial distribution of the earthquake sequence with a time-scale between the year-scale spatial geodetic data and the second-scale moment tensor of the strong earthquake has indicated the dynamic process of Pacific Plate subduction under the Eurasia Plate. According to the average slip distance of earthquake and the velocity of plate movement, it is predicted that a strong earthquake might occur in recent years.展开更多
Thick metal plate rolling process has become more and more important in building a flat roof of drilling on the bottom at sea. This is because not only the product quality requirement higher and higher but also the ma...Thick metal plate rolling process has become more and more important in building a flat roof of drilling on the bottom at sea. This is because not only the product quality requirement higher and higher but also the marketing competition. To improve the process of thick metal plate rolling and to increase productivity a numerical controlled rolling process is developed, which include the process planning, the mathematical model establishment and the numerical control system development. The process is for the 17 000 kN×3 000 mm movable up roller bending machine. According to the machine configuration non-symmetry rolling process is planed. This makes it possible to integrate all the steps of plate shaping up such as end side bending, several times of semi-shape bending and the last shape finishing. Since the process will perform under the numerical controlled condition whole steps of the process are considered can be worked in the automatic cycle. The mathematic model consists of two sections, the theory model and the experience parameters model. Which takes the original plate parameters such as geometry and mechanics, characters of the machine such as the movement limits, tonnage and so on as input and calculates all the parameters needed in process performing. Meanwhile, the mathematic Model is totally adapted to the control system. The numerical control system development scheme is based on all the works above. Here, a system plan is provided. The functional modules and hardware selection, in detail, are introduced. The system software on top level and the controlling software for controller are developed. And some unit techniques in the system such as timer setting, communication between system and controller, video integration, and the ability of resisting impact force are introduced. The process has been used successfully in production for more than two years. Practice approves that the process is robust.展开更多
Analyzed and studied the characters of high strength low alloy steel which contain Mo,Cr,Nb and Ni.etc.Following actual rolling,combining the feature of rolling mode,and exploiting the equipment advantage of 5 m Heavy...Analyzed and studied the characters of high strength low alloy steel which contain Mo,Cr,Nb and Ni.etc.Following actual rolling,combining the feature of rolling mode,and exploiting the equipment advantage of 5 m Heavy Plate Mill,optimized the material design,heating temperature and rolling method, stabilized rolling process of thin alloyed steel,the quality index was advanced.展开更多
The dimension variation of B610E steel during the quenching and tempering process was simulated by ABAQUS,the coefficient of heat transfer during quenching was verified by the buried thermocouple test and the trend of...The dimension variation of B610E steel during the quenching and tempering process was simulated by ABAQUS,the coefficient of heat transfer during quenching was verified by the buried thermocouple test and the trend of the dimension variation during the quenching process was also calculated by ABAQUS. It was shown by the comparison of simulated results and industrially measured results that only the simulation of thickness and width variation was accurate, while length variation needed further simulation. Besides, the dimension variation trend was identical with the measured results.展开更多
A plate's internal quality is very critical, especially for boilers and high-pressure vessels. The ultrasonic test (UT) is the main type of non-destructive flaw detection for heavy plates, which is important becaus...A plate's internal quality is very critical, especially for boilers and high-pressure vessels. The ultrasonic test (UT) is the main type of non-destructive flaw detection for heavy plates, which is important because one of the main reasons for plate defects is ultrasonic flaws. This study, based on Baosteel' s practical experience in the manufacture of heavy plates, elucidates the cause of defect formation by analyzing ultrasonic flaw testing maps and using special equipment, such as the scanning electron microscope, electron probe and the optical microscope. The author puts forward the following improvement measures: ① Ultrasonic flaws are caused by central porosity and segregation,[H] bubbles and inclusion in slabs.②Ultrasonic flaws are more likely to occur in the bottom and top of slabs rather than the other positions in the casting sequence. It is clear that one-quarter of the inner camber' s thickness is accumulated inclusion.③It is clear that overheating in the tundish and the flow of the casting mould have an effect on ultrasonic flaws caused by inclusions.④Soft reduction improves central porosity and segregation,which decreases the number of ultrasonic flaws in the plate.展开更多
To ensure the quality of heavy plate products as determined by ultrasonic inspection, it is necessary to effectively control defects such as cracks and shrinkage cavities in heavy plates. Generally, some defects such ...To ensure the quality of heavy plate products as determined by ultrasonic inspection, it is necessary to effectively control defects such as cracks and shrinkage cavities in heavy plates. Generally, some defects such as large size cracks exist due to insufficient deformation in the center of traditionally rolled plates. Compared with the traditional rolling process, gradient temperature rolling(GTR) process can effectively increase deformation inside heavy plates. In this study, the effect of GTR on crack healing was analyzed through a comparison experiment with the uniform temperature rolling(UTR). The results show that the GTR process could increase the plastic strain inside the heavy plate and effectively promote the healing process of the preset cracks. The degrees of crack healing at the center and quarter thickness position of the steel plate via GTR were greater than twice those of the plate via UTR. The GTR process can significantly reduce the internal defects of heavy plates and improve the defect detection level of heavy plate products. Also, The GTR process results in the formation of new crystal grains in the crack region, which is crucial to crack healing.展开更多
In this research we presented a non-cyanide plating process of Ni-P alloy coating on Mg alloy AZ91D. By applying a new process flow of electroless nickel plating in which zinc coating is used as transition of Ni-P coa...In this research we presented a non-cyanide plating process of Ni-P alloy coating on Mg alloy AZ91D. By applying a new process flow of electroless nickel plating in which zinc coating is used as transition of Ni-P coating on Mg alloy AZ91D, the process of copper transition coating plated in the cyanides bath can be replaced. A new bath composed of NiSO4 was established by orthogonal test. The results show that zinc transition coating can increase the adhesion and protect the Mg alloy substrate from the bath corrosion. The optimal plating bath composition is NiSO4·6H2O 20 g/L, NaH2PO2·H2O20g/L and C6H8O7·H2O 2.5 g/L, and optimal bath acidity and optimal plating temperature are pH 4.0 and 95℃, respectively. The present process flow is composed of ultrasonic cleaning→alkaline cleaning→acid pickling→activation→double immersing zinc→electroplating zinc→electroless nickel plating→passivation treatment. The present non-cyanide process of electroless nickel plating is harmless to our surroundings and Ni-P coating on Mg alloy AZ91D produced by present process possesses good adhesion and corrosion resistance.展开更多
A reasonable pre-treatment and an ultrasonic pre-plating Cu film were applied for sintering NdFeB permanent magnet. The samples were then plated in neutral bath (PH=7) for 40min and in acidic bath (PH=4.8~5.1) for 2h...A reasonable pre-treatment and an ultrasonic pre-plating Cu film were applied for sintering NdFeB permanent magnet. The samples were then plated in neutral bath (PH=7) for 40min and in acidic bath (PH=4.8~5.1) for 2h. A composite electroless plating with different phosphor content was obtained. The results show that the composite plating coatings are dense and have a strong bond with the substrate, which contribute to the excellent corrosion resistance of the plating coating.展开更多
The electroless plating of palladium and palladium alloy membranes is fast becoming an important and enabling technology. This is more so when juxtaposed with the rising demand for high purity hydrogen for application...The electroless plating of palladium and palladium alloy membranes is fast becoming an important and enabling technology. This is more so when juxtaposed with the rising demand for high purity hydrogen for applications particularly in proton exchange membrane fuel cells (PEMFC). The effect of process factors such as sensitization and activation during surface modification, concentration of the reducing agent, plating temperature, time, pH, additives, air aeration on plating efficiency, quality of the palladium film and deposit morphology is reviewed with the aim of identifying areas requiring further investigation. The paper also reviews how these process factors could be optimised for better plating efficiency and overall membrane quality. The concentration of the reducing agent has been identified as the limiting factor on plating efficiency albeit other process factors separately impact on the plating efficiency. Furthermore, bulk precipitation caused by concentration of the reducing agent has been identified as a major problem during electroless plating with hydrazine based plating baths. To ameliorate this problem, a multi step addition of the hydrazine reducer in separate portions has been recommended.展开更多
The material removal rate and required work- piece surface quality of thin-walled structure milling are greatly limited due to its severe vibration, which is directly associated with the dynamic characteristics of the...The material removal rate and required work- piece surface quality of thin-walled structure milling are greatly limited due to its severe vibration, which is directly associated with the dynamic characteristics of the system. Therefore, the suppression of vibration is an unavoidable problem during milling. A novel partial surface damping method is proposed to modify the mode of the thin walled cantilever plate and to suppress vibration during milling. Based on classical plate theory, the design criterion is analyzed and configuration of the partial surface damper is introduced, in which viscoelastic plate and constraining plate are attached to the surface of the plate to increase the system's natural frequency and loss factor. In order to obtain the energy expression of the cutting system, the Ritz method is used to describe the unknown displacements. Then, with Lagrange's equation, the natural frequency and loss factor are calculated. In addition, the plate is divided into a finite number of square elements, and the regulation of treated position is studied based on theoretic and experimental analysis. The milling tests are conducted to verify its damping performance and the experimentalresults show that with treatment of partial surface damper, the deformation of the hare plate is reduced from 0.27 mm to 0.1 mm, while the vibration amplitude of the bare plate is reduced from 0.08 mm to 0.01 mm. The proposed research provides the instruction to design partial surface damper.展开更多
The stability of composite palladium membranes is of key importance for their application in hydrogen energy systems. Most of these membranes are prepared by electroless plating, and beforehand the substrate surface i...The stability of composite palladium membranes is of key importance for their application in hydrogen energy systems. Most of these membranes are prepared by electroless plating, and beforehand the substrate surface is activated by a SnCl_2–PdCl_2 process, but this process leads to a residue of Sn, which has been reported to be harmful to the membrane stability. In this work, the Pd/Al_2O_3 membranes were prepared by electroless plating after the SnCl_2–PdCl_2 process. The amount of Sn residue was adjusted by the SnCl_2 concentration, activation times and additional Sn(OH)_2coating. The surface morphology, cross-sectional structure and elemental composition were analyzed by scanning electron microscopy(SEM), metallography and energy dispersive spectroscopy(EDS), respectively. Hydrogen permeation stability of the prepared palladium membranes were tested at450–600 °C for 400 h. It was found that the higher SnCl_2 concentration and activation times enlarged the Sn residue amount and led to a lower initial selectivity but a better membrane stability. Moreover, the additional Sn(OH)_2coating on the Al_2O_3 substrate surface also greatly improved the membrane selectivity and stability.Therefore, it can be concluded that the Sn residue from the SnCl_2–PdCl_2 process cannot be a main factor for the stability of the composite palladium membranes at high temperatures.展开更多
This process does not use general electroless plating solution containing formaldehyde(carcinogen) and phosphate(the object of waste water regulation). Furthermore, we succeeded in developing a new electroless copper ...This process does not use general electroless plating solution containing formaldehyde(carcinogen) and phosphate(the object of waste water regulation). Furthermore, we succeeded in developing a new electroless copper plating solution which is usable semi-permanently by using the special reducing agent. The electroless deposition forms a very thin conductive film on substrate. Therefore, it can prevent some appearance defects (e.g. pits, pin-holes, laminations and inclusions) that occur in the conventional ones. In addition, it is possible to eliminate electroplating of copper from the process by applying the exclusive nickel solution in electroplating. Therefore, the obtained metal parts can be recycled as high quality stainless steel. Given this copper electroplating-free process, 25 u m-thick nickel deposition at the stage of electroplating, at least, enables the metal layers to show properties as versatile as those of the conventional(its total thickness is 25 n m in the comparative conventional process).展开更多
To further improve the oxidation-resistance of materials and reduce the cost of grid plates in grate-kiln, a new kind of heat-resistant grid plate was developed. The microstructure of this grid plate with a life more ...To further improve the oxidation-resistance of materials and reduce the cost of grid plates in grate-kiln, a new kind of heat-resistant grid plate was developed. The microstructure of this grid plate with a life more than 18 months was studied by XRD, SEM and EDS techniques. The results show that high hardness, high intensity and good impact property make the new kind of heat-resistant grid plate and its oxide film have a higher resistance to deformation and abrasion at 900-1000℃ Besides, small grain size is beneficial to form a complete protective oxide film. The oxide film composed of SiO2 layer, Cr2O3 layer and Fe2O3 layer is rather thin and bonds closely with the backing. The forming of the chemical stable nickel-rich layer increases the density of Cr2O3 layer.展开更多
The shortage of current different approaches of the vehicle license plate(VLP) tilt correction is analyzed in the paper and a new rotary correction method put forward based on the former ways of the VLP tilt correctio...The shortage of current different approaches of the vehicle license plate(VLP) tilt correction is analyzed in the paper and a new rotary correction method put forward based on the former ways of the VLP tilt correction in the horizontal direction and the vertical direction Owing to the VLP tilt taking place in the vertical direction,the array of the image’s pixels of the same column is broken,and even different rows come into being superposition.The VLP tilt taking place in the horizontal direction,by which the array of the image’s pixels of the same row broken,and so much as different columns come into being superposition.展开更多
In the view of Reissner's and Kirchhoff's theories, respectively, we formulate the isotropicalized governing equations for the anisotropic plates, and give the proof of the equivalence relation between these t...In the view of Reissner's and Kirchhoff's theories, respectively, we formulate the isotropicalized governing equations for the anisotropic plates, and give the proof of the equivalence relation between these two plate-models for the simply-supported rectangular orthotropic plates. The well-known fundamental solutions of the isotrqpic plates are utlized for the spline integral equation analysis of anisotropic plates.Even with sparse meshes the satisfactory results can be obtained. The analysis of plates on two-parameter elastic foundation is so simple as the common case that only a few terms should be added to the formulas of fictitious loads.展开更多
Types of bimetal clad plate, manufacturing methods, and their fields of application were summarized. In particular,key aspects of the welding of clad-rolled stainless steel were described, including the weldability of...Types of bimetal clad plate, manufacturing methods, and their fields of application were summarized. In particular,key aspects of the welding of clad-rolled stainless steel were described, including the weldability of the base and clad metals, design criteria for the transition layer, the selection of the type of welding process and consumables used, types of blanking and welding bevels, preparation and assembly prior to welding, welding procedure requirements, post-weld cleaning and heat treatment, and welding quality inspection. This paper will serve as a reference for the welding technology used in future consumer applications in related fields.展开更多
基金Supported by Hi -tech Research and Development Program of China(No. 2001AA421200).
文摘The problem of ship hull plate processing surface fairing with constraints based on B-spline is solved in this paper. The algorithm for B-spline curve fairing with constraints is one of the most common methods in plane curve fairing. The algorithm can be applied to global and local curve fairing. It can constrain the perturbation range of the control points and the shape variation of the curve, and get a better fairing result in plane curves. In this paper, a new fairing algorithm with constraints for curves and surfaces in space is presented. Then this method is applied to the experiments of ship hull plate processing surface. Finally numerical results are obtained to show the efficiency of this method.
文摘The kinematics and dynamics of plate tectonics are frontal subjects in geosciences and the strong earthquake occurred along the plate boundary result directly from plate movement. By analyzing Ibaraki earthquake sequence, it has been found that the focal fault plane shows a special image of grading expansion along the direction of strike and adjustment along the dip direction respectively. With the consideration of strike, dip and slip directions of focal mechanism, we have confirmed that Ibaraki earthquake belongs to a thrust fault earthquake occurred under the Japan Trench. The cause of the earthquake sequence is discussed in the paper. The study on the temporal-spatial distribution of the earthquake sequence with a time-scale between the year-scale spatial geodetic data and the second-scale moment tensor of the strong earthquake has indicated the dynamic process of Pacific Plate subduction under the Eurasia Plate. According to the average slip distance of earthquake and the velocity of plate movement, it is predicted that a strong earthquake might occur in recent years.
文摘Thick metal plate rolling process has become more and more important in building a flat roof of drilling on the bottom at sea. This is because not only the product quality requirement higher and higher but also the marketing competition. To improve the process of thick metal plate rolling and to increase productivity a numerical controlled rolling process is developed, which include the process planning, the mathematical model establishment and the numerical control system development. The process is for the 17 000 kN×3 000 mm movable up roller bending machine. According to the machine configuration non-symmetry rolling process is planed. This makes it possible to integrate all the steps of plate shaping up such as end side bending, several times of semi-shape bending and the last shape finishing. Since the process will perform under the numerical controlled condition whole steps of the process are considered can be worked in the automatic cycle. The mathematic model consists of two sections, the theory model and the experience parameters model. Which takes the original plate parameters such as geometry and mechanics, characters of the machine such as the movement limits, tonnage and so on as input and calculates all the parameters needed in process performing. Meanwhile, the mathematic Model is totally adapted to the control system. The numerical control system development scheme is based on all the works above. Here, a system plan is provided. The functional modules and hardware selection, in detail, are introduced. The system software on top level and the controlling software for controller are developed. And some unit techniques in the system such as timer setting, communication between system and controller, video integration, and the ability of resisting impact force are introduced. The process has been used successfully in production for more than two years. Practice approves that the process is robust.
文摘Analyzed and studied the characters of high strength low alloy steel which contain Mo,Cr,Nb and Ni.etc.Following actual rolling,combining the feature of rolling mode,and exploiting the equipment advantage of 5 m Heavy Plate Mill,optimized the material design,heating temperature and rolling method, stabilized rolling process of thin alloyed steel,the quality index was advanced.
文摘The dimension variation of B610E steel during the quenching and tempering process was simulated by ABAQUS,the coefficient of heat transfer during quenching was verified by the buried thermocouple test and the trend of the dimension variation during the quenching process was also calculated by ABAQUS. It was shown by the comparison of simulated results and industrially measured results that only the simulation of thickness and width variation was accurate, while length variation needed further simulation. Besides, the dimension variation trend was identical with the measured results.
文摘A plate's internal quality is very critical, especially for boilers and high-pressure vessels. The ultrasonic test (UT) is the main type of non-destructive flaw detection for heavy plates, which is important because one of the main reasons for plate defects is ultrasonic flaws. This study, based on Baosteel' s practical experience in the manufacture of heavy plates, elucidates the cause of defect formation by analyzing ultrasonic flaw testing maps and using special equipment, such as the scanning electron microscope, electron probe and the optical microscope. The author puts forward the following improvement measures: ① Ultrasonic flaws are caused by central porosity and segregation,[H] bubbles and inclusion in slabs.②Ultrasonic flaws are more likely to occur in the bottom and top of slabs rather than the other positions in the casting sequence. It is clear that one-quarter of the inner camber' s thickness is accumulated inclusion.③It is clear that overheating in the tundish and the flow of the casting mould have an effect on ultrasonic flaws caused by inclusions.④Soft reduction improves central porosity and segregation,which decreases the number of ultrasonic flaws in the plate.
文摘To ensure the quality of heavy plate products as determined by ultrasonic inspection, it is necessary to effectively control defects such as cracks and shrinkage cavities in heavy plates. Generally, some defects such as large size cracks exist due to insufficient deformation in the center of traditionally rolled plates. Compared with the traditional rolling process, gradient temperature rolling(GTR) process can effectively increase deformation inside heavy plates. In this study, the effect of GTR on crack healing was analyzed through a comparison experiment with the uniform temperature rolling(UTR). The results show that the GTR process could increase the plastic strain inside the heavy plate and effectively promote the healing process of the preset cracks. The degrees of crack healing at the center and quarter thickness position of the steel plate via GTR were greater than twice those of the plate via UTR. The GTR process can significantly reduce the internal defects of heavy plates and improve the defect detection level of heavy plate products. Also, The GTR process results in the formation of new crystal grains in the crack region, which is crucial to crack healing.
文摘In this research we presented a non-cyanide plating process of Ni-P alloy coating on Mg alloy AZ91D. By applying a new process flow of electroless nickel plating in which zinc coating is used as transition of Ni-P coating on Mg alloy AZ91D, the process of copper transition coating plated in the cyanides bath can be replaced. A new bath composed of NiSO4 was established by orthogonal test. The results show that zinc transition coating can increase the adhesion and protect the Mg alloy substrate from the bath corrosion. The optimal plating bath composition is NiSO4·6H2O 20 g/L, NaH2PO2·H2O20g/L and C6H8O7·H2O 2.5 g/L, and optimal bath acidity and optimal plating temperature are pH 4.0 and 95℃, respectively. The present process flow is composed of ultrasonic cleaning→alkaline cleaning→acid pickling→activation→double immersing zinc→electroplating zinc→electroless nickel plating→passivation treatment. The present non-cyanide process of electroless nickel plating is harmless to our surroundings and Ni-P coating on Mg alloy AZ91D produced by present process possesses good adhesion and corrosion resistance.
文摘A reasonable pre-treatment and an ultrasonic pre-plating Cu film were applied for sintering NdFeB permanent magnet. The samples were then plated in neutral bath (PH=7) for 40min and in acidic bath (PH=4.8~5.1) for 2h. A composite electroless plating with different phosphor content was obtained. The results show that the composite plating coatings are dense and have a strong bond with the substrate, which contribute to the excellent corrosion resistance of the plating coating.
文摘The electroless plating of palladium and palladium alloy membranes is fast becoming an important and enabling technology. This is more so when juxtaposed with the rising demand for high purity hydrogen for applications particularly in proton exchange membrane fuel cells (PEMFC). The effect of process factors such as sensitization and activation during surface modification, concentration of the reducing agent, plating temperature, time, pH, additives, air aeration on plating efficiency, quality of the palladium film and deposit morphology is reviewed with the aim of identifying areas requiring further investigation. The paper also reviews how these process factors could be optimised for better plating efficiency and overall membrane quality. The concentration of the reducing agent has been identified as the limiting factor on plating efficiency albeit other process factors separately impact on the plating efficiency. Furthermore, bulk precipitation caused by concentration of the reducing agent has been identified as a major problem during electroless plating with hydrazine based plating baths. To ameliorate this problem, a multi step addition of the hydrazine reducer in separate portions has been recommended.
基金Supported by National Natural Science Foundation of China(Grant No.51575319)Young Scholars Program of Shandong University(Grant No.2015WLJH31)+1 种基金Major National Science and Technology Project of China(Grant No.2014ZX04012-014)Tai Shan Scholar Foundation,China(Grant No.TS20130922)
文摘The material removal rate and required work- piece surface quality of thin-walled structure milling are greatly limited due to its severe vibration, which is directly associated with the dynamic characteristics of the system. Therefore, the suppression of vibration is an unavoidable problem during milling. A novel partial surface damping method is proposed to modify the mode of the thin walled cantilever plate and to suppress vibration during milling. Based on classical plate theory, the design criterion is analyzed and configuration of the partial surface damper is introduced, in which viscoelastic plate and constraining plate are attached to the surface of the plate to increase the system's natural frequency and loss factor. In order to obtain the energy expression of the cutting system, the Ritz method is used to describe the unknown displacements. Then, with Lagrange's equation, the natural frequency and loss factor are calculated. In addition, the plate is divided into a finite number of square elements, and the regulation of treated position is studied based on theoretic and experimental analysis. The milling tests are conducted to verify its damping performance and the experimentalresults show that with treatment of partial surface damper, the deformation of the hare plate is reduced from 0.27 mm to 0.1 mm, while the vibration amplitude of the bare plate is reduced from 0.08 mm to 0.01 mm. The proposed research provides the instruction to design partial surface damper.
基金Supported by the National High Technology Research and Development Program of China(863 Program,2009AA05ZI03)the Natural Science Foundation of Jiangsu Province(BK 20130940,BK 20130916)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘The stability of composite palladium membranes is of key importance for their application in hydrogen energy systems. Most of these membranes are prepared by electroless plating, and beforehand the substrate surface is activated by a SnCl_2–PdCl_2 process, but this process leads to a residue of Sn, which has been reported to be harmful to the membrane stability. In this work, the Pd/Al_2O_3 membranes were prepared by electroless plating after the SnCl_2–PdCl_2 process. The amount of Sn residue was adjusted by the SnCl_2 concentration, activation times and additional Sn(OH)_2coating. The surface morphology, cross-sectional structure and elemental composition were analyzed by scanning electron microscopy(SEM), metallography and energy dispersive spectroscopy(EDS), respectively. Hydrogen permeation stability of the prepared palladium membranes were tested at450–600 °C for 400 h. It was found that the higher SnCl_2 concentration and activation times enlarged the Sn residue amount and led to a lower initial selectivity but a better membrane stability. Moreover, the additional Sn(OH)_2coating on the Al_2O_3 substrate surface also greatly improved the membrane selectivity and stability.Therefore, it can be concluded that the Sn residue from the SnCl_2–PdCl_2 process cannot be a main factor for the stability of the composite palladium membranes at high temperatures.
文摘This process does not use general electroless plating solution containing formaldehyde(carcinogen) and phosphate(the object of waste water regulation). Furthermore, we succeeded in developing a new electroless copper plating solution which is usable semi-permanently by using the special reducing agent. The electroless deposition forms a very thin conductive film on substrate. Therefore, it can prevent some appearance defects (e.g. pits, pin-holes, laminations and inclusions) that occur in the conventional ones. In addition, it is possible to eliminate electroplating of copper from the process by applying the exclusive nickel solution in electroplating. Therefore, the obtained metal parts can be recycled as high quality stainless steel. Given this copper electroplating-free process, 25 u m-thick nickel deposition at the stage of electroplating, at least, enables the metal layers to show properties as versatile as those of the conventional(its total thickness is 25 n m in the comparative conventional process).
文摘To further improve the oxidation-resistance of materials and reduce the cost of grid plates in grate-kiln, a new kind of heat-resistant grid plate was developed. The microstructure of this grid plate with a life more than 18 months was studied by XRD, SEM and EDS techniques. The results show that high hardness, high intensity and good impact property make the new kind of heat-resistant grid plate and its oxide film have a higher resistance to deformation and abrasion at 900-1000℃ Besides, small grain size is beneficial to form a complete protective oxide film. The oxide film composed of SiO2 layer, Cr2O3 layer and Fe2O3 layer is rather thin and bonds closely with the backing. The forming of the chemical stable nickel-rich layer increases the density of Cr2O3 layer.
文摘The shortage of current different approaches of the vehicle license plate(VLP) tilt correction is analyzed in the paper and a new rotary correction method put forward based on the former ways of the VLP tilt correction in the horizontal direction and the vertical direction Owing to the VLP tilt taking place in the vertical direction,the array of the image’s pixels of the same column is broken,and even different rows come into being superposition.The VLP tilt taking place in the horizontal direction,by which the array of the image’s pixels of the same row broken,and so much as different columns come into being superposition.
文摘In the view of Reissner's and Kirchhoff's theories, respectively, we formulate the isotropicalized governing equations for the anisotropic plates, and give the proof of the equivalence relation between these two plate-models for the simply-supported rectangular orthotropic plates. The well-known fundamental solutions of the isotrqpic plates are utlized for the spline integral equation analysis of anisotropic plates.Even with sparse meshes the satisfactory results can be obtained. The analysis of plates on two-parameter elastic foundation is so simple as the common case that only a few terms should be added to the formulas of fictitious loads.
文摘Types of bimetal clad plate, manufacturing methods, and their fields of application were summarized. In particular,key aspects of the welding of clad-rolled stainless steel were described, including the weldability of the base and clad metals, design criteria for the transition layer, the selection of the type of welding process and consumables used, types of blanking and welding bevels, preparation and assembly prior to welding, welding procedure requirements, post-weld cleaning and heat treatment, and welding quality inspection. This paper will serve as a reference for the welding technology used in future consumer applications in related fields.