Polylactic acid(PLA)is one of the most promising shape memory polymers with outstanding biocompatibility,while poly(ether ether ketone)(PEEK)is a special engineering plastic with excellent mechanical performance.In th...Polylactic acid(PLA)is one of the most promising shape memory polymers with outstanding biocompatibility,while poly(ether ether ketone)(PEEK)is a special engineering plastic with excellent mechanical performance.In this work,PEEK was selected to modify PLA,and a series of PLA blended with different PEEK contents(PLA/PEEK blends)were obtained.The effects of PEEK on thermodynamic,mechanical and shape memory properties of PLA/PEEK blends were investigated.The results showed that the thermal stabillity of the PL A/PEEK blend was improved with the PEEK content increase.The tensile strength reached the highest value of 20.6 MPa when the PEEK content was 10%.While the best shape memory performance occurred with the PEEK content of 15%,the shape recovery time was less than 2 s,and the shape fixation/recovery ratio was more than 99%.Furthermore,the programmable mimetic flower opening process was achieved by using PLA/PEEK blends with different PEEK content ratios.The above results indicated that the blend of an appropriate proportion of PEEK had positive effects on mechanical and deformation performances of PLA.展开更多
基金supported by the Project of National Key Research and Development Program of China(2018YFB1105100,2018YFC2001300 and 2018YFA0703300)the National Natural Science Foundation of China(Grant Nos.51822504,51675223 and 91848204)+4 种基金the Joint Foundation for Equipment Preresearch of Ministry of Education(2018G944.00084)the Key Scientific and Technological Project of Jilin Province(20180201051GX)the Program for JLU Science and Technology Innovative Research Team(2017TD-04)the National Postdoctoral Program for Innovative Talents(BX20180126)the China Postdoctoral Science Foundation(2018M641769).
文摘Polylactic acid(PLA)is one of the most promising shape memory polymers with outstanding biocompatibility,while poly(ether ether ketone)(PEEK)is a special engineering plastic with excellent mechanical performance.In this work,PEEK was selected to modify PLA,and a series of PLA blended with different PEEK contents(PLA/PEEK blends)were obtained.The effects of PEEK on thermodynamic,mechanical and shape memory properties of PLA/PEEK blends were investigated.The results showed that the thermal stabillity of the PL A/PEEK blend was improved with the PEEK content increase.The tensile strength reached the highest value of 20.6 MPa when the PEEK content was 10%.While the best shape memory performance occurred with the PEEK content of 15%,the shape recovery time was less than 2 s,and the shape fixation/recovery ratio was more than 99%.Furthermore,the programmable mimetic flower opening process was achieved by using PLA/PEEK blends with different PEEK content ratios.The above results indicated that the blend of an appropriate proportion of PEEK had positive effects on mechanical and deformation performances of PLA.
