Thermally insulating and fire-retardant bio-mimic structural composites with a negative Poisson's ratio for battery protection

Battery safety has attracted considerable attention worldwide due to the rapid development of wearable electronics and the steady increase in the production and use of electric vehicles.As battery failures are often associated with mechanical-thermal coupled behaviors,protective shielding materials with excellent mechanical robustness and flame-retardant properties are highly desired to mitigate thermal runaway.However,most of the thermal insulating materials are not strong enough to protect batteries from mechanical abuse,which is one of the most critical scenarios with catastrophic consequences.Here,inspired by wood,we have developed an effective approach to engineer a hierarchical nanocomposite via self-assembly of calcium silicate hydrate and polyvinyl alcohol polymer chains(referred as CSH wood).The versatile protective material CSH wood demonstrates an unprecedented combination of light weight(0.018 g cm-3),high stiffness(204 MPa in the axial direction),negative Poisson's ratio(-0.15),remarkable toughness(6.67×105 J m-3),superior thermal insulation(0.0204 W m-1 K-1 in the radial direction),and excellent fire retardancy(UL94-V0).When applied as a protective cover or a protective layer within battery packages,the tough CSH wood can resist high-impact load and block heat diffusion to block or delay the spread of fire,therefore significantly reducing the risk of property damage or bodily injuries caused by battery explosions.This work provides new pathways for fabricating advanced thermal insulating materials with large scalability and demonstrates great potential for the protection of electronic devices.

Statics, vibration, and buckling of sandwich plates with metamaterial cores characterized by negative thermal expansion and negative Poisson's ratio

This paper proposes a three-dimensional(3D)Maltese cross metamaterial with negative Poisson’s ratio(NPR)and negative thermal expansion(NTE)adopted as the core layers in sandwich plates,and aims to explore the relations between the mechanical responses of sandwich composites and the NPR or NTE of the metamaterial.First,the NPR and NTE of the metamaterial are derived analytically based on energy conservation.The effective elastic modulus and mass density of the 3D metamaterial are obtained and validated by the finite element method(FEM).Subsequently,the general governing equation of the 3D sandwich plate under thermal environments is established based on Hamilton’s principle with the consideration of the von Kármán nonlinearity.The differential quadrature(DQ)FEM(DQFEM)is utilized to obtain the numerical solutions.It is shown that NPR and NTE can enhance the global stiffness of sandwich structures.The geometric parameters of the Maltese cross metamaterial significantly affect the responses of the thermal stress,natural frequency,and critical buckling load.

Machine learning-based stiffness optimization of digital composite metamaterials with desired positive or negative Poisson's ratio

Mechanical metamaterials such as auxetic materials have attracted great interest due to their unusual properties that are dictated by their architectures.However,these architected materials usually have low stiffness because of the bending or rotation deformation mechanisms in the microstructures.In this work,a convolutional neural network(CNN)based self-learning multi-objective optimization is performed to design digital composite materials.The CNN models have undergone rigorous training using randomly generated two-phase digital composite materials,along with their corresponding Poisson's ratios and stiffness values.Then the CNN models are used for designing composite material structures with the minimum Poisson's ratio at a given volume fraction constraint.Furthermore,we have designed composite materials with optimized stiffness while exhibiting a desired Poisson's ratio(negative,zero,or positive).The optimized designs have been successfully and efficiently obtained,and their validity has been confirmed through finite element analysis results.This self-learning multi-objective optimization model offers a promising approach for achieving comprehensive multi-objective optimization.

Switchable hidden spin polarization and negative Poisson's ratio in two-dimensional antiferroelectric wurtzite crystals

Two-dimensional(2D)antiferroelectric materials have raised great research interest over the last decade.Here,we reveal a type of 2D antiferroelectric(AFE)crystal where the AFE polarization direction can be switched by a certain degree in the 2D plane.Such 2D functional materials are realized by stacking the exfoliated wurtzite(wz)monolayers with“self-healable”nature,which host strongly coupled ferroelasticity/antiferroelectricity and benign stability.The AFE candidates,i.e.,Zn X and Cd X(X=S,Se,Te),are all semiconductors with direct bandgap atΓpoint,which harbors switchable antiferroelectricity and ferroelasticity with low transition barriers,hidden spin polarization,as well as giant in-plane negative Poisson's ratio(NPR),enabling the co-tunability of hidden spin characteristics and auxetic magnitudes via AFE switching.The 2D AFE wz crystals provide a platform to probe the interplay of 2D antiferroelectricity,ferroelasticity,NPR,and spin effects,shedding new light on the rich physics and device design in wz semiconductors.

Research on Dynamic and Static Test Methods for Evaluating the Poisson's Ratio of Orien ted Strand Board

In this article,dynamic method and static method of testing Poisson's ratio of OSB(Oriented Strand Board)were proposed.Through modal and static numerical analyses,the position where the transverse stress is equal to zero was determined.The binary linear regression method was applied to express the gluing position of the strain gauge as a relational express ion that depended on the length-width ratio and width-thickness ratio of the canti-lever plate.Then the longitudinal and transverse Poisson's ratios of OSB were mea sured by the given dynamic and static methods.In addition,the test results of OSB Poisson's ratio were analyzed with the probability distribution of random variables.The results showed that using the proposed dynamic method and static method,the test results for longitudinal and transverse Poisson's ratios of OSB were quite consistent,despite the gluing position of the strain gauges being different.And these OSB Poisson's ratios were accorded with that obtained by the axial tensile method and the four-point bending method.OSB longitudinal and transverse Poisson's ratios followed Weibull distribution.

Upper crustal Poisson's ratio and coda-wave attenuation beneath Eastern Anatolia

The attenuation of seismic waves reflects the elastic nature of the media within which the waves propagate.In this study,we calculate the Coda-Q(Qc),frequency dependence(η),Vp/Vs and Poisson's(υ)ratios by using 2621 vertical component seismograms generated by 987 earthquakes recorded by 13 seismic stations in Eastern Anatolia,and creat a 2-D seismic tomographic Qc model for the region.The obtained model provides significant information for exploring the boundaries of adjacent tectonic units within the upper crust and interpreting their dynamic characteristics.The 2-D Qc model and the other parameters are consistent with the seismotectonic features of Eastern Anatolia.Highly heterogeneous Qc values are observed in the study area dividing it into north-south directed bands of low and high attenuation.The highestηvalues were obtained beneath the northwestern and eastern parts of the study region.Clear,high and lowυvalues are obtained in the western and eastern parts of the study area,respectively.The spatial variations in the measured parameters are consistent with many geophysical observations including low Pn velocities,efficient Sn blockage,high heat flow,and widespread volcanism.Different upper crustal thicknesses and inhomogeneous stress distribution along the East and North Anatolian Fault Zones may also contribute to the observed heterogeneities.

Effects of porosity on seismic velocities, elastic moduli and Poisson's ratios of solid materials and rocks

The generalized mixture rule(GMR) is used to provide a unified framework for describing Young's(E),shear(G) and bulk(K) moduli, Lame parameter(l), and P- and S-wave velocities(V_p and V_s) as a function of porosity in various isotropic materials such as metals, ceramics and rocks. The characteristic J values of the GMR for E, G, K and l of each material are systematically different and display consistent correlations with the Poisson's ratio of the nonporous material(v_0). For the materials dominated by corner-shaped pores, the fixed point at which the effective Poisson's ratio(n) remains constant is at v_0=0.2, and J(G) > J(E) > J(K) > J(l) and J(G) < J(E) < J(K) < J(l) for materials with v_0> 0.2 and v_0< 0.2, respectively.J(V_s) > J(V_p) and J(V_s) < J(V_p) for the materials with v_0 > 0.2 and v_0< 0.2, respectively. The effective n increases, decreases and remains unchanged with increasing porosity for the materials with v_0 < 0.2,v_0 > 0.2 and v_0 =0.2, respectively. For natural rocks containing thin-disk-shaped pores parallel to mineral cleavages, grain boundaries and foliation, however, the n fixed point decreases nonlinearly with decreasing pore aspect ratio(a: width/length). With increasing depth or pressure, cracks with smaller a values are progressively closed, making the n fixed point rise and finally reach to the point at v_0=0.2.

Crustal thicknesses and Poisson's ratios beneath the Chuxiong-Simao Basin in the Southeast Margin of the Tibetan Plateau

In the Southeast Margin of the Tibetan Plateau, low-velocity sedimentary layers that would significantly affect the accuracy of the H-κ stacking of receiver functions are widely distributed.In this study, we use teleseismic waveform data of 475 events from 97 temporary broadband seismometers deployed by ChinArray Phase I to obtain crustal thicknesses and Poisson's ratios within the Chuxiong-Simao Basin and adjacent area, employing an improved method in which the receiver functions are processed through a resonance-removal filter, and the H-κ stacking is time-corrected.Results show that the crustal thickness ranges from 30 to 55 km in the study area, reaching its thickest value in the northwest and thinning toward southwest, southeast and northeast.The apparent variation of crustal thickness around the Red River Fault supports the view of southeastern escape of the Tibetan Plateau.Relatively thin crustal thickness in the zone between Chuxiong City and the Red River Fault indicates possible uplift of mantle in this area.The positive correlation between crustal thickness and Poisson's ratio is likely to be related to lower crust thickening.Comparison of results obtained from different methods shows that the improved method used in our study can effectively remove the reverberation effect of sedimentary layers.

Negative Poisson's ratio and peripheral strain of an NPR anchor cable

Materials with a negative Poisson’s ratio effect perform significantly better than traditional materials for rock mass impact resistance,shear resistance,and energy absorption.Based on these advantages,a negative Poisson’s ratio anchor cable(NPR anchor cable)with high elongation and constant resistance was developed and successfully applied in the field of mine disaster control.However,theoretical and experimental research on the negative Poisson’s ratio effect and peripheral strain characteristics of NPR anchor cables is currently incomplete.This study used several theories and methods,such as static tensile,peripheral strain measurement,and static negative Poisson’s ratio measurement,to investigate the radial deformation law of an NPR anchor cable and the negative Poisson’s ratio characteristics.Experimental results elucidated constant resistance changes in an NPR anchor cable during operation,the motion of the constant resistance body in the constant resistance sleeve,and the deformation law of the constant resistance sleeve.Negative Poisson’s ratio characteristics of the NPR anchor cable and its superior energy absorption characteristics were verified and it provided a theoretical and experimental basis for energy absorption mechanisms of an NPR anchor cable.

A note on influence of stress anisotropy on the Poisson's ratio of dry sand

In this study, extender and bender element tests were conducted investigating the small-strain Poisson's ratio of variable sands, with a focus on the effect of stress anisotropy in order to quantify the sensitivity of Poisson's ratio to the applied deviatoric stress. Four different uniform sands were tested, including a biogenic sand, a crushed rock and two natural sands, covering a wide range of particle shapes. From these sands, eleven samples were prepared in the laboratory and were tested under variable stress paths,maintaining a constant mean effective pressure while increasing the deviatoric compressive load. Under the application of these given stress paths, the data analysis indicated that the sensitivity of Poisson's ratio to the stress ratio was more pronounced for sands with irregularly shaped particles in comparison to sands with fairly rounded and spherical grains. For sands with very irregularly shaped particles, the increase of Poisson's ratio from the isotropic to the anisotropic stress state reached 50%, while this increase for natural sands with fairly rounded particles was in the order of 20%.

Study of crustal thickness and poisson's ratio of the south of Erenhot area by teleseismic receiver function

The Xing'an Mongolian Orogenic Belt(XMOB) and the northern margin of North China Craton(NCC) have undergone multistage tectonic superimposition and the tectonic evolution is extremely complicated. We collect the teleseismic data of 44 temporary broadband seismic stations deployed in the XMOB and the northern margin of NCC to calculate the P wave receiver functions. The crustal thickness and average crustal ratio as well as the Poisson's ratios beneath 33 stations are estimated using the H-κ stacking method. The results show:(1) the crustal thickness of the study area ranges from 38.7 to 42.7 km, with an average thickness of 41.2 km. There is a great difference in crustal thickness on both sides of Solonker suture zone. The characteristics of crustal thickness support the geodynamic model that the Paleo-Asian Ocean subducted and closed at the Solonker suture zone.(2) The Poisson's ratios in the study area are low, ranging from 0.215 to 0.277, with an average value of 0.243, suggesting that the rock composition of the area is dominated by felsic-acid rocks.(3) There exists a negative correlation between the Poisson's ratio and the crustal thickness. Combined with the lower values of Poisson's ratio, we speculate that the delamination is the major mechanism in crustal extension and thinning in the study area.

Modeling of Fatigue Crack Growth Closure Considering the Integrative Effect of Cyclic Stress Ratio,Specimen Thickness and Poisson's Ratio

Key components of large structures in aeronautics industry are required to be made light and have long enough fatigue lives.It is of vital importance to estimate the fatigue life of these structures accurately.Since the FCG process is affected by various factors,no universal model exists due to the complexity of the mechanisms.Most of the existing models are obtained by fitting the experimental data and could hardly describe the integrative effect of most existing factors simultaneously.In order to account for the integrative effect of specimen parameters,material property and loading conditions on FCG process,a new model named integrative influence factor model(IIF) is proposed based on the plasticity-induced crack closure theory.Accordingly to the predictions of crack opening ratio(γ) and effective stress intensity factor range ratio(U) with different material under various loading conditions,predictions of γ and U by the IIF model are completely identical to the theoretical results from the plane stress state to the plane strain state when Poisson's ratio equals 1/3.When Poisson's ratio equals 0.3,predictions of γ and U by the IIF model are larger than the predictions by the existing model,and more close to the theoretical results.In addition,it describes the influence of R ratios on γ and U effectively in the whole region from-1.0 to 1.0.Moreover,several sets of test data of FCG rates in 5 kinds of aluminum alloys with various specimen thicknesses under different loading conditions are used to validate the IIF model,most of the test data are situated on the predicted curves or between the two curves that represent the specimen with different thicknesses under the same stress ratio.Some of the test data slightly departure from the predictions by the IIF model due to the surface roughness and errors in measurement.Besides,based on the analysis of the physical rule of crack opening ratios,a relative thickness of specimen is defined to describe the influence of material property,specimen thickness and so forth on FCG characteristics conveniently.In conclusion,the relative thickness of specimen simplifies the expression of FCG characteristic and provides a general parameter to analyze the fatigue characteristics of different materials with various thicknesses under different loading conditions.The IIF model describes the integrative effect of existing influence factors explicitly and quantitatively,and provides a helpful tool for fatigue property estimation of practical component and experiment design.

Near-zero Poisson's ratio and suppressed mechanical anisotropy in strained black phosphorene/SnSe van der Waals heterostructure:a first-principles study

Black phosphorene(BP)and its analogs have attracted intensive attention due to their unique puckered structures,anisotropic characteristics,and negative Poisson’s ratio.The van der Waals(vdW)heterostructures assembly by stacking different materials show novel physical properties,however,the parent materials do not possess.In this work,the first-principles calculations are performed to study the mechanical properties of the vdW heterostructure.Interestingly,a near-zero Poisson’s ratio ν_(zx)is found in BP/SnSe heterostructure.In addition,compared with the parent materials BP and SnSe with strong in-plane anisotropic mechanical properties,the BP/SnSe heterostructure shows strongly suppressed anisotropy.The results show that the vdW heterostructure has quite different mechanical properties compared with the parent materials,and provides new opportunities for the mechanical applications of the heterostructures.

Crustal Poisson's ratio anomalies in the eastern part of North China and their origins

Seismic tomography can provide both fine P-wave and S-wave velocity structures of the crust and upper mantle.In addition,with proper computation,Poisson's ratio images from the seismic velocities can be determined.However,it is unknown whether Poisson's ratio images have any advantages when compared with the P-wave and S-wave velocity images.For the purposes of this study,high-resolution seismic tomography under the eastern part of North China region was used to determine detailed 3-D crustal P- and S-wave seismic velocities structure,as well as Poisson's ratio images.Results of Poisson's ratio imaging show high Poisson's ratio(high-PR) anomalies located in the Hengshan-North Taihang-Zhangjiakou(H-NT-Z) region,demonstrating that Poisson's ratio imaging can provide new geophysical constraints for regional tectonic evolution.The H-NT-Z region shows a prominent and continuous high-PR anomaly in the upper crust.Based on Poisson's ratio images at different depths, we find that this high-PR anomaly is extending down to the middle crust with thickness up to about 26 km.According to rock physical property measurements and other geological data,this crustal Poisson's ratio anomaly can be explained by Mesozoic partial melting of the upper mantle and basaltic magma underplating related to the lithospheric thinning of the North China craton.

Characterization of the Crustal Thickness and Poisson's Ratio of the Binchuan Region

This paper presents the changes of crust thickness and Poissons ratios distribution in the Binchuan region,where the first air-gun transmitting station and its a small dense array were deployed.From September 2011 to January 2014,more than 239 teleseismic events of M≥6.0 were recorded in 16 stations in the Binchuan region.Their P-wave receiver functions were analyzed respectively.The high spatial resolution result shows that the average crust thickness of Binchuan region is 45.3km,it follows the rule of"deeper in the north and east part,shallower in the south and west part."The deepest region is in Xiaoyindian Station;the crust thickness is 47.9km;the shallowest region is in Paiying Station,it has the thickness of 42.1km.It shows that the deeper Moho surface nearby the Chenghai fault and shallower nearby the Honghe fault;the isoline distribution of thickness changes greatly nearby the Chenghai fault and slowly nearby the Honghe fault.From the distribution of Poissons ratios,it is unevenly in the study area with a great difference from the north part to the south part,which shows a characteristic of"lower in the north,higher in the south".The Poissons ratio nearby the Honghe fault is medium too high(0.26≤σ≤0.29);lower nearby the Chenghai fault(σ≤0.26).This paper concludes the possible reason of different characteristic between Poissons ratio and crust thickness is thicker in the upper crust in the Binchuan region.

基于改进Ratio统计量的重尾AR(p)时间序列均值变点检验

文章提出两个改进的Ratio统计量来研究重尾AR(p)时间序列均值变点检验问题,在原假设下推导了统计量的渐近分布,且在备择假设下证明了其一致性。由于重尾指数未知且难以估计,因此结合Wild Bootstrap重抽样方法来确定渐近分布的临界值;在均值变点存在的情形下,给出了变点位置的一致估计量。数值模拟结果表明:统计量的临界值均不受重尾指数和自回归系数的影响,其经验水平和经验势均取得满意的效果;尤其在原假设下,积分型Ratio统计量的经验水平表现出更好的稳健性,而在备择假设下,最值型Ratio统计量则具备更好的显著性。最后,基于一组股票数据,从实际应用角度进一步阐明所提方法的有效性和可行性。

Predictive Ability of Hypertriglyceridemic Waist,Hypertriglyceridemic Waist-to-Height Ratio,and Waist-to-Hip Ratio for Cardiometabolic Risk Factors Clustering Screening among Chinese Children and Adolescents

Objective Hypertriglyceridemic waist(HW),hypertriglyceridemic waist-to-height ratio(HWHtR),and waist-to-hip ratio(WHR)have been shown to be indicators of cardiometabolic risk factors.However,it is not clear which indicator is more suitable for children and adolescents.We aimed to investigate the relationship between HW,HWHtR,WHR,and cardiovascular risk factors clustering to determine the best screening tools for cardiometabolic risk in children and adolescents.Methods This was a national cross-sectional study.Anthropometric and biochemical variables were assessed in approximately 70,000 participants aged 6–18 years from seven provinces in China.Demographics,physical activity,dietary intake,and family history of chronic diseases were obtained through questionnaires.ANOVA,χ2 and logistic regression analysis was conducted.Results A significant sex difference was observed for HWHtR and WHR,but not for HW phenotype.The risk of cardiometabolic health risk factor clustering with HW phenotype or the HWHtR phenotype was significantly higher than that with the non-HW or non-HWHtR phenotypes among children and adolescents(HW:OR=12.22,95%CI:9.54-15.67;HWHtR:OR=9.70,95%CI:6.93-13.58).Compared with the HW and HWHtR phenotypes,the association between risk of cardiometabolic health risk factors(CHRF)clustering and high WHR was much weaker and not significant(WHR:OR=1.14,95%CI:0.97-1.34).Conclusion Compared with HWHtR and WHR,the HW phenotype is a more convenient indicator with higher applicability to screen children and adolescents for cardiovascular risk factors.

Neutrophil-to-lymphocyte ratio and platelet-to-lymphocyte ratio:Markers predicting immune-checkpoint inhibitor efficacy and immune-related adverse events

We conducted a comprehensive review of existing prediction models pertaining to the efficacy of immune-checkpoint inhibitor(ICI)and the occurrence of immune-related adverse events(irAEs).The predictive potential of neutrophil-to-lymphocyte ratio(NLR)and platelet-to-lymphocyte ratio(PLR)in determining ICI effectiveness has been extensively investigated,while limited research has been conducted on predicting irAEs.Furthermore,the combined model incor-porating NLR and PLR,either with each other or in conjunction with additional markers such as carcinoembryonic antigen,exhibits superior predictive capabilities compared to individual markers alone.NLR and PLR are promising markers for clinical applications.Forthcoming models ought to incorporate established efficacious models and newly identified ones,thereby constituting a multifactor composite model.Furthermore,efforts should be made to explore effective clinical application approaches that enhance the predictive accuracy and efficiency.

Isotopic dependence of the yield ratios of light fragments from different projectiles and their unified neutron skin thicknesses

The yield ratios of neutron-proton(R(n/p))and^(3)H-^(3)He(R(^(3)H∕^(3)He))with reduced rapidity from 0 to 0.5 were simulated at 50 MeV/u even-even ^(36−56)Ca+^(40)Ca,even-even ^(48−78)Ni+^(58)Ni,and ^(100−139)Sn(every third isotopes)+112 Sn for full reduced impact parameters using the isospin-dependent quantum molecular dynamics(IQMD)model.The neutron and proton density distributions and root-mean-square radii of the reaction systems were obtained using the Skyrme-Hartree-Fock model,which was used for the phase space initialization of the projectile and target in IQMD.We defined the unified neutron skin thickness asΔRnp=<r^(2)>^(1∕2) n−<r^(2)>^(1∕2)p,which was negative for neutron-deficient nuclei.The unifiedΔRnp values for nuclei with the same relative neutron excess from different isotopic chains were nearly equal,except for extreme neutron-rich isotopes,which is a type of scaling behavior.The yield ratios of the three isotopic chain-induced reactions,which depended on the reduced impact parameter and unified neutron skin thickness,were studied.The results showed that both R(n/p)and R(^(3)H∕^(3)He)decreased with a reduced impact parameter for extreme neutron-deficient isotopes;however,they increased with reduced impact parameters for extreme neutron-rich isotopes,and increased with theΔRnp of the projectiles for all reduced impact parameters.In addition,a scaling phenomenon was observed betweenΔR np and the yield ratios in peripheral colli-sions from different isotopic chain projectiles(except for extreme neutron-rich isotopes).Thus,R(n/p)and R(^(3)H∕^(3)He)from peripheral collisions were suggested as experimental probes for extracting the neutron or proton skin thicknesses of non-extreme neutron-rich nuclei from different isotopic chains.

Optimal scheduling of a township integrated-energy system using the adjustable heat-electricity ratio model

With the expansion and implementation of rural revitalization strategies,there is a constant need for new energy sources for the construction of new townships.Consequently,integrated energy systems with the interconnection and interaction of multiple energy sources are developing rapidly.Biomass energy,a renewable green energy source with low pollution and wide distribution,has significant application potential in integrated energy systems.Considering the application of biomass energy in townships,this study established an integrated biomass energy system and proposed a model to optimize its operation.Lowest economic cost and highest clean energy utilization rate were considered as the objective functions.In addition,a plan was suggested to adjust the heat-electricity ratio based on the characteristics of the combined heat and power of the biomass.Finally,a simulation analysis conducted for a town in China was discussed,demonstrating that the construction of a township integrated-energy system and the use of biomass can significantly reduce operating costs and improve the energy utilization rate.Moreover,by adjusting the heat-electricity ratio,the economic cost was further reduced by 6.70%,whereas the clean energy utilization rate was increased by 5.14%.