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Polyethylene glycol fusion repair of severed rat sciatic nerves reestablishes axonal continuity and reorganizes sensory terminal fields in the spinal cord 被引量:1
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作者 Emily A.Hibbard Liwen Zhou +5 位作者 Cathy Z.Yang Karthik Venkudusamy Yessenia Montoya Alexa Olivarez George D.Bittner Dale R.Sengelaub 《Neural Regeneration Research》 SCIE CAS 2025年第7期2095-2107,共13页
Peripheral nerve injuries result in the rapid degeneration of distal nerve segments and immediate loss of motor and sensory functions;behavioral recovery is typically poor.We used a plasmalemmal fusogen,polyethylene g... Peripheral nerve injuries result in the rapid degeneration of distal nerve segments and immediate loss of motor and sensory functions;behavioral recovery is typically poor.We used a plasmalemmal fusogen,polyethylene glycol(PEG),to immediately fuse closely apposed open ends of severed proximal and distal axons in rat sciatic nerves.We have previously reported that sciatic nerve axons repaired by PEG-fusion do not undergo Wallerian degeneration,and PEG-fused animals exhibit rapid(within 2–6 weeks)and extensive locomotor recovery.Furthermore,our previous report showed that PEG-fusion of severed sciatic motor axons was non-specific,i.e.,spinal motoneurons in PEG-fused animals were found to project to appropriate as well as inappropriate target muscles.In this study,we examined the consequences of PEG-fusion for sensory axons of the sciatic nerve.Young adult male and female rats(Sprague–Dawley)received either a unilateral single cut or ablation injury to the sciatic nerve and subsequent repair with or without(Negative Control)the application of PEG.Compound action potentials recorded immediately after PEG-fusion repair confirmed conduction across the injury site.The success of PEG-fusion was confirmed through Sciatic Functional Index testing with PEG-fused animals showing improvement in locomotor function beginning at 35 days postoperatively.At 2–42 days postoperatively,we anterogradely labeled sensory afferents from the dorsal aspect of the hindpaw following bilateral intradermal injection of wheat germ agglutinin conjugated horseradish peroxidase.PEG-fusion repair reestablished axonal continuity.Compared to unoperated animals,labeled sensory afferents ipsilateral to the injury in PEG-fused animals were found in the appropriate area of the dorsal horn,as well as inappropriate mediolateral and rostrocaudal areas.Unexpectedly,despite having intact peripheral nerves,similar reorganizations of labeled sensory afferents were also observed contralateral to the injury and repair.This central reorganization may contribute to the improved behavioral recovery seen after PEG-fusion repair,supporting the use of this novel repair methodology over currently available treatments. 展开更多
关键词 AXOTOMY dorsal horn peripheral nerve injury PLASTICITY polyethylene glycol(PEG) sciatic nerve sensory terminals wheat germ agglutinin horseradish peroxidase
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Polyethylene glycol has immunoprotective effects on sciatic allografts, but behavioral recovery and graft tolerance require neurorrhaphy and axonal fusion
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作者 Tyler A.Smith Liwen Zhou +6 位作者 Cameron L.Ghergherehchi Michelle Mikesh Cathy Z.Yang Haley O.Tucker JuliAnne Allgood Jared S.Bushman George D.Bittner 《Neural Regeneration Research》 SCIE CAS 2025年第4期1192-1206,共15页
Behavioral recovery using(viable)peripheral nerve allografts to repair ablation-type(segmental-loss)peripheral nerve injuries is delayed or poor due to slow and inaccurate axonal regeneration.Furthermore,such peripher... Behavioral recovery using(viable)peripheral nerve allografts to repair ablation-type(segmental-loss)peripheral nerve injuries is delayed or poor due to slow and inaccurate axonal regeneration.Furthermore,such peripheral nerve allografts undergo immunological rejection by the host immune system.In contrast,peripheral nerve injuries repaired by polyethylene glycol fusion of peripheral nerve allografts exhibit excellent behavioral recovery within weeks,reduced immune responses,and many axons do not undergo Wallerian degeneration.The relative contribution of neurorrhaphy and polyethylene glycol-fusion of axons versus the effects of polyethylene glycol per se was unknown prior to this study.We hypothesized that polyethylene glycol might have some immune-protective effects,but polyethylene glycol-fusion was necessary to prevent Wallerian degeneration and functional/behavioral recovery.We examined how polyethylene glycol solutions per se affect functional and behavioral recovery and peripheral nerve allograft morphological and immunological responses in the absence of polyethylene glycol-induced axonal fusion.Ablation-type sciatic nerve injuries in outbred Sprague–Dawley rats were repaired according to a modified protocol using the same solutions as polyethylene glycol-fused peripheral nerve allografts,but peripheral nerve allografts were loose-sutured(loose-sutured polyethylene glycol)with an intentional gap of 1–2 mm to prevent fusion by polyethylene glycol of peripheral nerve allograft axons with host axons.Similar to negative control peripheral nerve allografts not treated by polyethylene glycol and in contrast to polyethylene glycol-fused peripheral nerve allografts,animals with loose-sutured polyethylene glycol peripheral nerve allografts exhibited Wallerian degeneration for all axons and myelin degeneration by 7 days postoperatively and did not recover sciatic-mediated behavioral functions by 42 days postoperatively.Other morphological signs of rejection,such as collapsed Schwann cell basal lamina tubes,were absent in polyethylene glycol-fused peripheral nerve allografts but commonly observed in negative control and loose-sutured polyethylene glycol peripheral nerve allografts at 21 days postoperatively.Loose-sutured polyethylene glycol peripheral nerve allografts had more pro-inflammatory and less anti-inflammatory macrophages than negative control peripheral nerve allografts.While T cell counts were similarly high in loose-sutured-polyethylene glycol and negative control peripheral nerve allografts,loose-sutured polyethylene glycol peripheral nerve allografts expressed some cytokines/chemokines important for T cell activation at much lower levels at 14 days postoperatively.MHCI expression was elevated in loose-sutured polyethylene glycol peripheral nerve allografts,but MHCII expression was modestly lower compared to negative control at 21 days postoperatively.We conclude that,while polyethylene glycol per se reduces some immune responses of peripheral nerve allografts,successful polyethylene glycol-fusion repair of some axons is necessary to prevent Wallerian degeneration of those axons and immune rejection of peripheral nerve allografts,and produce recovery of sensory/motor functions and voluntary behaviors.Translation of polyethylene glycol-fusion technologies would produce a paradigm shift from the current clinical practice of waiting days to months to repair ablation peripheral nerve injuries. 展开更多
关键词 allograft rejection AXOTOMY macrophage MYELIN nerve repair polyethylene glycol(PEG) sciatic nerve T cell transplantation Wallerian degeneration
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Polyethylene glycol fusion repair of severed sciatic nerves accelerates recovery of nociceptive sensory perceptions in male and female rats of different strains
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作者 Liwen Zhou Karthik Venkudusamy +9 位作者 Emily A.Hibbard Yessenia Montoya Alexa Olivarez Cathy Z.Yang Adelaide Leung Varun Gokhale Guhan Periyasamy Zeal Pathak Dale R.Sengelaub George D.Bittner 《Neural Regeneration Research》 SCIE CAS 2025年第9期2667-2681,共15页
Successful polyethylene glycol fusion(PEG-fusion)of severed axons following peripheral nerve injuries for PEG-fused axons has been reported to:(1)rapidly restore electrophysiological continuity;(2)prevent distal Walle... Successful polyethylene glycol fusion(PEG-fusion)of severed axons following peripheral nerve injuries for PEG-fused axons has been reported to:(1)rapidly restore electrophysiological continuity;(2)prevent distal Wallerian Degeneration and maintain their myelin sheaths;(3)promote primarily motor,voluntary behavioral recoveries as assessed by the Sciatic Functional Index;and,(4)rapidly produce correct and incorrect connections in many possible combinations that produce rapid and extensive recovery of functional peripheral nervous system/central nervous system connections and reflex(e.g.,toe twitch)or voluntary behaviors.The preceding companion paper describes sensory terminal field reo rganization following PEG-fusion repair of sciatic nerve transections or ablations;howeve r,sensory behavioral recovery has not been explicitly explored following PEG-fusion repair.In the current study,we confirmed the success of PEG-fusion surgeries according to criteria(1-3)above and more extensively investigated whether PEG-fusion enhanced mechanical nociceptive recovery following sciatic transection in male and female outbred Sprague-Dawley and inbred Lewis rats.Mechanical nociceptive responses were assessed by measuring withdrawal thresholds using von Frey filaments on the dorsal and midplantar regions of the hindpaws.Dorsal von Frey filament tests were a more reliable method than plantar von Frey filament tests to assess mechanical nociceptive sensitivity following sciatic nerve transections.Baseline withdrawal thresholds of the sciatic-mediated lateral dorsal region differed significantly across strain but not sex.Withdrawal thresholds did not change significantly from baseline in chronic Unoperated and Sham-operated rats.Following sciatic transection,all rats exhibited severe hyposensitivity to stimuli at the lateral dorsal region of the hindpaw ipsilateral to the injury.However,PEG-fused rats exhibited significantly earlier return to baseline withdrawal thresholds than Negative Control rats.Furthermore,PEG-fused rats with significantly improved Sciatic Functional Index scores at or after 4 weeks postoperatively exhibited yet-earlier von Frey filament recove ry compared with those without Sciatic Functional Index recovery,suggesting a correlation between successful PEG-fusion and both motor-dominant and sensory-dominant behavioral recoveries.This correlation was independent of the sex or strain of the rat.Furthermore,our data showed that the acceleration of von Frey filament sensory recovery to baseline was solely due to the PEG-fused sciatic nerve and not saphenous nerve collateral outgrowths.No chronic hypersensitivity developed in any rat up to 12 weeks.All these data suggest that PEG-fusion repair of transection peripheral nerve injuries co uld have important clinical benefits. 展开更多
关键词 autophagia AXOTOMY collateral sprouting neuropathic pain peripheral nerve repair polyethylene glycol fusion(PEG-fusion) saphenous nerve sensory neurons sex and strain Wallerian degeneration
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Experimental Study of the Influence of Intrinsic Parameters on the Thermal Reactivity of Sawdust, Polyethylene Terephthalate and Composite
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作者 Ange Brel Boukongou Timoléon Andzi Barhé 《Journal of Materials Science and Chemical Engineering》 2024年第3期9-20,共12页
Several works have been based on the study of thermal variations in biomass to derive more valuable products such as fuels capable of replacing oil in the event of a crisis or activated carbon used as an adsorbent mat... Several works have been based on the study of thermal variations in biomass to derive more valuable products such as fuels capable of replacing oil in the event of a crisis or activated carbon used as an adsorbent material, widely used in industry for the elimination of unwanted materials, both in liquid and gaseous environments. A study of thermal parameters such as: heating speed, retention time, drying temperature, carbonization temperature, particle size, was carried out with the aim of determining the characteristic factors of the carbonization of Polyethylene terephthalate (PET), sawdust (SC) and sawdust/polyethylene terephthalate (CPS) mixture. The results of the immediate analysis revealed a very low level of ash in PET (0.013%) compared to the level of ash in sawdust (2.9%), as well as a high level of fixed carbon (82.960%), which suggests the presence of mineral oxides and a significant carbon matrix unlike PET, which indicates a very significant organic matrix (essentially made up of organic matter) with the absence of mineral oxides. The study of thermal parameters showed the water loss from Sawdust (SC) and the Sawdust/Polyethylene terephthalate (CPS) mixture, an increase with temperature, unlike that of PET whose variation is essentially zero. Without heat treatment, sawdust alone contains approximately 7% water. The optimal drying temperature for this study is 110˚C for a stay of 24 hours. It appears that the largest mass losses for the PET samples are between 87.19% and 96.05%, followed by that of the mixture, between 47.33% and 64.37%. And the lowest are observed, those of sawdust (from 24.02% to 62.6%). However, here we can say that the influence of the mass is not great, given the slight difference between the losses by temperature. The results of the study of the influence of grain size showed that the differences are insignificant, even if we vary the diameter of the grains from simple to triple. To better minimize physical constraints such as the intragranular diffusibility of the volatile matter and the homogeneity of the temperature in the grains, 75 μm particles are found to be optimal for our study. It can be noted when studying the heating rate that the mass loss at the end of the reaction is approximately the same depending on each precursor material. However, it has been demonstrated that the heating rate strongly influences the nature of the reaction products both for volatile materials and for the solid residue as well as on the kinetic parameters of the chemical reaction. Furthermore, the variation in apparent density shows a decrease as a function of the increase in the residence time of the materials in the reactor. As the carbonization time increases, the apparent density decreases. We note, for the lignocellulosic material, that the apparent density stabilizes after 60 minutes. 展开更多
关键词 Intrinsic Parameters Thermal Reactivity SAWDUST polyethylene terephthalate COMPOSITE
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Vertically aligned montmorillonite aerogel-encapsulated polyethylene glycol with directional heat transfer paths for efficient solar thermal energy harvesting and storage
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作者 Qijing Guo Cong Guo +2 位作者 Hao Yi Feifei Jia Shaoxian Song 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第5期907-916,共10页
The conversion and storage of photothermal energy using phase change materials(PCMs)represent an optimal approach for harnessing clean and sustainable solar energy.Herein,we encapsulated polyethylene glycol(PEG)in mon... The conversion and storage of photothermal energy using phase change materials(PCMs)represent an optimal approach for harnessing clean and sustainable solar energy.Herein,we encapsulated polyethylene glycol(PEG)in montmorillonite aerogels(3D-Mt)through vacuum impregnation to prepare 3D-Mt/PEG composite PCMs.When used as a support matrix,3D-Mt can effectively prevent PEG leakage and act as a flame-retardant barrier to reduce the flammability of PEG.Simultaneously,3D-Mt/PEG demonstrates outstanding shape retention,increased thermal energy storage density,and commendable thermal and chemical stability.The phase transition enthalpy of 3D-Mt/PEG can reach 167.53 J/g and remains stable even after 50 heating-cooling cycles.Furthermore,the vertical sheet-like structure of 3D-Mt establishes directional heat transport channels,facilitating efficient phonon transfer.This configuration results in highly anisotropic thermal conductivities that ensure swift thermal responses and efficient heat conduction.This study addresses the shortcomings of PCMs,including the issues of leakage and inadequate flame retardancy.It achieves the development and design of 3D-Mt/PEG with ultrahigh strength,superior flame retardancy,and directional heat transfer.Therefore,this work offers a design strategy for the preparation of high-performance composite PCMs.The 3D-Mt/PEG with vertically aligned and well-ordered array structure developed in this research shows great potential for thermal management and photothermal conversion applications. 展开更多
关键词 montmorillonite aerogel polyethylene glycol phase change materials solar thermal energy storage flame retardant
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Recycling and depolymerization of waste polyethylene terephthalate bottles by alcohol alkali hydrolysis 被引量:11
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作者 SUN Cong-hao CHEN Xiang-ping +1 位作者 ZHUO Qiang ZHOU Tao 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第3期543-549,共7页
In this work,a novel alcohol alkali hydrolysis method was explored for the preparation of terephthalic acid(TPA)from waste polyethylene terephthalate(PET).First,a series of single factor experiments on the depolymeriz... In this work,a novel alcohol alkali hydrolysis method was explored for the preparation of terephthalic acid(TPA)from waste polyethylene terephthalate(PET).First,a series of single factor experiments on the depolymerization rate of waste PET bottles and the yield of TPA were conducted to determine the optimized experimental conditions,in terms of reaction time,reaction temperature,dosage of ethylene glycol and sodium bicarbonate,amount of distilled water and stirring rate.Then IR spectra and elemental analysis were carried out for the characterization of obtained product.Under optimal experimental conditions,over 98%PET can be depolymerized into the target product(TPA)and the purity and yield of TPA are over 97%and 94%,respectively.Both the experimental and analytical results support a feasible process for the preparation of TPA from waste PET.It is expected that this alcohol alkali hydrolysis method can promise an effective way for the sustainable recycling of waste PET. 展开更多
关键词 waste polyethylene terephthalate terephthalic acid alcohol alkali hydrolysis ethylene glycol
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Surface Treatment of Polyethylene Terephthalate Film Using Atmospheric Pressure Glow Discharge in Air 被引量:6
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作者 方志 邱毓昌 王辉 《Plasma Science and Technology》 SCIE EI CAS CSCD 2004年第6期2576-2580,共5页
Non-thermal plasmas under atmospheric pressure are of great interest in polymer surface processing because of their convenience, effectiveness and low cost. In this paper, the treatment of Polyethylene terephthalate (... Non-thermal plasmas under atmospheric pressure are of great interest in polymer surface processing because of their convenience, effectiveness and low cost. In this paper, the treatment of Polyethylene terephthalate (PET) film surface for improving hydrophilicity using the non-thermal plasma generated by atmospheric pressure glow discharge (APGD) in air is conducted. The discharge characteristics of APGD are shown by measurement of their electrical discharge parameters and observation of light-emission phenomena, and the surface properties of PET before and after the APGD treatment are studied using contact angle measurement, x-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). It is found that the APGD is homogeneous and stable in the whole gas gap, which differs from the commonly filamentary dielectric barrier discharge (DBD). A short time (several seconds) APGD treatment can modify the surface characteristics of PET film markedly and uniformly. After 10 s APGD treatment, the 展开更多
关键词 non-thermal plasma dielectric barrier discharge (DBD) atmospheric pressure glow discharge (APGD) surface treatment polyethylene terephthalate (PET)
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Synthesis of titanium oxycarbonitride by carbothermal reduction and nitridation of ilmenite with recycling of polyethylene terephthalate (PET) 被引量:1
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作者 Eltefat Ahmadi Ahmad Fauzi +3 位作者 Hashim Hussin Norlia Baharun Kamar Shah Ariffin Sheikh Abdul Rezan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2017年第4期444-454,共11页
An innovative and sustainable carbothermal reduction and nitridation(CTRN) process of ilmenite(FeTiO_3) using a mixture of polyethylene terephthalate(PET) and coal as the primary reductant under an H_2–N_2 atmosphere... An innovative and sustainable carbothermal reduction and nitridation(CTRN) process of ilmenite(FeTiO_3) using a mixture of polyethylene terephthalate(PET) and coal as the primary reductant under an H_2–N_2 atmosphere was proposed. The use of PET as an alternative source of carbon not only enhances the porosity of the pellets but also results in the separation of Fe from titanium oxycarbonitride(TiOxCyNz) particles because of the differences in surface tension. The experiments were carried out at 1250°C for 3 h using four different PET contents ranging from 25wt% to 100wt% in the reductant. X-ray diffraction(XRD),scanning electron microscopy(SEM) in conjunction with energy-dispersive X-ray spectroscopy(EDX),and LECO elemental analysis were used to study the phases and microstructures of the reduced samples. In the case of 75wt% PET,iron distinctly separated from the synthesized Ti OxCyNz phase. With increasing PET content in the sample,the reduction and nitridation rates substantially increased. The synthesis of an oxycarbonitride with stoichiometry of TiO_(0.02)C_(0.13)N_(0.85) with minimal intermediate titanium sub-oxides was achieved. The results also showed that the iron particles formed from CTRN of FeTiO_3 exhibited a spherical morphology,which is conducive for Fe removal via the Becher process. 展开更多
关键词 carbothermal reduction NITRIDATION polyethylene terephthalate TITANIUM oxycarbonitride ILMENITE
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Surface Modification of Polyethylene Terephthalate(PET) Fiber by Roll-to-Roll Treatment in Atmospheric Ar/O_2 Dielectric Barrier Discharge(DBD) Plasma 被引量:2
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作者 李嘉灵 林捷 +3 位作者 刁颖 胡倩倩 张菁 徐金洲 《Journal of Donghua University(English Edition)》 EI CAS 2011年第1期88-92,共5页
In this work,polyethylene terephthalate(PET) fibers were continuously treated by atmospheric dielectric barrier discharge(DBD) in Ar mixed O2 plasma,and the discharge was characterized by electrical function and optic... In this work,polyethylene terephthalate(PET) fibers were continuously treated by atmospheric dielectric barrier discharge(DBD) in Ar mixed O2 plasma,and the discharge was characterized by electrical function and optical diagnostics.It is found that the interfacial adhesion strength between treated PET fiber and resorcinol formaldehyde latex(RFL)(little)-rubber was improved(about 50%) by the measurement of interfacial shear strength(IFSS) and peel test.The wettability was improved rapidly in the initial treatment time.It is considered that oxidation chemical reaction as the major role of PET fiber surface modification is ahead of the physical etching effect.The high density of atomic oxygen in the plasma by optical emission spectroscopy supports the purpose.According to the scanning electron micrograph(SEM) image in the work,the longer treatment time obviously caused physical etching effect,which shall be less responsible for the improvement of the wettability. 展开更多
关键词 atmospheric pressure plasma polyethylene terephthalate(PET) fiber interfacial shear strength(IFSS) adhesion strength gas analyzer
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Mechariical and Abrasion Properties of Polyethylene Terephthalate Films Coated with SiO2/Epoxy Hybrid Material 被引量:1
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《Journal of Donghua University(English Edition)》 EI CAS 2013年第6期521-524,共4页
Hybrid materials were prepared using a silane coupling agent, tetraethoxysilane ( TEOS ) as the precursor, dilute hydrochloric acid as the catalyst, and epoxy as the matrices. The films coated with hybrid materials ... Hybrid materials were prepared using a silane coupling agent, tetraethoxysilane ( TEOS ) as the precursor, dilute hydrochloric acid as the catalyst, and epoxy as the matrices. The films coated with hybrid materials were expected to improve abrasion resistance and mechanical properties. The morphology, mechanical properties, adhesion, and abrasion resistance of the polyethylene terephthalate (PET) films were characterized using an atomic force microscope, a tensile testing machine, a bagger knife, and a reciprocating fabric abrasion tester. The result of research indicated that the modification significantly affected the abrasion resistance and roughness. The-tensile strength and abrasion resistance of the modified PET films increased by 40% and 50% respectively at 3 % TEOS mass fraction. 展开更多
关键词 polyethylene terephthalate PET films surface modification SOL-GEL abrasion resistance
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The Aging Study on Polyethylene Terephthalate with Surface Modification by Water Vapor Plasma 被引量:1
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作者 敖玲 钮金真 +2 位作者 刘裕明 胡建芳 陈慧英 《Plasma Science and Technology》 SCIE EI CAS CSCD 2001年第3期761-764,共4页
The aging effects of the contact angle and surface energy on polyethylene terephthalate (PET) have been investigated with surface modification by water vapor plasma. The experimental results show that the contact ang... The aging effects of the contact angle and surface energy on polyethylene terephthalate (PET) have been investigated with surface modification by water vapor plasma. The experimental results show that the contact angle of water and PET decreases obviously and surface energy increases. However, with the increase of the aging time, the contact angle and surface energy change back gradually to original state. 展开更多
关键词 The Aging Study on polyethylene terephthalate with Surface Modification by Water Vapor Plasma PET
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Effect of Knitting Process on Elastic Property of Polyethylene Terephthalate (PET)/Polybutylene Terephthalate (PBT) Warp Knitted Fabric 被引量:1
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作者 陈晴 马丕波 +2 位作者 缪旭红 蒋高明 冒海文 《Journal of Donghua University(English Edition)》 EI CAS 2016年第4期553-556,561,共5页
This study investigated the elastic elongation and elastic recovery of the elastic warp knitted fabric made of polyethylene terephthalate( PET) and polybutylene terephthalate( PBT)filament. The effect of knitting para... This study investigated the elastic elongation and elastic recovery of the elastic warp knitted fabric made of polyethylene terephthalate( PET) and polybutylene terephthalate( PBT)filament. The effect of knitting parameter on the elasticity of PBT /PET warp knitted fabric was analyzed. The increase of drawing density( from 16 to 26 courses per centimeter( CPC)) on machine resulted in the decrease of elongation at the weft direction. But,the elongation at the warp direction fluctuated as drawing density increasing. The yarn run-in speed influenced the elongation of PET /PBT warp knitted fabric as well. When the yarn run-in speed of GB1( front bar) was kept a constant,the increase of GB2( back bar) yarn run-in speed caused the gradual enhancement of the elastic elongation at the warp direction,but the different trends of the elastic elongation at the weft direction. When yarn run-in speed of GB2 was kept a constant,the increase of GB1 yarn run-in speed enlarged the elastic warp elongation from 104.16 to 124.97 mm,while the weft elongation decreased from 110.34 to 98.03 mm.Eventually yarn run-in speeds of GB1 and GB2 were retained at1 360 and 1 170 mm / rack respectively under 20 CPC drawing density. It could not only balance the two directions of elongation but also reach the highest elongation at both directions( 126. 32 and115.88 mm) under 100 N tension. These results provide a better understanding of characteristics of PET / PBT warp knitted fabric,and its elastic elongation and recovery behavior for development and effective applications. 展开更多
关键词 elongation fabric terephthalate polyethylene courses filament elasticity drawing directions cotton
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DEPOLYMERIZATION AND KINETICS OF DEPOLYMERIZATION OF POLYETHYLENE TEREPHTHALATE USING DIBUTYLTIN OXIDE CATALYST
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作者 T.Naruephat D.Somsak +1 位作者 V.Tharapong P.Amorn 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2006年第2期139-145,共7页
Depolymerization of poly(ethylene terephthalate) (PET) was performed in the tubular bomb microreactor which contained the solution of PET in methanol and dibutyltin oxide at the temperature ranging from 433 K to 4... Depolymerization of poly(ethylene terephthalate) (PET) was performed in the tubular bomb microreactor which contained the solution of PET in methanol and dibutyltin oxide at the temperature ranging from 433 K to 473 K, the reaction time from 5 to 45 min and the catalyst-to-PET ratio of 0.3%-2% by weight. The optimal condition for PET depolymerization catalyzed by dibutyltin oxide is the temperature of 443-453 K, the reaction time of 20-25 min and 0.8% by weight of catalyst. By using differential methods, the activation energy for the depolymerization process was found to be 154.05 kJ/mol in the temperature range from 433-463 K. 展开更多
关键词 DEPOLYMERIZATION polyethylene terephthalate Dibutyltin oxide DEGRADATION KINETICS
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Utilization of waste polyethylene terephthalate as a reducing agent in the reduction of iron ore composite pellets
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作者 Gkhan Polat Burak Birol Muhlis Nezihi Saridede 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2014年第8期748-754,共7页
The increasing consumption of plastics inevitably results in increasing amounts of waste plastics. Because of their long degradation periods, these wastes negatively affect the natural environment. Numerous studies ha... The increasing consumption of plastics inevitably results in increasing amounts of waste plastics. Because of their long degradation periods, these wastes negatively affect the natural environment. Numerous studies have been conducted to recycle and eliminate waste plastics. The potential for recycling waste plastics in the iron and steel industry has been underestimated; the high C and H contents of plastics may make them suitable as alternative reductants in the reduction process of iron ore. This study aims to substitute plastic wastes for coal in reduction melting process and to investigate their performance during reduction at high temperature. We used a common type of waste plastic, polyethylene terephthalate (PET), because of its high carbon and hydrogen contents. Composite pellets containing PET wastes, coke, and magnetite iron ore were reduced at selected temperatures of 1400 and 1450℃ for reduction time from 2 to 10 min to investigate the reduction melting behavior of these pellets. The results showed that an increased temperature and reduction time increased the reduction ratio of the pellets. The optimum experimental conditions for obtaining metallic iron (iron nuggets) were reduction at 1450℃ for 10 min using composite pellets containing 60% PET and 40% coke. 展开更多
关键词 polyethylene terephthalate (PET) waste recycling reducing agents iron ore pellets ore reduction
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Structural Changes of Polyethylene Terephthalate Fibers Grafted by Acrylamide
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作者 施琴芬 戴礼兴 《Journal of Donghua University(English Edition)》 EI CAS 2003年第3期1-4,共4页
A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spe... A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spectrophotometer ( IR ), and differential scanning calorimetry(DSC). At the same time, the moisture regain, dyeability, strength, and elongation at break of the samples are measured and their relations with structural changes are discussed. Compared with ungrafted fiber, shape of the fiber cross-section, IR characteristic absorption peaks, and melting behavior of the grafted fibers have been changed, causing the fiber dyeability and moisture regain to be increased, and mechanical properties to be changed. 展开更多
关键词 polyethylene terephthalate fiber GRAFT ACRYLAMIDE STRUCTURE
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Recycling Polyethylene Terephthalate (PET) Packaging as the Basis of Economic Projects and Solution of Social and Environmental Problems in Russia
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作者 Tatiana Kasyanenko Oleg Filimonov 《Journal of Modern Accounting and Auditing》 2013年第8期1093-1104,共12页
In this article, based on the analysis of the current environmental situation in Russia and other countries, as well as of the problem of recycling plastic waste in the Russian Federation (RF), the authors clearly s... In this article, based on the analysis of the current environmental situation in Russia and other countries, as well as of the problem of recycling plastic waste in the Russian Federation (RF), the authors clearly show the effectiveness of investments in the processing of polymer debris on the example of polyethylene terephthalate (PET) waste (granulates, flakes). In the frame of case study of social and environmental investment project on creating enterprise that will engage in collection, recycling, and sale of the consumer PET packaging in Russia, the authors demonstrate the economic feasibility of the creation of such kind of enterprises taking into account market conditions and the features of the existing system of taxation in Russia. The realization of the project will also help in solving environmental and social problems of large cities, in particular, will create more jobs (in terms of 6% of unemployment rate in the country). The study also identifies the main obstacles in the way of waste recycling in Russia, and the recommendations for improvement of normative base of the industry are given. 展开更多
关键词 waste recycling polyethylene terephthalate (PET) containers polymer recycling PET PET granulates PET flakes
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Synergistic Effect of Atmospheric Pressure Plasma Pre-Treatment on Alkaline Etching of Polyethylene Terephthalate Fabrics and Films
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作者 Amel E.A.ELABID 郭颖 +2 位作者 石建军 丁可 张菁 《Plasma Science and Technology》 SCIE EI CAS CSCD 2016年第4期346-352,共7页
Dyeing of PET materials by traditional methods presents several problems.Plasma technology has received enormous attention as a solution for the environmental problems related with textile surface modifications,and th... Dyeing of PET materials by traditional methods presents several problems.Plasma technology has received enormous attention as a solution for the environmental problems related with textile surface modifications,and there has been a rapid development and commercialization of plasma technology over the past decade.In this work,the synergistic effect of atmospheric pressure plasma on alkaline etching and deep coloring of dyeing properties on polyethylene terephthalate(PET)fabrics and films was investigated.The topographical changes of the PET surface were investigated by atomic force microscopy(AFM)images,which revealed a smooth surface morphology of the untreated sample whereas a high surface roughness for the plasma and/or alkaline treated samples.The effects of atmospheric pressure plasma on alkaline etching of the structure and properties of PET were investigated by means of differential scanning calorimetry(DSC),the main objective of performing DSC was to investigate the effect of the plasma pre-treatment on the T_g and T_m.Using a tensile strength tester YG065 H and following a standard procedure the maximum force and elongation at maximum force of PET materials was investigated.Oxygen and argon plasma pre-treatment was found to increase the PET fabric weight loss rate.The color strength of PET fabrics was increased by various plasma pre-treatment times.The penetration of plasma and alkaline reactive species deep into the PET structure results in better dyeability and leaves a significant effect on the K/S values of the plasma pre-treated PET.It indicated that plasma pre-treatment has a great synergistic effect with the alkaline treatment of PET. 展开更多
关键词 atmospheric pressure plasma synergistic effect alkaline treatment polyethylene terephthalate materials K/S value surface roughness
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Studying the Curing Conditions of Unsaturated Polyesters from Secondary Polyethylene Terephthalate Alcoholysis Products
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作者 Asror B. Juraev Farhad A. Magrupov +3 位作者 Muzafar G. Alimukhamedov Ravshan I. Adilov Muqaddas M. Shokirova Muqadam G. Ishmukhamedova 《Open Journal of Polymer Chemistry》 2020年第4期77-86,共10页
<span style="font-family:Verdana;">The technological properties of the curing conditions for unsaturated polyesters synthesized on the basis of the alcoholysis products of secondary polyethylene tereph... <span style="font-family:Verdana;">The technological properties of the curing conditions for unsaturated polyesters synthesized on the basis of the alcoholysis products of secondary polyethylene terephthalate and unsaturated polyesters used in the production of fiberglass pipes were studied. It is shown that unsaturated polyesters synthesized on the basis of alcoholysis products can completely replace imported resins of grades 196 and 196A in the production of fiberglass pipes.</span> 展开更多
关键词 Secondary polyethylene terephthalate Alcoholysis Product Unsaturated Polyesters Grades PN-MA-03 PN-MA-03A 196 and 196A Technological and Physical-Mechanical Properties
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Effect of Polyethylene Terephthalate Plastic Waste on the Physico-Mechanical and Thermal Characteristics of Stabilized Laterite Bricks
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作者 Aboubacar Sidiki Toure Moussa Tamboura +4 位作者 Antoine Padou Diarra Adama Coulibaly Dodo Kayentao Kélétigui Daou Mah Fatoumata Traore 《Open Journal of Applied Sciences》 2023年第6期910-920,共11页
The present work investigated the effect of polyethylene terephthalate (PET) plastic waste on the physico-mechanical and thermal properties of cement-stabilized laterite bricks to see the durability of the modified br... The present work investigated the effect of polyethylene terephthalate (PET) plastic waste on the physico-mechanical and thermal properties of cement-stabilized laterite bricks to see the durability of the modified bricks (CSLB). Samples were formulated by mixing laterite, cement, and different percentages of PET (0%, 3%, 5%, and 7%) by volume. The bricks were produced using the M7MI Hydraform standard interlocking block and kept in the shade for a curing period of 28 days. The addition of 3% to 5% PET to the laterite stabilized with 10% cement results in a decrease in both dry and wet compressive strength, which is determined using the Controlab compression machine. However, the obtained results are in concordance with the standards. The thermal conductivity of CSLB, determined using the box method with the EI700 measurement cell, decreases as the PET content of the mixture increases. A decrease in bulk density from 1.67 to 1.58 g/cm<sup>3</sup> was observed. 展开更多
关键词 Plastic Waste polyethylene terephthalate Laterite Bricks Cement Stabilization Thermal Conductivity
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Effect of Irradiation Crosslinking on Polyethylene Terephthalate Flame-Retardant Fabric
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作者 朱士凤 施楣梧 +2 位作者 曲丽君 田明伟 袭祥龙 《Journal of Donghua University(English Edition)》 EI CAS 2016年第4期533-535,共3页
Irradiation cross-linking of flame-retardant polyethylene terephthalate( FR-PET) fabric with the presence of trimethylolpropane triacrylate( TMPTA) was studied. Thermal gravimetric( TG) analysis,differential scanning ... Irradiation cross-linking of flame-retardant polyethylene terephthalate( FR-PET) fabric with the presence of trimethylolpropane triacrylate( TMPTA) was studied. Thermal gravimetric( TG) analysis,differential scanning calorimetry( DSC) and scanning electron microscopy( SEM) were used to analyze the effects of irradiation crosslinking on structure and property of FR-PET fabric with TMPTA. The cross-linking was promoted by the introduced sensitizer. The gel content was 5.94% at the lower dose of 90 kGy and it arrived at the highest level of 13.01% with the increased doses. There were no melt drips of FR-PET fabric after irradiation cross-linking while the flame retardance disappeared at the time of combustion. The melting temperature of irradiated fabric decreased and TG analysis showed that the onset temperature of degradation of FR-PET fabric and the amount of nonvolatile residue at 800℃ increased as the irradiation dosage increased,but it changed a little compared with the pure FR-PFT fabric. SEM photographs showed that the residue char of irradiated PET fabrics after vertical test remained the intrinsic crossed structure,and the enlarged graph showed that the char was uniformly distributed and it was tight honeycombs structure. 展开更多
关键词 irradiation linking fabric irradiated tight calorimetry retardant flame gravimetric melting
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