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Preparation and characterization of organic polymer modified composite polyaluminum chloride 被引量:4
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作者 SHI Bao-you TANG Hong-xiao 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第2期214-220,共7页
Compared with traditional aluminum salts, polyaluminum chloride (PACI) has better coagulation-flocculation performance in turbidity removal. However, it is still inferior to organic polymers in terms of bridging fun... Compared with traditional aluminum salts, polyaluminum chloride (PACI) has better coagulation-flocculation performance in turbidity removal. However, it is still inferior to organic polymers in terms of bridging function. In order to improve the aggregating property of PACl, different composite PACl flocculants were prepared with various organic polymers. The effect of organic polymer on the distribution or Al(Ⅲ) species in composite flocculants was studied using ^27TAl NMR and Al-ferron complexation methods. The charge neutralization and surface adsorption characteristics of composite flocculants were also investigated. Jar tests were conducted to evaluate the turbidity removal efficacy of organic polymer modified composite flocculants. The study shows that cationic polymer and anionic polymer have significant influences on the coagulation-flocculation behaviors of PACl. Both cationic and anionic polymers can improve the turbidity removal performancc of PACl but the mechanisms arc much different: cationic organic polymer mainly increases the charge neutralization ability, but anionic polymer mainly enhances the bridging function. 展开更多
关键词 polyaluminum chloride(pacl organic polymer composite flocculant
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铝的水溶液化学特征及其聚合物生成机制 被引量:3
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作者 刘会娟 曲久辉 《高技术通讯》 CAS CSCD 北大核心 2005年第9期106-110,共5页
聚合氯化铝(PACl)是水处理中应用较广泛的絮凝剂.研究表明,PACl中各种铝聚合物的含量直接影响其絮凝效率.本文综述铝的水解聚合特性以及制备絮凝剂过程中的铝聚合物生成机制,着重介绍了Al13聚合物的结构特性、生成机制以及制备过程中各... 聚合氯化铝(PACl)是水处理中应用较广泛的絮凝剂.研究表明,PACl中各种铝聚合物的含量直接影响其絮凝效率.本文综述铝的水解聚合特性以及制备絮凝剂过程中的铝聚合物生成机制,着重介绍了Al13聚合物的结构特性、生成机制以及制备过程中各种因素的影响,为Al13絮凝剂的进一步研究奠定了基础. 展开更多
关键词 聚合氯化铝 聚合物 生成机制 铝聚合物 机制 化学特征 水溶液 AL13 制备过程 絮凝剂 絮凝效率
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