Microplastic is a new kind of pollutant.It exists widely in the aquatic environment and seriously endangers the aquatic ecosystem.In this study,the coagulating sedimentation method was used to remove microplastics in ...Microplastic is a new kind of pollutant.It exists widely in the aquatic environment and seriously endangers the aquatic ecosystem.In this study,the coagulating sedimentation method was used to remove microplastics in water.Polyethylene(PE)was selected as the representative of microplastics,polyferric sulfate(PFS),polyaluminum chloride(PAC)and aluminum sulfate(AS)were used as coagulant,and polyacrylamide(PAM)was used as coagulant aid to study the effects of pH,coagulant concentration and sedimentation time on the removal of PE by single and composite coagulant.The results showed that when the dosage of PFS was 0.5 g/L and pH was 5.0,the removal rate could reach 82.14%,which was better than PAC and AS,indicating that PFS had better coagulation and sedimentation performance for PE;the composite coagulant of PFS+PAC+AS(1 g/L+0.2 g/L+0.2 g/L,pH was 5.0)had the highest removal rate of PE,reaching 96.06%;the removal rate of PE increased with the increase in sedimentation time,but considering that the longer sedimentation time has less contribution to the improvement of removal rate,it is recommended that 4 h is appropriate.展开更多
Nano-sized TiO2 doped La^3＋ , was used as photocatalysis to degrade polyethylene （PE） film in solid-state reaction. It made PE lose its mass fraction of 14.5%, and formed more quantities of CO2 and more wax yields ...Nano-sized TiO2 doped La^3＋ , was used as photocatalysis to degrade polyethylene （PE） film in solid-state reaction. It made PE lose its mass fraction of 14.5%, and formed more quantities of CO2 and more wax yields after UV irradiation for 288 h. SEM imagines displayed more and bigger holes and pits in the PE film. FT-IR spectra showed that there is a lower absorbance of groups of - CH2 and - CH3 in PE/ TiO2 and 0. 1% La2O3/TiO2/PE composite materials than that in PE film sample of photodegradation, and more carbonyl groups in PE/0.1% LaEO3/TiO2. La^3＋ doping TiO2 improves TiO2 activities of oxidation and erosion of PE film under UV irradiation.展开更多
基金Supported by Innovation and Entrepreneurship Training Program for College Students(202210580015).
文摘Microplastic is a new kind of pollutant.It exists widely in the aquatic environment and seriously endangers the aquatic ecosystem.In this study,the coagulating sedimentation method was used to remove microplastics in water.Polyethylene(PE)was selected as the representative of microplastics,polyferric sulfate(PFS),polyaluminum chloride(PAC)and aluminum sulfate(AS)were used as coagulant,and polyacrylamide(PAM)was used as coagulant aid to study the effects of pH,coagulant concentration and sedimentation time on the removal of PE by single and composite coagulant.The results showed that when the dosage of PFS was 0.5 g/L and pH was 5.0,the removal rate could reach 82.14%,which was better than PAC and AS,indicating that PFS had better coagulation and sedimentation performance for PE;the composite coagulant of PFS+PAC+AS(1 g/L+0.2 g/L+0.2 g/L,pH was 5.0)had the highest removal rate of PE,reaching 96.06%;the removal rate of PE increased with the increase in sedimentation time,but considering that the longer sedimentation time has less contribution to the improvement of removal rate,it is recommended that 4 h is appropriate.
文摘Nano-sized TiO2 doped La^3＋ , was used as photocatalysis to degrade polyethylene （PE） film in solid-state reaction. It made PE lose its mass fraction of 14.5%, and formed more quantities of CO2 and more wax yields after UV irradiation for 288 h. SEM imagines displayed more and bigger holes and pits in the PE film. FT-IR spectra showed that there is a lower absorbance of groups of - CH2 and - CH3 in PE/ TiO2 and 0. 1% La2O3/TiO2/PE composite materials than that in PE film sample of photodegradation, and more carbonyl groups in PE/0.1% LaEO3/TiO2. La^3＋ doping TiO2 improves TiO2 activities of oxidation and erosion of PE film under UV irradiation.
