Poly （3, 4-ethylenedioxythiophene） （PEDOT）, together with its dopes, such as poly （styrene sulfonate） （PSS）, has been acknowledged to have a wide range of biomedical applications as an important conducting pol...Poly （3, 4-ethylenedioxythiophene） （PEDOT）, together with its dopes, such as poly （styrene sulfonate） （PSS）, has been acknowledged to have a wide range of biomedical applications as an important conducting polymer. In this study, gelatin can be polymerized into PEDOT/PSS polymers on indium tin oxide （ITO）-coated glass. PEDOT/PSS/gelatin layer on ITO-coated glass significantly decreases electrochemical impedance spectroscopy （EIS） and increases charge delivery capacity relative to the gelatin layer and bare ITO- coated glass, comparable to the PEDOT/PSS layer on ITO-coated glass. PEDOT/PSS/gelatin layer on ITO- coated glass enhances pheochromocytoma （PC 12） cell affinity, possesses a high biocompatibility and promotes PC 12 cell growth by delivery of electrical stimulation. These results suggest that gelatin can be incorporated into the PEDOT/PSS polymers through electrochemical polymerization and the PEDOT/PSS/gelatin layer on ITO-coated glass possesses high electrochemical and biological activities.展开更多
An innovative,ternary nanocomposite composed of overoxidized poly(3,4-ethylenedioxythiophene)(OPEDOT),gold nanoparticles(Au NPs),and electrochemically reduced graphene oxide(ERGO)was prepared on a glassy carbon electr...An innovative,ternary nanocomposite composed of overoxidized poly(3,4-ethylenedioxythiophene)(OPEDOT),gold nanoparticles(Au NPs),and electrochemically reduced graphene oxide(ERGO)was prepared on a glassy carbon electrode(GCE)(OPEDOT-Au NPs-ERGO/GCE)through homogeneous chemical reactions and heterogeneous electrochemical methods.The morphology,composition,and structure of this nanocomposite were characterized by transmission electron microscopy,scanning electron microscopy,X-ray diffraction,and X-ray photoelectron spectroscopy.The electrochemical properties of the OPEDOT-Au NPs-ERGO/GCE were investigated by cyclic voltammetry using potassium ferricyanide and hexaammineruthenium(III)chloride redox probe systems.This modified electrode shows excellent electro-catalytic activity for dopamine(DA)and uric acid(UA)under physiological p H conditions,but inhibits the oxidation of ascorbic acid(AA).Linear voltammetric responses were obtained when DA concentrations of approximately 4.0-100μM and UA concentrations of approximately 20-100μM were used.The detection limits(S/N=3)for DA and UA were 1.0 and 5.0μM,respectively,under physiological conditions and in the presence of 1.0 m M of AA.This developed method was applied to the simultaneous detection of DA and UA in human urine,where satisfactory recoveries from 96.7%to 105.0%were observed.This work demonstrates that the developed OPEDOT-Au NPs-ERGO ternary nanocomposite,with its excellent ion-selectivity and electro-catalytic activity,is a promising candidate for the simultaneous detection of DA and UA in the presence of AA in physiological and pathological studies.展开更多
Pheniramine maleate (PA), an antihistamine, was determined by Differential Pulse Stripping voltammetry using nano polypyrrole (Ppy) and nano poly(3,4-ethylenedioxythiophene) (PEDOT) modified glassy carbon electrodes. ...Pheniramine maleate (PA), an antihistamine, was determined by Differential Pulse Stripping voltammetry using nano polypyrrole (Ppy) and nano poly(3,4-ethylenedioxythiophene) (PEDOT) modified glassy carbon electrodes. The cyclic voltammetric behavior of pheniramine was studied in aqueous acidic, neutral and alkaline conditions. One well-defined oxidation peak was observed in the cyclic voltammograms at all pHs. The influence of pH, scan rate and concentration revealed irreversible electron transfer and the oxidation was diffusion controlled adsorption. The SEM analysis confirmed good accumulation of PA on the electrode surface. A systematic study of influence of various experimental parameters that affect the stripping voltammetric response was carried out and the maximum peak current conditions were arrived at. Calibration was made under maximum peak current conditions. The range of study was 0.05 to 0.4 μg/mL on Ppy/GCE and 0.025 to 0.4μg/mL on PEDOT/GCE and the lower limit of determination were 0.035μg/mL on Ppy/GCE and 0.016μg/mL on PEDOT/GCE. The suitability of the method for the determination of PA in pharmaceutical preparations and urine samples was also ascertained.展开更多
[Objective] This paper was to introduce the chemical oxidative synthesis process, properties and test methods of 3,4-ethylenedioxythiophene(EDOT). [Method] The poor water solubility of EDOT was solved by using polyeth...[Objective] This paper was to introduce the chemical oxidative synthesis process, properties and test methods of 3,4-ethylenedioxythiophene(EDOT). [Method] The poor water solubility of EDOT was solved by using polyethylene glycol 20000(PEG) as the surfactant. The monomer was polymerized by chemical oxidative synthesis. The product was analyzed and verified by infrared spectrum, X-ray diffraction, ultraviolet-visible absorption spectra.[Result] The conductivity of the product was the best when the mass ratio of PEG and EDOT was 1∶1. The effects of oxidant dose and reaction time on the conductivity and yield of the product showed certain regularity. [Conclusion] EDOT could be polymerized by PEG and FeCl3, and the polymerization product was PEDOT.展开更多
Composites of Maghnite-H, a Montmorillonite sheet silicate clay, exchanged with protons, and Poly(3,4-ethylenedioxythiophene) (PEDOT) were prepared by in situ chemical polymerization of the 3,4-ethylenedioxythiophene,...Composites of Maghnite-H, a Montmorillonite sheet silicate clay, exchanged with protons, and Poly(3,4-ethylenedioxythiophene) (PEDOT) were prepared by in situ chemical polymerization of the 3,4-ethylenedioxythiophene, without the use of solvent or oxidant. The effect of changing monomer/clay ratio was studied and the resultant composite structures were characterized by Inferred spectroscopy, 27Al and 13CSolid-State NMR spectroscopy, scanning electron microscopy and powder X-ray diffraction. All analyses are consistent with a structure were the polymer is (partially) intercalated into the clay structure, which in favourable cases lead to exfoliation. The presence of the clay in the polymer leads to a desired increase in thermal stability as witnessed by thermogravimetry.展开更多
Conventional chloromethylation, paraformaldehyde/hydrogen chloride in acetic acid medium, was applied to 1,2- dimethoxybenzene. Chloroform-soluble poly（3,4-dimethoxy-o-tolylene） was obtained with an intrinsic viscos...Conventional chloromethylation, paraformaldehyde/hydrogen chloride in acetic acid medium, was applied to 1,2- dimethoxybenzene. Chloroform-soluble poly（3,4-dimethoxy-o-tolylene） was obtained with an intrinsic viscosity of 0.034 dL g^-1. The polymer was evaluated as a condensation redox polymer precursor formed by a Friedel-Crafts reaction. Cleavage of the methoxy groups present in this polymer resulted in poly（3,4-dihydroxy-o-tolylene） which manifested a great air-oxidation resistance. The redox property of the latter polymer was found to be 1017 mV by potentiometric titration with 0.05 N ceric ammonium nitrate at 25℃. This midpotential was compared to that of catechol, a monomeric analogue, under the same titration conditions.展开更多
A rational design of efficient low-band-gap non-fullerene acceptors(NFAs)for high-performance organic solar cells(OSCs)remains challenging;the main constraint being the decrease in the energy level of the lowest unocc...A rational design of efficient low-band-gap non-fullerene acceptors(NFAs)for high-performance organic solar cells(OSCs)remains challenging;the main constraint being the decrease in the energy level of the lowest unoccupied molecular orbitals(LUMOs)as the bandgap of A-D-A-type NFAs decrease.Therefore,the short current density(J_(sc))and open-circuit voltage(V_(oc))result in a trade-off relationship,making it difficult to obtain efficient OSCs.Herein,three NFAs(IFL-ED-4 F,IDT-ED-4 F,and IDTT-ED-2 F)were synthesized to address the above-mentioned issue by introducing 3,4-ethylenedioxythiophene(EDOT)as aπ-bridge.These NFAs exhibit relatively low bandgaps(1.67,1.42,and 1.49 eV,respectively)and upshifted LUMO levels(-3.88,-3.84,and-3.81 eV,respectively)compared with most reported low-band-gap NFAs.Consequently,the photovoltaic devices based on IDT-ED-4 F blended with a PBDB-T donor polymer showed the best power conversion efficiency(PCE)of 10.4%with a high J_(sc) of 22.1 mA cm^(-2) and Voc of 0.884 V among the examined NFAs.In contrast,IDTT-ED-4 F,which was designed with an asymmetric structure of the D-p-A type,showed the lowest efficiency of 1.5%owing to the poor morphology and charge transport properties of the binary blend.However,when this was introduced as the third component of the PM6:BTP-BO-4 Cl,complementary absorption and cascade energy-level alignment between the two substances could be achieved.Surprisingly,the IDTT-ED-4 F-based ternary blend device not only improved the Jscand Voc,but also achieved a PCE of 15.2%,which is approximately 5.3%higher than that of the reference device with a minimized energy loss of 0.488 eV.In addition,the universality of IDTT-ED-2 F as a third component was effectively demonstrated in other photoactive systems,specifically,PM6:BTPe C9 and PTB7-Th:IEICO-4 F.This work facilitates a better understanding of the structure–property relationship for utilizing efficient EDOT-bridged NFAs in high-performance OSC applications.展开更多
A novel poly (amide-imide) was prepared from a novel monomer: 5,6-diphenyl-chloroformyl-3,4-benzenedicarboxylic anhydride and bis (4-aminophenyl) ether. The polymer was characterized by FTIR. (HNMR)-H-1. DSC and TGA.
Synthesis and characteristics of poly(3,4-azopyridylene)(PAP),conductivity and oxygen-binding affinity of its complex with meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinatocobalt(II)(COP)were studied.PAP was p...Synthesis and characteristics of poly(3,4-azopyridylene)(PAP),conductivity and oxygen-binding affinity of its complex with meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinatocobalt(II)(COP)were studied.PAP was prepared by oxidative polymerization of 3,4-diaminopyridine(DAP)in DMF solution using CuCl/pyridine as the catalyst.IR and NMR results showed that the peak of amido group in DAP was converted to the azo group in PAP and a π conjugated polymer was synthesized.The average molecular weight of PAP was determined to be 5.0×10~3.The PAP-CoP complex was prepared by complexing the pyridyl group of PAP with the fifth coordination site of CoP in DMF solution.In comparison with the CoP complex with a non-π conjugated polymer,the PAP-CoP complex shows good electroconductivity of 5.8×10^(-6) S cm^(-1).The PAP-CoP complex displays a reversible change in the UV-Visible absorption spectrum from the deoxy form to the oxy or oxygen-binding one with an isosbestic point,in response to the partial oxygen pressure of the atmosphere.The oxygen- response behavior was monitored at the absorbance ascribed to the oxy form at 548 nm to give the oxygen-binding affinity. The oxygen-binding equilibrium curves of PAP-CoP complex obey a Langmuir isotherm.DMF has great effects on the oxygen-binding properties of the PAP-CoP complex.The oxygen-binding affinity of PAP-CoP complex in the solid state is higher than that in DMF solution.With decreasing temperature,the oxygen-binding affinity of the PAP-CoP complex increases.展开更多
Conductive poly（3,4-ethylenedioxythiophene） coated terylene textile represented by PEDOT/CTT was prepared via in-situ polymerization.It is found that the PEDOT nano-particles with diameter of 100 nm spread over the ...Conductive poly（3,4-ethylenedioxythiophene） coated terylene textile represented by PEDOT/CTT was prepared via in-situ polymerization.It is found that the PEDOT nano-particles with diameter of 100 nm spread over the surface of terylene fibers resulting in a good conductivity of 2.67×10-2 S/cm,as measured by a four-probe method.Moreover,the PEDOT/CTT exhibits an electrochromic behavior,which takes a variation of color from pale blue to dark blue when the applied potential changed from-0.420 V to 01.0 V vs.SCE.展开更多
基金Funded by National Natural Science Foundation of China(Nos.11179015,51173108)Innovation Program of Shanghai Municipal Education Commission(No.12ZZ143)
文摘Poly （3, 4-ethylenedioxythiophene） （PEDOT）, together with its dopes, such as poly （styrene sulfonate） （PSS）, has been acknowledged to have a wide range of biomedical applications as an important conducting polymer. In this study, gelatin can be polymerized into PEDOT/PSS polymers on indium tin oxide （ITO）-coated glass. PEDOT/PSS/gelatin layer on ITO-coated glass significantly decreases electrochemical impedance spectroscopy （EIS） and increases charge delivery capacity relative to the gelatin layer and bare ITO- coated glass, comparable to the PEDOT/PSS layer on ITO-coated glass. PEDOT/PSS/gelatin layer on ITO- coated glass enhances pheochromocytoma （PC 12） cell affinity, possesses a high biocompatibility and promotes PC 12 cell growth by delivery of electrical stimulation. These results suggest that gelatin can be incorporated into the PEDOT/PSS polymers through electrochemical polymerization and the PEDOT/PSS/gelatin layer on ITO-coated glass possesses high electrochemical and biological activities.
基金Financial supports from the Natural Science Foundation of Shaanxi Province,China(Grant No.:2020JM-652)Fundamental Research Funds for the Central Universities of Xi’an Jiaotong University(Grant No.:xzy012020054)Cultivation Project of Xi’an Health Committee(Grant No.:2020MS02)。
文摘An innovative,ternary nanocomposite composed of overoxidized poly(3,4-ethylenedioxythiophene)(OPEDOT),gold nanoparticles(Au NPs),and electrochemically reduced graphene oxide(ERGO)was prepared on a glassy carbon electrode(GCE)(OPEDOT-Au NPs-ERGO/GCE)through homogeneous chemical reactions and heterogeneous electrochemical methods.The morphology,composition,and structure of this nanocomposite were characterized by transmission electron microscopy,scanning electron microscopy,X-ray diffraction,and X-ray photoelectron spectroscopy.The electrochemical properties of the OPEDOT-Au NPs-ERGO/GCE were investigated by cyclic voltammetry using potassium ferricyanide and hexaammineruthenium(III)chloride redox probe systems.This modified electrode shows excellent electro-catalytic activity for dopamine(DA)and uric acid(UA)under physiological p H conditions,but inhibits the oxidation of ascorbic acid(AA).Linear voltammetric responses were obtained when DA concentrations of approximately 4.0-100μM and UA concentrations of approximately 20-100μM were used.The detection limits(S/N=3)for DA and UA were 1.0 and 5.0μM,respectively,under physiological conditions and in the presence of 1.0 m M of AA.This developed method was applied to the simultaneous detection of DA and UA in human urine,where satisfactory recoveries from 96.7%to 105.0%were observed.This work demonstrates that the developed OPEDOT-Au NPs-ERGO ternary nanocomposite,with its excellent ion-selectivity and electro-catalytic activity,is a promising candidate for the simultaneous detection of DA and UA in the presence of AA in physiological and pathological studies.
文摘Pheniramine maleate (PA), an antihistamine, was determined by Differential Pulse Stripping voltammetry using nano polypyrrole (Ppy) and nano poly(3,4-ethylenedioxythiophene) (PEDOT) modified glassy carbon electrodes. The cyclic voltammetric behavior of pheniramine was studied in aqueous acidic, neutral and alkaline conditions. One well-defined oxidation peak was observed in the cyclic voltammograms at all pHs. The influence of pH, scan rate and concentration revealed irreversible electron transfer and the oxidation was diffusion controlled adsorption. The SEM analysis confirmed good accumulation of PA on the electrode surface. A systematic study of influence of various experimental parameters that affect the stripping voltammetric response was carried out and the maximum peak current conditions were arrived at. Calibration was made under maximum peak current conditions. The range of study was 0.05 to 0.4 μg/mL on Ppy/GCE and 0.025 to 0.4μg/mL on PEDOT/GCE and the lower limit of determination were 0.035μg/mL on Ppy/GCE and 0.016μg/mL on PEDOT/GCE. The suitability of the method for the determination of PA in pharmaceutical preparations and urine samples was also ascertained.
基金Natural Science Foundation of Guangxi Province(2017GXNSFAA198274)
文摘[Objective] This paper was to introduce the chemical oxidative synthesis process, properties and test methods of 3,4-ethylenedioxythiophene(EDOT). [Method] The poor water solubility of EDOT was solved by using polyethylene glycol 20000(PEG) as the surfactant. The monomer was polymerized by chemical oxidative synthesis. The product was analyzed and verified by infrared spectrum, X-ray diffraction, ultraviolet-visible absorption spectra.[Result] The conductivity of the product was the best when the mass ratio of PEG and EDOT was 1∶1. The effects of oxidant dose and reaction time on the conductivity and yield of the product showed certain regularity. [Conclusion] EDOT could be polymerized by PEG and FeCl3, and the polymerization product was PEDOT.
文摘Composites of Maghnite-H, a Montmorillonite sheet silicate clay, exchanged with protons, and Poly(3,4-ethylenedioxythiophene) (PEDOT) were prepared by in situ chemical polymerization of the 3,4-ethylenedioxythiophene, without the use of solvent or oxidant. The effect of changing monomer/clay ratio was studied and the resultant composite structures were characterized by Inferred spectroscopy, 27Al and 13CSolid-State NMR spectroscopy, scanning electron microscopy and powder X-ray diffraction. All analyses are consistent with a structure were the polymer is (partially) intercalated into the clay structure, which in favourable cases lead to exfoliation. The presence of the clay in the polymer leads to a desired increase in thermal stability as witnessed by thermogravimetry.
文摘Conventional chloromethylation, paraformaldehyde/hydrogen chloride in acetic acid medium, was applied to 1,2- dimethoxybenzene. Chloroform-soluble poly（3,4-dimethoxy-o-tolylene） was obtained with an intrinsic viscosity of 0.034 dL g^-1. The polymer was evaluated as a condensation redox polymer precursor formed by a Friedel-Crafts reaction. Cleavage of the methoxy groups present in this polymer resulted in poly（3,4-dihydroxy-o-tolylene） which manifested a great air-oxidation resistance. The redox property of the latter polymer was found to be 1017 mV by potentiometric titration with 0.05 N ceric ammonium nitrate at 25℃. This midpotential was compared to that of catechol, a monomeric analogue, under the same titration conditions.
基金supported by the KU Research Professor Program of Konkuk Universitythe Korea Institute of Energy Technology Evaluation and Planning (KETEP)+1 种基金the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20193091010110)a National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (No. 2020R1A2C201091611)。
文摘A rational design of efficient low-band-gap non-fullerene acceptors(NFAs)for high-performance organic solar cells(OSCs)remains challenging;the main constraint being the decrease in the energy level of the lowest unoccupied molecular orbitals(LUMOs)as the bandgap of A-D-A-type NFAs decrease.Therefore,the short current density(J_(sc))and open-circuit voltage(V_(oc))result in a trade-off relationship,making it difficult to obtain efficient OSCs.Herein,three NFAs(IFL-ED-4 F,IDT-ED-4 F,and IDTT-ED-2 F)were synthesized to address the above-mentioned issue by introducing 3,4-ethylenedioxythiophene(EDOT)as aπ-bridge.These NFAs exhibit relatively low bandgaps(1.67,1.42,and 1.49 eV,respectively)and upshifted LUMO levels(-3.88,-3.84,and-3.81 eV,respectively)compared with most reported low-band-gap NFAs.Consequently,the photovoltaic devices based on IDT-ED-4 F blended with a PBDB-T donor polymer showed the best power conversion efficiency(PCE)of 10.4%with a high J_(sc) of 22.1 mA cm^(-2) and Voc of 0.884 V among the examined NFAs.In contrast,IDTT-ED-4 F,which was designed with an asymmetric structure of the D-p-A type,showed the lowest efficiency of 1.5%owing to the poor morphology and charge transport properties of the binary blend.However,when this was introduced as the third component of the PM6:BTP-BO-4 Cl,complementary absorption and cascade energy-level alignment between the two substances could be achieved.Surprisingly,the IDTT-ED-4 F-based ternary blend device not only improved the Jscand Voc,but also achieved a PCE of 15.2%,which is approximately 5.3%higher than that of the reference device with a minimized energy loss of 0.488 eV.In addition,the universality of IDTT-ED-2 F as a third component was effectively demonstrated in other photoactive systems,specifically,PM6:BTPe C9 and PTB7-Th:IEICO-4 F.This work facilitates a better understanding of the structure–property relationship for utilizing efficient EDOT-bridged NFAs in high-performance OSC applications.
文摘A novel poly (amide-imide) was prepared from a novel monomer: 5,6-diphenyl-chloroformyl-3,4-benzenedicarboxylic anhydride and bis (4-aminophenyl) ether. The polymer was characterized by FTIR. (HNMR)-H-1. DSC and TGA.
基金This work was supported by the National Natural Science Foundation of China(No.50373035)Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry
文摘Synthesis and characteristics of poly(3,4-azopyridylene)(PAP),conductivity and oxygen-binding affinity of its complex with meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinatocobalt(II)(COP)were studied.PAP was prepared by oxidative polymerization of 3,4-diaminopyridine(DAP)in DMF solution using CuCl/pyridine as the catalyst.IR and NMR results showed that the peak of amido group in DAP was converted to the azo group in PAP and a π conjugated polymer was synthesized.The average molecular weight of PAP was determined to be 5.0×10~3.The PAP-CoP complex was prepared by complexing the pyridyl group of PAP with the fifth coordination site of CoP in DMF solution.In comparison with the CoP complex with a non-π conjugated polymer,the PAP-CoP complex shows good electroconductivity of 5.8×10^(-6) S cm^(-1).The PAP-CoP complex displays a reversible change in the UV-Visible absorption spectrum from the deoxy form to the oxy or oxygen-binding one with an isosbestic point,in response to the partial oxygen pressure of the atmosphere.The oxygen- response behavior was monitored at the absorbance ascribed to the oxy form at 548 nm to give the oxygen-binding affinity. The oxygen-binding equilibrium curves of PAP-CoP complex obey a Langmuir isotherm.DMF has great effects on the oxygen-binding properties of the PAP-CoP complex.The oxygen-binding affinity of PAP-CoP complex in the solid state is higher than that in DMF solution.With decreasing temperature,the oxygen-binding affinity of the PAP-CoP complex increases.
文摘Conductive poly（3,4-ethylenedioxythiophene） coated terylene textile represented by PEDOT/CTT was prepared via in-situ polymerization.It is found that the PEDOT nano-particles with diameter of 100 nm spread over the surface of terylene fibers resulting in a good conductivity of 2.67×10-2 S/cm,as measured by a four-probe method.Moreover,the PEDOT/CTT exhibits an electrochromic behavior,which takes a variation of color from pale blue to dark blue when the applied potential changed from-0.420 V to 01.0 V vs.SCE.
