聚萘乙炔的光致发光与电致发光

用可溶性前聚物法制备的聚 １，４萘乙炔（ Ｐ Ｎ Ｖ）制成单层有机电致发光器件。该器件阳极为 Ｉ Ｔ Ｏ，阴极为 Ｃａ，器件在正向偏压４ Ｖ 左右时开始发光，发光谱峰值为６０５ ｎｍ ，最高亮度为１４０ Ｃｄ／ｍ ２ 。文章分析了 Ｐ Ｎ Ｖ 发光器件的发光机理，并给出了器件的能带模型。

丁氧基聚萘乙炔-漆酚缩醛抗静电涂料的研制

用丁氧基聚萘乙炔／漆酚缩醛树脂制成的抗静电涂料，具有良好的耐溶剂、耐油品、耐腐蚀性和导电稳定性，能克服传统的掺合型抗静电涂料中所存在的缺陷。

聚(β-烷氧基)对萘乙炔的超声合成

Poly(β-alkoxy,naphthalene vinylene) (PAONV) was synthesized from β-naphthol and H(CH2)mBr(m=4,6,8,9) under ultrasonic irradiation.The influences of reaction conditions on the yield of intermediates and polymers were studied.The structure of intermediates and polymers were characterized with IR and 1H NMR spectroscopy.These results showed that the total yield of PAONV under ultrasonic irradiation was 70.0%—74.4%,higher than that under reflux stirring.The reaction time was shortened from 35 h to 20 h.The yield of etherification in the C2H5ONa system was higher than that in the NaOH system.The dimetyl sufoxide as a strong polar solvent favored the yield of dehydrochlorination.The best reaction times of etherification, chloromethylation, dehydrochlorination were 5 h,5 h,10 h,respectively.

聚单乙氧基萘乙炔(PEONV)的电致发光特性

用可溶性前聚物法制备了单乙氧基取代的聚1．4萘乙炔（PEONV）。并采用PEONV作为有源层制作了单层结构电致发光器件。该器件的阳极为ITO，阴极为Ca，器件在正向偏压4V时开始发光，发光谱峰值605nm。最高亮度为156cd／m2。发光峰与未取代的PNV器件相比没有明显变化。文章对此作出了初步解释。

含氯前聚物法(CPR)合成聚萘乙炔前聚物

研究了含氯前聚物法合成聚萘乙炔中催化剂、单体浓度、碱滴加速度、反应介质、反应温度对前聚合物产率、分子量等的影响。用红外光谱 (FTIR)、核磁 (NMR)、色谱 质谱 (GC -MS)。