A new cadmium（Ⅱ） coordination polymer with unique structure was synthesized under diffusion process by employing triangular N-containing ligand tris（4-（pyridyl） phenyi） amine （Tppa）. Complex 1 crystallizes in...A new cadmium（Ⅱ） coordination polymer with unique structure was synthesized under diffusion process by employing triangular N-containing ligand tris（4-（pyridyl） phenyi） amine （Tppa）. Complex 1 crystallizes in the space group Pbcn, with a = 28.906（3）, b = 13.5294（14）, c = 17.8727（18） A, V= 6989.7（12） A^3, C66H48CdCl2N8, Mr = 1136.42, De = 1.080 g/cm^3, F（000） = 2328, μ= 0.428 mm^-1 and Z = 4. Complex 1 features a 2D → 3D framework with the coexistence of inclined polycatenation and polythreading. In addition, the luminescent property of complex 1 was studied.展开更多
A three-dimensional flexible organic framework FOF-1 has been synthesized from the condensation of a tetratopic acylhydrazine and a rigid 4,4-diphenyl-4,4-bipyridinium dialdehyde in water through the quantitative form...A three-dimensional flexible organic framework FOF-1 has been synthesized from the condensation of a tetratopic acylhydrazine and a rigid 4,4-diphenyl-4,4-bipyridinium dialdehyde in water through the quantitative formation of hydrazone bond. FOF-1 is further applied to construct a polycatenane framework FOF-pc-1 through the quantitative cucurbit[7]uril encapsulation for the diphenylbipyridinium subunits of the framework by making use of the dynamic nature of the hydrazone bond in water. The bipyridinium subunits in both frameworks can be reduced their radical cation counterparts to produce conjugated radical cation-linked dynamic organic frameworks rc-FOF-1 or rc-FOF-pc-1. Polycatenation is revealed to enhance the stability of the dynamic frameworks in water, whereas depolycatenation can be reached for both FOF-pc-1 and rc-FOF-pc-1 by using a ferrocene guest to form a more stable complex with CB[7].展开更多
基金Supported by the National Natural Science Foundation of China(21301005)the Natural Science Foundation of Anhui Province(1408085QB31)
文摘A new cadmium（Ⅱ） coordination polymer with unique structure was synthesized under diffusion process by employing triangular N-containing ligand tris（4-（pyridyl） phenyi） amine （Tppa）. Complex 1 crystallizes in the space group Pbcn, with a = 28.906（3）, b = 13.5294（14）, c = 17.8727（18） A, V= 6989.7（12） A^3, C66H48CdCl2N8, Mr = 1136.42, De = 1.080 g/cm^3, F（000） = 2328, μ= 0.428 mm^-1 and Z = 4. Complex 1 features a 2D → 3D framework with the coexistence of inclined polycatenation and polythreading. In addition, the luminescent property of complex 1 was studied.
基金financially supported by the National Natural Science Foundation of China (Nos. 21890732, 21890730 and21921003)。
文摘A three-dimensional flexible organic framework FOF-1 has been synthesized from the condensation of a tetratopic acylhydrazine and a rigid 4,4-diphenyl-4,4-bipyridinium dialdehyde in water through the quantitative formation of hydrazone bond. FOF-1 is further applied to construct a polycatenane framework FOF-pc-1 through the quantitative cucurbit[7]uril encapsulation for the diphenylbipyridinium subunits of the framework by making use of the dynamic nature of the hydrazone bond in water. The bipyridinium subunits in both frameworks can be reduced their radical cation counterparts to produce conjugated radical cation-linked dynamic organic frameworks rc-FOF-1 or rc-FOF-pc-1. Polycatenation is revealed to enhance the stability of the dynamic frameworks in water, whereas depolycatenation can be reached for both FOF-pc-1 and rc-FOF-pc-1 by using a ferrocene guest to form a more stable complex with CB[7].
