A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl4 ethanol solution as precursors. The product was characterized by FTIR, ^29Si NMR, UV-Vis, and XRD. Struc...A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl4 ethanol solution as precursors. The product was characterized by FTIR, ^29Si NMR, UV-Vis, and XRD. Struc-tural and ingrediental analyses suggest that this material has a layered structure with cubic cage-like polyhedral oligo-silsesquioxane as building blocks and titanium as bridging atoms.展开更多
Plasmonic superlattices of nanoparticles(NPs)possess unique“surface lattice resonances”properties that facilitates their wide applications in plasmonic sensing,photocatalysis,and nanoscale light manipulation.However...Plasmonic superlattices of nanoparticles(NPs)possess unique“surface lattice resonances”properties that facilitates their wide applications in plasmonic sensing,photocatalysis,and nanoscale light manipulation.However,it is still challenging to manufacture superlattices with precisely controllable NPs distance and break the size limitation of NPs.Herein,we provided an effective strategy to construct NPs superlattices via shape-persistent polyhedral oligosilsesquioxane(POSS)molecular nanoparticles govern interfacial assembly.As a nanoscale molecule with diameter of 1.5 nm,the POSS-SH molecule provides sufficient rigid steric hindrance and hydrophobic effect for tailoring the uniformity and controllable distance between NPs in superlattices.Interestingly,synergistically with hydrophilic ligands of polyethylene glycol(PEG-SH)with optimized ratio,the rigid POSS ligands can effectively regulate the distance between NPs in a fixed range of 2.3—2.8 nm,which is independent of ligands molecular weight and particle size.Furthermore,the effective approach can be universal to anisotropic NPs for manufacturing monolayer films with high NPs density.We believe this nanoscale molecule tailored interfacial self-assembly strategy can effectively break the size of NPs and assembly obstacles for superlattice monolayer film.Additionally,the definite distance between NPs in superlattices can minimize optical energy attenuation and facilitates the applications such as surface-enhanced Raman spectroscopy and photocatalysis.展开更多
基金Supported by the National Natural Science Foundation of China(No.20273021)the Key Project of Shanghai Science and Technology Committee(No.05JC14070)the Excellent Young Teachers Program of Ministry of Education.
文摘A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl4 ethanol solution as precursors. The product was characterized by FTIR, ^29Si NMR, UV-Vis, and XRD. Struc-tural and ingrediental analyses suggest that this material has a layered structure with cubic cage-like polyhedral oligo-silsesquioxane as building blocks and titanium as bridging atoms.
基金support from the National Natural Science Foundation of China (52222316,52103325,52111530128)the Ten Thousand People Plan of Zhejiang Province (2019R51012)+1 种基金the Zhejiang Provincial Natural Science Foundation of China (Z22B050001)the China Postdoctoral Science Foundation (2022M713020).
文摘Plasmonic superlattices of nanoparticles(NPs)possess unique“surface lattice resonances”properties that facilitates their wide applications in plasmonic sensing,photocatalysis,and nanoscale light manipulation.However,it is still challenging to manufacture superlattices with precisely controllable NPs distance and break the size limitation of NPs.Herein,we provided an effective strategy to construct NPs superlattices via shape-persistent polyhedral oligosilsesquioxane(POSS)molecular nanoparticles govern interfacial assembly.As a nanoscale molecule with diameter of 1.5 nm,the POSS-SH molecule provides sufficient rigid steric hindrance and hydrophobic effect for tailoring the uniformity and controllable distance between NPs in superlattices.Interestingly,synergistically with hydrophilic ligands of polyethylene glycol(PEG-SH)with optimized ratio,the rigid POSS ligands can effectively regulate the distance between NPs in a fixed range of 2.3—2.8 nm,which is independent of ligands molecular weight and particle size.Furthermore,the effective approach can be universal to anisotropic NPs for manufacturing monolayer films with high NPs density.We believe this nanoscale molecule tailored interfacial self-assembly strategy can effectively break the size of NPs and assembly obstacles for superlattice monolayer film.Additionally,the definite distance between NPs in superlattices can minimize optical energy attenuation and facilitates the applications such as surface-enhanced Raman spectroscopy and photocatalysis.
