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杂多酸离子液体催化剂的制备及其合成可降解聚酯PES的催化性能
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作者 王戊 赵园园 +2 位作者 冉维婷 王海玥 郭立颖 《沈阳工业大学学报》 CAS 北大核心 2024年第4期397-402,共6页
为了分析杂多酸离子液体催化剂的催化性能,以Fe为中心杂原子、Mo为配位原子,制备了杂多酸阴离子,并将其与1-羟丙基-3-甲基咪唑溴盐通过离子交换反应制备功能化杂多酸离子液体催化剂([HO-(CH_(2))_(2)-mim]_(5)[Ti(H_(2)O)FeMo_(11)O_(39... 为了分析杂多酸离子液体催化剂的催化性能,以Fe为中心杂原子、Mo为配位原子,制备了杂多酸阴离子,并将其与1-羟丙基-3-甲基咪唑溴盐通过离子交换反应制备功能化杂多酸离子液体催化剂([HO-(CH_(2))_(2)-mim]_(5)[Ti(H_(2)O)FeMo_(11)O_(39)])。利用FT-IR、UV、XRD和TGA对所制催化剂进行结构表征与性能测试,通过正交试验优化工艺参数,探讨投料比、催化剂用量、酯交换反应温度和时间对其催化性能的影响。结果表明:所制催化剂结构正确,热性能良好,并具有较好催化效果。最佳工艺条件为:投料比2,催化剂质量分数1.0%,反应温度220℃,反应时间5 h,该条件下PES收率为75.32%。 展开更多
关键词 废弃电解液 杂多酸离子液体催化剂 碳酸乙烯酯 聚丁二酸二甲酯 耦合反应 pes收率 投料比 酯交换反应
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PPy/SMANa/PES导电复合膜的制备及其抗污性能
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作者 李坤天 谭妍妍 +3 位作者 薛禹 武晓 张道海 秦舒浩 《精细化工》 EI CAS CSCD 北大核心 2024年第6期1362-1371,共10页
为改善聚醚砜(PES)膜的抗污性能,以苯乙烯-马来酸酐钠共聚物(SMANa)为添加剂,采用非溶剂诱导相分离法制备了SMANa/PES膜(简称SP膜)。然后采用气相聚合法,以FeCl_(3)作为氧化剂,在SP膜上沉积导电聚吡咯(PPy)层,制备了PPy/SMANa/PES导电... 为改善聚醚砜(PES)膜的抗污性能,以苯乙烯-马来酸酐钠共聚物(SMANa)为添加剂,采用非溶剂诱导相分离法制备了SMANa/PES膜(简称SP膜)。然后采用气相聚合法,以FeCl_(3)作为氧化剂,在SP膜上沉积导电聚吡咯(PPy)层,制备了PPy/SMANa/PES导电复合膜(简称PSP膜)。采用FTIR、SEM和接触角测试仪表征SP膜、PSP膜的结构和形貌,采用超滤错流过滤法对两种膜的水通量和抗污性能进行了测试。考察了不同FeCl_(3)浓度、反应时间和反应温度对制备的PSP膜性能的影响。结果表明,当FeCl_(3)浓度0.8 mol/L、反应温度30℃、反应时间5 min时,制备的PSP膜表现出最佳的抗污性能,在0.1 MPa的过滤压力下,其纯水通量高达409.6 L/(m^(2)·h),为SP膜的83.8%,超声冲洗后的通量恢复率达到86.6%,比SP膜提高16.6%。 展开更多
关键词 聚醚砜 聚吡咯 超滤膜 导电性 抗污性能 水处理技术
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Preparation of Durable Antibacterial Polyester Fabrics by Grafting with the Natural Quaternary Ammonium Compound Betaine
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作者 Md Shariful Islam Md Kamrul Hasan +3 位作者 Arifur Rahman Shakhauat Hossen Md Anwarul Islam Sachi Xinbo Ding 《Materials Sciences and Applications》 2024年第9期378-398,共21页
Recently, the textile industry has increasingly advocated for natural resource-based healthcare textiles. This research presents a facile and eco-friendly approach to developing durable antibacterial polyester fabrics... Recently, the textile industry has increasingly advocated for natural resource-based healthcare textiles. This research presents a facile and eco-friendly approach to developing durable antibacterial polyester fabrics. Polyester fabric was first subjected to an alkaline hydrolysis to impart hydroxyl groups on the fiber surface. A natural antibacterial agent, betaine, was then covalently bonded to the hydrolyzed polyester fiber surface through esterification. XPS, Raman, SEM, and Wicking measurements were carried out to verify the esterification reaction. Antibacterial tests confirmed that betaine treatment grafted polyester fabrics revealed a remarkable antibacterial effect with inhibition rates > 99.9% against both E. coli and S. aureus and still remained inhibition rates of up to 91.5% against both bacteria after home washing for 20 cycles. Moreover, the modification significantly increased the capillary effect of polyester fabric but did not cause apparent adverse effects on the fabric’s hand or tensile strength. Overall, this grafting strategy for durable, antibacterial polyester fabric represents a significant practicality in the textile industry. 展开更多
关键词 polyester Fabric BETAINE ANTIBACTERIAL DURABILITY CAPILLARY
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征稿通知|“IEEE PES CHINA WIP高电压工程与新技术”专题《高电压技术》《高压电器》《湖北电力》联合征稿
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《湖北电力》 2024年第1期134-134,共1页
为进一步推动女性科技工作者的影响力与贡献力,时值世界第114个国际劳动妇女节到来之际,IEEE PES WIP(IEEE PES Women in Power)联合《高电压技术》《高压电器》《湖北电力》,面向广大IEEE PES WIP会员征集关于“IEEE PES CHINA WIP高... 为进一步推动女性科技工作者的影响力与贡献力,时值世界第114个国际劳动妇女节到来之际,IEEE PES WIP(IEEE PES Women in Power)联合《高电压技术》《高压电器》《湖北电力》,面向广大IEEE PES WIP会员征集关于“IEEE PES CHINA WIP高电压工程与新技术”专题的高水平科技论文。本专题拟于2024年下半年刊发,真诚欢迎广大IEEE PES WIP中国区会员联合国内外专家学者以及国家级科研计划承担单位踊跃投稿! 展开更多
关键词 高电压技术 科技论文 贡献力 WIP pes IEEE 高电压工程
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热处理工艺对PES亲水膜性能的影响研究
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作者 李亮 苟阁 +2 位作者 王建明 姬靖 陈顺权 《化工新型材料》 CAS CSCD 北大核心 2024年第11期71-74,共4页
采用非溶剂致相分离法,以聚醚砜(PES)、聚乙烯吡咯烷酮(PVP-K90)、N,N-二甲基乙酰胺(DMAc)为原料制备PES亲水平板膜,探讨和分析了热处理工艺对PES亲水膜性能的影响。结果表明:热处理工艺对膜PVP溶出值影响较大,热处理温度越高,热处理时... 采用非溶剂致相分离法,以聚醚砜(PES)、聚乙烯吡咯烷酮(PVP-K90)、N,N-二甲基乙酰胺(DMAc)为原料制备PES亲水平板膜,探讨和分析了热处理工艺对PES亲水膜性能的影响。结果表明:热处理工艺对膜PVP溶出值影响较大,热处理温度越高,热处理时间越长,膜PVP溶出值越低。热处理温度对膜力学性能影响不大。随着热处理时间的增加,膜亲水性逐渐升高。热处理有利于膜水通量的提升,当热处理温度为80℃时,膜水通量为最大值。 展开更多
关键词 非溶剂致相 聚醚砜 聚乙烯吡咯烷酮 热处理 亲水膜
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TiO2-PES Fibrous Composite Material for Ammonia Removal Using UV-A Photocatalyst
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作者 Anh Phuong Le Thi Masaru Ohshiro Takaomi Kobayashi 《Journal of Materials Science and Chemical Engineering》 2024年第1期1-19,共19页
This study focused on the development and characterization of TiO<sub>2</sub>-PES composite fibers with varying TiO<sub>2</sub> loading amounts using a phase inversion process. The resulting co... This study focused on the development and characterization of TiO<sub>2</sub>-PES composite fibers with varying TiO<sub>2</sub> loading amounts using a phase inversion process. The resulting composite fibers exhibited a sponge-like structure with embedded TiO<sub>2</sub> nanoparticles within a polymer matrix. Their photocatalytic performance for ammonia removal from aqueous solutions under UV-A light exposure was thoroughly investigated. The findings revealed that PeTi8 composite fibers displayed superior adsorption capacity compared to other samples. Moreover, the study explored the impact of pH, light intensity, and catalyst dosage on the photocatalytic degradation of ammonia. Adsorption equilibrium isotherms closely followed the Langmuir model, with the results indicating a correlation between qm values of 2.49 mg/g and the porous structure of the adsorbents. The research underscored the efficacy of TiO<sub>2</sub> composite fibers in the photocatalytic removal of aqueous under  UV-A light. Notably, increasing the distance between the photocatalyst and the light source resulted in de-creased hydroxyl radical concentration, influencing photocatalytic efficiency. These findings contribute to our understanding of TiO<sub>2</sub> composite fibers as promising photocatalysts for ammonia removal in water treatment applications. 展开更多
关键词 Ammonia Removal PHOTOCATALYST TiO2-pes Composite Fiber Fibrous Material
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Co-Ni LDHs/PES杂化膜协同PMS降解印染废水的研究 被引量:1
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作者 周延慧 董延茂 +3 位作者 袁妍 赵丹 李屹 谢纬君 《水处理技术》 CAS CSCD 北大核心 2023年第2期46-51,56,共7页
分别采用共沉淀法和相转化法制备了Co-Ni层状双氢氧化物(Co-Ni LDHs)和Co-Ni LDHs杂化聚醚砜膜(Co-Ni LDHs/PES)。通过FT-IR、XRD、SEM、TEM、EDX和拉伸强度测试对产物进行了表征。结果表明,所制备的Co-Ni LDHs/PES膜具有优异的机械性... 分别采用共沉淀法和相转化法制备了Co-Ni层状双氢氧化物(Co-Ni LDHs)和Co-Ni LDHs杂化聚醚砜膜(Co-Ni LDHs/PES)。通过FT-IR、XRD、SEM、TEM、EDX和拉伸强度测试对产物进行了表征。结果表明,所制备的Co-Ni LDHs/PES膜具有优异的机械性和亲水性。当LDHs的负载量为5 mg/L,PMS和AO7浓度分别为1 mmol/L和0.05 mmol/L时,反应20 min,AO7的去除率高达96.58%。Co-Ni LDHs/PES的离子浸出量远小于Co-Ni LDHs。重复使用四次后,Co-Ni LDHs/PES仍具有良好的催化性能。通过自由基猝灭实验和XPS分析研究了Co-Ni LDHs/PES的催化降解机理。在LDHs/PMS体系中同时产生了SO_(4)^(·-)、·OH、^(1)O_(2)和OO_(2)^(·-),其中后者在AO7降解中发挥了重要作用。 展开更多
关键词 Co-Ni LDHs Co-Ni LDHs/pes 催化 离子浸出
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DMA-MPC共聚物亲水改性PES膜及抗蛋白吸附性能研究 被引量:2
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作者 杨紫云 陈聪 +3 位作者 刘巧鸿 李雅倩 彭跃莲 安全福 《膜科学与技术》 CAS CSCD 北大核心 2023年第4期1-9,36,共10页
蛋白污染严重制约着聚醚砜(PES)膜的实际应用,提高膜表面的亲水性是降低蛋白吸附现象的有效方法.在等离子体处理PES膜的表面进行了一步沉积接枝聚-多巴胺甲基丙烯酰胺-2-甲基丙烯酰氧乙基磷酸胆碱(DMA-MPC),然后考察了改性膜的亲水性与... 蛋白污染严重制约着聚醚砜(PES)膜的实际应用,提高膜表面的亲水性是降低蛋白吸附现象的有效方法.在等离子体处理PES膜的表面进行了一步沉积接枝聚-多巴胺甲基丙烯酰胺-2-甲基丙烯酰氧乙基磷酸胆碱(DMA-MPC),然后考察了改性膜的亲水性与抗污染性.研究结果表明,经过等离子处理,使PES膜表面增加了含胺基的反应位点,其与DMA-MPC反应后形成稳定的共价键,在最优改性条件下PES改性膜的水接触角可降至37.7°±1°,在保持牛血清蛋白(BSA)高截留率的同时,通量提高至1060±30 L/(m^(2)·h·MPa),通量保持率从47%±1%提高至73%±1%.改性膜在循环测试中展现出优异的稳定性,为减少PES膜表面蛋白吸附提供了新的方法. 展开更多
关键词 聚醚砜 亲水改性 两性离子共聚物 多巴胺衍生物 抗蛋白吸附
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Fabrication of ZIF-8 membranes on dual-layer ZnO-PES/PES organic hollow fibers by in-situ crystallization 被引量:3
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作者 Zhengchi Yin Xiaoke Wu +5 位作者 Yanwei Yang Huayu Zhang Wangtao Li Ruimin Zhu Qiancheng Zheng Zhengbao Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第3期101-110,共10页
Compared to inorganic supports, polymeric supports can offer additional benefits, e.g., easier processing and cheaper. However, the organic surface has weak adhesion to the zeolitic imidazolate frameworks(ZIFs) membra... Compared to inorganic supports, polymeric supports can offer additional benefits, e.g., easier processing and cheaper. However, the organic surface has weak adhesion to the zeolitic imidazolate frameworks(ZIFs) membrane layer, which usually requires complex surface modification or seeding. Herein, we demonstrate that a dual-layer asymmetric polymer support prepared by a simple spinning process is a good candidate for the preparation of ZIF-8 membrane. The inner layer of the support is an organic hollow fiber(PES) with finger-like pores, and the outer layer is a ZnO-PES composite layer with finger-like pores also. The ZnO-PES composite layer is expected to contain uniform ZnO crystals in the polymer matrix, i.e., the ZnO particles in the skin layer of the support are not easy to fall off. Under the induction of ZnO particles in the outer layers, continuous ZIF-8 membranes can be prepared by single in-situ crystallization, showing good adhesion to the supports. The obtained ZIF-8 membranes show a H_(2) permeance of 8.7 × 10^(-8)mol·m^(-2)·s^(-1)·Pa^(-1) with a H_(2)/N_(2) ideal separation selectivity of 18.0. The design and preparation of this dual-layer polymer support is expected to promote the large-scale application of MOF membranes on polymer supports. 展开更多
关键词 Dual-layer pes hollow fiber In-situ crystallization ZIF-8 membrane Gas separation ZNO
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PE纤维与细橡胶颗粒对泡沫混凝土弯曲韧性的影响 被引量:1
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作者 吴昊 龙广成 +2 位作者 杨恺 曾晓辉 唐卓 《建筑材料学报》 EI CAS CSCD 北大核心 2024年第3期206-214,共9页
研究了聚乙烯(PE)纤维及其与细橡胶颗粒复掺对泡沫混凝土弯曲破坏模式、峰值强度、能量吸收特性和弯曲韧性的影响,并结合孔结构分析和微观形貌观察探究了其作用机理.结果表明:PE纤维使泡沫混凝土出现多缝开裂模式,显著提升了其峰值强度... 研究了聚乙烯(PE)纤维及其与细橡胶颗粒复掺对泡沫混凝土弯曲破坏模式、峰值强度、能量吸收特性和弯曲韧性的影响,并结合孔结构分析和微观形貌观察探究了其作用机理.结果表明:PE纤维使泡沫混凝土出现多缝开裂模式,显著提升了其峰值强度、能量吸收能力和弯曲韧性;复掺细橡胶颗粒可以进一步提升泡沫混凝土试件的比能量吸收和弯曲韧性;掺入PE纤维可以降低泡沫混凝土的平均孔径;复掺细橡胶颗粒导致泡沫混凝土试件的平均孔径增大,联通孔增多,对其峰值强度有不利影响;PE纤维及细橡胶颗粒提升泡沫混凝土弯曲韧性的主要原因在于其削弱了裂纹尖端的应力集中,同时增强了能量耗散作用. 展开更多
关键词 泡沫混凝土 PE纤维 细橡胶颗粒 弯曲韧性 机理
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Studying the Effect of Polyester Fiber Blend Ratio and Pilling Cycle on Blended Knit Fabrics
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作者 Kazi Md. Elias Mohammad Obaidur Rahman H. M. Zakir Hossain 《Journal of Textile Science and Technology》 2023年第4期227-243,共17页
Pilling is a severe concern for blended fabrics. The aesthetic look and smoothness are the buyers’ prime requirements. The main focus of the study was to see the pilling behavior from various percentages of polyester... Pilling is a severe concern for blended fabrics. The aesthetic look and smoothness are the buyers’ prime requirements. The main focus of the study was to see the pilling behavior from various percentages of polyester fiber blend ratio as well as the different pilling cycles on blended fabrics. The cotton, polyester, and elastane prepared the study fabrics. These fabrics are (90% Cotton/5% Polyester/5% Elastane, 90% Cotton/6% Polyester/4% Elastane, 90% Cotton/7% Polyester/3% Elastane, 90% Cotton/8% Polyester/2% Elastane, and 90% Cotton/9% Polyester/1% Elastane, 85% Cotton/10% Polyester/5% Elastane, 85% Cotton/11% Polyester/4% Elastane, 85% Cotton/12% Polyester/3% Elastane, 85% Cotton/13% Polyester/2% Elastane, and 85% Cotton/ 14% Polyester/1% Elastane, 80% Cotton/15% Polyester/5% Elastane, 80% Cotton/16% Polyester/4% Elastane, 80% Cotton/17% Polyester/3% Elastane, 80% Cotton/18% Polyester/2% Elastane, and 80% Cotton/19% Polyester/1% Elastane). The selected polyester blend ratios were 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18% and 19% respectively. The study used the Martindale pilling tester with 2000, 5000, and 7000 cycles, respectively. The evaluation followed the ISO 12945-2:2000. The study findings are that the polyester fiber blend ratio did not influence the pilling grade on blended fabrics for pilling cycles 2000, and the pilling grade remained constant at 4 - 5. The pilling grade started to deteriorate in pilling cycle 5000 for the fabrics 85%C/10%P/5%E, 85%C/11%P/4%E, 85%C/12%P/3%E, 85%C/ 13%P/2%E, 85%C/14%P/1%E showed the pilling grade 4, and the fabrics made from 80%C/15%P/5%E, 80%C/16%P/4%E, 80%C/17%P/3%E, 80%C/ 18%P/2%E, 80%C/19%P/1%E showed the pilling grade 4, 3, 3, 3, and 3 respectively. For the pilling cycles 7000, the pilling grade further deteriorated for the fabrics 80%C/15%P/5%E, 80%C/16%P/4%E, 80%C/17%P/3%E, 80%C/ 18%P/2%E, 80%C/19%P/1%E showed the pilling grade 3, 3, 2, 2, and 2 respectively. The study finds the dominance of polyester fiber throughout the experiment. The author hopes this study’s outcome will help new researchers, advanced researchers, and the textile industry’s sustainable development research and development team. 展开更多
关键词 PILLING Cotton polyester Elastane BLENDED Knit FABRIC
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Synthesis and Characterization of Novel Hydrolytically Degradable Polyesters
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作者 SUN Xin CHENG Zhengzai +8 位作者 DJOUONKEP Lesly Dasilva Wandji LAN Chupeng JIA Ruyan ZENG Sheng CHENG Junpeng TANG Ran LI Yi YUAN Beibei GAUTHLLER Mario 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第2期467-473,共7页
Six novel hydrolytically degradable polyesters were synthesized from thiodipropionic acid(TDPA)and five diols by melt polycondensation,and characterized by FT-IR,1H NMR,gel permeation chromatography,differential scann... Six novel hydrolytically degradable polyesters were synthesized from thiodipropionic acid(TDPA)and five diols by melt polycondensation,and characterized by FT-IR,1H NMR,gel permeation chromatography,differential scanning calorimetry and thermogravimetry analysis.The polystyrene-equivalent number-average(Mn)and weight-average molecular weight(Mw)of these polyesters ranged from 4900-11100 Da and 7900-20879 Da,respectively,with PDI values of 1.48-1.98.The melting point varied from 62.3-127.9℃,and the 50%mass-loss temperature ranged between 387-417℃.The degradation of these polyesters was studied in terms of relative weight loss in distilled water at different pH.Weight losses of 14%-26%were obtained at pH 7.0,26%-38%at pH 6.0,and 32%-43%at pH 8.3 over a 20-week period.The ecotoxicity study suggested that safety of the synthesized polyesters for the eisenia foetida.These results indicate that these polyesters have a combination of good thermal and degradability behaviors,which can be tailored through selection of the diol monomers used in the synthesis. 展开更多
关键词 thiodipropionic acid water-degradable polyester melt polycondensation thermal properties degradability tailoring
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Predicting Bursting Strength Behavior of Weft Knitted Fabrics Using Various Percentages of Cotton, Polyester, and Spandex Fibers
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作者 Kazi Md. Elias Mohammad Obaidur Rahman H. M. Zakir Hossain 《Journal of Textile Science and Technology》 2023年第4期273-290,共18页
The bursting strength is an essential quality parameter of knit fabric. The fabric structure, weight, types of fibers, and fiber blend proportion influence the bursting strength parameter. The tenacity of polyester fi... The bursting strength is an essential quality parameter of knit fabric. The fabric structure, weight, types of fibers, and fiber blend proportion influence the bursting strength parameter. The tenacity of polyester fiber is better than cotton and spandex. The study focused on predicting knit fabric bursting strength test value using different fibers (cotton, polyester, and spandex) with varying percentages of the blend ratio. This study used fifteen categories of blended fabrics. The Pearson Correlation and the hypothetical ANOVA regression analysis were conducted to do the statistical significance test. The experimental result reveals that the bursting strength test result increased with the increased percentage of polyester and suggested a suitable regression equation. The dominance of the polyester fiber was observed throughout the experiment, i.e., the higher the polyester blend proportion, the higher the bursting strength value. The inclusion of polyester in blends can reduce the cost of fabric. The developed prediction model or equation can help the fabric manufacturer make appropriate decisions regarding getting the expected bursting strength. The researcher hopes that the findings from this study will motivate new researchers, advanced researchers, and the textile manufacturing industry. 展开更多
关键词 Kilopascal Prediction Bursting-Strength Blended Fabric COTTON polyester SPANDEX
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One-step Eco-friendly Fabrication of Antibacterial Polyester Via On-line Amination Reaction by Melt Coextrusion
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作者 ZHANG Huan ZHAO Qinghua +4 位作者 ZHONG Yaping CAI Ruiyan LIU Ke WANG Dong LU Zhentan 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第5期1205-1212,共8页
The work is dedicated to develop a one-step eco-friendly method to prepare antibacterial polyethylene terephthalate(PET).We report a one-step eco-friendly method to manufacture antibacterial PET via on-line amination ... The work is dedicated to develop a one-step eco-friendly method to prepare antibacterial polyethylene terephthalate(PET).We report a one-step eco-friendly method to manufacture antibacterial PET via on-line amination reaction by melt coextrusion.Beside evenly mixing of poly(hexamethylene guanidine)(PHMG)and PET in the melt coextrusion procedure,the amination reaction also occurred between PHMG and PET under high temperature(230-270℃).The antibacterial ability of composite PET showed obvious PHMG concentration dependence,and antibacterial activity reached more than 99%when PHMG content was 2.5 wt%.Moreover,LIVE/DEAD fluorescence test further confirmed that the composite PET could kill bacteria quickly and efiectively(within 30 min);while negligible cytotoxicity was observed to HSF and HUVEC cells.Onestep eco-friendly fabrication of composite antibacterial PET was accomplished by on-line melt coextrusion.The composite antibacterial PET has potential use in multiple fields to combat with pathogenic including textiles,packaging materials,decoration materials and biomedical devices,etc. 展开更多
关键词 antibacterial polyester one-step eco-friendly method on-line amination reaction melt coextrusion cytocompatibility
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DJD-PES催化剂在30万t·a^(-1) Unipol聚乙烯装置上的应用 被引量:1
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作者 苏成武 赵金豹 王东方 《辽宁化工》 CAS 2023年第7期1058-1061,1068,共5页
介绍了DJD-PES催化剂在30万t·a^(-1)Unipol聚乙烯装置上工业应用情况,考察了DJD-PES催化剂的聚合适应性和产品性能,并与进口催化剂进行了比较。结果表明:DJD-PES催化剂的主要组成与进口催化剂相近,但微观结构与进口催化剂有一定差... 介绍了DJD-PES催化剂在30万t·a^(-1)Unipol聚乙烯装置上工业应用情况,考察了DJD-PES催化剂的聚合适应性和产品性能,并与进口催化剂进行了比较。结果表明:DJD-PES催化剂的主要组成与进口催化剂相近,但微观结构与进口催化剂有一定差异,内孔丰富,孔径略小而孔体积大。工业应用结果表明,DJD-PES催化剂操作平稳,反应器温度稳定性优于进口催化剂;催化剂聚合活性高,聚乙烯粉料堆积密度高,粒径分布窄,粒子形态好而细粉含量低。 展开更多
关键词 UNIPOL 聚乙烯 DJD-pes 催化剂 工业应用
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Characterization of Unsaturated Polyester Filled with Waste Coconut Shells, Walnut Shells, and Carbon Fibers
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作者 Marwah Subhi Attallah Reem Alaa Mohammed Ruaa Haitham Abdel-Rahim 《Fluid Dynamics & Materials Processing》 EI 2023年第10期2449-2469,共21页
This study aims to evaluate the erosion behavior and the hardness of hybrid composites made of varying amounts of coconut shells,walnut shells,and carbonfibers dispersed in a polyester matrix.MINITAB(L16)Taguchi experi... This study aims to evaluate the erosion behavior and the hardness of hybrid composites made of varying amounts of coconut shells,walnut shells,and carbonfibers dispersed in a polyester matrix.MINITAB(L16)Taguchi experiments were used to determine the optimal combination of parameters.In particular,an erosion device con-sisting of a motor with a constantflow rate of 45 L/min,a pump with a diameter of 40 mm,a nozzle with a dia-meter of 5 mm,and a tank made of“perspex glass”55 cm long,30 cm tall,and 25 cm wide was used.The tests were conducted by varying the sample-to-nozzle distance,the pattern angle,and the sand particle size.The results have revealed that the presence of 7.5%by weight of waste coconut shell,for conditions corresponding to 90°angle,sand size 425μm,stand distance 30 cm,gives the best wear resistance(3.04×10^(-5) g/g).Thefiller content and sand particle size affect the erosive rate,with the angle playing a secondary role.The distance between the sample and the nozzle has a weaker effect on erosive wear.The hardness results show that the models(UP-5%carbonfiber-2.5-3.5-4.5-5.5-6.5-7.5 wt.%waste coconut shell)give the best values for prayer compared to the samples(UP-5 wt.%carbonfiber-2.5-3.5-4.5-5.5-6.5-7.5 wt.%waste walnut shell). 展开更多
关键词 Unsaturated polyester resin carbonfiber waste coconut shell walnut shell erosive behavior Taguchi’s method L16
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中国废旧军服面料回收利用的研究现状及发展前景 被引量:2
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作者 刘洋 姚响 +2 位作者 杨革生 郁秀峰 张耀鹏 《现代纺织技术》 北大核心 2024年第1期119-129,共11页
为促进废旧军服面料的高值化回收利用,总结了国内07式军服的种类及其面料特征,系统分析了目前开纤纺纱法、再生聚酯切片法、涤棉分离技术等废旧军服面料的回收利用方法,并对废旧军服面料回收再利用的发展前景进行展望。分析表明:目前废... 为促进废旧军服面料的高值化回收利用,总结了国内07式军服的种类及其面料特征,系统分析了目前开纤纺纱法、再生聚酯切片法、涤棉分离技术等废旧军服面料的回收利用方法,并对废旧军服面料回收再利用的发展前景进行展望。分析表明:目前废旧军服面料的回收利用主要聚焦于简单再利用或回收涤纶组分制备高值再生聚酯切片,较少关注军服面料中其余组分的高值回收利用。针对废旧军服面料中含量相对较高的涤棉混纺面料,采用有效的涤棉分离技术高效分离涤纶和棉纤维,并以此作为原料分别制备再生聚酯切片和再生溶解浆,进一步以再生棉浆粕为原料制备再生纤维素产品将非常有前景。因而,开发高效的涤棉分离、废旧涤纶和棉纤维的高值化利用技术是实现废旧军服面料综合利用的重要发展方向。 展开更多
关键词 废旧军服 涤棉分离 高值回收利用 再生聚酯切片 再生Lyocell纤维
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丙烯酸酯增深剂的制备及在涤纶织物中的应用 被引量:1
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作者 刘小培 王俊伟 +4 位作者 董学亮 张彦昌 靳瑞文 宋跃 李中贤 《印染》 北大核心 2024年第1期57-61,共5页
利用乳液聚合法制备丙烯酸酯增深剂,并用于阿拉伯国家专用黑色涤纶织物增深整理。当增深剂质量浓度为40 g/L,焙烘温度为140℃,焙烘时间为3 min时,整理织物的增深比达39.46%,撕裂强力、耐摩擦和耐皂洗色牢度无明显变化,织物表面被一层颗... 利用乳液聚合法制备丙烯酸酯增深剂,并用于阿拉伯国家专用黑色涤纶织物增深整理。当增深剂质量浓度为40 g/L,焙烘温度为140℃,焙烘时间为3 min时,整理织物的增深比达39.46%,撕裂强力、耐摩擦和耐皂洗色牢度无明显变化,织物表面被一层颗粒状微球组成的膜状物包覆,织物表面C元素质量分数从73.22%减少到70.17%,O元素质量分数从26.78%减少到25.44%,新引入了4.39%N元素。 展开更多
关键词 增深剂 丙烯酸酯 涤纶织物
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Multi-output Gaussian Process Regression Model with Combined Kernel Function for Polyester Esterification Processes
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作者 王恒骞 耿君先 陈磊 《Journal of Donghua University(English Edition)》 CAS 2023年第1期27-33,共7页
In polyester fiber industrial processes,the prediction of key performance indicators is vital for product quality.The esterification process is an indispensable step in the polyester polymerization process.It has the ... In polyester fiber industrial processes,the prediction of key performance indicators is vital for product quality.The esterification process is an indispensable step in the polyester polymerization process.It has the characteristics of strong coupling,nonlinearity and complex mechanism.To solve these problems,we put forward a multi-output Gaussian process regression(MGPR)model based on the combined kernel function for the polyester esterification process.Since the seasonal and trend decomposition using loess(STL)can extract the periodic and trend characteristics of time series,a combined kernel function based on the STL and the kernel function analysis is constructed for the MGPR.The effectiveness of the proposed model is verified by the actual polyester esterification process data collected from fiber production. 展开更多
关键词 seasonal and trend decomposition using loess(STL) multi-output Gaussian process regression combined kernel function polyester esterification process
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Knee locking caused by osteochondroma of the proximal tibia adjacent to the pes anserinus:A case report
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作者 Tatsuru Sonobe Michiyuki Hakozaki +3 位作者 Yohei Matsuo Yojiro Takahashi Katsuhiro Yoshida Shinichi Konno 《World Journal of Clinical Cases》 SCIE 2023年第23期5595-5601,共7页
BACKGROUND Osteochondroma is one of the most common benign bone tumors,and it may cause bone and joint deformities and limited range of motion of an adjacent joint.The pes anserinus region is one of the most frequent ... BACKGROUND Osteochondroma is one of the most common benign bone tumors,and it may cause bone and joint deformities and limited range of motion of an adjacent joint.The pes anserinus region is one of the most frequent sites of osteochondroma,but knee locking caused by osteochondromas in the pes anserinus region is extremely rare.CASE SUMMARY We describe a 13-year-old Japanese girl’s extra-articular knee locking that occurred when the semitendinosus tendon got caught in osteochondroma that had developed in the pes anserinus region.The osteochondroma was surgically resected.The postoperative outcome has been excellent,with no recurrence of knee locking or tumor one-year post-surgery.CONCLUSION When a young person develops knee locking,the possibility of extra-articular as well as intra-articular locking should be considered.Osteochondroma,one of the causes of extra-articular locking,can be treated with surgery with good postoperative results. 展开更多
关键词 Extra-articular knee locking Impingement OSTEOCHONDROMA pes anserinus Tibia Surgery Case report
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